Safety Data Sheet Issue Date: 16-May-2019 Revision Date: 20-May-2019 Version 1 _____________________________________________________________________________________________ Page 1 / 8 1. IDENTIFICATION Product identifier Product Name SPLASH Heavy Duty Degreaser RTU Other means of identification SDS #/Part # 320019-35 Recommended use of the chemical and restrictions on use Recommended Use Cleaner/Degreaser. Details of the supplier of the safety data sheet Manufacturer Address FMP 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 Phone: 888-784-0802 Emergency telephone number Emergency Telephone INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Purple liquid Physical state Liquid Odor None Classification Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1 Signal Word Danger Hazard statements Causes severe skin burns and eye damage Precautionary Statements - Prevention Do not breathe dusts or mists Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection SPLASH-028 - Heavy Duty Degreaser RTU Revision Date: 20-May-2019 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 8 Precautionary Statements - Response Immediately call a POISON CENTER or doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower Wash contaminated clothing before reuse IF INHALED: Remove person to fresh air and keep comfortable for breathing Immediately call a POISON CENTER or doctor IF SWALLOWED: Rinse mouth. Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No Weight-% Potassium hydroxide 1310-58-3 <1 Glycerol 56-81-5 <1 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST AID MEASURES Description of first aid measures General Advice Immediately call a poison center or doctor/physician. Eye Contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. Skin Contact Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician. Ingestion Rinse mouth. Do NOT induce vomiting. Most important symptoms and effects, both acute and delayed Symptoms Causes severe skin burns and eye damage. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. SPLASH-028 - Heavy Duty Degreaser RTU Revision Date: 20-May-2019 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 8 Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Do not breathe dusts or mists. Wash face, hands and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing and eye/face protection. Conditions for safe storage, including any incompatibilities Storage Conditions Store locked up. Incompatible Materials None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Potassium hydroxide 1310-58-3 Ceiling: 2 mg/m3 (vacated) Ceiling: 2 mg/m3 Ceiling: 2 mg/m3 Glycerol 56-81-5 - TWA: 15 mg/m3 mist, total particulate TWA: 5 mg/m3 mist, respirable fraction (vacated) TWA: 10 mg/m3 mist, total particulate (vacated) TWA: 5 mg/m3 mist, respirable fraction - Appropriate engineering controls Engineering Controls Apply technical measures to comply with the occupational exposure limits. Individual protection measures, such as personal protective equipment SPLASH-028 - Heavy Duty Degreaser RTU Revision Date: 20-May-2019 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 8 Eye/Face Protection Refer to 29 CFR 1910.133 for eye and face protection regulations. Skin and Body Protection Refer to 29 CFR 1910.138 for appropriate skin and body protection. Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Purple liquid Odor None Color Purple Odor Threshold Not determined Property Values Remarks ? Method pH 12.7-13.3 Melting point / freezing point Not determined Boiling point / boiling range Not determined Flash point Not determined Evaporation Rate Not determined Flammability (Solid, Gas) Liquid-Not applicable Flammability Limit in Air Upper flammability or explosive limits Not determined Lower flammability or explosive limits Not determined Vapor Pressure Not determined Vapor Density Not determined Relative Density 1.010 Water Solubility Not determined Solubility in other solvents Not determined Partition Coefficient Not determined Autoignition temperature Not determined Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to Avoid Keep out of reach of children. Incompatible materials None known based on information supplied. Hazardous decomposition products None known based on information supplied. SPLASH-028 - Heavy Duty Degreaser RTU Revision Date: 20-May-2019 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 8 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Avoid contact with eyes. Skin Contact Avoid contact with skin. Inhalation Do not inhale. Ingestion Do not ingest. Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Alcohols, C9-11 ethoxylated 68439-46-3 = 1378 mg/kg ( Rat ) = 1400 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) - Potassium hydroxide 1310-58-3 = 284 mg/kg ( Rat ) - - Quaternary Cocoalkylamine Ethoxylate 61791-10-4 = 580 mg/kg ( Rat ) - - Glycerol 56-81-5 = 12600 mg/kg ( Rat ) > 10 g/kg ( Rabbit ) > 570 mg/m3 ( Rat ) 1 h Symptoms related to the physical, chemical and toxicological characteristics Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation Causes severe skin burns. Serious eye damage/eye irritation Causes severe eye damage. Carcinogenicity Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Numerical measures of toxicity Not determined. 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical name Algae/aquatic plants Fish Crustacea Potassium hydroxide 1310-58-3 80: 96 h Gambusia affinis mg/L LC50 static Glycerol 51 - 57: 96 h Oncorhynchus mykiss 500: 24 h Daphnia magna mg/L SPLASH-028 - Heavy Duty Degreaser RTU Revision Date: 20-May-2019 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 8 56-81-5 mL/L LC50 static EC50 Persistence/Degradability Not determined. Bioaccumulation There is no data for this product. Mobility Chemical name Partition coefficient Potassium hydroxide 1310-58-3 0.65 0.83 Glycerol 56-81-5 -1.76 Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status Chemical name California Hazardous Waste Status Potassium hydroxide 1310-58-3 Toxic Corrosive 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT Not regulated IATA Not regulated IMDG Not regulated 15. REGULATORY INFORMATION International Inventories Chemical name TSCA TSCA Inventory Status DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AICS Alcohols, C9-11 ethoxylated X ACTIVE X X X X X Potassium hydroxide X ACTIVE X X X X X X X Quaternary Cocoalkylamine Ethoxylate X ACTIVE X X X X X X Glycerol X ACTIVE X X X X X X X SPLASH-028 - Heavy Duty Degreaser RTU Revision Date: 20-May-2019 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 8 Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA Chemical name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Potassium hydroxide 1310-58-3 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) Chemical name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Potassium hydroxide 1000 lb X US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts Pennsylvania Potassium hydroxide 1310-58-3 X X X Glycerol 56-81-5 X X X SPLASH-028 - Heavy Duty Degreaser RTU Revision Date: 20-May-2019 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 8 16. OTHER INFORMATION NFPA Health Hazards Not determined Flammability Not determined Instability Not determined Special Hazards Not determined HMIS Health Hazards Not determined Flammability Not determined Physical hazards Not determined Personal Protection Not determined Issue Date: 16-May-2019 Revision Date: 20-May-2019 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet A D D ITIO N A L P R O D U C T IN FO R M A TIO N D IS C LO S U R E RTU ?H eavy?D uty?D egreaser?Pressure?W ash?D etergent CA S# R aw ?M aterial Functional?Purpose List?of?Concern Links?to?Lists?of?Concern 7732?18?5 W ater 68439?46?3 C9?11?A lcohol?ethoxylate Surfactant EU ?CM R EU ?Respiratory?Sensitizers https://ec.europa.eu/grow th/sectors/cosm etics/products/cm r?substances_en https://echa.europa.eu/inform ation?on?chem icals/cl?inventory? database?p_p_id=dissclinventory_W A R_dissclinventoryportlet& p_p_lifecycle=0& p_p_state=norm al& p_p_m ode=view & p_p_col_id =colum n?1& p_p_col_pos=1& p_p_col_count=2 1310?58?3 Potassium ?H ydroxide pH ?M odifier EU ?Fragrance?A llergens EU ?Respiratory?Sensitizers EU ?CM R https://ec.europa.eu/health/sites/health/files/endocrine_disruptors/docs/cosm etic_1223_2009_regulation_en.pdf https://echa.europa.eu/inform ation?on?chem icals/cl?inventory? database?p_p_id=dissclinventory_W A R_dissclinventoryportlet& p_p_lifecycle=0& p_p_state=norm al& p_p_m ode=view & p_p_col_id =colum n?1& p_p_col_pos=1& p_p_col_count=2 https://ec.europa.eu/grow th/sectors/cosm etics/products/cm r?substances_en 61791?10?4 Q uaternary?coco?alkylam ine?ethoxylate Surfactant EU ?CM R https://ec.europa.eu/grow th/sectors/cosm etics/products/cm r?substances_en 56?81?5 G lycerin Surfactant EU ?CM R EU ?Respiratory?Sensitizers https://ec.europa.eu/grow th/sectors/cosm etics/products/cm r?substances_en https://echa.europa.eu/inform ation?on?chem icals/cl?inventory? database?p_p_id=dissclinventory_W A R_dissclinventoryportlet& p_p_lifecycle=0& p_p_state=norm al& p_p_m ode=view & p_p_col_id =colum n?1& p_p_col_pos=1& p_p_col_count=2 22473?78?5 Tetram m onium ?salt?of?ethylenediam inetetraacetic?acid Chelator EU ?Respiratory?Sensitizers https://echa.europa.eu/inform ation?on?chem icals/cl?inventory? database?p_p_id=dissclinventory_W A R_dissclinventoryportlet& p_p_lifecycle =0& p_p_state=norm al& p_p_m ode=view & p_p_col_id=colum n?1& p_p_col_pos=1& p_p_col_count=2 1116737* D YE???L83022?LIQ U ITIN T?RED ?ST D ye 1115323* D YE???L85015?LIQ U ITIN T?BLU E?H P D ye *W ERKS?N U M BER https://leginfo.legislature.ca.gov/faces/billN avClient.xhtm l?bill_id=201720180SB258