MATERIAL SAFETY DATA SHEET PRO II 9000 Air-intake Throttle Plate Synthetic Cleaner STEPS 1 & 2 1 / 8 Section 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: PRO II 9000 Air-intake Throttle Plate Synthetic Cleaner STEPS 1 & 2 Product Number: 72401 Product Use: Cleaner. Manufacturer/Supplier: International Lubricants, Inc. P.O. Box 24743, Seattle WA 98124-0743, USA Phone Number: (206) 762-5343 (800) 333-LUBE (5823) Emergency Phone: CHEM TEL (800) 255-3924 CHEM TEL (813) 248-0585 Date of Preparation: December 15, 2011 Section 2: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER EXTREMELY FLAMMABLE AEROSOL. CONTENTS UNDER PRESSURE. CONTAINER MAY EXPLODE IF HEATED. HARMFUL IF SWALLOWED. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. Do not puncture. Do not burn. Store away from heat. Potential Health Effects: See Section 11 for more information. Likely Routes of Exposure: Skin contact, skin absorption, eye contact, and inhalation. Eye: May irritate eyes. Skin: May irritate skin. Ingestion: Not a normal route of exposure. May be harmful if swallowed. May cause stomach distress, nausea or vomiting. Inhalation: Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Aspiration of material into lungs can cause chemical pneumonitis. Chronic Effects: Prolonged or repeated exposure can cause drying, defatting and dermatitis. Signs and Symptoms: Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Medical Conditions Aggravated By Exposure: Certain pre-existing conditions may make workers particularly susceptible to the effects of this chemical: asthma, allergies, impaired pulmonary function. Target Organs: Eyes, skin, respiratory system, central nervous system, gastrointestinal tract, blood, liver, kidneys. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Potential Environmental Effects: This product is not expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic systems. See Section 12 for more information. MATERIAL SAFETY DATA SHEET PRO II 9000 Air-intake Throttle Plate Synthetic Cleaner STEPS 1 & 2 2 / 8 Section 3: COMPOSITION / INFORMATION ON INGREDIENTS Ingredient CAS # Wt. % Acetone 67-64-1 40 - 70 Isobutane 75-28-5 7 - 13 Propane 74-98-6 7 - 13 Toluene 108-88-3 5 - 10 m-Xylene 108-38-3 1 - 5 Diacetone alcohol 123-42-2 1 - 5 Isopropanol 67-63-0 1 - 5 p-Xylene 106-42-3 1 - 5 Ethylbenzene 100-41-4 0.5 - 1.5 o-Xylene 95-47-6 0.5 - 1.5 1,2,4-Trimethylbenzene 95-63-6 0.1 ? 1 Section 4: FIRST AID MEASURES Eye Contact: Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain medical attention if irritation persists. Skin Contact: After contact with skin, wash immediately with plenty of water. Remove and wash contaminated clothing before re-use. If irritation persists, get medical attention. Inhalation: If breathed in, move person into fresh air. If symptoms persist, obtain medical attention. If breathing has stopped, trained personnel should administer CPR immediately. Ingestion: If swallowed, call a Poison Control Centre or doctor immediately. DO NOT induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. If swallowed, rinse mouth with water (only if the person is conscious). General Advice: In case of accident or if you feel unwell, seek medical advice immediately (show the label or MSDS where possible). Note to Physicians: Symptoms may be delayed. Section 5: FIRE FIGHTING MEASURES Flammability: Extremely flammable by WHMIS/OSHA criteria. Means of Extinction: Suitable Extinguishing Media: Powder, water spray, foam, carbon dioxide. Unsuitable Extinguishing Media: Not available. Products of Combustion: Oxides of carbon. Explosion Data: Sensitivity to Mechanical Impact: Not available. Sensitivity to Static Discharge: Not available. Protection of Firefighters: Pressurized container may explode when exposed to heat or flame. In case of fire and/or explosion do not breathe fumes. Firefighters should wear full protective clothing including self contained breathing apparatus. MATERIAL SAFETY DATA SHEET PRO II 9000 Air-intake Throttle Plate Synthetic Cleaner STEPS 1 & 2 3 / 8 Section 6: ACCIDENTAL RELEASE MEASURES Personal Precautions: Use personal protection recommended in Section 8. Isolate area. Remove sources of ignition. Keep unnecessary personnel away. Ruptured cylinders may rocket. Environmental Precautions: Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Methods for Containment: Prevent further leakage or spillage if safe to do so. Use sand, perlite or vermiculite as an absorbent for large spills of this material. Methods for Clean-Up: Sweep up or gather material and place in appropriate container for disposal. Allow gas to dissipate into the atmosphere. Other Information: Not available. Section 7: HANDLING AND STORAGE Handling: Keep away from heat, open flames or other sources of ignition. Avoid contact with eyes. Avoid contact with skin. Do not swallow. Do not breathe gas/fumes/vapor/spray. Use only in a well- ventilated area. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. Storage: Keep out of the reach of children. Do not store at temperatures above 49 ?C / 120 ?F. Store in a cool, dry, well-ventilated area. Keep away from food, drink and animal feedingstuffs. Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Exposure Limits Ingredient OSHA-PEL ACGIH-TLV Acetone 750 ppm 500 ppm Isobutane Not available. 1000 ppm Propane 1000 ppm 1000 ppm Toluene 200 ppm 20 ppm m-Xylene 100 ppm 100 ppm Diacetone alcohol 50 ppm 50 ppm Isopropanol 400 ppm 200 ppm p-Xylene 100 ppm 100 ppm Ethylbenzene 100 ppm 20 ppm o-Xylene 100 ppm 100 ppm 1,2,4-Trimethylbenzene Not available. 25 ppm Engineering Controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Personal Protective Equipment: Eye/Face Protection: Wear safety glasses with side shields. Hand Protection: Wear suitable gloves. Skin and Body Protection: Wear suitable protective clothing. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. MATERIAL SAFETY DATA SHEET PRO II 9000 Air-intake Throttle Plate Synthetic Cleaner STEPS 1 & 2 4 / 8 General Hygiene Considerations: Handle in accordance with good industrial hygiene and safety practice. Section 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear. Color: Colorless. Odour: Acetone. Odour Threshold: Not available. Physical State: Gas / Pressurized Liquid. pH (of concentrate): Not applicable. Viscosity (of concentrate): Not available. Freezing Point (of concentrate): Not available. Boiling Point (of concentrate): Not available. Flash Point (of concentrate): Not available. Evaporation Rate (of concentrate): < 1 (Diethyl ether = 1) Lower Flammability Limit: ~ 1.8% Upper Flammability Limit: ~ 9.5% Vapor Pressure: 40 ? 60 PSIG Vapor Density (of concentrate): > 1 (Air = 1) Specific Gravity (of concentrate): < 1 Solubility in Water (of concentrate): Partial. Coefficient of Water/Oil Distribution: Not available. Auto-ignition Temperature: Not available. Percent Volatile, wt. %: Not available. VOC content, wt. %: Not available. Section 10: STABILITY AND REACTIVITY Stability: Stable under recommended storage conditions. Contents under pressure. Container may explode if heated. Do not puncture. Do not burn. Conditions of Reactivity: Heat. Incompatible materials. Incompatible Materials: Oxidizers. Acids. Hazardous Decomposition Products: Oxides of carbon. Possibility of Hazardous Reactions: Will not occur. MATERIAL SAFETY DATA SHEET PRO II 9000 Air-intake Throttle Plate Synthetic Cleaner STEPS 1 & 2 5 / 8 Section 11: TOXICOLOGY INFORMATION EFFECTS OF ACUTE EXPOSURE Component Analysis Ingredient LD50 (oral) LC50 Acetone 5800 mg/kg, rat Not available. Isobutane Not available. 658 mg/L 4hr, rat Propane Not available. 658 mg/L 4hr, rat Toluene 636 mg/kg, rat 12.5 mg/L 4hr, rat; 26700 ppm 1hr, rat m-Xylene 5000 mg/kg, rat Not available. Diacetone alcohol 4000 mg/kg, rat Not available. Isopropanol 4396 mg/kg, rat 72.6 mg/L 4hr, rat p-Xylene 3392 mg/kg, rat 4550 ppm 4hr, rat Ethylbenzene 3500 mg/kg, rat 17.2 mg/L 4hr, rat o-Xylene 3609 mg/kg, rat 2180 ppm 4hr, rat 1,2,4-Trimethylbenzene 3400 mg/kg, rat 18000 mg/m? 4hr, rat Eye: May irritate eyes. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Skin: May irritate skin. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Ingestion: Not a normal route of exposure. May cause stomach distress, nausea or vomiting. May be harmful if swallowed Inhalation: Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Aspiration of material into lungs can cause chemical pneumonitis. EFFECTS OF CHRONIC EXPOSURE Target Organs: Not available. Chronic Effects: Not hazardous by WHMIS/OSHA criteria. Carcinogenicity: Hazardous by WHMIS/OSHA criteria. Ingredient Chemical Listed as Carcinogen or Potential Carcinogen * Acetone G-A4 Isobutane Not listed. Propane Not listed. Toluene G-A4, I-3, CP65 m-Xylene G-A4, I-3 Diacetone alcohol Not listed. Isopropanol G-A4, I-3 p-Xylene G-A4, I-3 Ethylbenzene G-A3, I-2B, CP65 o-Xylene G-A4, I-3 1,2,4-Trimethylbenzene Not listed. * See Section 15 for more information. Mutagenicity: Not hazardous by WHMIS/OSHA criteria. Reproductive Effects: Not hazardous by WHMIS/OSHA criteria. MATERIAL SAFETY DATA SHEET PRO II 9000 Air-intake Throttle Plate Synthetic Cleaner STEPS 1 & 2 6 / 8 Developmental Effects: Teratogenicity: Hazardous by WHMIS/OSHA criteria. Embryotoxicity: Hazardous by WHMIS/OSHA criteria. Respiratory Sensitization: Not hazardous by WHMIS/OSHA criteria. Skin Sensitization: Not hazardous by WHMIS/OSHA criteria. Toxicologically Synergistic Materials: Not available. Section 12: ECOLOGICAL INFORMATION Ecotoxicity: This product is not expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic systems. Persistence / Degradability: Not available. Bioaccumulation / Accumulation: Not available. Mobility in Environment: Not available. Section 13: DISPOSAL CONSIDERATIONS Disposal Instructions: This material and its container must be disposed of in a safe way. Dispose in accordance with all applicable regulations. Section 14: TRANSPORTATION INFORMATION DOT Classification ORM-D TDG Classification Limited Quantity Section 15: REGULATORY INFORMATION Federal Regulations Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. US: MSDS prepared pursuant to the Hazard Communication Standard (CFR29 1910.1200). SARA Title III Ingredient Section 302 (EHS) TPQ (lbs.) Section 304 EHS RQ (lbs.) CERCLA RQ (lbs.) Section 313 Acetone Not listed. Not listed. 5,000 313 Isobutane Not listed. Not listed. Not listed. Not listed. Propane Not listed. Not listed. Not listed. Not listed. Toluene Not listed. Not listed. 1,000 313 m-Xylene Not listed. Not listed. 1,000 313 Diacetone alcohol Not listed. Not listed. Not listed. Not listed. Isopropanol Not listed. Not listed. Not listed. 313 p-Xylene Not listed. Not listed. 100 313 Ethylbenzene Not listed. Not listed. 1,000 313 o-Xylene Not listed. Not listed. 1,000 313 1,2,4-Trimethylbenzene Not listed. Not listed. Not listed. 313 MATERIAL SAFETY DATA SHEET PRO II 9000 Air-intake Throttle Plate Synthetic Cleaner STEPS 1 & 2 7 / 8 State Regulations California Proposition 65: This product contains a chemical known to the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Global Inventories Ingredient Canada DSL/NDSL USA TSCA Acetone DSL Yes. Isobutane DSL Yes. Propane DSL Yes. Toluene DSL Yes. m-Xylene DSL Yes. Diacetone alcohol DSL Yes. Isopropanol DSL Yes. p-Xylene DSL Yes. Ethylbenzene DSL Yes. o-Xylene DSL Yes. 1,2,4-Trimethylbenzene DSL Yes. HMIS - Hazardous Materials Identification System Health ? 2* Flammability - 4 Physical Hazard - 0 PPE ? B NFPA - National Fire Protection Association: Health - 2 Fire - 4 Reactivity - 0 Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme WHMIS Classification(s): Class A - Compressed Gas Class B5 - Flammable Aerosol Class D2A - Carcinogenicity Class D2A - Teratogenicity and Embryotoxicity Class D2B - Skin/Eye Irritant WHMIS Hazard Symbols: SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: OSHA (O) Occupational Safety and Health Administration. ACGIH (G) American Conference of Governmental Industrial Hygienists. A1 - Confirmed human carcinogen. A2 - Suspected human carcinogen. A3 - Animal carcinogen. A4 - Not classifiable as a human carcinogen. A5 - Not suspected as a human carcinogen. IARC (I) International Agency for Research on Cancer. 1 - The agent (mixture) is carcinogenic to humans. 2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals. 2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in humans in the absence of sufficient evidence of carcinogenicity in experimental animals. 3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans. 4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans. MATERIAL SAFETY DATA SHEET PRO II 9000 Air-intake Throttle Plate Synthetic Cleaner STEPS 1 & 2 8 / 8 NTP (N) National Toxicology Program. 1 - Known to be carcinogens. 2 - Reasonably anticipated to be carcinogens. Section 16: OTHER INFORMATION Disclaimer: The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use. Canadian WHMIS Expiry Date: December 15, 2014 Version #: 2.0 Prepared by: Nexreg Compliance Inc. Phone: (519) 488-5126 www.nexreg.com