DUPLI-COLOR? BED ARMOR? (Aerosol) Not available. Aerosol. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : Dupli-Color Products Company 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. BAA2010 BAA2010Product code : Product Information Telephone Number : (800) 247-3270 Transportation Emergency Telephone Number : (800) 424-9300 Section 2. Hazards identification FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : Precautionary statements GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 18.2% (oral), 18.2% (dermal), 4.2% (inhalation) OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May cause an allergic skin reaction. Causes serious eye irritation. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. (lungs) :Hazard statements Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 1/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Section 2. Hazards identification Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Do not breathe dust or mist. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Pressurized container: Do not pierce or burn, even after use. Response : IF exposed or concerned: Get medical advice or attention. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage : Store locked up. Protect from sunlight. Store in a well-ventilated place. Do not expose to temperatures exceeding 50 ?C/122 ?F. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified : None known. Please refer to the SDS for additional information. Keep out of reach of children. Keep upright in a cool, dry place. Do not discard empty can in trash compactor. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Dimethyl Ether ?10 - ?25 115-10-6 Talc ?10 14807-96-6 2-Propanol ?5 67-63-0 Propylene Glycol ?5 57-55-6 Light Aliphatic Hydrocarbon ?3 64742-47-8 Carbon Black ?3 1333-86-4 Dipropylene Glycol Dimethyl Ether ?3 111109-77-4 Tetramethyl Decynediol <3 126-86-3 Acrylonitirile/Butadiene Polymer ?1 9003-18-3 2-(2-Methoxyethoxy)-ethanol ?0.3 111-77-3 Ingredient name CAS number% by weight Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 2/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 3/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. See toxicological information (Section 11) Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : Flammable aerosol.Remark : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 4/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50?C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Dimethyl Ether 115-10-6 OARS WEEL (United States, 4/2022). TWA: 1000 ppm 8 hours. Talc 14807-96-6 NIOSH REL (United States, 10/2020). TWA: 2 mg/m? 10 hours. Form: Respirable fraction ACGIH TLV (United States, 1/2024). TWA: 2 mg/m? 8 hours. Form: Respirable fraction 2-Propanol 67-63-0 ACGIH TLV (United States, 1/2024). Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) CAS # Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 5/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 400 ppm 10 hours. TWA: 980 mg/m? 10 hours. STEL: 500 ppm 15 minutes. STEL: 1225 mg/m? 15 minutes. OSHA PEL (United States, 5/2018). TWA: 400 ppm 8 hours. TWA: 980 mg/m? 8 hours. Propylene Glycol 57-55-6 OARS WEEL (United States, 4/2022). TWA: 10 mg/m? 8 hours. Light Aliphatic Hydrocarbon 64742-47-8 ACGIH TLV (United States, 1/2024). [Kerosene] Absorbed through skin. TWA: 200 mg/m?, (as total hydrocarbon vapor) 8 hours. Carbon Black 1333-86-4 ACGIH TLV (United States, 1/2024). TWA: 3 mg/m? 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2020). TWA: 3.5 mg/m? 10 hours. OSHA PEL (United States, 5/2018). TWA: 3.5 mg/m? 8 hours. Dipropylene Glycol Dimethyl Ether 111109-77-4 None. Tetramethyl Decynediol 126-86-3 None. Acrylonitirile/Butadiene Polymer 9003-18-3 None. 2-(2-Methoxyethoxy)-ethanol 111-77-3 None. talc (none asbestiform) 14807-96-6 CA British Columbia Provincial (Canada, 8/2023). Notes: the value is for particulate matter containing no asbestos and less than 1% crystalline silica. TWA: 2 mg/m? 8 hours. Form: Respirable CA Alberta Provincial (Canada, 3/2023). OEL: 2 mg/m? 8 hours. Form: Respirable particulate CA Ontario Provincial (Canada, 6/2019). TWA: 2 mg/m? 8 hours. Form: Respirable particulate matter. TWA: 2 f/cc 8 hours. CA Quebec Provincial (Canada, 2/2024). TWAEV: 2 mg/m? 8 hours. Form: respirable aerosol fraction CA Saskatchewan Provincial (Canada, 4/2021). TWA: 2 mg/m? 8 hours. Form: respirable fraction Isopropyl alcohol 67-63-0 CA Alberta Provincial (Canada, 3/2023). OEL: 984 mg/m? 15 minutes. OEL: 200 ppm 8 hours. OEL: 400 ppm 15 minutes. OEL: 492 mg/m? 8 hours. CA British Columbia Provincial (Canada, 8/2023). Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 6/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. CA Quebec Provincial (Canada, 2/2024). TWAEV: 200 ppm 8 hours. STEV: 400 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 4/2021). STEL: 400 ppm 15 minutes. TWA: 200 ppm 8 hours. Petroleum refining, hydrotreated light distillate 64742-47-8 CA British Columbia Provincial (Canada, 8/2023). [Kerosene/Jet fuels] Absorbed through skin. Notes: Application restricted to conditions in which there are negligible aerosol exposures. TWA: 200 mg/m?, (as total hydrocarbon vapour) 8 hours. CA Alberta Provincial (Canada, 3/2023). [Kerosene/Jet fuels] Absorbed through skin. OEL: 200 mg/m?, (as total hydrocarbon vapour) 8 hours. CA Ontario Provincial (Canada, 6/2019). Absorbed through skin. TWA: 200 mg/m?, (as total hydrocarbon vapour) 8 hours. CA Quebec Provincial (Canada, 2/2024). [kerosene] Absorbed through skin. TWAEV: 200 mg/m? 8 hours. Carbon black 1333-86-4 CA British Columbia Provincial (Canada, 8/2023). TWA: 3 mg/m? 8 hours. Form: Inhalable CA Ontario Provincial (Canada, 6/2019). TWA: 3 mg/m? 8 hours. Form: Inhalable particulate matter. CA Quebec Provincial (Canada, 2/2024). TWAEV: 3 mg/m? 8 hours. Form: inhalable aerosol fraction CA Alberta Provincial (Canada, 3/2023). OEL: 3.5 mg/m? 8 hours. CA Saskatchewan Provincial (Canada, 4/2021). STEL: 7 mg/m? 15 minutes. TWA: 3.5 mg/m? 8 hours. 2-Propanol 67-63-0 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. Light Aliphatic Hydrocarbon 64742-47-8 ACGIH TLV (United States, 1/2024). [Kerosene] Absorbed through skin. TWA: 200 mg/m?, (as total hydrocarbon vapor) 8 hours. Exposure limits Occupational exposure limits (Mexico) CAS # Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 7/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Environmental exposure controls : Biological exposure indices (United States) 2-Propanol ACGIH BEI (United States, 1/2024) BEI: 40 mg/l, acetone [in urine]. Sampling time: end of shift at end of workweek. Ingredient name Exposure indices Biological exposure indices (Canada) Biological exposure indices (Mexico) No exposure indices known. 2-Propanol Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 40 mg/L [non-specific.The determinant is nonspecific, since it can be found after exposure to other chemicals.], acetone [in urine]. Sampling time: at the end of the shift at the end of the work week. Ingredient name Exposure indices Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 8/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Respiratory protection : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Liquid. Not available. 0.98 1 [Air = 1] Not available.Odor pH Black.Color Evaporation rate 1.44 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: -29?C (-20.2?F) [Pensky-Martens Closed Cup] Not applicable. 7 Viscosity Kinematic (40?C (104?F)): >20.5 mm2/s (>20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : Appearance : Not available. : Flammable aerosol. : Lower: 0.6% Upper: 27% Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 9.33 kJ/g Aerosol product Molecular weight : Not applicable. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 101.3 kPa (760 mm Hg) Solubility(ies) : Media Result cold water Partially soluble Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 9/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Dimethyl Ether LC50 Inhalation Gas. Rat 164000 ppm 4 hours LC50 Inhalation Vapor Rat 309 g/m? 4 hours 2-Propanol LD50 Dermal Rabbit 12800 mg/kg - LD50 Oral Rat 5000 mg/kg - Propylene Glycol LD50 Dermal Rabbit 20800 mg/kg - LD50 Oral Rat 20 g/kg - Carbon Black LD50 Oral Rat >15400 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Talc Skin - Mild irritant Human - 72 hours 300 ug I - 2-Propanol Eyes - Moderate irritant Rabbit - 10 mg - Eyes - Moderate irritant Rabbit - 24 hours 100 mg - Eyes - Severe irritant Rabbit - 100 mg - Skin - Mild irritant Rabbit - 500 mg - Propylene Glycol Eyes - Mild irritant Rabbit - 100 mg - Eyes - Mild irritant Rabbit - 24 hours 500 mg - Skin - Mild irritant Human - 168 hours 500 mg - Skin - Mild irritant Woman - 96 hours 30 % - Skin - Moderate irritant Child - 96 hours 30 % C - Skin - Moderate irritant Human - 72 hours 104 mg I - Tetramethyl Decynediol Eyes - Severe irritant Rabbit - 0.1 Ml - Skin - Mild irritant Rabbit - 0.5 gm - 2-(2-Methoxyethoxy)-ethanol Eyes - Mild irritant Rabbit - 24 hours 500 mg - Eyes - Moderate irritant Rabbit - 500 mg - Product/ingredient name Result Score Exposure Observation Sensitization Species Information on toxicological effects Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 10/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) 2-Propanol Category 3 - Narcotic effects Light Aliphatic Hydrocarbon Category 3 - Narcotic effects Name Category Name Category Talc Category 1 inhalation lungs Aspiration hazard Name Result Light Aliphatic Hydrocarbon ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Classification Talc - 3 - 2-Propanol - 3 - Carbon Black - 2B - Product/ingredient name NTPIARCOSHA Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : May cause an allergic skin reaction. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following: pain or irritation watering redness : Not available. Potential acute health effects Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 11/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Section 11. Toxicological information Not available. Causes damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : Suspected of damaging the unborn child.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 28445.8 mg/kg Dermal 197047.53 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 12/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Section 12. Ecological information Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Not available. Product/ingredient name Aquatic half-life Photolysis Biodegradability 2-Propanol - - Readily Propylene Glycol - - Readily Toxicity 2-Propanol Acute EC50 7550 mg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 1400000 ?g/l Marine water Crustaceans - Crangon crangon 48 hours Acute LC50 4200 mg/l Fresh water Fish - Rasbora heteromorpha 96 hours Propylene Glycol Acute EC50 >110 ppm Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 1020000 ?g/l Fresh water Crustaceans - Ceriodaphnia dubia 48 hours Acute LC50 710000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Light Aliphatic Hydrocarbon Acute LC50 2200 ?g/l Fresh water Fish - Lepomis macrochirus 4 days 2-(2-Methoxyethoxy)-ethanol Acute EC50 >930 ppm Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 7500 ppm Fresh water Fish - Lepomis macrochirus 96 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. :Disposal methods Section 14. Transport information AEROSOLS AEROSOLS UN1950 UN1950 DOT Classification IMDG UN number UN proper shipping name TDG Classification UN1950 AEROSOLS Mexico Classification UN1950 AEROSOLS IATA UN1950 AEROSOLS, flammable Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 13/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Section 14. Transport information 2.1 - 2.1 - - Emergency schedules F-D, S- U Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to IMO instruments No. No. Not available. : Proper shipping name : Not available. : 2.1 - No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.13-2.17 (Class 2). 2.1 - No. - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. 2.1 - No. - 126 ERG No. 126 126 ERG No. ERG No. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Section 15. Regulatory information SARA 313 TSCA 5(a)2 proposed significant new use rules: 2-Methyl-4-isothiazolin-3-one; reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet, where applicable. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 International regulations Montreal Protocol Not listed. Stockholm Convention on Persistent Organic Pollutants Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 14/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Section 15. Regulatory information Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International lists : Not listed. Section 16. Other information 11/18/2024 History Date of printing Date of issue/Date of revision Version Date of previous issue : : : : Key to abbreviations : 11/18/2024 10/2/2024 32 Hazardous Material Information System (U.S.A.) 3 2 3 *Health Flammability Physical hazards Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS? ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS? Personal Protective Equipment (PPE) codes, consult the HMIS? Implementation Manual. FLAMMABLE AEROSOLS - Category 1 On basis of test data GASES UNDER PRESSURE - Compressed gas Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method SKIN SENSITIZATION - Category 1 Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Calculation method Procedure used to derive the classification Classification Justification ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 15/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Indicates information that has changed from previously issued version. Notice to reader N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision : 11/18/2024 Date of previous issue : 10/2/2024 Version : 32 16/16 BAA2010 DUPLI-COLOR? BED ARMOR? (Aerosol) SHW-85-NA-GHS-US