1. IDENTIFICATION Product identifier Product Name 101MA COPPER SPRAY-A-GASKET 9 OZ Other means of identification Product Code 80697 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Sealant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Serious eye damage/eye irritation Category 2 Carcinogenicity Category 2 Specific target organ toxicity (single exposure) Category 3 Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 10 Danger Extremely flammable aerosol Revision Date 22-Apr-2015 Causes serious eye irritation Suspected of causing cancer May cause drowsiness or dizziness Category 1 Extremely flammable aerosol Pressurized container: May burst if heated SAFETY DATA SHEET Version 3 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 _____________________________________________________________________________________________ Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Precautionary Statements - Storage Store locked up Do not expose to temperatures exceeding 122 ?F (50 ?C) Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0.1 % w/w 1,3-butadiene (EINECS No. 203-450-8). If the substance is not classified as a carcinogen or mutagen, at least the S-phrases (2-)9-16 (Table 3.2) should apply. This note applies only to certain complex oil-derived substances in Part 3 Unknown acute toxicity 2.5% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret PETROLEUM GASES, LIQUEFIED, SWEETENED 68476-86-8 30 - 60 * ACETONE 67-64-1 15 - 40 * DICHLOROMETHANE 75-09-2 10 - 30 * ETHYL ACETATE 141-78-6 3 - 7 * SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. 64742-89-8 1 - 5 * COPPER 7440-50-8 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES _____________________________________________________________________________________________ Page 2 / 10 80697 - 101MA COPPER SPRAY-A-GASKET 9 OZ Revision Date 22-Apr-2015 Physical state Liquid Aerosol Odor SolventAppearance Copper colored _____________________________________________________________________________________________ Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with soap and water. If symptoms persist, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms May cause redness and tearing of the eyes. Drowsiness. Dizziness. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Extremely flammable. Vapors may travel to source of ignition and flash back. Thermal decomposition can lead to release of irritating and toxic gases and vapors. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. _____________________________________________________________________________________________ Page 3 / 10 80697 - 101MA COPPER SPRAY-A-GASKET 9 OZ Revision Date 22-Apr-2015 _____________________________________________________________________________________________ Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Contents under pressure. Take precautionary measures against static discharges. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store locked up. Incompatible materials Strong oxidizing agents, Alkali 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ACETONE 67-64-1 STEL: 750 ppm TWA: 500 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 DICHLOROMETHANE 75-09-2 TWA: 50 ppm TWA: 25 ppm (vacated) TWA: 500 ppm (vacated) STEL: 2000 ppm 5 min in any 3 h (vacated) Ceiling: 1000 ppm STEL: 125 ppm see 29 CFR 1910.1052 IDLH: 2300 ppm ETHYL ACETATE 141-78-6 TWA: 400 ppm TWA: 400 ppm TWA: 1400 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 1400 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 1400 mg/m3 COPPER 7440-50-8 TWA: 1 mg/m3 Cu dust and mist TWA: 0.1 mg/m3 fume TWA: 1 mg/m3 dust and mist (vacated) TWA: 0.1 mg/m3 Cu dust, fume, mist IDLH: 100 mg/m3 Cu dust and mist TWA: 1 mg/m3 Cu dust and mist NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls _____________________________________________________________________________________________ Page 4 / 10 80697 - 101MA COPPER SPRAY-A-GASKET 9 OZ Revision Date 22-Apr-2015 _____________________________________________________________________________________________ Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid, Aerosol Appearance Copper colored Odor Solvent Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 44.9% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity _____________________________________________________________________________________________ Page 5 / 10 Relative density 1.05 Revision Date 22-Apr-2015 Flash point Water solubility Negligible None Solubility in other solvents No information available Gives a flame projection at full valve opening or flashback at any degree of valve opening pH Partition coefficient No information available No information available Evaporation rate >1 Autoignition temperature No information available Decomposition temperature No information available Butyl acetate = 1 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available 80697 - 101MA COPPER SPRAY-A-GASKET 9 OZ Vapor pressure Not determined Boiling point / boiling range > 38 ?C / 100 ?F No data available Vapor density >1 Remarks ? Method Air = 1 _____________________________________________________________________________________________ Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Take precautionary measures against static discharges. Incompatible materials Strong oxidizing agents, Alkali Hazardous Decomposition Products Carbon oxides Hydrogen chloride 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May be harmful by inhalation. Vapors may be irritating to eyes, nose, throat, and lungs. May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ACETONE 67-64-1 = 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h DICHLOROMETHANE 75-09-2 = 1600 mg/kg ( Rat ) - = 53 mg/L ( Rat ) 6 h = 76000 mg/m3 ( Rat ) 4 h ETHYL ACETATE 141-78-6 = 5620 mg/kg ( Rat ) > 18000 mg/kg ( Rabbit ) > 20 mL/kg ( Rabbit ) - SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. 64742-89-8 - = 3000 mg/kg ( Rabbit ) - Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA DICHLOROMETHANE 75-09-2 A3 Group 2A Reasonably Anticipated X ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 2A - Probably Carcinogenic to Humans NTP (National Toxicology Program) Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Chronic toxicity May cause adverse liver effects. _____________________________________________________________________________________________ Page 6 / 10 80697 - 101MA COPPER SPRAY-A-GASKET 9 OZ Revision Date 22-Apr-2015 _____________________________________________________________________________________________ Target Organ Effects Central nervous system, Central Vascular System (CVS), Eyes, kidney, Liver, Lungs, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 5387 mg/kg ATEmix (dermal) 90022 mg/kg ATEmix (inhalation-dust/mist) 334 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 40.5% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea ACETONE 67-64-1 - 4.74 - 6.33: 96 h Oncorhynchus mykiss mL/L LC50 6210 - 8120: 96 h Pimephales promelas mg/L LC50 static 8300: 96 h Lepomis macrochirus mg/L LC50 10294 - 17704: 48 h Daphnia magna mg/L EC50 Static 12600 - 12700: 48 h Daphnia magna mg/L EC50 DICHLOROMETHANE 75-09-2 500: 96 h Pseudokirchneriella subcapitata mg/L EC50 500: 72 h Pseudokirchneriella subcapitata mg/L EC50 140.8 - 277.8: 96 h Pimephales promelas mg/L LC50 flow-through 262 - 855: 96 h Pimephales promelas mg/L LC50 static 193: 96 h Lepomis macrochirus mg/L LC50 static 193: 96 h Lepomis macrochirus mg/L LC50 flow-through 1532 - 1847: 48 h Daphnia magna mg/L EC50 Static 190: 48 h Daphnia magna mg/L EC50 ETHYL ACETATE 141-78-6 3300: 48 h Desmodesmus subspicatus mg/L EC50 352 - 500: 96 h Oncorhynchus mykiss mg/L LC50 semi-static 220 - 250: 96 h Pimephales promelas mg/L LC50 flow-through 484: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 560: 48 h Daphnia magna mg/L EC50 Static SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. 64742-89-8 4700: 72 h Pseudokirchneriella subcapitata mg/L EC50 - - COPPER 7440-50-8 0.0426 - 0.0535: 72 h Pseudokirchneriella subcapitata mg/L EC50 static 0.031 - 0.054: 96 h Pseudokirchneriella subcapitata mg/L EC50 static 0.2: 96 h Pimephales promelas mg/L LC50 flow-through 0.052: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 1.25: 96 h Lepomis macrochirus mg/L LC50 static 0.3: 96 h Cyprinus carpio mg/L LC50 semi-static 0.8: 96 h Cyprinus carpio mg/L LC50 static 0.112: 96 h Poecilia reticulata mg/L LC50 flow-through 0.0068 - 0.0156: 96 h Pimephales promelas mg/L LC50 0.3: 96 h Pimephales promelas mg/L LC50 static 0.03: 48 h Daphnia magna mg/L EC50 Static Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient PETROLEUM GASES, LIQUEFIED, SWEETENED 68476-86-8 <=2.8 ACETONE 67-64-1 -0.24 DICHLOROMETHANE 75-09-2 1.25 _____________________________________________________________________________________________ Page 7 / 10 80697 - 101MA COPPER SPRAY-A-GASKET 9 OZ Revision Date 22-Apr-2015 _____________________________________________________________________________________________ ETHYL ACETATE 141-78-6 0.6 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number D001, F002 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes ACETONE 67-64-1 - Included in waste stream: F039 - U002 DICHLOROMETHANE 75-09-2 - Included in waste streams: F001, F002, F024, F025, F039, K009, K010, K156, K157, K158 - U080 ETHYL ACETATE 141-78-6 - Included in waste stream: F039 - U112 Chemical Name RCRA - Halogenated Organic Compounds RCRA - P Series Wastes RCRA - F Series Wastes RCRA - K Series Wastes DICHLOROMETHANE 75-09-2 Category I - Volatiles - Toxic waste waste number F025 Waste description: Condensed light ends, spent filters and filter aids, and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons, by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from one to and including five, with varying amounts and positions of chlorine substitution. - This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ACETONE 67-64-1 Ignitable DICHLOROMETHANE 75-09-2 Toxic ETHYL ACETATE 141-78-6 Toxic Ignitable COPPER 7440-50-8 Toxic 14. TRANSPORT INFORMATION DOT UN/ID no UN 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) _____________________________________________________________________________________________ Page 8 / 10 80697 - 101MA COPPER SPRAY-A-GASKET 9 OZ Revision Date 22-Apr-2015 _____________________________________________________________________________________________ Hazard Class 2.1 Emergency Response Guide Number 126 IATA UN/ID no UN 1950 Proper shipping name: Aerosols, flammable Hazard Class 2.1 Subsidiary hazard class 6.1 ERG Code 10P IMDG UN/ID no UN 1950 Proper shipping name: Aerosols Hazard Class 2.1 EmS-No F-D, S-U 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Not Listed. IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % DICHLOROMETHANE - 75-09-2 0.1 COPPER - 7440-50-8 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances DICHLOROMETHANE 75-09-2 - X X - _____________________________________________________________________________________________ Page 9 / 10 Revision Date 22-Apr-201580697 - 101MA COPPER SPRAY-A-GASKET 9 OZ _____________________________________________________________________________________________ COPPER 7440-50-8 - X X - CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ DICHLOROMETHANE 75-09-2 1 lb - RQ 1 lb final RQ RQ 0.454 kg final RQ ETHYL ACETATE 141-78-6 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ COPPER 7440-50-8 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 DICHLOROMETHANE - 75-09-2 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania ACETONE 67-64-1 X X X DICHLOROMETHANE 75-09-2 X X X ETHYL ACETATE 141-78-6 X X X COPPER 7440-50-8 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 22-Apr-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 10 / 10 - 80697 - 101MA COPPER SPRAY-A-GASKET 9 OZ HMIS NFPA Health hazards 3 Flammability 3 Revision Date 22-Apr-2015 Physical hazards 0 Personal protection B Health hazards 3 Flammability 3 Instability 0