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Splash/Fox
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Wash Tablets 100 ct
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700700.pdf
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Page 1 of 8 Safety Data Sheet Section 1: Identification Product Identifier Washer Fluid Cleaning Tablets Product Name Trade Name: SPLASH Windshield Washer Tablets PN (Part number): 100 Ct.-700700, 25 Ct.-700725 Relevant identified uses of the substance or mixture and uses advised against -Material for industrial applications -Industrial and professional use -Consumer end use Details of the supplier of the safety data sheet Manufacturer SPLASH Products 51 E. Maryland Ave. St. Paul, MN 55117 Phone: (651) 489-8211 Emergency telephone number 1-800-535-5053 Section 2: Hazard(s) Identification OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture Serious eye damage/eye irritation, Mild irritant Category 2B Skin corrosion/irritation, Irritant Category 2 GHS label elements Hazard pictograms Signal word-WARNING Hazard statements Causes skin irritation Causes eye irritation Page 2 of 8 Precautionary statements Prevention Avoid touching tablet directly. Do not get on skin or in eyes. Wash hands thoroughly after handling. Wear eye protection. Response IF SWALLOWED: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Drink large amounts of water. If patient feels unwell seek medical attention. IF ON SKIN (or hair): Wash with water for 15 minutes. If irritation occurs get medical attention. Take off contaminated clothing and wash it before reuse. IF IN EYES: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. If, eye irritation persists: Get medical attention. IF EXPOSED or CONCERNED: Immediately call a POISON CENTER or a doctor/physician. Storage Store in a well-ventilated place. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified Product is stable. Section 3: Composition/Information on Ingredients Substance/mixture: Mixture Chemical name: N/A Other means of identification: No CAS number/other identifiers Ingredient name % CAS number Sodium Carbonate 40-55 497-19-8 Citric Acid 40-55 77-92-9 Sodium Lauroyl Sarcosinate 1-10 137-16-6 Polyethylene Glycol 1-10 25322-68-3 Alcohol Ethoxylate <1 34398-01-1 Phthalocyanine dye <1 1330-38-7 Section 4: First Aid Measurements Description of necessary first aid measures Eye contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. Cold water may be used. Get medical attention immediately. Inhalation: Bring accident victims out into the fresh air. Call a physician immediately in severe cases or if recovery is not rapid. Skin contact: After contact with skin, wash immediately with plenty of water for 15 minutes. If irritation occurs, get medical attention. Remove contaminated clothing and wash before reuse. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Drink large amounts of water. Loosen tight clothing such as a collar, tie, belt or waistband. If patient feels unwell seek medical attention. Most important symptoms/effects, acute and delayed Page 3 of 8 Potential acute health effects Eye contact Can cause irritation to eyes and mucous membranes. Inhalation Sore throat, shortness of breath, coughing and congestion. Skin contact Irritation, itching, dermatitis. Ingestion Irritation to mucous membranes. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Exposure may aggravate acute or chronic asthma, emphysema and bronchitis. Specific treatments N/A Protection of first-aiders N/A See toxicological information (Section 11) Section 5: Fire Fighting Measures Extinguishing media Suitable extinguishing media SMALL FIRE: Use DRY chemical powder, CO2 or appropriate foam. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Unsuitable extinguishing media None known Specific hazards arising from the chemical None known Hazardous thermal decomposition products/Products of combustion Products of combustion are carbon oxides (CO, CO2) and oxides of sulfur. Special protective actions for fire fighters Prevent spills form entering storm sewers or drains and contact with soil. Special protective equipment for fire-fighters In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Section 6: Accidental Release Measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Environmental precautions Methods and materials for containment and cleaning up: Exposure to the spilled material may be irritating. Follow personal protective equipment recommendations found in