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Splash/Fox
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SPLASH BLEACH CASE 6 GAL
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BLEACH_SPLASH_207628.pdf
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Page 1 of 9 Safety Data Sheet Section 1: Identification Product Identifier Bleach Product Name Trade Name: SPLASH Chlor 6% Bleach PN (Part number): 207628 Relevant identified uses of the substance or mixture and uses advised against -Material for industrial applications -Industrial and professional use -Consumer end use Details of the supplier of the safety data sheet Manufacturer SPLASH Products 51 E. Maryland Ave. St. Paul, MN 55117 Phone: (651) 489-8211 Emergency telephone number 1-800-535-5053 Section 2: Hazard(s) Identification OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture Skin Corrosion/Irritation, Irritant Category 2 Serious Eye Damage/Eye Irritation, Irreversible effects Category 1 Acute hazards to the aquatic environment, Category 2 GHS label elements Hazard pictograms Signal word-DANGER Sodium Hypochlorite Hazard statements Page 2 of 9 Causes skin irritation Causes serious eye damage Toxic to aquatic life Precautionary statements Prevention Wash exposed skin thoroughly after handling. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Take off contaminated clothing and wash before use Store away from heat and ignition sources Keep away from flammable materials, ammonia and strong acids Response IF SWALLOWED: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. IF ON SKIN (or hair): Wash with soap and water. Get medical attention if irritation develops. Cold water may be used. IF IN EYES: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. Cold water may be used. Get medical attention immediately. IF EXPOSED or CONCERNED: Immediately call a POISON CENTER or a doctor/physician. Storage Store in a well-ventilated place. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified Product is stable. Section 3: Composition/Information on Ingredients Substance/mixture: Mixture Chemical name: Sodium Hypochlorite Other means of identification: Bleach CAS number/other identifiers Ingredient name % CAS number Sodium Hypochlorite 6 7681-52-9 Section 4: First Aid Measurements Description of necessary first aid measures Eye contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. Cold water may be used. Get medical attention immediately. Inhalation: Bring accident victims out into the fresh air. Call a physician immediately in severe cases or if recovery is not rapid. Skin contact: After contact with skin, wash immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Remove contaminated clothing and wash before reuse. Get medical attention if irritation develops and persists. Page 3 of 9 Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If victim is alert, rinse mouth and drink 1/2 to 1 glass of water to help dilute the material. Transport to nearest medical facility for additional treatment if symptoms occur. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact Splashes cause serious eye damage. Inhalation May irritate throat and mucus membranes. Skin contact Irritation, itching, dermatitis. Ingestion May cause nausea. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat symptomatically. Specific treatments N/A Protection of first-aiders N/A See toxicological information (Section 11) Section 5: Fire Fighting Measures Extinguishing media Suitable extinguishing media SMALL FIRE: Use DRY chemical powder, CO2 or appropriate foam. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Unsuitable extinguishing media None known Specific hazards arising from the chemical Not flammable or combustible. Hazardous thermal decomposition products/Products of combustion Products of combustion are carbon oxides (CO, CO2). Special protective actions for fire fighters Do not release runoff from fire control methods to sewers or waterways. Special protective equipment for fire-fighters In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Section 6: Accidental Release Measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Environmental precautions Page 4 of 9 Methods and materials for containment and cleaning up: Follow personal protective equipment recommendations found in Section 8 of this SDS. