Safety Data Sheet Issue Date: 06-May-2025 Revision Date: 06-May-2025 Version 1 Page 1 / 8 1. IDENTIFICATION Product identifier Product Name Circle K Global 50/50 4/1 Gal Other means of identification SDS # SPLASH-069 Product Code 700670 Recommended use of the chemical and restrictions on use Recommended Use For industrial use. Details of the supplier of the safety data sheet Manufacturer Address FMP 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 Phone: 888-784-0802 Emergency telephone number Emergency Telephone INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Physical state Liquid Classification Acute toxicity - Oral Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Reproductive toxicity Category 1B Signal word Danger Hazard statements Harmful if swallowed Harmful if inhaled May damage fertility or the unborn child SPLASH-069 - Circle K Global 50/50 4/1 Gal Revision Date: 06-May-2025 Page 2 / 8 Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Wear protective gloves/clothing and eye/face protection Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF INHALED: Remove person to fresh air and keep comfortable for breathing IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell Rinse mouth Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No. Weight-% ethane-1,2-diol 107-21-1 30-60 Potassium 2?ethylhexanoate 3164-85-0 1-5 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST AID MEASURES Description of first aid measures General Advice If exposed or concerned: Get medical advice/attention. Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Inhalation Remove person to fresh air and keep comfortable for breathing. Ingestion Call a poison center or doctor/physician if you feel unwell. Rinse mouth. Most important symptoms and effects, both acute and delayed Symptoms Harmful if swallowed. Harmful if inhaled. May damage fertility or the unborn child. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. SPLASH-069 - Circle K Global 50/50 4/1 Gal Revision Date: 06-May-2025 Page 3 / 8 Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing and eye/face protection. Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Conditions for safe storage, including any incompatibilities Storage Conditions Store locked up. Incompatible Materials None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH ethane-1,2-diol 107-21-1 STEL: 50 ppm vapor fraction STEL: 10 mg/m3 inhalable particulate matter, aerosol only TWA: 25 ppm vapor fraction - - Appropriate engineering controls Engineering Controls Apply technical measures to comply with the occupational exposure limits. SPLASH-069 - Circle K Global 50/50 4/1 Gal Revision Date: 06-May-2025 Page 4 / 8 Individual protection measures, such as personal protective equipment Eye/Face Protection Refer to 29 CFR 1910.133 for eye and face protection regulations. Skin and Body Protection Refer to 29 CFR 1910.138 for appropriate skin and body protection. Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Not determined Odor Not determined Color Yellow Odor Threshold Not determined Property Values Remarks ? Method pH No data available Melting point / freezing point No data available Initial boiling point and boiling range No data available Flash point No data available Evaporation rate Not determined Flammability (Solid, Gas) Not determined Flammability Limit in Air Upper flammability or explosive limits No data available Lower flammability or explosive limits No data available Vapor Pressure Not determined Relative vapor density No data available Relative Density Not determined Water Solubility Not determined Solubility in other solvents Not determined Partition Coefficient Not determined Autoignition temperature No data available Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to Avoid Keep out of reach of children. SPLASH-069 - Circle K Global 50/50 4/1 Gal Revision Date: 06-May-2025 Page 5 / 8 Incompatible materials None known based on information supplied. Hazardous decomposition products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Avoid contact with eyes. Skin Contact Avoid contact with skin. Inhalation Harmful if inhaled. Ingestion Harmful if swallowed. Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 ethane-1,2-diol 107-21-1 = 4700 mg/kg ( Rat ) = 10600 mg/kg ( Rat ) > 2.5 mg/L ( Rat ) 6 h Symptoms related to the physical, chemical and toxicological characteristics Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Carcinogenic potential is unknown. Reproductive toxicity May damage fertility or the unborn child. Numerical measures of toxicity The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 1,000.00 mg/kg ATEmix (dermal) 21,200.00 mg/kg ATEmix (inhalation-dust/mist) 3.00 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. SPLASH-069 - Circle K Global 50/50 4/1 Gal Revision Date: 06-May-2025 Page 6 / 8 Component Information Chemical name Algae/aquatic plants Fish Crustacea ethane-1,2-diol 107-21-1 EC50: 6500 - 13000mg/L (96h, Pseudokirchneriella subcapitata) LC50: =41000mg/L (96h, Oncorhynchus mykiss) LC50: 14 - 18mL/L (96h, Oncorhynchus mykiss) LC50: =27540mg/L (96h, Lepomis macrochirus) LC50: =40761mg/L (96h, Oncorhynchus mykiss) LC50: 40000 - 60000mg/L (96h, Pimephales promelas) LC50: =16000mg/L (96h, Poecilia reticulata) EC50: =46300mg/L (48h, Daphnia magna) Persistence/Degradability Not determined. Bioaccumulation There is no data for this product. Mobility Chemical name Partition coefficient ethane-1,2-diol 107-21-1 -1.36 Other adverse effects Not determined 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT Not regulated IATA Not regulated IMDG Not regulated 15. REGULATORY INFORMATION International Inventories Chemical name TSCA TSCA Inventory Status DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AIIC ethane-1,2-diol X ACTIVE X X X X X X X SPLASH-069 - Circle K Global 50/50 4/1 Gal Revision Date: 06-May-2025 Page 7 / 8 Chemical name TSCA TSCA Inventory Status DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AIIC Potassium 2?ethylhexanoate X ACTIVE X X X X X X X Potassium Tolyltriazole X X X X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing Chemicals Inventory PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical name Hazardous Substances RQs Extremely Hazardous Substances RQs Reportable Quantity (RQ) ethane-1,2-diol 107-21-1 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical name CAS No. Weight-% SARA 313 - Threshold Values % ethane-1,2-diol - 107-21-1 107-21-1 30-60 1.0 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals: Chemical name California Proposition 65 ethane-1,2-diol - 107-21-1 Developmental U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts Pennsylvania ethane-1,2-diol 107-21-1 X X X SPLASH-069 - Circle K Global 50/50 4/1 Gal Revision Date: 06-May-2025 Page 8 / 8 16. OTHER INFORMATION NFPA Health hazards - Flammability - Instability - Special hazards - HMIS Health hazards - Flammability - Physical hazards - Personal Protection Not determined Issue Date: 06-May-2025 Revision Date: 06-May-2025 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet