Lubegard? Automatic Transmission Protectant Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 02/13/2014 Revision date: 02/13/2014 Version: 1.0 02/13/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Lubegard? Automatic Transmission Protectant Product code : 60902, 50902, 50904, 50905, 50330 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Lubricant 1.3. Details of the supplier of the safety data sheet International Lubricants, Inc. P.O. Box 24743 98124-0743 Seattle - USA T (206) 762-5343 (800) 333-LUBE (5823) 1.4. Emergency telephone number Emergency number : ChemTel (800) 255-392 ChemTel (813) 248-0585 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Skin Sensitisation 1 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS07 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : May cause an allergic skin reaction. Precautionary statements (GHS-US) : Avoid breathing dust/fume/gas/mist/vapors/spray. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves. If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) 99 % of the mixture consists of ingredient(s) of unknown acute toxicity. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Distillates, petroleum, hydrotreated heavy paraffinic (CAS No) 64742-54-7 0.1 - 1 Not classified 1,3,4-Thiadiazole, 2,5-bis(octyldithio)- (CAS No) 13539-13-4 0.1 - 1 Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1 Ethylbenzene (CAS No) 100-41-4 < 0.1 Flam. Liq. 2 Acute Tox. 4 (Inhalation) Carc. 2 The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Lubegard? Automatic Transmission Protectant Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 02/13/2014 EN (English) 2/5 First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water. Remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause respiratory tract irritation. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. May cause sensitisation by skin contact. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Powder, water spray, foam, carbon dioxide. Unsuitable extinguishing media : None known. 5.2. Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, oxides of phosphorous. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Protective equipment : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. 6.1.2. For emergency responders No additional information available 6.2. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Vacuum or sweep material and place in a disposal container. Allow gas to dissipate harmlessly into the atmosphere. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Avoid contact with skin and eyes. Avoid breathing vapour or mist. Do not swallow. Handle and open container with care. Do not eat, drink or smoke when using this product. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed. Keep away from food, drink and animal foodstuffs. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Ethylbenzene (100-41-4) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 435 mg/m? Lubegard? Automatic Transmission Protectant Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 02/13/2014 EN (English) 3/5 Ethylbenzene (100-41-4) USA OSHA OSHA PEL (TWA) (ppm) 100 ppm 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Hand protection : Wear chemically resistant protective gloves. Eye protection : Safety glasses or goggles are recommended when using product. Skin and body protection : Wear suitable protective clothing. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear. Colour : Red. Odour : Characteristic. Odour threshold : No data available. pH : No data available. Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : No data available. Flash point : ~ 205 ?C (~ 400 ?F) (COC) Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Not Flammable. Vapour pressure : < 0.1 mm Hg Relative vapour density at 20 ?C : No data available. Relative density : 0.87 - 0.89 Solubility : Water: Insoluble. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. 10.5. Incompatible materials Oxidizers. Lubegard? Automatic Transmission Protectant Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 02/13/2014 EN (English) 4/5 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon, oxides of phosphorous. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Lubegard? Automatic Transmission Protectant LD50 oral rat Not available. LD50 dermal rabbit Not available. LC50 inhalation rat (mg/l) Not available. Distillates, petroleum, hydrotreated heavy paraffinic (64742-54-7) LD50 oral rat > 15000 mg/kg LD50 dermal rabbit > 5000 mg/kg Ethylbenzene (100-41-4) LD50 oral rat 3500 mg/kg LD50 dermal rabbit 15354 mg/kg LC50 inhalation rat 17.2 mg/l/4h Skin corrosion/irritation : Based on available data, the classification criteria are not met. Serious eye damage/irritation : Based on available data, the classification criteria are not met. Respiratory or skin sensitisation : May cause an allergic skin reaction. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Based on available data, the classification criteria are not met. Ethylbenzene (100-41-4) IARC group 2B National Toxicity Program (NTP) Status 1 Reproductive toxicity : Based on available data, the classification criteria are not met. Specific target organ toxicity (single exposure) : Based on available data, the classification criteria are not met. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : May cause respiratory tract irritation. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. May cause sensitisation by skin contact. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability Lubegard? Automatic Transmission Protectant Persistence and degradability Not established. 12.3. Bioaccumulative potential Lubegard? Automatic Transmission Protectant Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Lubegard? Automatic Transmission Protectant Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 02/13/2014 EN (English) 5/5 SECTION 14: Transport information In accordance with DOT 14.1. UN number Not applicable 14.2. UN proper shipping name Not applicable 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations Distillates, petroleum, hydrotreated heavy paraffinic (64742-54-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory 1,3,4-Thiadiazole, 2,5-bis(octyldithio)- (13539-13-47) Listed on the United States TSCA (Toxic Substances Control Act) inventory Ethylbenzene (100-41-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 0.1 % 15.2. US State regulations Lubegard? Automatic Transmission Protectant() State or local regulations This product contains a chemical known to the State of California to cause cancer. SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: IARC (I) International Agency for Research on Cancer. 1 - Carcinogenic to humans; 2A - Probably carcinogenic to humans; 2B - Possibly carcinogenic to humans; 3 - Not classifiable; 4 - Probably not carcinogenic to humans. NTP (N) National Toxicology Program. 1 - Evidence of Carcinogenicity; 2 - Known Human Carcinogens; 3 - Reasonably anticipated to be Human Carcinogen; 4 - Substances delisted from report on Carcinogens; 5 - Twelfth Report - Items under consideration. SECTION 16: Other information Date of preparation : February 13, 2014 Indication of changes : None. Other information : None. NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product