Page 1 of 8 Safety Data Sheet Section 1: Identification Product Identifier Detergent Product Name Trade Name: +32?F SPLASH All-Season Windshield Washer Fluid PN (Part number): 234193-35 Relevant identified uses of the substance or mixture and uses advised against -Material for industrial applications -Industrial and professional use -Consumer end use Details of the supplier of the safety data sheet Manufacturer SPLASH Products 51 Maryland Ave. E St. Paul, MN 55117 Phone: (651) 489-8211 Emergency telephone number 1-800-535-5053 Section 2: Hazard(s) Identification OSHA/HCS status This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture No Classification GHS label elements Hazard pictograms-No Pictograms Signal word-No Signal Words Hazard statements-No Hazard Statements Precautionary statements Prevention Wear protective gloves/protective clothing/eye protection/face protection. Take off contaminated clothing and wash before use Keep away from oxidizing materials and strong acids Response IF SWALLOWED: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. IF ON SKIN (or hair): Wash with soap and water. Get medical attention if irritation develops. Cold water may be used. Page 2 of 8 IF IN EYES: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. Cold water may be used. Get medical attention if irritation persists. IF EXPOSED or CONCERNED: Immediately call a POISON CENTER or a doctor/physician. Storage Store in a well-ventilated place. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified Product is stable. Section 3: Composition/Information on Ingredients Substance/mixture: Mixture Chemical name: None Other means of identification: No CAS number/other identifiers Ingredient name % CAS number No hazardous ingredients Section 4: First Aid Measurements Description of necessary first aid measures Eye contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. Cold water may be used. Get medical attention if irritation persists. Inhalation: Bring accident victims out into the fresh air. Call a physician immediately in severe cases or if recovery is not rapid. Skin contact: After contact with skin, wash immediately with plenty of water. Remove contaminated clothing and wash before reuse. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact May cause irritation to eyes Inhalation May irritate lungs Skin contact None Ingestion None Indication of immediate medical attention and special treatment needed, if necessary Notes to physician None. Specific treatments N/A Protection of first-aiders Page 3 of 8 N/A See toxicological information (Section 11) Section 5: Fire Fighting Measures Extinguishing media Suitable extinguishing media SMALL FIRE: Use DRY chemical powder, CO2 or appropriate foam. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Unsuitable extinguishing media None known Specific hazards arising from the chemical Closed containers exposed to heat may explode. Hazardous thermal decomposition products/Products of combustion Products of combustion are carbon oxides (CO, CO2). Special protective actions for fire fighters Do not release runoff from fire control methods to sewers or waterways. Special protective equipment for fire-fighters In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Section 6: Accidental Release Measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Environmental precautions Methods and materials for containment and cleaning up: Exposure to the spilled material may be severely irritating or toxic. Follow personal protective equipment recommendations found in Section 8 of this SDS. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including: the material spilled, the quantity of the spill, the area in which the spill occurred, and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Section 7: Handling and Storage Precautions for safe handling Protective measures, advice on general occupational hygiene and conditions for safe storage, including any incompatibilities: Keep container tightly closed in a cool, well-ventilated place. Keep away from oxidizing materials and strong acids. Section 8: Exposure Controls/Personal Protection Control parameters Occupational exposure limits Ingredient name Exposure limits Windshield washer fluid ACGIH OSHA Page 4 of 8 (TWA) (STEL) (TWA) (STEL) N/A N/A N/A N/A Appropriate engineering controls and Environmental exposure controls A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Individual protection measures Hygiene measures None Eye/face protection: Use chemical safety goggles. Skin protection Hand protection and Body protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Other skin protection Wash hands and other exposed areas with mild soap and water before eating or drinking. Respiratory protection: No respiratory protection required under normal circumstances. Respirator Type(s) (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full face piece particulate respirator (NIOSH type N100 filter) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, Glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in Oxygen- deficient atmospheres. Section 9: Physical and Chemical Properties Appearance Physical state: Blue liquid Odor: None Odor threshold: Not determined pH: 8.0 Specific Gravity: 1.000 Melting point: Not determined Boiling point: Not determined Flash point: >93 o C Evaporation rate (BuAc=1): Not determined Flammability (solid, gas): No Lower and upper explosive (flammable) limits: N/A Vapor pressure: Not determined Vapor density (Air=1): Not determined Solubility: Soluble in water Partition