SDS Repository

sds

Collection
Motorcraft
Description
 
Tags
Search Tag
Filename
ZC54.pdf
Source
 
Full Text
SAFETY DATA SHEET 1. Identification Product identifier Professional Strength Carpet & Upholstery Cleaner Other means of identification FIR No. 171146 Recommended use Carpet and upholstery cleaner Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Supplier Company Name Ford Motor Company Address Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 USA Telephone 1-800-392-3673 MSDS Information 1-800-448-2063 This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone numbers Poison Control Center: USA and Canada: 1-800-959-3673 INFOTRAC (Transportation): USA and Canada 1-800-535-5053 2. Hazard(s) identification Liquefied gasGases under pressurePhysical hazards Category 2Skin corrosion/irritationHealth hazards Category 2Serious eye damage/eye irritation Category 2Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Warning Hazard statement Contains gas under pressure; may explode if heated. Causes skin irritation. Causes serious eye irritation. Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary statement Prevention Wash thoroughly after handling. Avoid release to the environment. Wear protective gloves. Wear eye/face protection. Response If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Storage Protect from sunlight. Store in a well-ventilated place. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) May cause irritation of respiratory tract. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May be harmful if swallowed. May be harmful if absorbed through skin. Supplemental information None. FIR No.: 171146 SDS US Issue Date: 05-15-2015 Version: 01 1 / 9 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 68476-85-7Petroleum gases, liquefied 5 - < 10 110-91-8MORPHOLINE 1 - < 3 6834-92-0disodium metasilicate < 1 Specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. No specific first aid measures noted. Ingestion Rinse mouth. In the unlikely event of swallowing contact a physician or poison control center. Do not induce vomiting. Most important symptoms/effects, acute and delayed Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical During fire, gases hazardous to health may be formed. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. ALWAYS stay away from tanks engulfed in flame. Move containers from fire area if you can do so without risk. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Contents under pressure. Pressurized container may explode when exposed to heat or flame. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Emergency personnel need self-contained breathing equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. FIR No.: 171146 SDS US Issue Date: 05-15-2015 Version: 01 2 / 9 Methods and materials for containment and cleaning up This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Isolate area until gas has dispersed. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent product from entering drains. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 7. Handling and storage Precautions for safe handling Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store in a cool, dry place out of direct sunlight. Secure cylinders in an upright position at all times, close all valves when not in use. Store in original tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 70 mg/m3MORPHOLINE (CAS 110-91-8) 20 ppm PEL 1800 mg/m3Petroleum gases, liquefied (CAS 68476-85-7) 1000 ppm US. ACGIH Threshold Limit Values ValueComponents Type TWA 20 ppmMORPHOLINE (CAS 110-91-8) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type STEL 105 mg/m3MORPHOLINE (CAS 110-91-8) 30 ppm TWA 70 mg/m3 20 ppm TWA 1800 mg/m3Petroleum gases, liquefied (CAS 68476-85-7) 1000 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Exposure guidelines US - California OELs: Skin designation MORPHOLINE (CAS 110-91-8) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies MORPHOLINE (CAS 110-91-8) Skin designation applies. US - Tennessee OELs: Skin designation MORPHOLINE (CAS 110-91-8) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation MORPHOLINE (CAS 110-91-8) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation MORPHOLINE (CAS 110-91-8) Can be absorbed through the skin. FIR No.: 171146 SDS US Issue Date: 05-15-2015 Version: 01 3 / 9 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) MORPHOLINE (CAS 110-91-8) Can be absorbed through the skin. Appropriate engineering controls Use adequate ventilation to control airborne concentrations below the exposure limits/guidelines. If user operations generate a vapor, dust and/or mist, use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits/guidelines. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Suitable chemical protective gloves should be worn when the potential exists for prolonged or repeated skin exposure. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Nitrile gloves are recommended. Neoprene gloves are recommended. Other Wear appropriate chemical resistant clothing. Wear appropriate chemical resistant clothing if applicable. Respiratory protection If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid. Color Yellow. Odor Soapy. Odor threshold Not available. pH 9.2 - 10.8 ASTM D1293 pH concentration 100 % v/v Melting point/freezing point Not available. Initial boiling point and boiling range Not available. Flash point Not available. Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density 1.005 Relative density temperature 39.2 ?F (4 ?C) Solubility(ies) Solubility (water) COMPLETE Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. FIR No.: 171146 SDS US Issue Date: 05-15-2015 Version: 01 4 / 9 Decomposition temperature Not available. Viscosity Not available. Other information Kinematic viscosity < 14 cSt Kinematic viscosity temperature 104 ?F (40 ?C) VOC (Weight %) 4.8 % w/w CAM310 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Heat. Contact with incompatible materials. Incompatible materials Strong mineral acids. Strong oxidizing agents. Aluminum. Zinc. Chlorine. Hazardous decomposition products Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information Information on likely routes of exposure Inhalation May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Skin contact May be harmful in contact with skin. Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion May be harmful if swallowed. May cause discomfort if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Information on toxicological effects Acute toxicity Species Calculated/Test ResultsComponents disodium metasilicate (CAS 6834-92-0) LD50 Mouse Oral Acute 2400 mg/kg Rat 1280 mg/kg MORPHOLINE (CAS 110-91-8) LD50 Rabbit Dermal Acute 0.5 ml/kg LD50 Guinea pig Oral 0.09 g/kg Mouse 720 mg/kg Rat 1.05 g/kg Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye irritation. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. FIR No.: 171146 SDS US Issue Date: 05-15-2015 Version: 01 5 / 9 Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity MORPHOLINE (CAS 110-91-8) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Ecotoxicity SpeciesComponents Calculated/Test Results disodium metasilicate (CAS 6834-92-0) Aquatic EC50Crustacea 0.28 - 0.57 mg/l, 48 hoursWater flea (Ceriodaphnia dubia) LC50Fish 1800 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis) MORPHOLINE (CAS 110-91-8) Aquatic LC50Fish > 1 mg/l, 96 hoursZebra danio (Danio rerio) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) MORPHOLINE -0.86 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN1950UN number AerosolsUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk FIR No.: 171146 SDS US Issue Date: 05-15-2015 Version: 01 6 / 9 2.2Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IATA UN1950UN number AerosolsUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk 2.2Label(s) Not applicable.Packing group No.Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Forbidden.Passenger and cargo aircraft Other information Forbidden.Cargo aircraft only IMDG UN1950UN number AerosolsUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk 2.2Label(s) Not applicable.Packing group No.Marine pollutant Environmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. FIR No.: 171146 SDS US Issue Date: 05-15-2015 Version: 01 7 / 9 TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) MORPHOLINE (CAS 110-91-8) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) MORPHOLINE (CAS 110-91-8) US. Massachusetts RTK - Substance List MORPHOLINE (CAS 110-91-8) Petroleum gases, liquefied (CAS 68476-85-7) US. New Jersey Worker and Community Right-to-Know Act MORPHOLINE (CAS 110-91-8) Petroleum gases, liquefied (CAS 68476-85-7) US. Pennsylvania Worker and Community Right-to-Know Law MORPHOLINE (CAS 110-91-8) Petroleum gases, liquefied (CAS 68476-85-7) US. Rhode Island RTK Not regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. Other information, including date of preparation or last revision Issue date 05-15-2015 Version # 01 HMIS? ratings Health: 2 Flammability: 0 Physical hazard: 1 NFPA ratings Health: 2 Flammability: 0 Instability: 1 FIR No.: 171146 SDS US Issue Date: 05-15-2015 Version: 01 8 / 9 Preparation Information and Disclaimer To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. This document was prepared by FCSD-Toxicology, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA, based in part on information provided by the manufacturer. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. Part number(s) ZC-54 FIR No.: 171146 SDS US Issue Date: 05-15-2015 Version: 01 9 / 9