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234633 SPLASH DeIcer Aerosol with Scraper
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234633_SPLASH_DE-ICER_with_SCRAPER_SDS.pdf
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SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Issue date: 07/14/2023 Revision date: 07/14/2023 Version: 1.0 14/07/2023 EN (English US) 1/12 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Product code : 234633 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : De-Icer 1.3. Details of the supplier of the safety data sheet Factory Motor Parts 1380 Corporate center Curve Ste. 200 Eagan, MN 55121 T 651-454-4100 1.4. Emergency telephone number Emergency number : INFOTRAC: 1-800-535-5053 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS US classification Flammable aerosol Category 2 H223 Flammable aerosol Gases under pressure Compressed gas H280 Contains gas under pressure; may explode if heated Acute toxicity (oral) Category 3 H301 Toxic if swallowed Acute toxicity (dermal) Category 3 H311 Toxic in contact with skin Germ cell mutagenicity Category 1B H340 May cause genetic defects Carcinogenicity Category 1A H350 May cause cancer Specific target organ toxicity (single exposure) Category 1 H370 Causes damage to organs Full text of H- and EUH-statements: see section 16 2.2. Label elements GHS US labeling Hazard pictograms (GHS US) : Signal word (GHS US) : Danger Hazard statements (GHS US) : H223 - Flammable aerosol H280 - Contains gas under pressure; may explode if heated H301+H311 - Toxic if swallowed or in contact with skin H340 - May cause genetic defects H350 - May cause cancer H370 - Causes damage to organs Precautionary statements (GHS US) : P201 - Obtain special instructions P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 - Do not spray on an open flame or other ignition source. P251 - Pressurized container: Do not pierce or burn, even after use. P260 - Do not breathe dust,fumes,gas,mist,vapor spray P264 - Wash affected areas thoroughly after handling P270 - Do not eat, drink or smoke when using this product. P280 - Wear protective gloves,protective clothing,eye protection,face protection P301+P310 - If swallowed: Immediately call a poison control center, doctor,physician, P302+P352 - If on skin: Wash with plenty of soap and water P307+P311 - If exposed: Call a poison center/doctor. P308+P313 - If exposed or concerned: Get medical advice/attention. P312 - Call a POISON CONTROL CENTER, doctor, if you feel unwell. P321 - Specific treatment: See section 4.1 on SDS P322 - Specific treatment (see supplemental first aid instruction on this label) P330 - Rinse mouth. P361+P364 - Take off immediately all contaminated clothing and wash it before reuse. P405 - Store locked up. P410+P403 - Protect from sunlight. Store in a well-ventilated place. P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 14/07/2023 EN (English US) 2/12 P501 - Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. 2.3. Other hazards Other hazards which do not result in classification : Contains gas under pressure; may explode if heated. None under normal conditions. 2.4. Unknown acute toxicity (GHS US) No data available SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS US classification Methanol (CAS-No.) 67-56-1 50 ? 70 Flam. Liq. 2, H225 STOT SE 1, H370 Petroleum Gases, Liquefied, Sweetened (CAS-No.) 68476-86-8 10 ? 30 Flam. Gas 1, H220 Press. Gas (Comp.), H280 Muta. 1B, H340 Carc. 1A, H350 Water (CAS-No.) 7732-18-5 10 ? 30 Not classified Ethylene Glycol (CAS-No.) 107-21-1 1 ? 5 Acute Tox. 1 (Oral), H300 Acute Tox. 4 (Inhalation:vapour), H332 2-Aminoethanol (CAS-No.) 141-43-5 ? 0.071 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Corr. 1, H314 Sodium-2(3H)-Benzothiazolethione, Conc=50%, Aqueous Solution (CAS-No.) 2492-26-4 0.041 ? 0.043 Met. Corr. 1, H290 Skin Corr. 1A, H314 Skin Sens. 1, H317 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : IF exposed or concerned: Get medical advice/attention. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Call a POISON CENTER or doctor/physician. First-aid measures after inhalation : Cough. Remove victim to fresh air and keep at rest in a position comfortable for breathing. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Immediately call a poison center or doctor/physician. Wash with plenty of soap and water. Wash contaminated clothing before reuse. First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. Direct contact with the eyes is likely to be irritating. Immediately call a poison center or doctor/physician. Obtain medical attention if pain, blinking or redness persists. First-aid measures after ingestion : Immediately call a poison center or doctor/physician. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects : Causes damage to organs. Symptoms/effects after inhalation : Shortness of breath. Symptoms/effects after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Symptoms/effects after eye contact : May cause slight eye irritation . Inflammation/damage of the eye tissue. Irritation of the eye tissue. Redness of the eye tissue. Symptoms/effects after ingestion : Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 14/07/2023 EN (English US) 3/12 5.2. Special hazards arising from the substance or mixture Fire hazard : Highly flammable liquid and vapor. Flammable aerosol. Explosion hazard : May form flammable/explosive vapor-air mixture. Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. DO NOT fight fire when fire reaches explosives. Evacuate area. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Other information : Aerosol Level 2. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : No open flames. No smoking. Isolate from fire, if possible, without unnecessary risk. Remove ignition sources. Use special care to avoid static electric charges. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Safety glasses. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Avoid breathing dust,fume,gas,mist,vapor spray. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released product, collect/pump into suitable containers. Plug the leak, cut off the supply. Methods for cleaning up : Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Hazardous waste due to potential risk of explosion. Pressurized container: Do not pierce or burn, even after use. Precautions for safe handling : No open flames. No smoking. Use only non-sparking tools. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Do not spray on an open flame or other ignition source. Do not breathe dust,fumes,gas,mist,vapor spray. Hygiene measures : Wash contaminated clothing before reuse. Always wash hands after handling the product. Remove contaminated clothes. Separate working clothes from town clothes. Launder separately. Take off immediately all contaminated clothing and wash it before reuse. Observe normal hygiene standards. Keep container tightly closed. Do not eat, drink or smoke when using this product. Wash affected areas thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating, lighting equipment. Proper grounding procedures to avoid static electricity should be followed. Storage conditions : Keep container tightly closed. Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Do not expose to temperatures exceeding 50 ?C/ 122 ?F. Keep in fireproof place. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. Storage area : Store in a well-ventilated place. 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. No additional information available SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 14/07/2023 EN (English US) 4/12 Ethylene Glycol (107-21-1) USA - ACGIH - Occupational Exposure Limits ACGIH OEL TWA [ppm] 25 ppm (Vapor fraction) ACGIH OEL STEL 10 mg/m? (Inhalable fraction, Aerosol only) ACGIH OEL STEL [ppm] 50 ppm (Vapor fraction) Water (7732-18-5) No additional information available Sodium-2(3H)-Benzothiazolethione, Conc=50%, Aqueous Solution (2492-26-4) No additional information available 2-Aminoethanol (141-43-5) USA - ACGIH - Occupational Exposure Limits ACGIH OEL TWA [ppm] 3 ppm ACGIH OEL STEL [ppm] 6 ppm Petroleum Gases, Liquefied, Sweetened (68476-86-8) USA - ACGIH - Occupational Exposure Limits ACGIH OEL TWA [ppm] 1000 ppm Listed under Aliphatic hydrocarbon gases alkane C1-C4 USA - OSHA - Occupational Exposure Limits OSHA PEL (TWA) [1] 1800 mg/m? OSHA PEL (TWA) [2] 1000 ppm USA - NIOSH - Occupational Exposure Limits NIOSH REL (TWA) 1800 mg/m? NIOSH REL TWA [ppm] 1000 ppm Methanol (67-56-1) USA - ACGIH - Occupational Exposure Limits ACGIH OEL TWA 262 mg/m? ACGIH OEL TWA [ppm] 200 ppm ACGIH OEL STEL 328 mg/m? ACGIH OEL STEL [ppm] 250 ppm USA - OSHA - Occupational Exposure Limits OSHA PEL (TWA) [1] 260 mg/m? OSHA PEL (TWA) [2] 200 ppm USA - NIOSH - Occupational Exposure Limits NIOSH REL (TWA) 260 mg/m? NIOSH REL TWA [ppm] 200 ppm NIOSH REL (Ceiling) 325 mg/m? NIOSH REL C [ppm] 250 ppm 8.2. Appropriate engineering controls Appropriate engineering controls : Local exhaust venilation, vent hoods . Ensure good ventilation of the work station. Environmental exposure controls : Avoid release to the environment. 8.3. Individual protection measures/Personal protective equipment Personal protective equipment: Gloves. Safety glasses. Avoid all unnecessary exposure. Materials for protective clothing: Excellent resistance: Hand protection: Wear protective gloves Eye protection: Chemical goggles or safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: Where exposure through inhalation may occur from use, respiratory protection equipment is recommended SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 14/07/2023 EN (English US) 5/12 Personal protective equipment symbol(s): Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas Appearance : Liquid. Color : Colourless to light yellow. Odor : Mild . Sweet. Alcohol odour. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : 65 ?C (Lowest Component) Flash point : -96.23 ?C (Lowest Component) Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability : No data available Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : 0.85 Solubility : Soluble in alcohols. Soluble in water. Partition coefficient n-octanol/water (Log Pow) : No data available Partition coefficient n-octanol/water (Log Kow) : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosion limits : No data available 9.2. Other information VOC content : 84.9 % Gas group : Compressed gas SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Highly flammable liquid and vapor. May form flammable/explosive vapor-air mixture. Flammable aerosol. Contains gas under pressure; may explode if heated. Extreme risk of explosion by shock, friction, fire or other sources of ignition. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Open flame. Overheating. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products May release flammable gases. Toxic fume. . Carbon monoxide. Carbon dioxide. SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 14/07/2023 EN (English US) 6/12 SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity (oral) : Toxic if swallowed. Acute toxicity (dermal) : Toxic in contact with skin. Acute toxicity (inhalation) : Not classified ATE US (oral) 100 mg/kg body weight ATE US (dermal) 300 mg/kg body weight Ethylene Glycol (107-21-1) LD50 oral rat 7712 mg/kg body weight LD50 dermal rat > 3500 mg/kg body weight LC50 Inhalation - Rat > 2.5 mg/l 6 Hour by Air ATE US (oral) 0.5 mg/kg body weight ATE US (vapors) 11 mg/l/4h Sodium-2(3H)-Benzothiazolethione, Conc=50%, Aqueous Solution (2492-26-4) LD50 oral rat 5200 mg/kg LD50 dermal rabbit 5010 mg/kg ATE US (oral) 5200 mg/kg body weight ATE US (dermal) 5010 mg/kg body weight 2-Aminoethanol (141-43-5) LD50 oral rat 1089 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Male / female, Experimental value, Oral, 14 day(s)) LD50 dermal rabbit 1018 mg/kg (24 h, Rabbit, Inconclusive, insufficient data, Dermal) LC50 Inhalation - Rat > 1.3 mg/l air (6 h, Rat, Male / female, Experimental value, (maximum achievable concentration), Inhalation (vapours)) ATE US (oral) 1089 mg/kg body weight ATE US (dermal) 1018 mg/kg body weight ATE US (dust, mist) 1.5 mg/l/4h Methanol (67-56-1) LD50 oral rat ? 2528 mg/kg body weight application as 50% aqueous solution LD50 dermal rabbit 17100 mg/kg corresponding to 20 ml/kg bw according to the authors LC50 Inhalation - Rat 128.2 mg/l/4h Air ATE US (dermal) 17100 mg/kg body weight ATE US (vapors) 128.2 mg/l/4h ATE US (dust, mist) 128.2 mg/l/4h Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : May cause genetic defects. Carcinogenicity : May cause cancer. Reproductive toxicity : Not classified STOT-single exposure : Causes damage to organs. Methanol (67-56-1) STOT-single exposure Causes damage to organs. STOT-repeated exposure : Not classified Aspiration hazard : Not classified Viscosity, kinematic : No data available Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Toxic if swallowed. Toxic in contact with skin. Symptoms/effects : Causes damage to organs. Symptoms/effects after inhalation : Shortness of breath. Symptoms/effects after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Symptoms/effects after eye contact : May cause slight eye irritation . Inflammation/damage of the eye tissue. Irritation of the eye tissue. Redness of the eye tissue. SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 14/07/2023 EN (English US) 7/12 Symptoms/effects after ingestion : Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. SECTION 12: Ecological information 12.1. Toxicity Ethylene Glycol (107-21-1) LC50 - Fish [1] > 72860 mg/l (EPA 600/4-90/027, 96 h, Pimephales promelas, Static system, Fresh water, Experimental value, Nominal concentration) EC50 - Crustacea [1] > 100 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, Daphnia magna, Static system, Fresh water, Experimental value) 2-Aminoethanol (141-43-5) LC50 - Fish [1] 349 mg/l (EU Method C.1, 96 h, Cyprinus carpio, Semi-static system, Fresh water, Experimental value, GLP) EC50 - Crustacea [1] 27 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static system, Fresh water, Experimental value, Nominal concentration) ErC50 algae 2.8 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh water, Experimental value, GLP) Methanol (67-56-1) LC50 - Fish [1] 15400 mg/l (EPA 660/3 - 75/009, 96 h, Lepomis macrochirus, Flow-through system, Fresh water, Experimental value, Lethal) EC50 - Crustacea [1] 18260 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 96 h, Daphnia magna, Semi- static system, Fresh water, Experimental value, Locomotor effect) 12.2. Persistence and degradability SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Persistence and degradability Not established. Ethylene Glycol (107-21-1) Persistence and degradability Readily biodegradable in the soil. Readily biodegradable in water. Biochemical oxygen demand (BOD) 0.47 g O?/g substance Chemical oxygen demand (COD) 1.24 g O?/g substance ThOD 1.29 g O?/g substance Water (7732-18-5) Persistence and degradability Not established. Sodium-2(3H)-Benzothiazolethione, Conc=50%, Aqueous Solution (2492-26-4) Persistence and degradability Not established. 2-Aminoethanol (141-43-5) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Not established. Biochemical oxygen demand (BOD) 0.8 g O?/g substance Chemical oxygen demand (COD) 1.34 g O?/g substance ThOD 2.49 g O?/g substance Petroleum Gases, Liquefied, Sweetened (68476-86-8) Persistence and degradability Not established. Methanol (67-56-1) Persistence and degradability Readily biodegradable in the soil. Readily biodegradable in water. Not established. Biochemical oxygen demand (BOD) 0.6 ? 1.12 g O?/g substance Chemical oxygen demand (COD) 1.42 g O?/g substance ThOD 1.5 g O?/g substance 12.3. Bioaccumulative potential SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Bioaccumulative potential Not established. Ethylene Glycol (107-21-1) Partition coefficient n-octanol/water (Log Pow) -1.36 (Experimental value) Bioaccumulative potential Not bioaccumulative. Water (7732-18-5) Bioaccumulative potential Not established. Sodium-2(3H)-Benzothiazolethione, Conc=50%, Aqueous Solution (2492-26-4) Partition coefficient n-octanol/water (Log Pow) -0.46 Bioaccumulative potential Not bioaccumulative. SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 14/07/2023 EN (English US) 8/12 2-Aminoethanol (141-43-5) Partition coefficient n-octanol/water (Log Pow) -2.3 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method, 25 ?C) Bioaccumulative potential Bioaccumulation: not applicable. Not established. Petroleum Gases, Liquefied, Sweetened (68476-86-8) Bioaccumulative potential Not established. Methanol (67-56-1) BCF - Fish [1] 1 ? 4.5 (72 h, Cyprinus carpio, Static system, Fresh water, Experimental value) Partition coefficient n-octanol/water (Log Pow) -0.77 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established. 12.4. Mobility in soil Ethylene Glycol (107-21-1) Surface tension 48.4 mN/m (20 ?C) Organic Carbon Normalized Adsorption Coefficient (Log Koc) 0 (log Koc, SRC PCKOCWIN v2.0, QSAR) Ecology - soil Highly mobile in soil. Sodium-2(3H)-Benzothiazolethione, Conc=50%, Aqueous Solution (2492-26-4) Ecology - soil No (test)data on mobility of the component(s) available. 2-Aminoethanol (141-43-5) Surface tension No data available in the literature Organic Carbon Normalized Adsorption Coefficient (Log Koc) 1.16 (log Koc, Calculated value) Ecology - soil Highly mobile in soil. Methanol (67-56-1) Surface tension No data available in the literature Organic Carbon Normalized Adsorption Coefficient (Log Koc) -0.89 ? -0.21 (log Koc, Calculated value) Ecology - soil Highly mobile in soil. 12.5. Other adverse effects Effect on global warming : No known effects from this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Container under pressure. Do not drill or burn even after use. Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. Additional information : Handle empty containers with care because residual vapors are flammable. Flammable vapors may accumulate in the container. Ecology - waste materials : Avoid release to the environment. Hazardous waste due to toxicity. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT US DOT (ground) (DOT) : UN1950 Aerosols (Flammable, (each not exceeding 1 L capacity)), 2.1 UN-No.(DOT) : UN1950 Proper Shipping Name (DOT) : Aerosols Flammable, (each not exceeding 1 L capacity) Class (DOT) : 2.1 - Class 2.1 - Flammable gas 49 CFR 173.115 DOT Packaging Non Bulk (49 CFR 173.xxx) : None DOT Packaging Bulk (49 CFR 173.xxx) : None DOT Special Provisions (49 CFR 172.102) : N82 - See 173.306 of this subchapter for classification criteria for flammable aerosols. DOT Packaging Exceptions (49 CFR 173.xxx) : 306 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 75 kg DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 150 kg SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 14/07/2023 EN (English US) 9/12 DOT Vessel Stowage Location : A - The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel. DOT Vessel Stowage Other : 48 - Stow ??away from?? sources of heat,87 - Stow ??separated from?? Class 1 (explosives) except Division 14,126 - Segregation same as for Class 9, miscellaneous hazardous materials Other information : No supplementary information available. Transport by sea UN-No. (IMDG) : 1950 Proper Shipping Name (IMDG) : Aerosols Class (IMDG) : 2.1 - Flammable gases Air transport UN-No. (IATA) : 1950 Proper Shipping Name (IATA) : Aerosols Class (IATA) : 2.1 - Gases : Flammable Packing group (IATA) : III - Minor Danger SECTION 15: Regulatory information 15.1. US Federal regulations SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Fire hazard Immediate (acute) health hazard Sudden release of pressure hazard Ethylene