Section 8 of this SDS. Personal protective equipment needs must be evaluated based on information provided on this sheet and the Page 4 of 8 special circumstances created by the spill including: the material spilled, the quantity of the spill, the area in which the spill occurred, and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Gather and store in a sealed container pending a waste disposal evaluation. Prevent spills form entering storm sewers or drains and contact with soil. Section 7: Handling and Storage Precautions for safe handling Protective measures, advice on general occupational hygiene and conditions for safe storage, including any incompatibilities: Avoid contact with the eyes. Avoid repeated or prolonged contact with the skin or clothing. Avoid dust inhalation. Contact lenses should not be worn. Store in closed containers in cool, dry, isolated, well ventilated area away from heat, sources of ignition, and incompatibles. Avoid contamination with other ?look alike? materials that may produce a fire or explosion. Special precautions/ Procedures/ Label instructions: Store at controlled room temperature, 0 - 40 o C. Humidity of less than 40% is recommended to maintain product viability. Do not store near strong bases. Store in a well-ventilated area. Keep cool. Section 8: Exposure Controls/Personal Protection Control parameters Occupational exposure limits Ingredient name Exposure limits Overview: As with any chemical compositions care should always be used when handling to reduce the chance of dust formation or spillage. Avoid dust formation. Avoid touching the tablet directly. Good personal hygiene practices should always be followed. Wash hands thoroughly after handling this product. Wear eye protection. Appropriate engineering controls and Environmental exposure controls A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Individual protection measures Hygiene measures Good personal hygiene practices should always be followed. Wash hands thoroughly after handling this product. Eye/face protection: Use chemical safety goggles. Skin protection Hand protection and Body protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Other skin protection If prolonged or repeated skin contact is likely, neoprene gloves should be worn. Respiratory protection: No respiratory protection required under normal circumstances. Respirator Type(s) (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full face piece particulate respirator (NIOSH type N100 filter) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, Glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in Oxygen- deficient atmospheres. Section 9: Physical and Chemical Properties Appearance Physical state: Solid blue and white tablet Page 5 of 8 Odor: None Odor threshold: Not available pH: 6.0-8.0 Specific Gravity: Not Applicable Melting point: Not Applicable Boiling point: Not Applicable Flash point: Not applicable Evaporation rate (BuAc=1): Not applicable Flammability (solid, gas): No Lower and upper explosive (flammable) limits: Not applicable Vapor pressure: Not Applicable Vapor density (Air=1): Not Applicable Solubility: Soluble in water Partition coefficient: n-octanol/water: Not Established Auto-ignition temperature: Not Applicable Decomposition temperature: Not Established Viscosity: Not determined VOC%: 0 Section 10: Stability and Reactivity Reactivity Stable under recommended storage conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions Will not occur. Conditions to avoid Keep away from direct sunlight. Incompatible materials Strong oxidizing agents, strong acids and strong bases, reactive metals (e.g. sodium, calcium, zinc etc.) Hazardous decomposition products Thermal decomposition may produce carbon monoxide, carbon dioxide, and oxides of sulfur. Section 11: Toxicological Information Information on toxicological effects Acute toxicity Product/ingredient name Test Results Splash Windshield Washer Tablets Acute toxicity, oral (male rat) >2,000mg/kg Based on the individual ingredients amounts in the composition as a whole based on calculation outlined in Consumer Chemicals and Containers Regulations, 2001 of the Hazardous Products Act Section 36 subsection 1. Acute toxicity, dermal (rat) Not Classified Acute toxicity, inhalation (rat) Not Classified Summary Comments: Sensitization Page 6 of 8 Product/ingredient name Test Results Basis Splash Windshield Washer Tablets None known Summary Comments: Carcinogenicity Product/ingredient name Test