Flooded Lead Acid Battery, Wet Not available. This product, under the normal conditions of use, is an exempt "ARTICLE" and not subject to OSHA?s Hazard Communication Standard and its requirements for preparation of Safety Data Sheets (SDS). GHS product identifier Other means of identification Product type Section 1. Identification : : : Relevant identified uses of the substance or mixture and uses advised against SAFETY DATA SHEET Flooded Lead Acid Battery, Wet Product use : Automotive, Truck, Marine Area of application : Industrial applications. Manufacturer: 1-800-814-3390 (24/7) (GM Security) Infotrac 1-800-535-5053 (24/7) Emergency telephone number (with hours of operation) : Manufacturer : ACDelco 300 Renaissance Ctr Ste L1 Detroit, MI, 48243-1403 United States www.acdelco.com Telephone (General): 1-800-223-3526 Product code : Not available. Section 2. Hazards identification Classification of the substance or mixture : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute oral toxicity: 6% Percentage of the mixture consisting of ingredient(s) of unknown acute inhalation toxicity: 6% OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). H203 EXPLOSIVES - Division 1.3 H302 ACUTE TOXICITY (oral) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H314 SKIN CORROSION - Category 1 H318 SERIOUS EYE DAMAGE - Category 1 H350 CARCINOGENICITY - Category 1A H360 TOXIC TO REPRODUCTION - Category 1A H362 TOXIC TO REPRODUCTION - Effects on or via lactation H372 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 This product, under the normal conditions of use, is an exempt "ARTICLE" and not subject to OSHA?s Hazard Communication Standard and its requirements for preparation of Safety Data Sheets (SDS). Classifications provided are for the battery electrolyte and are only applicable in the event that the electrolyte is released. Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 1/18 United States Flooded Lead Acid Battery, Wet Section 2. Hazards identification Signal word : Danger Hazard statements : H203 - Explosive; fire, blast or projection hazard. H302 + H332 - Harmful if swallowed or if inhaled. H314 - Causes severe skin burns and eye damage. H350 - May cause cancer. H360 - May damage fertility or the unborn child. H362 - May cause harm to breast-fed children. H372 - Causes damage to organs through prolonged or repeated exposure. (blood system, kidneys, nervous system, teeth) Hazard pictograms : Precautionary statements Prevention : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P280 - Wear protective gloves, protective clothing and eye or face protection. P250 - Do not subject to grinding, shock or friction. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P271 - Use only outdoors or in a well-ventilated area. P260 - Do not breathe vapor. P263 - Avoid contact during pregnancy or while nursing. P270 - Do not eat, drink or smoke when using this product. P264 - Wash thoroughly after handling. Response : P372 - Explosion risk in case of fire. P373 - DO NOT fight fire when fire reaches explosives. P370 + P380 - In case of fire: Evacuate area. P308 + P313 - IF exposed or concerned: Get medical advice or attention. P304 + P340, P310 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor. P301 + P310, P330, P331 - IF SWALLOWED: Immediately call a POISON CENTER or doctor. Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353, P310 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Immediately call a POISON CENTER or doctor. P363 - Wash contaminated clothing before reuse. P305 + P351 + P338, P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor. Storage : P401 - Store in accordance with all local, regional, national and international regulations. P405 - Store locked up. Disposal : P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. Supplemental label elements : Keep container tightly closed. Do not breathe vapor or spray. Do not taste or swallow. Use only with adequate ventilation. Wash thoroughly after handling. Hazards not otherwise classified : Causes severe respiratory tract burns. Causes severe digestive tract burns. Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 2/18 United States Flooded Lead Acid Battery, Wet Section 3. Composition/information on ingredients lead - ?50 - ?75 7439-92-1 sulphuric acid - ?25 - ?40 7664-93-9 lead dioxide - ?25 - ?50 1309-60-0 1-Propene, homopolymer - ?10 - ?25 9003-07-0 Fiber glass - ?10 - antimony - ?5 7440-36-0 calcium - ?3 7440-70-2 lead sulphate - ?1 7446-14-2 tin - <1 7440-31-5 arsenic - <0.1 7440-38-2 Ingredient name CAS number% Other means of identification : Not available. Substance/mixture : Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Other names There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Get medical attention immediately. Call a poison center or physician. Wash contaminated skin with soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures This product, under the normal conditions of use, is an exempt "ARTICLE" and not subject to OSHA?s Hazard Communication Standard and its requirements for preparation of Safety Data Sheets (SDS). Classifications provided are for the battery electrolyte and are only applicable in the event that the electrolyte is released. Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 3/18 United States Flooded Lead Acid Battery, Wet Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Most important symptoms/effects, acute and delayed Inhalation : Harmful if inhaled. Severely corrosive to the respiratory system. Severely corrosive to the digestive tract. Causes severe burns. May cause burns to mouth, throat and stomach. Harmful if swallowed. :Ingestion Skin contact : Causes severe burns. Causes serious eye damage.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: stomach pains reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: pain or irritation redness blistering may occur reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain watering redness Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Use an extinguishing agent suitable for the surrounding fire. Extinguishing media Suitable extinguishing media : This product, under the normal conditions of use, is an exempt "ARTICLE" and not subject to OSHA?s Hazard Communication Standard and its requirements for preparation of Safety Data Sheets (SDS). Classifications provided are for the battery electrolyte and are only applicable in the event that the electrolyte is released. Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 4/18 United States Flooded Lead Acid Battery, Wet Section 5. Fire-fighting measures First move people out of line-of-sight of the scene and away from windows. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fight fire from protected location or maximum possible distance. Do not fight fire when it reaches the material. Withdraw from fire and let it burn. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide sulfur oxides metal oxide/oxides Explosive material with fire, blast or projection hazard. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Fire- fighters' protective clothing will only provide limited protection. Special protective equipment for fire-fighters : : : Avoid short circuiting the battery.Remark : Do not use water jet.Unsuitable extinguishing media : Special protective actions for fire-fighters : hydrogen fluoride Arsine gas Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : : Accidental releases pose a serious fire or explosion hazard. Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". This product, under the normal conditions of use, is an exempt "ARTICLE" and not subject to OSHA?s Hazard Communication Standard and its requirements for preparation of Safety Data Sheets (SDS). Classifications provided are for the battery electrolyte and are only applicable in the event that the electrolyte is released. Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 5/18 United States Flooded Lead Acid Battery, Wet Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). The spilled material may be neutralized with sodium carbonate, sodium bicarbonate or sodium hydroxide. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from alkalis. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Avoid contact during pregnancy or while nursing. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid shock and friction. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Keep away from alkalis. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling This product, under the normal conditions of use, is an exempt "ARTICLE" and not subject to OSHA?s Hazard Communication Standard and its requirements for preparation of Safety Data Sheets (SDS). Classifications provided are for the battery electrolyte and are only applicable in the event that the electrolyte is released. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 6/18 United States Flooded Lead Acid Battery, Wet Section 8. Exposure controls/personal protection lead ACGIH TLV (United States, 1/2022). [Lead and inorganic compounds as Pb] TWA: 0.05 mg/m?, (as Pb) 8 hours. NIOSH REL (United States, 10/2020). TWA: 0.05 mg/m? 8 hours. OSHA PEL (United States, 5/2018). [Lead inorganic (as Pb)] TWA: 50 ?g/m?, (as Pb) 8 hours. sulphuric acid NIOSH REL (United States, 10/2020). TWA: 1 mg/m? 10 hours. ACGIH TLV (United States, 1/2022). TWA: 0.2 mg/m? 8 hours. Form: Thoracic fraction OSHA PEL (United States, 5/2018). TWA: 1 mg/m? 8 hours. lead dioxide ACGIH TLV (United States, 1/2022). [Lead and inorganic compounds as Pb] TWA: 0.05 mg/m?, (as Pb) 8 hours. OSHA PEL (United States, 5/2018). [Lead inorganic (as Pb)] TWA: 50 ?g/m?, (as Pb) 8 hours. 1-Propene, homopolymer None. Fiber glass None. antimony ACGIH TLV (United States, 1/2022). [Antimony and compounds as Sb] TWA: 0.5 mg/m?, (as Sb) 8 hours. NIOSH REL (United States, 10/2020). [antimony] TWA: 0.5 mg/m? 10 hours. OSHA PEL (United States, 5/2018). [Antimony and compounds (as Sb)] TWA: 0.5 mg/m?, (as Sb) 8 hours. calcium None. lead sulphate ACGIH TLV (United States, 1/2022). [Lead and inorganic compounds as Pb] TWA: 0.05 mg/m?, (as Pb) 8 hours. OSHA PEL (United States, 5/2018). [Lead inorganic (as Pb)] TWA: 50 ?g/m?, (as Pb) 8 hours. tin ACGIH TLV (United States, 1/2022). [Tin and inorganic compounds, excluding Tin hydride and indium tin oxide as Sn] TWA: 2 mg/m?, (as Sn) 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2020). TWA: 2 mg/m? 10 hours. OSHA PEL (United States, 5/2018). [Tin, inorganic compounds (except oxides) (as Sn)] TWA: 2 mg/m?, (as Sn) 8 hours. arsenic ACGIH TLV (United States, 1/2022). [Arsenic and inorganic compounds as As] TWA: 0.01 mg/m?, (as As) 8 hours. NIOSH REL (United States, 10/2020). [arsenic inorganic compounds as As] CEIL: 0.002 mg/m?, (as As) 15 minutes. OSHA PEL (United States, 5/2018). [Arsenic, inorganic compounds (as As)] Ingredient name Exposure limits Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 7/18 United States Flooded Lead Acid Battery, Wet Section 8. Exposure controls/personal protection TWA: 10 ?g/m?, (as As) 8 hours. Hand protection A respirator is not needed under normal and intended conditions of product use. Not required under normal conditions of use. If handling damaged battery cells leaking electrolyte, wear chemical resistant gloves. Not required under normal conditions of use. If operating conditions cause high dust concentrations to be produced, use dust goggles. Eye/face protection Respiratory protection : : : Body protection Not required under normal conditions of use. If handling damaged battery cells leaking electrolyte, wear a long disposable lab coat or apron. : Environmental exposure controls : Not required under normal conditions of use. Appropriate engineering controls : Not required under normal conditions of use. Not required under normal conditions of use. Eyewash stations and emergency showers should be available in case of exposure to leaking battery cells. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Biological exposure indices lead ACGIH BEI (United States, 1/2022) [LEAD AND INORGANIC COMPOUNDS] BEI: 200 ?g/l, lead [in blood]. Sampling time: not critical. lead dioxide ACGIH BEI (United States, 1/2022) [LEAD AND INORGANIC COMPOUNDS] BEI: 200 ?g/l, lead [in blood]. Sampling time: not critical. lead sulphate ACGIH BEI (United States, 1/2022) [LEAD AND INORGANIC COMPOUNDS] BEI: 200 ?g/l, lead [in blood]. Sampling time: not critical. arsenic ACGIH BEI (United States, 1/2022) [ARSENIC, ELEMENTAL AND SOLUBLE INORGANIC COMPOUNDS (excludes gallium arsenide and arsine)] BEI: 35 ?g As/l, inorganic arsenic plus methylated metabolites [in urine]. Sampling time: end of workweek. Ingredient name Exposure indices Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 8/18 United States Flooded Lead Acid Battery, Wet Section 9. Physical and chemical properties Physical state Melting point/freezing point Relative density Liquid. [Battery acid] 327.4?C (621.3?F) [Lead] 1.21 to 1.3 [Battery acid] Sharp.,Pungent.(Battery acid)Odor pH Clear.(Battery acid)Color Evaporation rate Not available. <1 [Battery acid] Not available.Odor threshold : : : : : : : : Appearance SADT Not available.: Decomposition temperature : Not available. Viscosity Not available.: Flow time (ISO 2431) : Not available. Density Not available.: The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. Flash point Not available.: Boiling point, initial boiling point, and boiling range : Electrolyte.(Battery acid): 110 - 112 ?C (230 - 233.6 ?F)?C Lead: 1749 ?C (3180.2 ?F) Vapor pressure Relative vapor density 3.4 [Air = 1] [Electrolyte.] 1.6 kPa (11.71095 mm Hg) [Battery acid]: : Flammability : Avoid short circuiting the battery. Lower and upper explosion limit/flammability limit : Not available. Auto-ignition temperature Not available. Not applicable.Partition coefficient: n- octanol/water : : Particle characteristics Median particle size : Not applicable. Other information Solubility(ies) : Physical/chemical properties comments : No additional information. Not available. Section 10. Stability and reactivity The product is stable.Chemical stability : Possibility of hazardous reactions : Hazardous reactions or instability may occur under certain conditions of storage or use. Conditions may include the following: shock friction high temperature Reactions may include the following: risk of projection hazard risk of causing fire Reactivity : This product has a fire hazard, giving rise to considerable heat and either a minor blast hazard or a minor projection hazard or both. Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 9/18 United States Flooded Lead Acid Battery, Wet Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoid shock and friction. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Attacks many metals producing extremely flammable hydrogen gas which can form explosive mixtures with air. Reactive or incompatible with the following materials: alkalis : : Incompatible materials : Under normal conditions of storage and use, hazardous polymerization will not occur. Reactive or incompatible with the following materials: oxidizing materials, reducing materials, combustible materials, organic materials, metals, acids and moisture. Avoid high temperatures. Avoid overcharging. Do not open or disassemble. Section 11. Toxicological information Acute toxicity lead LC50 Inhalation Dusts and mists Rat - Male, Female >5.05 mg/l 4 hours LD50 Dermal Rat - Male, Female >2000 mg/kg - LD50 Oral Rat - Male, Female >2000 mg/kg - sulphuric acid LC50 Inhalation Dusts and mists Rat 0.255 mg/l 4 hours LD50 Oral Rat 2140 mg/kg - 1-Propene, homopolymer LD50 Oral Rat >8 g/kg - antimony LD50 Oral Rat 100 mg/kg - tin LC50 Inhalation Dusts and mists Rat - Male, Female >4.75 mg/l 4 hours LD50 Dermal Rat - Male, Female >2000 mg/kg - LD50 Oral Rat - Female >2000 mg/kg - arsenic LD50 Oral Rat 763 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Conclusion/Summary : Not available. Mutagenicity Conclusion/Summary : Not available. Irritation/Corrosion sulphuric acid Eyes - Severe irritant Rabbit - 250 ug - Eyes - Severe irritant Rabbit - 0.5 minutes 5 mg - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on toxicological effects Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 10/18 United States Flooded Lead Acid Battery, Wet Section 11. Toxicological information Teratogenicity Conclusion/Summary : Not available. Reproductive toxicity Conclusion/Summary : Not available. Information on the likely routes of exposure Inhalation : Harmful if inhaled. Severely corrosive to the respiratory system. Severely corrosive to the digestive tract. Causes severe burns. May cause burns to mouth, throat and stomach. Harmful if swallowed. :Ingestion Skin contact : Causes severe burns. Causes serious eye damage.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following: pain watering redness Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) calcium Category 3 - Respiratory tract irritation Name Category Name Category lead Category 1 oral, inhalation blood system, kidneys, nervous system sulphuric acid Category 2 - teeth lead dioxide Category 2 - blood system, kidneys, nervous system antimony Category 2 inhalation - lead sulphate Category 2 - - arsenic Category 2 - bone marrow, liver, nervous system Aspiration hazard Not available. Route of exposure Target organs Route of exposure Target organs : Routes of entry anticipated: Oral, Dermal, Inhalation, Eyes. Potential acute health effects Classification lead - 2B Reasonably anticipated to be a human carcinogen. sulphuric acid - 1 Known to be a human carcinogen. lead dioxide - 2A Reasonably anticipated to be a human carcinogen. 1-Propene, homopolymer - 3 - lead sulphate - 2A Reasonably anticipated to be a human carcinogen. arsenic + 1 Known to be a human carcinogen. Product/ingredient name NTPIARCOSHA Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 11/18 United States Flooded Lead Acid Battery, Wet Section 11. Toxicological information Causes damage to organs through prolonged or repeated exposure.General : May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : May damage fertility or the unborn child. May cause harm to breast-fed children. Reproductive toxicity : Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: stomach pains reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: pain or irritation redness blistering may occur reduced fetal weight increase in fetal deaths skeletal malformations : : : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Acute toxicity estimates Product/ingredient name Flooded Lead Acid Battery, Wet 979.8 2889.6 N/A 48.7 1.0 lead 2500 2500 N/A N/A N/A sulphuric acid 2140 N/A N/A N/A 0.255 lead dioxide 500 N/A N/A 11 N/A antimony 100 N/A N/A N/A 1.5 lead sulphate 500 N/A N/A N/A 1.5 tin 2500 2500 N/A N/A N/A arsenic 100 N/A N/A 3 N/A Oral (mg/ kg) Dermal (mg/kg) Inhalation (gases) (ppm) Inhalation (vapors) (mg/l) Inhalation (dusts and mists) (mg/ l) Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 12/18 United States Flooded Lead Acid Battery, Wet Section 11. Toxicological information Section 12. Ecological information Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Not available. Toxicity lead Acute EC50 105 ppb Marine water Algae - Chaetoceros sp. - Exponential growth phase 72 hours Acute EC50 0.489 mg/l Marine water Algae - Ulva pertusa 96 hours Acute EC50 8000 ?g/l Fresh water Aquatic plants - Lemna minor 4 days Acute LC50 530 ?g/l Fresh water Crustaceans - Ceriodaphnia reticulata 48 hours Acute LC50 0.594 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 0.44 ppm Fresh water Fish - Cyprinus carpio - Juvenile (Fledgling, Hatchling, Weanling) 96 hours Chronic NOEC 0.25 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.03 ?g/l Fresh water Fish - Cyprinus carpio 4 weeks sulphuric acid Acute EC50 >100 mg/l Fresh water Algae - Desmodesmus subspicatus 72 hours Acute EC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 42500 ?g/l Marine water Crustaceans - Pandalus montagui - Adult 48 hours Acute LC50 36 ul/L Marine water Fish - Agonus cataphractus 96 hours antimony Acute LC50 18000 ?g/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 22 mg/l Fresh water Fish - Pimephales promelas 96 hours calcium Chronic NOEC 90 mg/l Fresh water Fish - Oreochromis niloticus 30 days lead sulphate Acute IC50 82 ?g/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 54500 ?g/l Fresh water Crustaceans - Diaptomus forbesi 48 hours Acute LC50 750 ?g/l Marine water Fish - Cynoglossus joyneri - Larvae 96 hours arsenic Acute EC50 0.172 mg/l Marine water Algae - Ulva pertusa 96 hours Acute LC50 1700 ?g/l Fresh water Crustaceans - Simocephalus vetulus 48 hours Acute LC50 1900 ?g/l Fresh water Daphnia - Daphnia pulex 48 hours Acute LC50 9900 ?g/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 0.0625 mg/l Marine water Algae - Ulva pertusa 96 hours Product/ingredient name SpeciesResult Exposure Conclusion/Summary : Not available. Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 13/18 United States Flooded Lead Acid Battery, Wet Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods This product, under the normal conditions of use, is an exempt "ARTICLE" and not subject to OSHA?s Hazard Communication Standard and its requirements for preparation of Safety Data Sheets (SDS). Classifications provided are for the battery electrolyte and are only applicable in the event that the electrolyte is released. Section 14. Transport information Batteries, wet, filled with acid 8 - BATTERIES, WET, FILLED WITH ACID 8 - Batteries, wet, filled with acid UN2794 8 - UN2794 UN2794 DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user No. No. No. Shipper must follow all applicable International, Federal, State, Provincial, and/or Local laws when preparing dangerous goods shipments including but not limited to classification, packaging, marking, labeling, and shipping dangerous goods. : Additional information DOT Classification IMDG IATA : : : Reportable quantity 14.286 lbs / 6.4857 kg [1.3652 gal / 5.1679 L]. Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. Limited quantity No. Packaging instruction Exceptions: 159. Non-bulk: 159. Bulk: 159. Quantity limitation Passenger aircraft/rail: 30 kg. Special provisions A51 Emergency schedules F-A, S-B Special provisions 295 The environmentally hazardous substance mark may appear if required by other transportation regulations. Quantity limitation Passenger and Cargo Aircraft: 30 kg. Packaging instructions: 870. Cargo Aircraft Only: Packaging instructions: 870. Limited Quantities - Passenger Aircraft: Forbidden. Packaging instructions: Forbidden. Special provisions A51, A164, A183, A802 Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 14/18 United States Flooded Lead Acid Battery, Wet Section 14. Transport information Transport in bulk according to IMO instruments : Not available. Section 15. Regulatory information U.S. Federal regulations Clean Water Act (CWA) 307: lead; lead dioxide; antimony; lead sulphate; arsenic Clean Water Act (CWA) 311: sulphuric acid; lead sulphate : Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) : Listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Listed TSCA 8(a) CDR Exempt/Partial exemption: Not determined TSCA 12(b) one-time export: lead sulphate TSCA 12(b) annual export notification: lead United States inventory (TSCA 8b): All components are active or exempted. SARA 302/304 SARA 304 RQ : 2272.7 lbs / 1031.8 kg [217.2 gal / 822.2 L] sulphuric acid ?25 - ?40 Yes. 1000 66.3 1000 66.3 Composition/information on ingredients Name % EHS (lbs) (lbs)(gallons) (gallons) SARA 302 TPQ SARA 304 RQ SARA 311/312 Classification : EXPLOSIVES - Division 1.3 ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (inhalation) - Category 4 SKIN CORROSION - Category 1 SERIOUS EYE DAMAGE - Category 1 CARCINOGENICITY - Category 1A TOXIC TO REPRODUCTION - Category 1A TOXIC TO REPRODUCTION - Effects on or via lactation SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 HNOC - Corrosive to digestive tract [severe] HNOC - Corrosive to respiratory tract [severe] Composition/information on ingredients Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 15/18 United States Flooded Lead Acid Battery, Wet Section 15. Regulatory information SARA 313 Product name CAS number % SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. sulphuric acid 7664-93-9 ?25 - ?40 antimony 7440-36-0 ?5 sulphuric acid 7664-93-9 ?25 - ?40 antimony 7440-36-0 ?5 Form R - Reporting requirements Supplier notification State regulations lead ?50 - ?75 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 1A TOXIC TO REPRODUCTION - Effects on or via lactation SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 sulphuric acid ?25 - ?40 ACUTE TOXICITY (inhalation) - Category 2 SKIN CORROSION - Category 1A SERIOUS EYE DAMAGE - Category 1 CARCINOGENICITY - Category 1A SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 HNOC - Corrosive to digestive tract [severe] HNOC - Corrosive to respiratory tract [severe] lead dioxide ?25 - ?50 OXIDIZING SOLIDS - Category 3 ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (inhalation) - Category 4 CARCINOGENICITY - Category 1B TOXIC TO REPRODUCTION - Category 1A SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 antimony ?5 ACUTE TOXICITY (oral) - Category 3 ACUTE TOXICITY (inhalation) - Category 4 CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 calcium ?3 SUBSTANCES AND MIXTURES, WHICH IN CONTACT WITH WATER, EMIT FLAMMABLE GASES - Category 2 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 lead sulphate ?1 ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (inhalation) - Category 4 CARCINOGENICITY - Category 1B TOXIC TO REPRODUCTION - Category 1A SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 arsenic <0.1 ACUTE TOXICITY (oral) - Category 3 ACUTE TOXICITY (inhalation) - Category 3 CARCINOGENICITY - Category 1A SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Name % Classification Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 16/18 United States Flooded Lead Acid Battery, Wet Section 15. Regulatory information The following components are listed: LEAD; SULFURIC ACID; LEAD DIOXIDE; ANTIMONY; CALCIUM; SULFURIC ACID, LEAD (2+) SALT Massachusetts : California Prop. 65 New York : The following components are listed: Lead; Sulfuric acid; Antimony; Lead sulfate New Jersey : The following components are listed: LEAD; SULFURIC ACID; LEAD DIOXIDE; ANTIMONY; CALCIUM; LEAD SULPHATE Pennsylvania : The following components are listed: LEAD COMPOUNDS; SULFURIC ACID; LEAD COMPOUNDS; ANTIMONY COMPOUNDS; CALCIUM; SULFURIC ACID, LEAD(2+) SALT (1:1) International regulations WARNING: This product can expose you to chemicals including Lead, which is known to the State of California to cause cancer and birth defects or other reproductive harm. This product can expose you to chemicals including Strong inorganic acid mists containing sulfuric acid, Lead and lead compounds, Lead and lead compounds and Arsenic, which are known to the State of California to cause cancer. For more information go to www.P65Warnings. ca.gov. Lead Yes. Yes. Strong inorganic acid mists containing sulfuric acid - - Lead and lead compounds - - Lead and lead compounds - - Arsenic Yes. - Ingredient name No significant risk level Maximum acceptable dosage level Chemical Weapon Convention List Schedules I, II & III Chemicals Montreal Protocol Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Informed Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Lead (Pb) Heavy metals - Annex 1 Listed Ingredient name List name Status Not listed. Section 16. Other information Hazardous Material Information System (U.S.A.) Health Flammability Physical hazards Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS? ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered trademark and service mark of the American Coatings Association, Inc. * 4 0 3 Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 17/18 United States Flooded Lead Acid Battery, Wet Section 16. Other information History Sphera Solutions Date of issue/Date of revision Version Prepared by To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Notice to reader Date of previous issue : : : : References : HCS (U.S.A.) - Hazard Communication Standard International transport regulations Key to abbreviations : 05/02/2023 No previous validation 1 2 0 3 National Fire Protection Association (U.S.A.) Health Instability/Reactivity Flammability The customer is responsible for determining the PPE code for this material. For more information on HMIS? Personal Protective Equipment (PPE) codes, consult the HMIS? Implementation Manual. ATE = Acute Toxicity Estimate AMP = Acceptable maximum peak above the acceptable ceiling concentration for an 8-hr shift BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available UN = United Nations Special hazards Indicates information that has changed from previously issued version. Procedure used to derive the classification Classification Justification EXPLOSIVES - Division 1.3 Expert judgment ACUTE TOXICITY (oral) - Category 4 Calculation method ACUTE TOXICITY (inhalation) - Category 4 Calculation method SKIN CORROSION - Category 1 On basis of test data SERIOUS EYE DAMAGE - Category 1 On basis of test data CARCINOGENICITY - Category 1A Calculation method TOXIC TO REPRODUCTION - Category 1A Calculation method TOXIC TO REPRODUCTION - Effects on or via lactation Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Calculation method Date of issue/Date of revision : 05/02/2023 Date of previous issue : No previous validation Version : 1 18/18 United States