Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g), Rev. 2012 and GHS Rev 03. Page 1 of 10 Revision Date: 02/2015 1. Identification Product identifier Trade name Enhanced PAG Relevant identified uses of the substance or mixture and uses advised against Product description PAG Refrigeration Lubricant with Performance Enhancer Details of the supplier of the safety data sheet Manufacturer/supplier Santech Industries 1401 Valley View Lane #100, Irving, TX 75061 817-509-2518 Emergency telephone number 817-509-2518 2. Hazard(s) Identification Classification of the substance or mixture Acute Tox. 4. - H302. Harmful if swallowed Skin Irrit. 2. - H315. Causes skin irritation Eye Irrit. 2B - H320. Causes eye irritation Skin Sen. - H317. May cause an allergic skin reaction Label elements GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS07 Signal word Warning Hazard-determining components of labeling 91-20-3 Naphthalene Enhanced PAG PAG Refrigeration Lubricant with Performance Enhancer 2. Hazard(s) Identification (continued) Hazard statements Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Precautionary statements Avoid breathing dust/fume/gas/mist/vapors/spray Wear protective gloves. Wear eye protection / face protection. Avoid release to the environment. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If swallowed: Call a poison center/doctor if you feel unwell. Specific treatment (see on this label). Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Rinse mouth. If on skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. Dispose of contents/container in accordance with local/regional/national/ international regulations. Classification system NFPA ratings (scale 0-4) Health=1; Fire=1; Reactivity=0 HMIS-ratings (scale 0 - 4) Health=1; Fire=1; Reactivity=0 Other Hazards None known 3. Composition / Information on Ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Dangerous Components 91-20-3 Naphthalene Acute Tox. 4, H320, Skin Irrit. 2, H315, Eye Irrit 2B, H320, Skin Sens. 1, H317 < 2.5% Page 2 of 10 Revision Date: 02/2015 Enhanced PAG PAG Refrigeration Lubricant with Performance Enhancer 4. First-aid Measures Description of first aid measures General information Symptoms may even occur after several hours; therefore observe area effected for at least 48 hours after the accident. After inhalation In case of unconsciousness, place patient securely on side position for transportation. After skin contact Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. After eye contact Rinse opened eye for at least 15 minutes under running water. If symptoms persist, consult a doctor. After swallowing Do not induce vomiting without medical advice. Get medical attention. Information for doctor Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5. Fire-fighting Measures Extinguishing media Suitable extinguishing agents Water, carbon dioxide, foam or dry extinguishing media. Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixture If incinerated, product may release toxic gases including: Carbon Oxides and Nitrogen Oxides (NOx). Advice for firefighters Protective equipment As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent), and full protective gear to prevent contact with skin and eyes. 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures Particular danger of slipping on leaked/spilled product. Keep away from ignition sources. Avoid contact with skin, eyes and clothing. Proper protective equipment should be used. Environmental precautions Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up After material has been absorbed, area may be flushed with water or wet-brushed to clean. Absorb with liquid-binding material (ie. sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to section 13. Ensure adequate ventilation. Dispose of the collected material according to regulations. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Page 3 of 10 Revision Date: 02/2015 Enhanced PAG PAG Refrigeration Lubricant with Performance Enhancer Page 4 of 10 Revision Date: 02/2015 7. Handling and Storage Handling Precautions for safe handling Keep away from sources of ignition. Store in cool, dry place in tightly closed receptacles. Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires No special measures required. Conditions for safe storage, including any incompatibilities Store away from strong acids, strong bases, strong oxidizing agents, strong reducing agents, and Alkalis. Storage Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility Not required. Further information about storage conditions Keep receptacle tightly sealed. Specific end use(s) No further relevant information available. 8. Exposure Controls / Personal Protection Additional information about design of technical systems No further data; see section 7. Control parameters Ingredients with limit values that require monitoring at workplace This product does not contain any relevant quantities of materials with critical values that have to be monitored at a workspace. DNELs No further relevant information PNECs No further relevant information Additional Information The list value during the making were used as a basis Exposure controls Personal protective equipment General protective and hygienic measures Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Breathing equipment Not required. Protection of hands Protective gloves. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/the chemical mixture. Select glove material based on penetration times, rates of diffusion and degradation. Enhanced PAG PAG Refrigeration Lubricant with Performance Enhancer Page 5 of 10 Revision Date: 02/2015 Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. 8. Exposure Controls / Personal Protection (continued) Penetration time of glove material The exact break-through time has to be determined and observed by the manufacturer of the protective gloves. Eye protection Safety glasses 9. Physical and Chemical Properties Information on basic physical and chemical properties General Information Appearance Form Liquid Color Clear amber Odor Characteristic Odor threshold Not determined. pH-value Not determined. Change in condition Melting point/Melting range Not determined. Boiling point/Boiling range > 200?C (> 392?F) Flash point > 218?C (> 424?F) Flammability (solid, gaseous): Not applicable. Ignition temperature 350?C (662?F) Decomposition temperature Not determined. Auto igniting Product is not self-igniting. Danger of explosion Product does not present an explosion hazard. Explosion limits Lower Not determined. Upper Not determined. Vapor pressure @ 25?C (77?F) <0.001 kPa Density @ 20?C (68?F) 0.91 g/cm? (7.594 lbs/gal) Relative density Not determined. Vapor density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with water Insoluble. Partition coefficient (n-octanol/water): Not determined. Enhanced PAG PAG Refrigeration Lubricant with Performance Enhancer Page 6 of 10 Revision Date: 02/2015 9. Physical and Chemical Properties (continued) Viscosity Dynamic Not determined. Kinematic Not determined. Solvent content Organic solvents 0.0 % Other information No further relevant information available. 10. Stability and Reactivity Reactivity Stable under normal conditions Chemical stability Stable under normal conditions. Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials Strong acids, strong bases, strong oxidizing agents, strong reducing agents, and Alkalis. Hazardous decomposition products Carbon Oxides and Nitrogen Oxides (NOx). 11. Toxicological Information Information on toxicological effects The toxicity of this product is unknown. Acute toxicity LD/LC50 values that are relevant for classification 91-20-3 Naphthalene Oral: LD50 490 mg/kg (rat) Dermal: LD50 5000 mg/kg (rat) Inhalative: LC50/4 h 0.34 mg/l (rat) Primary irritant effect: on the skin: Irritant to skin and mucous membranes. May cause an allergic skin reaction. on the eye: Irritating effect. Causes serious eye irritation. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful. Irritant. 12. Ecological Information Toxicity Aquatic toxicity: Avoid release into the environment. Runoff from fire control or dilution water may cause pollution. 91-20-3 Naphthalene: EC50 1.00-3.40 mg/l (daphnia) Persistence and degradability No further relevant information available. Behavior in environmental systems Bioaccumulative potential No further relevant information available. Enhanced PAG PAG Refrigeration Lubricant with Performance Enhancer 12. Ecological Information (continued) Mobility in soil No further relevant information available. Ecotoxical effects Remark No further information available Additional ecological information General notes: Do not allow product to reach ground water, water course or sewage system Results of PBT and vPvB assessment PBT Not applicable. vPvB Not applicable. Other adverse effects No further relevant information available. 13. Disposal Considerations Waste Treatment Methods Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings Recommendation Dispose of as unused product. Disposal must be made according to official regulations. 14. Transportation Information UN-Number DOT, ADR, IMDG, IATA Non-Regulated Material UN proper shipping name DOT, ADR, ADN, IMDG, IATA Non-Regulated Material Transport hazard class(es) DOT, ADR, ADN, IMDG, IATA Class: Non-Regulated Material Packing group DOT, ADR, IMDG, IATA Non-Regulated Material Environmental hazards Marine pollutant No Special precautions for user Not applicable. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. UN ?Model Regulation? -- Page 7 of 10 Revision Date: 02/2015 Enhanced PAG PAG Refrigeration Lubricant with Performance Enhancer 15. Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances) None of the ingredients are listed Section 313 (Specific toxic chemical listings): None of the ingredients are listed TSCA (Toxic Substances Control Act): 91-20-3 Naphthalene Proposition 65 Chemicals known to cause cancer: None of the ingredients are listed Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed Chemicals known to cause reproductive toxicity for males: None of the ingredients are listed Chemicals known to cause developmental toxicity: None of the ingredients are listed Carcinogenic categories EPA (Environmental Protection Agency) 91-20-3 Naphthalene TLV (Threshold Limit Value established by ACGIH) 91-20-3 Naphthalene NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients are listed. GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS07 Signal word Warning Hazard-determining components of labeling 91-20-3 Naphthalene Hazard statements Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. Harmful to aquatic life with long lasting effects. Page 8 of 10 Revision Date: 02/2015 Enhanced PAG PAG Refrigeration Lubricant with Performance Enhancer Page 9 of 10 Revision Date: 02/2015 15. Regulatory Information (continued) Precautionary statements Avoid breathing dust/fume/gas/mist/vapors/spray Wear protective gloves. Wear eye protection / face protection. Avoid release to the environment. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If swallowed: Call a poison center/doctor if you feel unwell. Specific treatment (see on this label). Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Rinse mouth. If on skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. Dispose of contents/container in accordance with local/regional/national/ international regulations. National regulations The product is subject to be labeled according with the prevailing version of the regulations on hazardous substances. All ingredients are listed. State Right to Know 91-20-3 Naphthalene Acute Tox. 4, H320, Skin Irrit. 2, H315, Eye Irrit 2B, H320, Skin Sens. 1, H317 < 2.5% Chemical safety assessment: A Chemical Safety Assessment has not been carried out. Enhanced PAG PAG Refrigeration Lubricant with Performance Enhancer 16. Other Information The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as of the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied and shall not establish a legally valid contractual relationship. It is the responsibility of the user to determine applicability of this information and the suitability of the material or product for any particular purpose. Date of preparation / last revision 02/04/2015 / - Abbreviations and acronyms: ADR: Accord europ?en sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent : Flammable liquids, Hazard Category 4 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 Carc. 2: Carcinogenicity, Hazard Category 2 Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1 : Hazardous to the aquatic environment - AcuteHazard, Category 3 Aquatic Chronic 1: Hazardous to the aquatic environment - Chronic Hazard, Category 1 Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3 Data compared to the previous version altered SDS created by MSDS Authoring Services www.msdsauthoring.com - (877) 204-9106 Page 10 of 10 Revision Date: 02/2015 Enhanced PAG PAG Refrigeration Lubricant with Performance Enhancer Santech Industries - 1401 Valley View Lane #100 - Irving, TX 75061 Phone:817-509-2518 - Fax:817-694-7317