1. IDENTIFICATION Product identifier Product Name 14H THREAD SEALANT W/PTFE 4 FL.OZ. Other means of identification Product Code 80632 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Sealant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 4 Carcinogenicity Category 2 Specific target organ toxicity (single exposure) Category 1 Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 10 Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Danger Flammable liquids Revision Date 24-Apr-2015 Harmful if swallowed May cause cancer Causes damage to organs Flammable Liquid Category 3 SAFETY DATA SHEET Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA _____________________________________________________________________________________________ Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Do not breathe dust/fume/gas/mist/vapors/spray Keep away from heat/sparks/open flames/hot surfaces. ? No smoking Keep container tightly closed Take precautionary measures against static discharge Precautionary Statements - Response IF exposed: Call a POISON CENTER or doctor/physician Specific treatment (see supplemental first aid instructions on this label) IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth In case of fire: Use Water spray, fog or regular foam for extinction Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Harmful to aquatic life with long lasting effects. Unknown acute toxicity 65.99515% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret TALC 14807-96-6 15 - 40 * ETHANOL 64-17-5 10 - 30 * CASTOR OIL 8001-79-4 10 - 30 * POLYVINYL RESIN 63148-65-2 5 - 10 * 2-PROPANOL 67-63-0 1 - 5 * TITANIUM DIOXIDE 13463-67-7 1 - 5 * METHANOL 67-56-1 1 - 5 * POLYTETRAFLUOROETHYLENE 9002-84-0 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. _____________________________________________________________________________________________ Page 2 / 10 Revision Date 24-Apr-201580632 - 14H THREAD SEALANT W/PTFE 4 FL.OZ. Appearance White Physical state Paste Odor Alcoholic _____________________________________________________________________________________________ 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with soap and water. If symptoms persist, call a physician. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Flammable. Keep product and empty container away from heat and sources of ignition. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Remove all sources of ignition. Use personal protective equipment as required. Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up _____________________________________________________________________________________________ Page 3 / 10 80632 - 14H THREAD SEALANT W/PTFE 4 FL.OZ. Revision Date 24-Apr-2015 _____________________________________________________________________________________________ Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Store locked up. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH TALC 14807-96-6 TWA: 2 mg/m3 particulate matter containing no asbestos and <1% crystalline silica, respirable fraction (vacated) TWA: 2 mg/m3 respirable dust <1% Crystalline silica, containing no Asbestos TWA: 20 mppcf if 1% Quartz or more, use Quartz limit IDLH: 1000 mg/m3 TWA: 2 mg/m3 containing no Asbestos and <1% Quartz respirable dust ETHANOL 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 2-PROPANOL 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 TITANIUM DIOXIDE 13463-67-7 TWA: 10 mg/m3 TWA: 15 mg/m3 total dust (vacated) TWA: 10 mg/m3 total dust IDLH: 5000 mg/m3 METHANOL 67-56-1 STEL: 250 ppm TWA: 200 ppm S* TWA: 200 ppm TWA: 260 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 260 mg/m3 (vacated) STEL: 250 ppm (vacated) STEL: 325 mg/m3 (vacated) S* IDLH: 6000 ppm TWA: 200 ppm TWA: 260 mg/m3 STEL: 250 ppm STEL: 325 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems _____________________________________________________________________________________________ Page 4 / 10 80632 - 14H THREAD SEALANT W/PTFE 4 FL.OZ. Revision Date 24-Apr-2015 _____________________________________________________________________________________________ Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Paste Appearance White Odor Alcoholic Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 36.7% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. _____________________________________________________________________________________________ Page 5 / 10 Flash point Water solubility Partially soluble 23 ?C / 74 ?F Solubility in other solvents No information available Tag Closed Cup pH Partition coefficient No information available No information available Evaporation rate < 1 Autoignition temperature No information available 80632 - 14H THREAD SEALANT W/PTFE 4 FL.OZ. Decomposition temperature No information available Butyl acetate = 1 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: 12.7% Values Lower flammability limit: 2.3% Revision Date 24-Apr-2015 Vapor pressure 33 mm Hg @ 68?F Boiling point / boiling range 82 ?C / 180 ?F No data available Vapor density >1 Remarks ? Method Air = 1 Relative density 1.06-1.10 _____________________________________________________________________________________________ Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Fluorides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Harmful by inhalation. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion May be harmful if swallowed. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ETHANOL 64-17-5 = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h 2-PROPANOL 67-63-0 = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m3 ( Rat ) 4 h TITANIUM DIOXIDE 13463-67-7 > 10000 mg/kg ( Rat ) - - METHANOL 67-56-1 = 6200 mg/kg ( Rat ) = 15800 mg/kg ( Rabbit ) = 22500 ppm ( Rat ) 8 h = 64000 ppm ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA TALC 14807-96-6 - Group 3 - - ETHANOL 64-17-5 A3 Group 1 Known X 2-PROPANOL 67-63-0 - Group 1 - X TITANIUM DIOXIDE 13463-67-7 - Group 2B - X POLYTETRAFLUOROETHY LENE 9002-84-0 - Group 3 - - ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans Not classifiable as a human carcinogen NTP (National Toxicology Program) Known - Known Carcinogen _____________________________________________________________________________________________ Page 6 / 10 80632 - 14H THREAD SEALANT W/PTFE 4 FL.OZ. Revision Date 24-Apr-2015 _____________________________________________________________________________________________ OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Chronic toxicity May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Contains a known or suspected reproductive toxin. Target Organ Effects Blood, Central nervous system, Central Vascular System (CVS), Eyes, Gastrointestinal tract (GI), Liver, Lungs, Reproductive System, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 1811 mg/kg ATEmix (dermal) 6521 mg/kg ATEmix (inhalation-dust/mist) 11.7 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 35.44605% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea TALC 14807-96-6 - 100: 96 h Brachydanio rerio g/L LC50 semi-static - ETHANOL 64-17-5 - 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 9268 - 14221: 48 h Daphnia magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50 2-PROPANOL 67-63-0 1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50 11130: 96 h Pimephales promelas mg/L LC50 static 9640: 96 h Pimephales promelas mg/L LC50 flow-through 1400000: 96 h Lepomis macrochirus ?g/L LC50 13299: 48 h Daphnia magna mg/L EC50 METHANOL 67-56-1 - 28200: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static 19500 - 20700: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 13500 - 17600: 96 h Lepomis macrochirus mg/L LC50 flow-through 18 - 20: 96 h Oncorhynchus mykiss mL/L LC50 static - Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient ETHANOL 64-17-5 -0.32 2-PROPANOL 67-63-0 0.05 METHANOL 67-56-1 -0.77 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS _____________________________________________________________________________________________ Page 7 / 10 Revision Date 24-Apr-201580632 - 14H THREAD SEALANT W/PTFE 4 FL.OZ. _____________________________________________________________________________________________ Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes METHANOL 67-56-1 - Included in waste stream: F039 - U154 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ETHANOL 64-17-5 Toxic Ignitable 2-PROPANOL 67-63-0 Toxic Ignitable METHANOL67-56-1 Toxic Ignitable 14. TRANSPORT INFORMATION DOT UN/ID no 1133 Proper shipping name: Adhesives, Limited Quantity (LQ) Hazard Class 3 Packing Group III Emergency Response Guide Number 128 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1133 Proper shipping name: Adhesives, Limited Quantity (LQ) Hazard Class 3 Packing Group III EmS-No F-E, S-D 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not Listed. ENCS Not Listed. IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory _____________________________________________________________________________________________ Page 8 / 10 80632 - 14H THREAD SEALANT W/PTFE 4 FL.OZ. Revision Date 24-Apr-2015 _____________________________________________________________________________________________ DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % 2-PROPANOL - 67-63-0 1.0 METHANOL - 67-56-1 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) METHANOL 67-56-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 ETHANOL - 64-17-5 Carcinogen Developmental TITANIUM DIOXIDE - 13463-67-7 Carcinogen METHANOL - 67-56-1 Developmental METHYL ISOBUTYL KETONE - 108-10-1 Carcinogen Developmental U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania TALC 14807-96-6 X X X ETHANOL 64-17-5 X X X 2-PROPANOL 67-63-0 X X X TITANIUM DIOXIDE 13463-67-7 X X X WATER 7732-18-5 - - X METHANOL 67-56-1 X X X POLYTETRAFLUOROETHYLENE 9002-84-0 - - X _____________________________________________________________________________________________ Page 9 / 10 Revision Date 24-Apr-201580632 - 14H THREAD SEALANT W/PTFE 4 FL.OZ. _____________________________________________________________________________________________ METHYL ISOBUTYL KETONE 108-10-1 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 24-Apr-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 10 / 10 - Revision Date 24-Apr-2015 HMIS NFPA Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B Health hazards 2 Flammability 3 80632 - 14H THREAD SEALANT W/PTFE 4 FL.OZ. Instability 0