Safety Data Sheet Issue Date: 12-May-2023 Revision Date: 12-May-2023 Version 1 Page 1 / 7 1. IDENTIFICATION Product identifier Product Name SPLASH Premium RV & Marine Antifreeze -75?F Other means of identification SDS # 619535-35 (Gallon), 535055 (55 Gallon), 535250 (250 Gallon Tote) Recommended use of the chemical and restrictions on use Recommended Use Antifreeze. Details of the supplier of the safety data sheet Manufacturer Address FMP 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 Phone: 888-784-0802 Emergency telephone number Emergency Telephone INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Clear, Red liquid Physical state Liquid Odor Odorless Classification This chemical does not meet the hazardous criteria set forth by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). However, this Safety Data Sheet (SDS) contains valuable information critical to the safe handling and proper use of this product. This SDS should be retained and available for employees and other users of this product. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No Weight-% Glycerol 56-81-5 15-20 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST AID MEASURES Description of first aid measures Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Inhalation Remove to fresh air. SPLASH Premium RV & Marine Antifreeze -75?F Revision Date: 12-May-2023 Page 2 / 7 Ingestion Clean mouth with water and drink afterwards plenty of water. Most important symptoms and effects, both acute and delayed Symptoms None known. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible Materials None known based on information supplied. SPLASH Premium RV & Marine Antifreeze -75?F Revision Date: 12-May-2023 Page 3 / 7 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Glycerol 56-81-5 - TWA: 15 mg/m3 mist, total particulate TWA: 5 mg/m3 mist, respirable fraction (vacated) TWA: 10 mg/m3 mist, total particulate (vacated) TWA: 5 mg/m3 mist, respirable fraction - Appropriate engineering controls Engineering Controls Apply technical measures to comply with the occupational exposure limits. Individual protection measures, such as personal protective equipment Eye/Face Protection Refer to 29 CFR 1910.133 for eye and face protection regulations. Skin and Body Protection Refer to 29 CFR 1910.138 for appropriate skin and body protection. Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Clear, red liquid Odor Odorless Color Pink Odor Threshold Not determined Property Values Remarks ? Method pH No data available Melting point / freezing point No data available Initial boiling point and boiling range No data available Flash point No data available Evaporation Rate Not determined Flammability (Solid, Gas) Liquid-Not applicable Flammability Limit in Air Upper flammability or explosive limits No data available Lower flammability or explosive limits No data available Vapor Pressure Not determined Vapor Density No data available Relative Density 1.0517 Water Solubility Not determined Solubility in other solvents Not determined Partition Coefficient Not determined Autoignition temperature No data available SPLASH Premium RV & Marine Antifreeze -75?F Revision Date: 12-May-2023 Page 4 / 7 Hyphen Not determined Kinematic viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to Avoid Keep out of reach of children. Incompatible materials None known based on information supplied. Hazardous decomposition products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Avoid contact with eyes. Skin Contact Avoid contact with skin. Inhalation Do not inhale. Ingestion Do not ingest. Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Glycerol 56-81-5 = 12600 mg/kg ( Rat ) > 10 g/kg ( Rabbit ) > 2.75 mg/L ( Rat ) 4 h 1,2 Propanediol 57-55-6 = 20 g/kg ( Rat ) = 20800 mg/kg ( Rabbit ) - Dipotassium Phosphate 7758-11-4 - > 5000 mg/kg ( Rabbit ) - Bronopol 52-51-7 = 180 mg/kg ( Rat ) = 1600 mg/kg ( Rat ) > 5 g/m3 ( Rat ) 6 h Sodium Nitrate 7631-99-4 = 1267 mg/kg ( Rat ) - - 5-Chloro-2-methyl-4-isothiazolin-3- one 26172-55-4 = 481 mg/kg ( Rat ) - = 1.23 mg/L ( Rat ) 4 h 2-Methyl-4-isothiazolin-3-one 2682-20-4 232 - 249 mg/kg ( Rat ) = 120 mg/kg ( Rat ) = 200 mg/kg ( Rabbit ) = 0.11 mg/L ( Rat ) 4 h SPLASH Premium RV & Marine Antifreeze -75?F Revision Date: 12-May-2023 Page 5 / 7 Symptoms related to the physical, chemical and toxicological characteristics Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Nitrate or nitrite ingested under conditions that result in endogenous nitrosation are considered carcinogens. Chemical name ACGIH IARC NTP OSHA Sodium Nitrate 7631-99-4 Group 2A X Legend IARC (International Agency for Research on Cancer) Group 2A - Probably Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Numerical measures of toxicity The following values are calculated based on chapter 3.1 of the GHS document Oral LD50 57,190.40 mg/kg Dermal LD50 46,433.40 mg/kg ATEmix (inhalation-dust/mist) 13.7914 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical name Algae/aquatic plants Fish Crustacea Glycerol 56-81-5 LC50: 51 - 57mL/L (96h, Oncorhynchus mykiss) 1,2 Propanediol 57-55-6 EC50: =19000mg/L (96h, Pseudokirchneriella subcapitata) LC50: =51600mg/L (96h, Oncorhynchus mykiss) LC50: 41 - 47mL/L (96h, Oncorhynchus mykiss) LC50: =51400mg/L (96h, Pimephales promelas) LC50: =710mg/L (96h, Pimephales promelas) EC50: >1000mg/L (48h, Daphnia magna) Sodium Nitrate 7631-99-4 LC50: =2000mg/L (96h, Lepomis macrochirus) LC50: 994.4 - 1107mg/L (96h, Oncorhynchus mykiss) 5-Chloro-2-methyl-4-isothiazolin-3- one 26172-55-4 EC50: 0.11 - 0.16mg/L (72h, Pseudokirchneriella subcapitata) EC50: 0.03 - 0.13mg/L (96h, Pseudokirchneriella subcapitata) LC50: =1.6mg/L (96h, Oncorhynchus mykiss) EC50: =4.71mg/L (48h, Daphnia magna) EC50: 0.12 - 0.3mg/L (48h, Daphnia magna) EC50: 0.71 - 0.99mg/L (48h, Daphnia magna) Persistence/Degradability Not determined. Bioaccumulation There is no data for this product. SPLASH Premium RV & Marine Antifreeze -75?F Revision Date: 12-May-2023 Page 6 / 7 Mobility Chemical name Partition coefficient Glycerol 56-81-5 -1.75 Other adverse effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT Not regulated IATA Not regulated IMDG Not regulated 15. REGULATORY INFORMATION International Inventories Chemical name TSCA TSCA Inventory Status DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AIIC Glycerol X ACTIVE X X X X X X X 1,2 Propanediol X ACTIVE X X X X X X X Dipotassium Phosphate X ACTIVE X X X X X X X Bronopol X ACTIVE X X X X X X X Sodium Nitrate X ACTIVE X X X X X X X 5-Chloro-2-methyl-4- isothiazolin-3-one X ACTIVE X X X X X X X 2-Methyl-4-isothiazolin-3-one X ACTIVE X X X X X X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances SPLASH Premium RV & Marine Antifreeze -75?F Revision Date: 12-May-2023 Page 7 / 7 US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts Pennsylvania Glycerol 56-81-5 X X X 1,2 Propanediol 57-55-6 X X Sodium Nitrate 7631-99-4 X X X 16. OTHER INFORMATION NFPA Health hazards - Flammability - Instability - Special hazards - HMIS Health hazards - Flammability - Physical hazards - Personal Protection Not determined Issue Date: 12-May-2023 Revision Date: 12-May-2023 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet