DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange Not available. Aerosol. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : Dupli-Color Products Company 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. DE1622 DE1622Product code : Product Information Telephone Number : (800) 247-3270 Transportation Emergency Telephone Number : (800) 424-9300 Section 2. Hazards identification FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 1B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 17% (oral), 17% (dermal), 19% (inhalation) OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 1/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Avoid breathing dust or mist. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Pressurized container: Do not pierce or burn, even after use. Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store in a well-ventilated place. Keep container tightly closed. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified : DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations. Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. May damage fertility or the unborn child. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Keep upright in a cool, dry place. Do not discard empty can in trash compactor. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Mixture Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 2/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Acetone ?25 - ?50 67-64-1 Propane ?10 - ?25 74-98-6 n-Butyl Acetate ?10 123-86-4 Butane ?10 106-97-8 2-Propoxyethanol ?3 2807-30-9 Zirconium 2-Ethylhexanoate ?0.3 22464-99-9 Methyl Ethyl Ketoxime ?0.3 96-29-7 Light Aromatic Hydrocarbons ?0.3 64742-95-6 Cobalt 2-Ethylhexanoate ?0.3 136-52-7 Hydrotreated Heavy Petroleum Naphtha ?0.3 64742-48-9 Ingredient name CAS number% by weight Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact : May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Potential acute health effects Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 3/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 4/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : Flammable aerosol.Remark : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50?C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing gas. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) : Precautions for safe handling Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 5/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Acetone 67-64-1 ACGIH TLV (United States, 1/2024). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 250 ppm 10 hours. TWA: 590 mg/m? 10 hours. OSHA PEL (United States, 5/2018). TWA: 1000 ppm 8 hours. TWA: 2400 mg/m? 8 hours. Propane 74-98-6 NIOSH REL (United States, 10/2020). TWA: 1000 ppm 10 hours. TWA: 1800 mg/m? 10 hours. OSHA PEL (United States, 5/2018). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m? 8 hours. ACGIH TLV (United States, 1/2024). Oxygen Depletion [Asphyxiant]. Explosive potential. n-Butyl Acetate 123-86-4 NIOSH REL (United States, 10/2020). TWA: 150 ppm 10 hours. TWA: 710 mg/m? 10 hours. STEL: 200 ppm 15 minutes. STEL: 950 mg/m? 15 minutes. OSHA PEL (United States, 5/2018). TWA: 150 ppm 8 hours. TWA: 710 mg/m? 8 hours. ACGIH TLV (United States, 1/2024). [Butyl acetates] STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. Butane 106-97-8 NIOSH REL (United States, 10/2020). TWA: 800 ppm 10 hours. TWA: 1900 mg/m? 10 hours. ACGIH TLV (United States, 1/2024). [Butane] Explosive potential. STEL: 1000 ppm 15 minutes. 2-Propoxyethanol 2807-30-9 None. Zirconium 2-Ethylhexanoate 22464-99-9 ACGIH TLV (United States, 1/2024). Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) CAS # Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 6/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection [Zirconium and compounds] TWA: 5 mg/m?, (as Zr) 8 hours. STEL: 10 mg/m?, (as Zr) 15 minutes. NIOSH REL (United States, 10/2020). [zirconium compounds] TWA: 5 mg/m?, (as Zr) 10 hours. STEL: 10 mg/m?, (as Zr) 15 minutes. OSHA PEL (United States, 5/2018). [Zirconium compounds] TWA: 5 mg/m?, (as Zr) 8 hours. Methyl Ethyl Ketoxime 96-29-7 OARS WEEL (United States, 4/2022). Skin sensitizer. TWA: 10 ppm 8 hours. Light Aromatic Hydrocarbons 64742-95-6 None. Cobalt 2-Ethylhexanoate 136-52-7 ACGIH TLV (United States, 1/2024). [cobalt and inorganic compounds] Skin sensitizer. Inhalation sensitizer. TWA: 0.02 mg/m?, (as Co) 8 hours. Hydrotreated Heavy Petroleum Naphtha 64742-48-9 None. acetone 67-64-1 CA Alberta Provincial (Canada, 3/2023). OEL: 1200 mg/m? 8 hours. OEL: 1800 mg/m? 15 minutes. OEL: 500 ppm 8 hours. OEL: 750 ppm 15 minutes. CA British Columbia Provincial (Canada, 8/2023). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. CA Quebec Provincial (Canada, 2/2024). TWAEV: 250 ppm 8 hours. STEV: 500 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 4/2021). STEL: 750 ppm 15 minutes. TWA: 500 ppm 8 hours. Normal propane 74-98-6 CA Alberta Provincial (Canada, 3/2023). OEL: 1000 ppm 8 hours. CA Saskatchewan Provincial (Canada, 4/2021). STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours. CA British Columbia Provincial (Canada, 8/2023). Oxygen Depletion [Asphyxiant]. Explosive potential. CA Ontario Provincial (Canada, 6/2019). Oxygen Depletion [Asphyxiant]. Explosive potential. CA Quebec Provincial (Canada, 2/2024). Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 7/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Oxygen Depletion [Asphyxiant]. Explosive potential. n-butyl acetate 123-86-4 CA Alberta Provincial (Canada, 3/2023). OEL: 200 ppm 15 minutes. OEL: 950 mg/m? 15 minutes. OEL: 150 ppm 8 hours. OEL: 713 mg/m? 8 hours. CA Saskatchewan Provincial (Canada, 4/2021). STEL: 200 ppm 15 minutes. TWA: 150 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). [butyl acetates, all isomers] STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA British Columbia Provincial (Canada, 8/2023). [butyl acetate, all isomers] STEL: 150 ppm 15 minutes. TWA: 50 ppm 8 hours. CA Quebec Provincial (Canada, 2/2024). [butyl acetates] STEV: 150 ppm 15 minutes. TWAEV: 50 ppm 8 hours. Butane 106-97-8 CA Alberta Provincial (Canada, 3/2023). OEL: 1000 ppm 8 hours. CA Quebec Provincial (Canada, 2/2024). TWAEV: 800 ppm 8 hours. TWAEV: 1900 mg/m? 8 hours. CA Saskatchewan Provincial (Canada, 4/2021). [Butane] STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours. CA British Columbia Provincial (Canada, 8/2023). [butane, all isomers] Explosive potential. STEL: 1000 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). [Butane, All isomers] Explosive potential. STEL: 1000 ppm 15 minutes. 2-Propoxyethanol 2807-30-9 CA Ontario Provincial (Canada, 6/2019). Absorbed through skin. TWA: 110 mg/m? 8 hours. TWA: 25 ppm 8 hours. Zirconium 2-Ethylhexanoate 22464-99-9 CA Alberta Provincial (Canada, 3/2023). [Zirconium and compounds] OEL: 5 mg/m?, (as Zr) 8 hours. OEL: 10 mg/m?, (as Zr) 15 minutes. CA British Columbia Provincial (Canada, 8/2023). [Zirconium and compounds] TWA: 5 mg/m?, (as Zr) 8 hours. STEL: 10 mg/m?, (as Zr) 15 minutes. CA Quebec Provincial (Canada, 2/2024). [Zirconium and compounds] TWAEV: 5 mg/m?, (as Zr) 8 hours. STEV: 10 mg/m?, (as Zr) 15 minutes. CA Ontario Provincial (Canada, 6/2019). [Zirconium and compounds] Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 8/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection STEL: 10 mg/m?, (as Zr) 15 minutes. TWA: 5 mg/m?, (as Zr) 8 hours. Methyl Ethyl Ketoxime 96-29-7 OARS WEEL (United States, 4/2022). Skin sensitizer. TWA: 10 ppm 8 hours. Cobalt 2-Ethylhexanoate 136-52-7 CA British Columbia Provincial (Canada, 8/2023). [cobalt and inorganic compounds (inhalable)] Skin sensitizer. Inhalation sensitizer. Notes: No British Columbia exposure limit at this time CA British Columbia Provincial (Canada, 8/2023). [Cobalt and inorganic compounds] Skin sensitizer. Inhalation sensitizer. TWA: 0.02 mg/m?, (as Co) 8 hours. Form: Total CA Ontario Provincial (Canada, 6/2019). [Cobalt and inorganic compounds] TWA: 0.02 mg/m?, (as Co) 8 hours. CA Saskatchewan Provincial (Canada, 4/2021). [Cobalt and inorganic compounds] STEL: 0.06 mg/m?, (measured as Co) 15 minutes. TWA: 0.02 mg/m?, (measured as Co) 8 hours. CA Quebec Provincial (Canada, 2/2024). [Cobalt elemental, and inorganic compounds] Skin sensitizer. Inhalation sensitizer. TWAEV: 0.02 mg/m?, (as Co) 8 hours. Form: inhalable aerosol fraction Acetone 67-64-1 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 500 ppm 8 hours. STEL: 750 ppm 15 minutes. n-Butyl Acetate 123-86-4 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 150 ppm 8 hours. STEL: 200 ppm 15 minutes. Zirconium 2-Ethylhexanoate 22464-99-9 NOM-010-STPS-2014 (Mexico, 4/2016). [Circonio y compuestos] TWA: 5 mg/m?, (as Zr) 8 hours. STEL: 10 mg/m?, (as Zr) 15 minutes. Cobalt 2-Ethylhexanoate 136-52-7 NOM-010-STPS-2014 (Mexico, 4/2016). [Cobalto y compuestos inorg?nicos] TWA: 0.02 mg/m?, (as Co) 8 hours. Exposure limits Occupational exposure limits (Mexico) CAS # Biological exposure indices (United States) Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 9/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Acetone ACGIH BEI (United States, 1/2024) BEI: 25 mg/l, acetone [in urine]. Sampling time: end of shift. Cobalt 2-Ethylhexanoate ACGIH BEI (United States, 1/2024) [cobalt and inorganic compounds including cobalt oxides] BEI: 15 ?g/l, not combined with tungsten carbide - cobalt [in urine]. Sampling time: end of shift at end of workweek. BEI: Nonquantitative: Biological monitoring should be considered for this compound based on the review; however, a specific BEI? could not be determined due to insufficient data., cobalt with tungsten carbide - cobalt [in urine]. Sampling time: end of shift at end of workweek. Ingredient name Exposure indices Biological exposure indices (Canada) Biological exposure indices (Mexico) No exposure indices known. Acetone Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 50 mg/L [non-specific.The determinant is nonspecific, since it can be found after exposure to other chemicals.], acetone [in urine]. Sampling time: at the end of the work shift. Cobalt 2-Ethylhexanoate Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) [cobalt and its compounds] BEI: 1 ?g/l [Basal level.The determinant may be present in the biological sample obtained from subjects who have not been occupationally exposed, at a concentration that could affect the interpretation of the results. These background levels are included in the valu; semi-quantitative.The biological determinant is an indicator of chemical exposure, but the quantitative interpretation of the measure is ambiguous. These biological determinants should be used as a screening test if a quantitative test is not possible.], cobalt [in blood]. Sampling time: at the end of the shift at the end of the work week. BEI: 15 ?g/l [Basal level.The determinant Ingredient name Exposure indices Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 10/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Environmental exposure controls : may be present in the biological sample obtained from subjects who have not been occupationally exposed, at a concentration that could affect the interpretation of the results. These background levels are included in the valu], cobalt [in urine]. Sampling time: at the end of the shift at the end of the work week. Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 11/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Liquid. Not available. 0.75 1.55 [Air = 1] Not available.Odor pH Orange.Color Evaporation rate 5.6 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: -29?C (-20.2?F) [Pensky-Martens Closed Cup] Not applicable. Not applicable. Viscosity Kinematic (40?C (104?F)): <20.5 mm2/s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : Appearance : Not available. : Flammable aerosol. : Lower: 1.26% Upper: 15.8% Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 27.446 kJ/g Aerosol product Molecular weight : Not applicable. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 101.3 kPa (760 mm Hg) Solubility(ies) : Media Result cold water Not soluble Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 12/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 11. Toxicological information Acute toxicity Acetone LD50 Oral Rat 5800 mg/kg - n-Butyl Acetate LD50 Dermal Rabbit >17600 mg/kg - LD50 Oral Rat 10768 mg/kg - Butane LC50 Inhalation Vapor Rat 658000 mg/m? 4 hours 2-Propoxyethanol LD50 Oral Rat 3089 mg/kg - Zirconium 2-Ethylhexanoate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat >5 g/kg - Methyl Ethyl Ketoxime LD50 Oral Rat 930 mg/kg - Light Aromatic Hydrocarbons LD50 Oral Rat 8400 mg/kg - Cobalt 2-Ethylhexanoate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat 1.22 g/kg - Hydrotreated Heavy Petroleum Naphtha LC50 Inhalation Vapor Rat 8500 mg/m? 4 hours LD50 Oral Rat >6 g/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion Acetone Eyes - Mild irritant Human - 186300 ppm - Eyes - Mild irritant Rabbit - 10 uL - Eyes - Moderate irritant Rabbit - 24 hours 20 mg - Eyes - Severe irritant Rabbit - 20 mg - Skin - Mild irritant Rabbit - 395 mg - Skin - Mild irritant Rabbit - 24 hours 500 mg - n-Butyl Acetate Eyes - Moderate irritant Rabbit - 100 mg - Skin - Moderate irritant Rabbit - 24 hours 500 mg - 2-Propoxyethanol Eyes - Severe irritant Rabbit - 100 mg - Eyes - Severe irritant Rabbit - 24 hours 750 ug - Skin - Mild irritant Guinea pig - 24 hours 1 Ml - Skin - Mild irritant Rabbit - 24 hours 500 mg - Methyl Ethyl Ketoxime Eyes - Severe irritant Rabbit - 100 uL - Light Aromatic Hydrocarbons Eyes - Mild irritant Rabbit - 24 hours 100 uL - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on toxicological effects Classification Cobalt 2-Ethylhexanoate - 2B Reasonably anticipated to be a human carcinogen. Product/ingredient name NTPIARCOSHA Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 13/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 11. Toxicological information Teratogenicity Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Acetone Category 3 - Respiratory tract irritation Category 3 Narcotic effects n-Butyl Acetate Category 3 - Narcotic effects 2-Propoxyethanol Category 3 - Narcotic effects Methyl Ethyl Ketoxime Category 1 - upper respiratory tract Category 3 Narcotic effects Light Aromatic Hydrocarbons Category 3 - Respiratory tract irritation Category 3 Narcotic effects Name Category Name Category Methyl Ethyl Ketoxime Category 2 - blood system Aspiration hazard Name Result Light Aromatic Hydrocarbons ASPIRATION HAZARD - Category 1 Hydrotreated Heavy Petroleum Naphtha ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Information on the likely routes of exposure Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact : May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness : Not available. Potential acute health effects Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 14/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 11. Toxicological information Not available. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : May damage the unborn child.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : May damage fertility. Skin contact Ingestion Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 125105.34 mg/kg Dermal 44550.3 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information Toxicity Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 15/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Zirconium 2-Ethylhexanoate - 2.96 Low Methyl Ethyl Ketoxime - 2.5 to 5.8 Low Light Aromatic Hydrocarbons - 10 to 2500 High Cobalt 2-Ethylhexanoate - 15600 High Hydrotreated Heavy Petroleum Naphtha - 10 to 2500 High Product/ingredient name Aquatic half-life Photolysis Biodegradability Acetone - - Readily n-Butyl Acetate - - Readily Light Aromatic Hydrocarbons - - Readily Acetone Acute EC50 7200000 ?g/l Fresh water Algae - Selenastrum sp. 96 hours Acute LC50 4.42589 ml/L Marine water Crustaceans - Acartia tonsa - Copepodid 48 hours Acute LC50 7460000 ?g/l Fresh water Daphnia - Daphnia cucullata 48 hours Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - Neonate 21 days Chronic NOEC 5 ?g/l Marine water Fish - Gasterosteus aculeatus - Larvae 42 days n-Butyl Acetate Acute LC50 32 mg/l Marine water Crustaceans - Artemia salina 48 hours Acute LC50 18000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Methyl Ethyl Ketoxime Acute LC50 843000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. :Disposal methods Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 16/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 14. Transport information AEROSOLS 2.1 - AEROSOLS 2.1 - UN1950 UN1950 - Emergency schedules F-D, S- U DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to IMO instruments No. No. Not available. : Proper shipping name : Not available. : TDG Classification UN1950 AEROSOLS 2.1 - No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.13-2.17 (Class 2). Mexico Classification UN1950 AEROSOLS 2.1 - No. - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. IATA UN1950 AEROSOLS, flammable 2.1 - No. - 126 ERG No. 126 126 ERG No. ERG No. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Section 15. Regulatory information SARA 313 SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet, where applicable. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 International regulations Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 17/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 15. Regulatory information Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International lists : Montreal Protocol Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Section 16. Other information 9/30/2024 History Date of printing Date of issue/Date of revision Version Date of previous issue : : : : 9/30/2024 8/31/2024 26 Hazardous Material Information System (U.S.A.) 2 4 3 *Health Flammability Physical hazards Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS? ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS? Personal Protective Equipment (PPE) codes, consult the HMIS? Implementation Manual. FLAMMABLE AEROSOLS - Category 1 On basis of test data GASES UNDER PRESSURE - Compressed gas On basis of test data SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method SKIN SENSITIZATION - Category 1 Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 1B Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method Procedure used to derive the classification Classification Justification Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 18/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Indicates information that has changed from previously issued version. Key to abbreviations : Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision : 9/30/2024 Date of previous issue : 8/31/2024 Version : 26 19/19 DE1622 DUPLI-COLOR? Engine Enamel with Ceramic Chrysler Orange SHW-85-NA-GHS-US