Page 1 of 9 Safety Data Sheet Section 1: Identification Product Identifier Concentrated Dye Solution Product Name Trade Name: SPLASH On Tap 5 Gal. Solution PN (Part number): 234005-PRP Relevant identified uses of the substance or mixture and uses advised against -Material for industrial applications -Industrial and professional use -Consumer end use Details of the supplier of the safety data sheet Manufacturer SPLASH Products 51 E. Maryland Ave. St. Paul, MN 55117 Phone: (651) 489-8211 Emergency telephone number 1-800-535-5053 Section 2: Hazard(s) Identification OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture Acute toxicity, Oral Category 5 Acute toxicity, Inhalation Category 5 Serious eye damage/eye irritation, Mild Irritant 2B Specific Target Organ Toxicity (STOT) following single exposure, Category 3 GHS label elements Hazard pictograms Signal word-WARNING Page 2 of 9 Hazard statements May be harmful if swallowed May be harmful if inhaled Causes eye irritation May cause drowsiness or dizziness Precautionary statements Prevention Do not breathe mist/fume/gas/vapors/spray Wash hands thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. Take off contaminated clothing and wash before use Store away from heat and ignition sources Keep away from oxidizing materials and strong acids Response IF SWALLOWED: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Rinse mouth. If large quantities of this material are swallowed, call a physician or poison center immediately. Loosen tight clothing such as a collar, tie, belt or waistband. IF ON SKIN (or hair): Wash with soap and water. Get medical attention if irritation develops. Cold water may be used. IF IN EYES: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. Cold water may be used. Get medical attention immediately. IF EXPOSED or CONCERNED: Immediately call a POISON CENTER or a doctor/physician. Storage Store in a well-ventilated place. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified Product is stable. Section 3: Composition/Information on Ingredients Substance/mixture: Mixture Chemical name: N/A Other means of identification: No CAS number/other identifiers Ingredient name % CAS number Nonylphenol polyethylene glycol ether <1 127087-87-0 Ethylene Glycol <1 107-21-1 Section 4: First Aid Measurements Description of necessary first aid measures Eye contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. Cold water may be used. Get medical attention immediately. Inhalation: Bring accident victims out into the fresh air. Call a physician immediately in severe cases or if recovery is not rapid. Page 3 of 9 Skin contact: After contact with skin, wash immediately with plenty of water. Remove contaminated clothing and wash before reuse. Ingestion: DO NOT DELAY. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If victim is alert, rinse mouth and drink 1/2 to 1 glass of water to help dilute the material. Transport to nearest medical facility for additional treatment. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact Splashes may cause irritation, pain, eye damage. Inhalation Vapor inhalation is generally not a problem unless heated or misted. Exposure to vapors over an extended time period has caused throat irritation and headache. May cause nausea, vomiting, dizziness and drowsiness. Pulmonary edema and central nervous system depression may also develop. When heated or misted, has produced rapid, involuntary eye movement and coma. Skin contact Irritation, itching, dermatitis. Ingestion Initial symptoms in massive dosage parallel alcohol intoxication, progressing to CNS depression, vomiting, headache, rapid respiratory and heart rate, lowered blood pressure, stupor, collapse, and unconsciousness with convulsions. Death from respiratory arrest or cardiovascular collapse may follow. Lethal dose in humans: 100 ml (3-4 ounces pure ethylene glycol). Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Kidney toxicity may be recognized by blood in the urine or increased or decreased urine flow. Other signs and symptoms can include nausea, vomiting, abdominal cramps, and diarrhea, lumbar pain shortly after ingestion, and possibly narcosis and death. Eye irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blurred vision. Skin irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blisters. Respiratory irritation signs and symptoms may include a temporary burning sensation of the nose and throat, coughing, and/or difficulty breathing. Specific treatments IMMEDIATE TREATMENT IS EXTREMELY IMPORTANT! May cause significant renal, respiratory, and CNS toxicity. May cause significant acidosis. Call a doctor or poison control center for guidance. Protection of first-aiders N/A See toxicological information (Section 11) Section 5: Fire Fighting Measures Extinguishing media Suitable extinguishing media SMALL FIRE: Use DRY chemical powder, CO2 or appropriate foam. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Unsuitable extinguishing media Do not use direct water stream. May spread fire. Specific hazards arising from the chemical Material will not burn unless preheated. Closed containers exposed to heat may explode. Hazardous thermal decomposition products/Products of combustion Products of combustion are carbon oxides (CO, CO2). Page 4 of 9 Special protective actions for fire fighters Do not release runoff from fire control methods to sewers or waterways. Special protective equipment for fire-fighters In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Section 6: Accidental Release Measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Environmental precautions Methods and materials for containment and cleaning up: Exposure to the spilled material may be severely irritating or toxic. Follow personal protective equipment recommendations found in Section 8 of this SDS. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including: the material spilled, the quantity of the spill, the area in which the spill occurred, and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. Section 7: Handling and Storage Precautions for safe handling Protective measures, advice on general occupational hygiene and conditions for safe storage, including any incompatibilities: Use local exhaust extraction over processing area. Handle and open container with care in a well-ventilated area. Do not empty into drains. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Handling Temperature: Ambient; 60 ?C maximum. Avoid breathing vapors or contact with material. Only use in well ventilated areas. Wash thoroughly after handling. On guidance on selection of personal protective equipment see Chapter 8 of this Safety Data Sheet. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Store in a well-ventilated area. Keep cool. Section 8: Exposure Controls/Personal Protection Control parameters Occupational exposure limits Ingredient name Exposure limits Nonylphenol polyethylene glycol ether ACGIH OSHA (TWA) (STEL) (TWA) (STEL) 10 mg/m3 N/A 10 mg/m 3 N/A Ethylene Glycol ACGIH OSHA (TWA) (STEL) (TWA) (STEL) 100 ppm N/A 100 ppm N/A Appropriate engineering controls and Environmental exposure controls A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, Page 5 of 9 preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Individual protection measures Hygiene measures Wash hands before eating, drinking, smoking and using the toilet. Launder contaminated clothing before re-use. Eye/face protection: Use chemical safety goggles. Skin protection Hand protection and Body protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Other skin protection Wash hands and other exposed areas with mild soap and water before eating or drinking. Respiratory protection: No respiratory protection required under normal circumstances. Respirator Type(s) (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full face piece particulate respirator (NIOSH type N100 filter) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, Glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in Oxygen- deficient atmospheres. Section 9: Physical and Chemical Properties Appearance Physical state: Purple liquid Odor: None Odor threshold: Not Determined pH: 7.0 Specific Gravity: 1.0 Melting point: Not Determined Boiling point: Not Determined Flash point: Not Determined Evaporation rate (BuAc=1): Not Determined Flammability (solid, gas): No Lower and upper explosive (flammable) limits: LEL 7%, UEL 28% (Ethylene Glycol) Vapor pressure: Not Determined Vapor density (Air=1): Not Determined Solubility: Soluble in water Partition coefficient: n-octanol/water: Not Established Auto-ignition temperature: Not Applicable Decomposition temperature: Not Established Viscosity: Not determined VOC%: 0 Section 10: Stability and Reactivity Reactivity Stable under recommended storage conditions. Page 6 of 9 Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions Will not occur. Conditions to avoid High temperature. Incompatible materials Strong oxidizing agents Hazardous decomposition products Will not occur. Section 11: Toxicological Information Information on toxicological effects Acute toxicity Product/ingredient name Test Results Nonylphenol polyethylene glycol ether Acute toxicity, oral (male rat) LD50 = 960 mg/kg Acute toxicity, dermal LD50 = 2,000 mg/kg Acute toxicity, inhalation (rat, dust/mist) LC50: 1.15 mg/L 4.00 Hours Ethylene Glycol Acute toxicity, oral (male rat) LD50 = 4,700 mg/kg Acute toxicity, dermal LD50 = 10,626 mg/kg Acute toxicity, inhalation (rat) No Data Available Summary Comments: Sensitization Product/ingredient name Test Results Basis Nonylphenol polyethylene glycol ether No evidence of sensitization effect Ethylene Glycol No evidence of sensitization effect Summary Comments: Carcinogenicity Product/ingredient name Test Results Basis Nonylphenol polyethylene glycol ether No known carcinogenic effects Ethylene Glycol No known carcinogenic effects Summary Comments: Specific target organ toxicity (single exposure) Product/ingredient name Test Results Basis Nonylphenol polyethylene glycol ether This material is not an STOT-SE toxicant Ethylene Glycol Ingestion may cause drowsiness and dizziness. Inhalation of vapors or mists may cause irritation to the respiratory system. Summary Comments: Specific target organ toxicity (repeated exposure) Product/ingredient name Test Results Basis Nonylphenol polyethylene glycol ether In animals, effects have been reported on the following organs: Kidney, liver. Ethylene Glycol May cause damage to organs or organ systems through prolonged or repeated exposure. Kidney: can cause kidney damage. Page 7 of 9 Summary Comments: Aspiration hazard Product/ingredient name Test Results Basis Nonylphenol polyethylene glycol ether Based on physical properties, not likely to be an aspiration hazard Ethylene Glycol Ingestion may cause drowsiness and dizziness. Inhalation of vapors or mists may cause irritation to the respiratory system Summary Comments: Information on the likely routes of exposure Eyes, oral, skin Potential acute health effects Eye contact: May cause