1. IDENTIFICATION Product identifier Product Name 26BR HIGH TEMP RTV RED SILICONE GASKET MAKER 3 OZ Other means of identification Product Code 81160 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Sealant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 9 SAFETY DATA SHEET Version 1 Causes skin irritation Causes serious eye irritation Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 04-Mar-2015 Warning _____________________________________________________________________________________________ Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Precautionary Statements - Storage Store in a well-ventilated place. Keep cool Protect from moisture Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information The classification as a carcinogen need not apply if the full refining history is known and it can be shown that the substance from which it is produced is not a carcinogen. This note applies only to certain complex oil derived substances in Annex I Unknown acute toxicity 12.3% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Chemical Name CAS No Weight-% Trade Secret POLY (DIMETHYLSILOXANE), HYDROXY TERMINATED 70131-67-8 40 - 70 * AMORPHOUS SILICA 7631-86-9 7 - 13 * DISTILLATES (PETROLEUM), HYDROTREATED MIDDLE 64742-46-7 3 - 7 * IRON OXIDE 1309-37-1 1 - 5 * TITANIUM DIOXIDE 13463-67-7 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. _____________________________________________________________________________________________ Page 2 / 9 Revision Date 04-Mar-201581160 - 26BR HIGH TEMP RTV RED SILICONE GASKET MAKER 3 OZ Odor Acetic acidAppearance Red Physical state Paste _____________________________________________________________________________________________ Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Self-protection of the first aider Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Flood with water to complete polymerization and scrape off floor. Sweep up and shovel into suitable containers for disposal. _____________________________________________________________________________________________ Page 3 / 9 81160 - 26BR HIGH TEMP RTV RED SILICONE GASKET MAKER 3 OZ Revision Date 04-Mar-2015 _____________________________________________________________________________________________ Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moisture. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH AMORPHOUS SILICA 7631-86-9 - (vacated) TWA: 6 mg/m3 <1% Crystalline silica TWA: 20 mppcf : (80)/(% SiO2) mg/m3 TWA IDLH: 3000 mg/m3 TWA: 6 mg/m3 IRON OXIDE 1309-37-1 TWA: 5 mg/m3 respirable fraction TWA: 10 mg/m3 fume TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 10 mg/m3 fume and total dust Iron oxide (vacated) TWA: 5 mg/m3 respirable fraction regulated under Rouge IDLH: 2500 mg/m3 Fe dust and fume TWA: 5 mg/m3 Fe dust and fume TITANIUM DIOXIDE 13463-67-7 TWA: 10 mg/m3 TWA: 15 mg/m3 total dust (vacated) TWA: 10 mg/m3 total dust IDLH: 5000 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES _____________________________________________________________________________________________ Page 4 / 9 81160 - 26BR HIGH TEMP RTV RED SILICONE GASKET MAKER 3 OZ Revision Date 04-Mar-2015 _____________________________________________________________________________________________ Information on basic physical and chemical properties Physical state Paste Appearance Red Odor Acetic acid Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) <3% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Exposure to air or moisture over prolonged periods. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides, Nitrogen oxides (NOx), Formaldehyde, May release 2-butanone oxime (ethyl methyl ketoxime) at elevated temperature 11. TOXICOLOGICAL INFORMATION _____________________________________________________________________________________________ Page 5 / 9 Does not apply Evaporation rate <1 Autoignition temperature No information available Decomposition temperature No information available Butyl acetate = 1 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available 81160 - 26BR HIGH TEMP RTV RED SILICONE GASKET MAKER 3 OZ Vapor pressure 10 mm Hg Boiling point / boiling range Not Applicable No data available Vapor density >1 Remarks ? Method Air = 1 Polymerization Relative density 1.05 Revision Date 04-Mar-2015 Flash point Water solubility Not applicable > 93 ?C / > 199 ?F Polymerization Solubility in other solvents No information available Tag Closed Cup pH Partition coefficient No information available _____________________________________________________________________________________________ Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 POLY (DIMETHYLSILOXANE), HYDROXY TERMINATED 70131-67-8 - > 16 mL/kg ( Rabbit ) > 8750 mg/m3 ( Rat ) 7 h AMORPHOUS SILICA 7631-86-9 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 2.2 mg/L ( Rat ) 1 h DISTILLATES (PETROLEUM), HYDROTREATED MIDDLE 64742-46-7 = 7400 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 4.6 mg/L ( Rat ) 4 h IRON OXIDE 1309-37-1 > 10000 mg/kg ( Rat ) - - TITANIUM DIOXIDE 13463-67-7 > 10000 mg/kg ( Rat ) - - Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA AMORPHOUS SILICA 7631-86-9 - Group 3 - - IRON OXIDE 1309-37-1 - Group 3 - - TITANIUM DIOXIDE 13463-67-7 - Group 2B - X IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans Not classifiable as a human carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target Organ Effects Eyes, Lungs, Respiratory system, Skin, Teeth. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 17289 mg/kg ATEmix (dermal) 6094 mg/kg ATEmix (inhalation-dust/mist) 4.8 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity None known 82.1% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea _____________________________________________________________________________________________ Page 6 / 9 Revision Date 04-Mar-201581160 - 26BR HIGH TEMP RTV RED SILICONE GASKET MAKER 3 OZ _____________________________________________________________________________________________ AMORPHOUS SILICA 7631-86-9 440: 72 h Pseudokirchneriella subcapitata mg/L EC50 5000: 96 h Brachydanio rerio mg/L LC50 static 7600: 48 h Ceriodaphnia dubia mg/L EC50 DISTILLATES (PETROLEUM), HYDROTREATED MIDDLE 64742-46-7 - 35: 96 h Pimephales promelas mg/L LC50 flow-through 10000: 96 h Pimephales promelas mg/L LC50 static - Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable This product contains one or more substances that are listed with the State of California as a hazardous waste. 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Does not comply ENCS Does not comply IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory _____________________________________________________________________________________________ Page 7 / 9 81160 - 26BR HIGH TEMP RTV RED SILICONE GASKET MAKER 3 OZ Revision Date 04-Mar-2015 _____________________________________________________________________________________________ DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 TITANIUM DIOXIDE - 13463-67-7 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania AMORPHOUS SILICA 7631-86-9 X X X IRON OXIDE 1309-37-1 X X X TITANIUM DIOXIDE 13463-67-7 X X X ACETIC ACID 64-19-7 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 04-Mar-2015 _____________________________________________________________________________________________ Page 8 / 9 Health hazards 1 Flammability 1 Revision Date 04-Mar-2015 Instability 0 - HMIS NFPA Health hazards 1 Flammability 1 81160 - 26BR HIGH TEMP RTV RED SILICONE GASKET MAKER 3 OZ Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 9 / 9 81160 - 26BR HIGH TEMP RTV RED SILICONE GASKET MAKER 3 OZ Revision Date 04-Mar-2015