Glycol (107-21-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 CERCLA RQ 5000 lb SARA Section 311/312 Hazard Classes Immediate (acute) health hazard SARA Section 313 - Emission Reporting 1 % Water (7732-18-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Sodium-2(3H)-Benzothiazolethione, Conc=50%, Aqueous Solution (2492-26-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard 2-Aminoethanol (141-43-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Petroleum Gases, Liquefied, Sweetened (68476-86-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Fire hazard Sudden release of pressure hazard Methanol (67-56-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 CERCLA RQ 5000 lb SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Fire hazard SARA Section 313 - Emission Reporting 1 % 15.2. International regulations CANADA SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. WHMIS Classification Class B Division 5 - Flammable Aerosol SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 14/07/2023 EN (English US) 10/12 Ethylene Glycol (107-21-1) Listed on the Canadian DSL (Domestic Substances List) Water (7732-18-5) Listed on the Canadian DSL (Domestic Substances List) Sodium-2(3H)-Benzothiazolethione, Conc=50%, Aqueous Solution (2492-26-4) Listed on the Canadian DSL (Domestic Substances List) 2-Aminoethanol (141-43-5) Listed on the Canadian DSL (Domestic Substances List) Petroleum Gases, Liquefied, Sweetened (68476-86-8) Listed on the Canadian DSL (Domestic Substances List) Methanol (67-56-1) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects EU-Regulations Water (7732-18-5) Sodium-2(3H)-Benzothiazolethione, Conc=50%, Aqueous Solution (2492-26-4) 2-Aminoethanol (141-43-5) Petroleum Gases, Liquefied, Sweetened (68476-86-8) Methanol (67-56-1) Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] 15.2.2. National regulations Ethylene Glycol (107-21-1) Listed on EPA Hazardous Air Pollutant (HAPS) Water (7732-18-5) Sodium-2(3H)-Benzothiazolethione, Conc=50%, Aqueous Solution (2492-26-4) 2-Aminoethanol (141-43-5) Petroleum Gases, Liquefied, Sweetened (68476-86-8) Methanol (67-56-1) Listed on EPA Hazardous Air Pollutant (HAPS) 15.3. US State regulations SPLASH DE-ICER WITH SCRAPER CAP 11 OZ.() U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No State or local regulations U.S. - California - Proposition 65 Ethylene Glycol (107-21-1) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No Yes No No SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 14/07/2023 EN (English US) 11/12 Water (7732-18-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No No No No Sodium-2(3H)-Benzothiazolethione, Conc=50%, Aqueous Solution (2492-26-4) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No No No No 2-Aminoethanol (141-43-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No No No No Petroleum Gases, Liquefied, Sweetened (68476-86-8) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No No No No Methanol (67-56-1) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No Yes No No Ethylene Glycol (107-21-1) State or local regulations U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. ? New York City ? Right to Know Hazardous Substances List U.S. - Pennsylvania - RTK (Right to Know) List 2-Aminoethanol (141-43-5) State or local regulations U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. ? New York City ? Right to Know Hazardous Substances List U.S. - Pennsylvania - RTK (Right to Know) List Methanol (67-56-1) State or local regulations U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. ? New York City ? Right to Know Hazardous Substances List SECTION 16: Other information Other information : None. Full text of H-phrases: ------ H220 Extremely flammable gas ------ H223 Flammable aerosol ------ H225 Highly flammable liquid and vapor ------ H280 Contains gas under pressure; may explode if heated ------ H290 May be corrosive to metals SPLASH DE-ICER WITH SCRAPER CAP 11 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 14/07/2023 EN (English US) 12/12 ------ H300 Fatal if swallowed ------ H301 Toxic if swallowed ------ H302 Harmful if swallowed ------ H311 Toxic in contact with skin ------ H312 Harmful in contact with skin ------ H314 Causes severe skin burns and eye damage ------ H317 May cause an allergic skin reaction ------ H332 Harmful if inhaled ------ H340 May cause genetic defects ------ H350 May cause cancer ------ H370 Causes damage to organs NFPA health hazard : 2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury. NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions. NFPA reactivity : 0 - Material that in themselves are normally stable, even under fire conditions. Hazard Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 3 Serious Hazard Physical : 1 Slight Hazard Personal protection : B The Supplier identified in Section 1 of this SDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied. Published by Ruben Morales