severe eye irritation. Inhalation: Low toxicity by inhalation. Skin contact: Prolonged contact may cause slight skin irritation with local redness. Ingestion: Harmful if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Eye contact: Eye irritation. Inhalation: Vapor may cause irritation of the upper respiratory tract (nose and throat). Skin contact: Skin irritation. Ingestion: May irritate the gastrointestinal tract, cause nausea, and vomiting. Potential chronic health effects (Nonylphenol polyethylene glycol ether and Ethylene Glycol) Carcinogenicity: No known carcinogens. Mutagenicity: No evidence of mutagenic activity. Teratogenicity: For Nonylphenol polyethylene glycol ether: Has been toxic to the fetus in laboratory animals at doses toxic to the mother. Did not cause birth defects in laboratory animals Developmental effects: Not a developmental toxicant. Fertility effects: Does not impair fertility. Section 12: Ecological Information Toxicity Acute Fish toxicity: (Nonylphenol polyethylene glycol ether) LC50 - Pimephales promelas (fathead minnow) ? 6.6 mg/L - 96 h Acute Fish toxicity: (Ethylene Glycol) LC50 - Oncorhynchus mykiss (rainbow trout) ? 18,500 mg/L - 96 h Acute toxicity for daphnia: (Nonylphenol polyethylene glycol ether) EC50 - Daphnia magna (Water flea) ? 21.4 mg/L - 48 h Acute toxicity for daphnia: (Ethylene Glycol) EC50 - Daphnia magna (Water flea) ? 74,000 mg/L - 48 h Acute toxicity for algae: (Nonylphenol polyethylene glycol ether and Ethylene Glycol) No information available Acute bacterial toxicity: (Nonylphenol polyethylene glycol ether and Ethylene Glycol) EC50 ? Bacterial - >5000 mg/L Ecotoxicology Assessment: (Nonylphenol polyethylene glycol ether) Material is expected to be slightly toxic to aquatic life. Persistence and degradability Page 8 of 9 Biodegradability: (Nonylphenol polyethylene glycol ether and Ethylene Glycol) When released into the soil, this material is expected to readily biodegrade. When released into water, this material is expected to readily biodegrade. When released into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals. Stability in water: (Nonylphenol polyethylene glycol ether and Ethylene Glycol) When released into the soil, these materials are expected to leach into groundwater. Dissolves in water. Photodegradation: (Ethylene Glycol) When released into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals. Volatility (Henry's Law constant): (Nonylphenol polyethylene glycol ether) Partition coefficient n-octanol/water (log Kow) = No information available Volatility (Henry's Law constant): (Ethylene Glycol) Partition coefficient n-octanol/water (log Kow) = -1.36 Bioaccumulative potential Bioaccumulation: (Nonylphenol polyethylene glycol ether) Bioaccumulation Cyprinus carpio (Carp) ? No information available Bioconcentration factor (BCF): 5.8 Mobility in soil: (Nonylphenol polyethylene glycol ether and Ethylene Glycol) Distribution among environmental compartments: When released into the soil, this material is expected to leach into groundwater and is water soluble and may spread in water systems. Other adverse effects: When released into the air, ethylene glycol is expected to exist in the aerosol phase with a short half-life. When released into air, this material is ethylene glycol to have a half-life between 10 and 30 days. When released into the air, this material is expected to be readily removed from the atmosphere by wet deposition. Based on stringent OECD test guidelines, nonylphenol polyethylene glycol ether cannot be considered as readily biodegradable; however, these results do not necessarily mean that the material is not biodegradable under environmental conditions. Section 13: Disposal Considerations Disposal methods Dispose in accordance with applicable international, national and local laws, ordinances and statutes. Section 14: Transport Information DOT Proper Shipping Name: Limited Quantity, Consumer Commodity, ORM-D Exemptions: Per 49 CFR 173.155 (pg III, inner package not over 5.0 L) Transport hazard Class(es): N/A Packing Group: N/A Land Transport ADR/RID and GGVS/GGVE (Cross Border / Domestic) Transport Hazard Class(es): N/A Maritime Transport IMDG/GGVSea Transport Hazard Class(es): N/A Marine Pollutant: Yes (Nonylphenol polyethylene glycol ether) Air Transport ICAO-TI and IATA-DGR Transport Hazard Class(es): N/A Section 15: Regulatory Information Page 9 of 9 Chemical Inventory Status-Part 1 Ingredient (CAS#) TSCA EC Japan Australia Nonylphenol polyethylene glycol ether (127087-87-0) Yes No Yes Yes Chemical Inventory Status-Part 2 Ingredient (CAS#) Korea Canada Canada Philippines DSL NDSL Nonylphenol polyethylene glycol ether (127087-87-0) Yes Yes No Yes Federal, State & International Regulations-Part 1 SARA 302 SARA 313 Ingredient (CAS#) RQ TPQ List Chemical Category Nonylphenol polyethylene glycol ether (127087-87-0) No No No No Federal, State & International Regulations-Part 2 RCRA TSCA Ingredient (CAS#) CERCLA 261.33 8(d) Nonylphenol polyethylene glycol ether (127087-87-0) No No Yes Chemical Weapons Convention: No TSCA 12b: No CDTA: No SARA 311/312: Acute: Yes, Chronic: No, Fire: No, Pressure: No, Reactivity: No Mixture/Liquid Australian Hazchem Code: No information found Poison Schedule: No information found Section 16: Other Information History Date of issue: 04/15/15 Version: 1a Revised Sections(s): New Prepared by: Andrew Gioino, SPLASH PRODUCTS Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of the suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.