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including: the material spilled, the quantity of the spill, the area in which the spill occurred, and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. Section 7: Handling and Storage Precautions for safe handling Protective measures, advice on general occupational hygiene and conditions for safe storage, including any incompatibilities: Avoid contact with skin and eyes. Wash hands thoroughly after handling. Mixing this product with acid or ammonia releases chlorine gas. Keep container tightly closed. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves, clothing, and eye and face protection. Keep container tightly closed in a cool, well-ventilated place. Keep away from flammable materials and strong acids. Do not store near acids. Keep out of reach of children. Store in suitable labeled containers. Keep away from foodstuffs. Store in a cool place and out of direct sunlight. Section 8: Exposure Controls/Personal Protection Control parameters Occupational exposure limits Ingredient name Exposure limits Sodium Hypochlorite ACGIH OSHA (TWA) (STEL) (TWA) (STEL) 0.5 ppm 1.0 ppm 0.5 ppm 1.0 ppm Appropriate engineering controls and Environmental exposure controls A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Individual protection measures Hygiene measures Wash hands before eating, drinking, smoking and using the toilet. Launder contaminated clothing before re-use. Eye/face protection: Use chemical safety goggles. Skin protection Hand protection and Body protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Other skin protection Wash hands and other exposed areas with mild soap and water before eating or drinking. Respiratory protection: No respiratory protection required under normal circumstances. Respirator Type(s) (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full face piece particulate respirator (NIOSH type N100 filter) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, Glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full face piece Page 5 of 9 positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in Oxygen- deficient atmospheres. Section 9: Physical and Chemical Properties Appearance Physical state: Slightly yellow liquid Odor: Chlorine Odor threshold: Not determined pH: 11.5-12.5 Specific Gravity: 1.047 Melting point: No Data Available Boiling point: 100 o C Flash point: Not Applicable Evaporation rate (BuAc=1): Not Determined Flammability (solid, gas): No Lower and upper explosive (flammable) limits: Not Applicable Vapor pressure: No Data Available Vapor density (Air=1): No Data Available Solubility: Soluble in water Partition coefficient: n-octanol/water: Not Established Auto-ignition temperature: Not Applicable Decomposition temperature: Not Established Viscosity: Not determined VOC%: 0 Section 10: Stability and Reactivity Reactivity Stable under recommended storage conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions Mixing this product with acid or ammonia releases chlorine gas. Conditions to avoid Exposure to air or moisture over prolonged periods; Excessive heat, exposure to light, reduced alkalinity, and contamination of any kind. Reduced alkalinity or contamination can result in evolution of chlorine (toxic) gas. Decrease in pH such as by mixing with other than water, and contamination with items mentioned below as incompatible can result in evolution of chlorine (toxic) gas. Incompatible materials Strong acids and bases; Oxidizing agents; Ether, ammonia compounds, hydrogen peroxide, all acids, alum, reducing agents, human or animal waste, oxidizable or combustible materials such as wood, cloth or organic materials, organic chemicals such as solvents and solvent based cleaning compounds, fuels and fuel oils, amines, methanol, propane, organic polymers, ethylene glycol, insecticides, heavy metals such as iron, copper, magnesium, aluminum, tin, steel, stainless steel, carbon steel, manganese, zinc, chromium, nickel, cobalt and their alloys, sodium sulfite, sodium bisulfite, sodium hydrosulfite, sodium thiosulfate. Do not mix this product with any of the foregoing or hazardous gases can result. Hazardous decomposition products Carbon oxides Nitrogen oxides (NOx) Page 6 of 9 Sulfur oxides Oxides of phosphorus Section 11: Toxicological Information Information on toxicological effects Acute toxicity Product/ingredient name Test Results Sodium Hypochlorite Acute toxicity, oral (male rat) LD50 > 8,200 mg/kg Acute toxicity, dermal (male rat) LD50 = 10,000 mg/kg Acute toxicity, inhalation (male rat) LC50 = 10,500 mg/kg Summary Comments: Sensitization Product/ingredient name Test Results Basis Sodium Hypochlorite No evidence of sensitization effect Summary