coefficient: n-octanol/water: Not Established Auto-ignition temperature: Not Applicable Decomposition temperature: Not Established Viscosity: Not determined Page 5 of 8 VOC%: 0 Section 10: Stability and Reactivity Reactivity Stable under recommended storage conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions Will not occur. Conditions to avoid None Incompatible materials Strong acids Strong bases Strong oxidizing agents Strong reducing agents Hazardous decomposition products Will not occur. Section 11: Toxicological Information Information on toxicological effects Acute toxicity Product/ingredient name Test Results Windshield Washer Fluid Acute toxicity, oral (male rat) LD50 = 5,628 mg/kg (estimated) Acute toxicity, dermal LD50 = 15,800 mg/kg (estimated) Acute toxicity, inhalation (rat) LC50 = Not Determined Summary Comments: Sensitization Product/ingredient name Test Results Basis Windshield Washer Fluid No evidence of sensitization effect Summary Comments: Carcinogenicity Product/ingredient name Test Results Basis Windshield Washer Fluid No known carcinogenic effects Summary Comments: Specific target organ toxicity (single exposure) Product/ingredient name Test Results Basis Windshield Washer Fluid STOT-one-time exposure-oral Not Determined STOT-one-time exposure-dermal Not Determined STOT-one-time exposure-inhalation Not Determined Summary Comments: Specific target organ toxicity (repeated exposure) Product/ingredient name Test Results Basis Windshield Washer Fluid Not Determined Page 6 of 8 Summary Comments: Aspiration hazard Product/ingredient name Test Results Basis Windshield Washer Fluid Human exposure studies Not Determined Summary Comments: Information on the likely routes of exposure None Potential acute health effects Eye contact: May be irritating to the eyes. Inhalation: Not expected to be a hazard. Skin contact: Not expected to be a hazard. Ingestion: Not expected to be a hazard. Symptoms related to the physical, chemical and toxicological characteristics Eye contact: Eye irritation. Inhalation: None expected. Skin contact: None expected. Ingestion: None expected. Potential chronic health effects (Windshield Washer Fluid) Carcinogenicity: No known carcinogens. Mutagenicity: No data available. Teratogenicity: No data available. Developmental effects: No data available. Fertility effects: No data available. Numerical measures of toxicity Acute toxicity estimates No data available Section 12: Ecological Information Toxicity Acute Fish toxicity: (Windshield Washer Fluid) LC50 - Oncorhynchus mykiss (rainbow trout) - No data available LC50 ? Lepomis macrochirus (Bluegill) - No data available Acute toxicity for daphnia: (Windshield Washer Fluid) EC50 - Daphnia magna (Water flea) - No data available EC100 - Daphnia magna (Water flea) - No data available Acute toxicity for algae: (Windshield Washer Fluid) EC50 - Scenedesmus capricornutum (fresh water algae) - No data available Acute bacterial toxicity: (Windshield Washer Fluid) No data available. Ecotoxicology Assessment: (Windshield Washer Fluid) Material is not expected to be toxic to aquatic life. Persistence and degradability Biodegradability: (Windshield Washer Fluid) Not expected to bioaccumulate. Page 7 of 8 Stability in water: (Windshield Washer Fluid) When released into the soil, this material is expected to quickly evaporate. Photodegradation: (Windshield Washer Fluid) No data available Volatility (Henry's Law constant): (Windshield Washer Fluid) Partition coefficient n-octanol/water (log Kow) = No data available Bioaccumulative potential Bioaccumulation: (Windshield Washer Fluid) Bioaccumulation Cyprinus carpio (Carp) ? No data available Bioconcentration factor (BCF): No data available Mobility in soil: (Windshield Washer Fluid) Distribution among environmental compartments: When released into the soil, this material is expected to quickly evaporate. Other adverse effects: Section 13: Disposal Considerations Disposal methods Dispose in accordance with applicable international, national and local laws, ordinances and statutes. Section 14: Transport Information UN Number: Not Regulated UN Proper Shipping Name: Transport hazard Class(es): Packing Group: Land Transport ADR/RID and GGVS/GGVE (Cross Border / Domestic) Transport Hazard Class(es): Not Regulated Maritime Transport IMDG/GGVSea Transport Hazard Class(es): Not Regulated Marine Pollutant: No Air Transport ICAO-TI and IATA-DGR Transport Hazard Class(es): Not Regulated Section 15: Regulatory Information Chemical Inventory Status-Part 1 Ingredient (CAS#) TSCA EC Japan Australia Windshield Washer Fluid Yes Yes Yes Yes Chemical Inventory Status-Part 2 Ingredient (CAS#) Korea Canada Canada Philippines DSL NDSL Windshield Washer Fluid Yes Yes No Yes Page 8 of 8 Federal, State & International Regulations-Part 1 SARA 302 SARA 313 Ingredient (CAS#) RQ TPQ List Chemical Category Windshield Washer Fluid No No Yes No Federal, State & International Regulations-Part 2 RCRA TSCA Ingredient (CAS#) CERCLA 261.33 8(d) Windshield Washer Fluid No No No Chemical Weapons Convention: No TSCA 12b: No CDTA: No SARA 311/312: Acute: No, Chronic: No, Fire: Yes, Pressure: No, Reactivity: No Mixture/Liquid Australian Hazchem Code: No information found Poison Schedule: No information found Section 16: Other Information History Date of issue: 05/13/15 Version: 1b. Revised Sections(s): (1b) Elimination of methanol Prepared by: Andrew Gioino, SPLASH PRODUCTS Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of the suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.