Results Basis Splash Windshield Washer Tablets None known Summary Comments: Specific target organ toxicity (single exposure) Product/ingredient name Test Results Basis Splash Windshield Washer Tablets None known Summary Comments: Specific target organ toxicity (repeated exposure) Product/ingredient name Test Results Basis Splash Windshield Washer Tablets None known Summary Comments: Aspiration hazard Product/ingredient name Test Results Basis Splash Windshield Washer Tablets None known Summary Comments: Information on the likely routes of exposure Potential acute health effects Eye contact: May cause eye irritation on direct contact. Inhalation: May cause respiratory tract irritation if large amounts of dust are inhaled. Skin contact: May cause skin irritation on prolonged or repeated direct contact. Ingestion: May cause slight intestinal irritation if large quantities are swallowed. Symptoms related to the physical, chemical and toxicological characteristics Eye contact: Eye irritation. Inhalation: May cause irritation of the mucous membranes and upper respiratory tract. Skin contact: Skin irritation. Ingestion: May irritate the gastrointestinal tract. Potential chronic health effects (Splash Windshield Washer Tablets) Carcinogenicity: None of the ingredients are listed by IARC, NTP, OSHA or ACGIH as a carcinogen. Mutagenicity: None known Teratogenicity: None known Developmental effects: None known Fertility effects: None known Numerical measures of toxicity Acute toxicity estimates None known Section 12: Ecological Information Toxicity Acute Fish toxicity: (Splash Windshield Washer Tablets) Page 7 of 8 No data available Acute toxicity for daphnia: (Splash Windshield Washer Tablets) No data available Acute toxicity for algae: (Splash Windshield Washer Tablets) No data available Acute bacterial toxicity: (Splash Windshield Washer Tablets) No data available Ecotoxicology Assessment: (Splash Windshield Washer Tablets) This product has been approved by the US EPA to carry the Design for the Environment logo. Persistence and degradability Biodegradability: (Splash Windshield Washer Tablets) No data available Stability in water: (Splash Windshield Washer Tablets) No data available Photodegradation: (Splash Windshield Washer Tablets) No data available Volatility (Henry's Law constant): (Splash Windshield Washer Tablets) No data available Bioaccumulative potential Bioaccumulation: (Splash Windshield Washer Tablets) No data available Bioconcentration factor (BCF): No data available Mobility in soil: (Splash Windshield Washer Tablets) Distribution among environmental compartments: No data available Other adverse effects: This product does not contain chlorine bleach, phosphates or EDTA. Section 13: Disposal Considerations Disposal methods No components in this product are classified as a hazardous waste. Dispose in accordance with applicable international, national and local laws, ordinances and statutes. Do not dump into any body of water or onto the ground. Section 14: Transport Information UN Number: Not regulated DOT Proper Shipping Name: Not hazardous Exemptions: N/A Transport hazard Class(es): N/A Packing Group: N/A Land Transport ADR/RID and GGVS/GGVE (Cross Border / Domestic) Transport Hazard Class(es): N/A Maritime Transport IMDG/GGVSea Transport Hazard Class(es): N/A Marine Pollutant: No Page 8 of 8 Air Transport ICAO-TI and IATA-DGR Transport Hazard Class(es): N/A Section 15: Regulatory Information Chemical Inventory Status-Part 1 Ingredient (CAS#) TSCA EC Japan Australia Splash Windshield Washer Tablets Yes Yes Yes Yes Chemical Inventory Status-Part 2 Ingredient (CAS#) Korea Canada Canada Philippines DSL NDSL Splash Windshield Washer Tablets Yes Yes No Yes Federal, State & International Regulations-Part 1 SARA 302 SARA 313 Ingredient (CAS#) RQ TPQ List Chemical Category Splash Windshield Washer Tablets No No No No Federal, State & International Regulations-Part 2 RCRA TSCA Ingredient (CAS#) CERCLA 261.33 8(d) Splash Windshield Washer Tablets No No No Chemical Weapons Convention: No TSCA 12b: No CDTA: No SARA 311/312: Acute: No, Chronic: No, Fire: No, Pressure: No, Reactivity: No Mixture/solid Australian Hazchem Code: No information found Poison Schedule: No information found Section 16: Other Information History Date of issue: 04/14/15 Version: 1a Revised Sections(s): New Prepared by: Andrew Gioino, SPLASH PRODUCTS Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of the suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.