Comments: Carcinogenicity Product/ingredient name Test Results Basis Sodium Hypochlorite No known carcinogenic effects Summary Comments: Specific target organ toxicity (single exposure) Product/ingredient name Test Results Basis Sodium Hypochlorite Not Classified Summary Comments: Specific target organ toxicity (repeated exposure) Product/ingredient name Test Results Basis Sodium Hypochlorite Not Classified Summary Comments: Aspiration hazard Product/ingredient name Test Results Basis Sodium Hypochlorite Not Classified Summary Comments: Information on the likely routes of exposure Inhalation, Eye contact, Skin contact. Potential acute health effects Eye contact: Causes serious eye damage. Inhalation: Health injuries are not known or expected under normal use. Skin contact: Causes skin irritation. Ingestion: Health injuries are not known or expected under normal use. Symptoms related to the physical, chemical and toxicological characteristics Eye contact: Redness, pain, irritation. Inhalation: No symptoms known or expected. Skin contact: Redness, irritation. Ingestion: No symptoms known or expected. Page 7 of 9 Potential chronic health effects (Sodium Hypochlorite) Carcinogenicity: No data available. Mutagenicity: No data available. Teratogenicity: No data available. Developmental effects: No data available. Fertility effects: No data available. Section 12: Ecological Information Toxicity Acute Fish toxicity: (Sodium Hypochlorite) LC50 - Oncorhynchus gorbuscha (Pink Salmon) ? 0.023 mg/l - 96 h Acute toxicity for daphnia: (Sodium Hypochlorite) EC50 - Daphnia magna (Water flea) ? 2.10 mg/l - 96 h Acute toxicity for algae: (Sodium Hypochlorite) EC50 - Chlorophyta (fresh water algae) ? 0.84 mg/l - 24 h Acute bacterial toxicity: (Sodium Hypochlorite) No data available. Ecotoxicology Assessment: (Sodium Hypochlorite) Material is expected to be toxic to aquatic life. Persistence and degradability Biodegradability: (Sodium Hypochlorite) Not applicable. Stability in water: (Sodium Hypochlorite) This material is believed not to persist in the environment. Photodegradation: (Sodium Hypochlorite) Decomposes in air and light to release chlorine gas, oxygen and sodium chloride solution (salt water). Volatility (Henry's Law constant): (Sodium Hypochlorite) Partition coefficient n-octanol/water (log Kow) = No Data Available Bioaccumulative potential Bioaccumulation: (Sodium Hypochlorite) Bioaccumulation Cyprinus carpio (Carp) ? Not Applicable Bioconcentration factor (BCF): Not Applicable This material is believed not to persist in the environment Mobility in soil: (Sodium Hypochlorite) Distribution among environmental compartments: This material is not expected to bioconcentrate in organisms. Other adverse effects: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic life. Section 13: Disposal Considerations Disposal methods Dispose in accordance with applicable international, national and local laws, ordinances and statutes. Section 14: Transport Information UN Number: N/A DOT Proper Shipping Name: Limited Quantity, Consumer Commodity, ORM-D Page 8 of 9 Exemptions: Per 49 CFR 173.154 (pg III, inner package not over 5.0 L) Transport hazard Class(es): N/A Packing Group: N/A Land Transport ADR/RID and GGVS/GGVE (Cross Border / Domestic) Transport Hazard Class(es): N/A Maritime Transport IMDG/GGVSea Transport Hazard Class(es): N/A Marine Pollutant: No Air Transport ICAO-TI and IATA-DGR Transport Hazard Class(es): N/A Section 15: Regulatory Information Chemical Inventory Status-Part 1 Ingredient (CAS#) TSCA EC Japan Australia Sodium Hypochlorite (7681-52-9) Yes Yes Yes Yes Chemical Inventory Status-Part 2 Ingredient (CAS#) Korea Canada Canada Philippines DSL NDSL Sodium Hypochlorite (7681-52-9) Yes Yes No Yes Federal, State & International Regulations-Part 1 SARA 302 SARA 313 Ingredient (CAS#) RQ TPQ List Chemical Category Sodium Hypochlorite (7681-52-9) No No No No Federal, State & International Regulations-Part 2 RCRA TSCA Ingredient (CAS#) CERCLA 261.33 8(d) Sodium Hypochlorite (7681-52-9) 100 lb. No No Chemical Weapons Convention: No TSCA 12b: No CDTA: No SARA 311/312: Acute: Yes, Chronic: No, Fire: No, Pressure: No, Reactivity: No Mixture/Liquid Australian Hazchem Code: None allocated Poison Schedule: S5 Section 16: Other Information History Date of issue: 04/14/15 Page 9 of 9 Version: 1a Revised Sections(s): New Prepared by: Andrew Gioino, SPLASH PRODUCTS Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of the suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.