MATERIAL SAFETY DATA SHEET PRO II 9000? Complete Fuel System & Injection Cleaner STEP 3 1 / 7 Section 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: PRO II 9000? Complete Fuel System & Injection Cleaner STEP 3 Product Number: 72402 Product Use: Cleaner. Manufacturer/Supplier: International Lubricants, Inc. P.O. Box 24743, Seattle WA 98124-0743, USA Phone Number: (206) 762-5343 (800) 333-LUBE (5823) Emergency Phone: CHEM TEL (800) 255-3924 CHEM TEL (813) 248-0585 Date of Preparation: April 9, 2010 Section 2: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING FLAMMABLE. HARMFUL IF SWALLOWED. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. Potential Health Effects: See Section 11 for more information. Likely Routes of Exposure: Skin contact, skin absorption, eye contact, inhalation, and ingestion. Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: Harmful if swallowed. May cause stomach distress, nausea or vomiting. Harmful: may cause lung damage if swallowed. Inhalation: May cause respiratory tract irritation. This product may be aspirated into the lungs and cause chemical pneumonitis. Chronic Effects: Prolonged or repeated contact may dry skin and cause irritation. Signs and Symptoms: Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Medical Conditions Aggravated By Exposure: Asthma. Allergies. Target Organs: Skin, eyes, gastrointestinal tract and respiratory system. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Potential Environmental Effects: May cause long-term adverse effects in the aquatic environment See Section 12 for more information. MATERIAL SAFETY DATA SHEET PRO II 9000? Complete Fuel System & Injection Cleaner STEP 3 2 / 7 Section 3: COMPOSITION / INFORMATION ON INGREDIENTS Ingredient CAS # Wt. % m-Xylene 108-38-3 30 - 60 p-Xylene 106-42-3 10 - 30 Ethylbenzene 100-41-4 10 - 30 o-Xylene 95-47-6 7 - 13 Toluene 108-88-3 0.1 - 1 Medium aliphatic solvent naphtha (petroleum) C9-C12 64742-88-7 5 - 10 1,2,4-Trimethylbenzene 95-63-6 0.5 - 1.5 Trimethylbenzene 25551-13-7 1 - 5 1,3,5-Trimethylbenzene 108-67-8 0.1 - 1 Di-tert-butyl peroxide 110-05-4 1 - 5 Amines, C12-14-tert-alkyl 68955-53-3 1 - 5 Section 4: FIRST AID MEASURES Eye Contact: In case of contact, immediately flush eyes with plenty of water. If easy to do, remove contact lenses, if worn. Skin Contact: In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Ingestion: If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. General Advice: In case of accident or if you feel unwell, seek medical advice immediately (show the label or MSDS where possible). Note to Physicians: Symptoms may not appear immediately. Section 5: FIRE FIGHTING MEASURES Flammability: Flammable by WHMIS/OSHA criteria. Means of Extinction: Suitable Extinguishing Media: Powder, water spray, foam, carbon dioxide. Unsuitable Extinguishing Media: Not available. Products of Combustion: May include, and are not limited to: oxides of carbon. Explosion Data: Sensitivity to Mechanical Impact: Not available. Sensitivity to Static Discharge: Not available. Protection of Firefighters: Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Section 6: ACCIDENTAL RELEASE MEASURES Personal Precautions: Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition. Environmental Precautions: This material is a water pollutant. Keep out of drains, sewers, ditches, and waterways. Minimize use of water to prevent environmental contamination. MATERIAL SAFETY DATA SHEET PRO II 9000? Complete Fuel System & Injection Cleaner STEP 3 3 / 7 Methods for Containment: Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for Clean-Up: Vacuum or sweep material and place in a disposal container. Allow gas to dissipate harmlessly into the atmosphere. Other Information: Not available. Section 7: HANDLING AND STORAGE Handling: Keep away from sources of ignition. No smoking. Avoid contact with skin and eyes. Do not swallow. Do not breathe gas/fumes/vapor/spray. Use only in well-ventilated areas. Handle and open container with care. When using do not eat or drink. Wash hands before eating, drinking, or smoking. Storage: Keep out of the reach of children. Keep container tightly closed. Do not store at temperatures above 49 ?C. Keep away from food, drink and animal feedingstuffs. Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Exposure Limits Ingredient OSHA-PEL ACGIH-TLV m-Xylene 100 ppm 100 ppm p-Xylene 100 ppm 100 ppm Ethylbenzene 100 ppm 100 ppm o-Xylene 100 ppm 100 ppm Toluene 200 ppm 50 ppm Medium aliphatic solvent naphtha (petroleum) C9-C12 100 ppm 100 ppm 1,2,4-Trimethylbenzene Not available. 25 ppm Trimethylbenzene 25 ppm 25 ppm 1,3,5-Trimethylbenzene Not available. 25 ppm Di-tert-butyl peroxide Not available. Not available. Amines, C12-14-tert-alkyl Not available. Not available. Engineering Controls: Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal Protective Equipment: Eye/Face Protection: Wear eye/face protection. Hand Protection: Wear suitable gloves. Skin and Body Protection: Wear suitable protective clothing. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. General Hygiene Considerations: Handle according to established industrial hygiene and safety practices. Section 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear. Color: Yellow. Odour: Characteristic. MATERIAL SAFETY DATA SHEET PRO II 9000? Complete Fuel System & Injection Cleaner STEP 3 4 / 7 Odour Threshold: Not available. Physical State: Liquid. pH: Not available. Viscosity: Not available. Freezing Point: Not available. Boiling Point: ~ 141 ?C (~ 285.8 ?F) Flash Point: ~ 32 ?C (~ 89.6 ?F) Evaporation Rate: Not available. Lower Flammability Limit: 1.0 Upper Flammability Limit: 7.0 Vapor Pressure: Not available. Vapor Density: Not available. Specific Gravity: 7.218 Solubility in Water: Not available. Coefficient of Water/Oil Distribution: Not available. Auto-ignition Temperature: Not available. Percent Volatile, wt. %: 86.72 VOC content, wt. %: Not available. Section 10: STABILITY AND REACTIVITY Stability: Stable under normal storage conditions. Keep in a cool place. Conditions of Reactivity: Heat. Incompatible materials. Incompatible Materials: Oxidizers. Hazardous Decomposition Products: May include, and are not limited to: oxides of carbon. Possibility of Hazardous Reactions: No dangerous reaction known under conditions of normal use. Section 11: TOXICOLOGY INFORMATION EFFECTS OF ACUTE EXPOSURE Component Analysis Ingredient LD50 (oral) LC50 m-Xylene 5000 mg/kg, rat Not available. p-Xylene 3392 mg/kg, rat 4550 ppm 4hrs, rat Ethylbenzene 3500 mg/kg, rat 17.2 mg/L 4hr, rat o-Xylene 3609 mg/kg, rat 2180 ppm 4hr, rat Toluene 636 mg/kg, rat 12.5 mg/L 4hr, rat; 26700 ppm 1hr, rat Medium aliphatic solvent naphtha (petroleum) C9-C12 > 5000 mg/kg, rat > 5.28 mg/L 4hr, rat 1,2,4-Trimethylbenzene 3400 mg/kg, rat 18000 mg/m? 4 hrs, rat Trimethylbenzene 8970 mg/kg, rat Not available. 1,3,5-Trimethylbenzene 5000 mg/kg, rat 24000 mg/m? 4hrs, rat Di-tert-butyl peroxide 25000 mg/kg, rat 4100 ppm 4hrs, rat Amines, C12-14-tert-alkyl 300 mg/kg, rat Not available. MATERIAL SAFETY DATA SHEET PRO II 9000? Complete Fuel System & Injection Cleaner STEP 3 5 / 7 Eye: May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Skin: May cause skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Ingestion: Harmful if swallowed. May cause stomach distress, nausea or vomiting. Harmful: may cause lung damage if swallowed. Inhalation: May cause respiratory tract irritation. This product may be aspirated into the lungs and cause chemical pneumonitis. EFFECTS OF CHRONIC EXPOSURE Target Organs: Not available. Chronic Effects: Not hazardous by WHMIS/OSHA criteria. Carcinogenicity: Hazardous by WHMIS/OSHA criteria. Ingredient Chemical Listed as Carcinogen or Potential Carcinogen * m-Xylene G-A4, I-3 p-Xylene G-A4, I-3 Ethylbenzene G-A3, I-2B, CP65 o-Xylene G-A4, I-3 Toluene G-A4, I-3, CP65 Medium aliphatic solvent naphtha (petroleum) C9-C12 Not listed. 1,2,4-Trimethylbenzene Not listed. Trimethylbenzene Not listed. 1,3,5-Trimethylbenzene Not listed. Di-tert-butyl peroxide Not listed. Amines, C12-14-tert-alkyl Not listed. * See Section 15 for more information. Mutagenicity: Not hazardous by WHMIS/OSHA criteria. Reproductive Effects: Not hazardous by WHMIS/OSHA criteria. Developmental Effects: Teratogenicity: Hazardous by WHMIS/OSHA criteria. Embryotoxicity: Hazardous by WHMIS/OSHA criteria. Respiratory Sensitization: Not hazardous by WHMIS/OSHA criteria. Skin Sensitization: Not hazardous by WHMIS/OSHA criteria. Toxicologically Synergistic Materials: Not available. Section 12: ECOLOGICAL INFORMATION Ecotoxicity: May cause long-term adverse effects in the aquatic environment Persistence / Degradability: Not available. Bioaccumulation / Accumulation: Not available. Mobility in Environment: Not available. Section 13: DISPOSAL CONSIDERATIONS Disposal Instructions: This material and its container must be disposed of in a safe way. MATERIAL SAFETY DATA SHEET PRO II 9000? Complete Fuel System & Injection Cleaner STEP 3 6 / 7 Section 14: TRANSPORTATION INFORMATION DOT Classification UN1993, Flammable liquid, n.o.s. (Xylene) Class 3; PG III TDG Classification UN1993, Flammable liquid, n.o.s. (Xylene) Class 3; PG III IATA Classification UN1993, Flammable liquid, n.o.s. (Xylene) Class 3; PG III Section 15: REGULATORY INFORMATION Federal Regulations Canadian: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. US: MSDS prepared pursuant to the Hazard Communication Standard (CFR29 1910.1200). SARA Title III Ingredient Section 302 (EHS) TPQ (lbs.) Section 304 EHS RQ (lbs.) CERCLA RQ (lbs.) Section 313 m-Xylene Not listed. Not listed. 1,000 313 p-Xylene Not listed. Not listed. 100 313 Ethylbenzene Not listed. Not listed. 1,000 313 o-Xylene Not listed. Not listed. 1,000 313 Toluene Not listed. Not listed. 1,000 313 Medium aliphatic solvent naphtha (petroleum) C9-C12 Not listed. Not listed. Not listed. Not listed. 1,2,4-Trimethylbenzene Not listed. Not listed. Not listed. 313 Trimethylbenzene Not listed. Not listed. Not listed. Not listed. 1,3,5-Trimethylbenzene Not listed. Not listed. Not listed. Not listed. Di-tert-butyl peroxide Not listed. Not listed. Not listed. Not listed. Amines, C12-14-tert-alkyl Not listed. Not listed. Not listed. Not listed. State Regulations California Proposition 65: This product contains chemicals known to the State of California to cause cancer. Global Inventories Ingredient Canada DSL/NDSL USA TSCA m-Xylene DSL Yes. p-Xylene DSL Yes. Ethylbenzene DSL Yes. o-Xylene DSL Yes. Toluene DSL Yes. Medium aliphatic solvent naphtha (petroleum) C9-C12 DSL Yes. 1,2,4-Trimethylbenzene DSL Yes. Trimethylbenzene DSL Yes. 1,3,5-Trimethylbenzene DSL Yes. Di-tert-butyl peroxide DSL Yes. Amines, C12-14-tert-alkyl DSL Yes. MATERIAL SAFETY DATA SHEET PRO II 9000? Complete Fuel System & Injection Cleaner STEP 3 7 / 7 NFPA - National Fire Protection Association: Health - 2 Fire - 2 Reactivity - 0 Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme WHMIS Classification(s): Class B2 - Flammable Liquid Class D2A - Carcinogenicity Class D2A - Teratogenicity and Embryotoxicity Class D2B - Skin/Eye Irritant WHMIS Hazard Symbols: SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: OSHA (O) Occupational Safety and Health Administration. ACGIH (G) American Conference of Governmental Industrial Hygienists. A1 - Confirmed human carcinogen. A2 - Suspected human carcinogen. A3 - Animal carcinogen. A4 - Not classifiable as a human carcinogen. A5 - Not suspected as a human carcinogen. IARC (I) International Agency for Research on Cancer. 1 - The agent (mixture) is carcinogenic to humans. 2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals. 2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in humans in the absence of sufficient evidence of carcinogenicity in experimental animals. 3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans. 4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans. NTP (N) National Toxicology Program. 1 - Known to be carcinogens. 2 - Reasonably anticipated to be carcinogens. Section 16: OTHER INFORMATION Disclaimer: The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use. Expiry Date: April 9, 2013 Version #: 1.0 Prepared by: Nexreg Compliance Inc. (519) 488-5126 www.nexreg.com