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1. IDENTIFICATION Product identifier Product Name RUST DISSOLVER GEL 8 FL.OZ Other means of identification Product Code 81756 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Rust dissolver Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 1 Sub-category B Serious eye damage/eye irritation Category 1 Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 9 Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Causes severe skin burns and eye damage Revision Date 29-Apr-2015 SAFETY DATA SHEET Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Danger _____________________________________________________________________________________________ Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Immediately call a POISON CENTER or doctor/physician Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a POISON CENTER or doctor/physician IF SWALLOWED: Rinse mouth. DO NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Harmful to aquatic life with long lasting effects. Unknown acute toxicity 3.1302% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret WATER 7732-18-5 40 - 70 * PHOSPHORIC ACID 7664-38-2 10 - 30 * 2-PROPANOL 67-63-0 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). _____________________________________________________________________________________________ Page 2 / 9 81756 - RUST DISSOLVER GEL 8 FL.OZ Revision Date 29-Apr-2015 Appearance Pink Physical state Gel Odor Lime _____________________________________________________________________________________________ Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with soap and water. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. _____________________________________________________________________________________________ Page 3 / 9 81756 - RUST DISSOLVER GEL 8 FL.OZ Revision Date 29-Apr-2015 _____________________________________________________________________________________________ Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Store locked up. Keep from freezing. Incompatible materials Strong oxidizing agents, Caustics 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH PHOSPHORIC ACID 7664-38-2 STEL: 3 mg/m3 TWA: 1 mg/m3 TWA: 1 mg/m3 (vacated) TWA: 1 mg/m3 (vacated) STEL: 3 mg/m3 IDLH: 1000 mg/m3 TWA: 1 mg/m3 STEL: 3 mg/m3 2-PROPANOL 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Gel Appearance Pink Odor Lime Odor threshold No information available _____________________________________________________________________________________________ Page 4 / 9 81756 - RUST DISSOLVER GEL 8 FL.OZ Revision Date 29-Apr-2015 _____________________________________________________________________________________________ Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 2.4% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Keep from freezing. Incompatible materials Strong oxidizing agents, Caustics Hazardous Decomposition Products Carbon oxides Phosphorus 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Causes burns. Eye contact Corrosive to the eyes and may cause severe damage including blindness. _____________________________________________________________________________________________ Page 5 / 9 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available 81756 - RUST DISSOLVER GEL 8 FL.OZ Vapor pressure 12 mmHg @ 20?C Boiling point / boiling range 100 ?C / 212 ?F No data available Vapor density >1 Remarks ? Method Air = 1 Relative density 1.18 Flash point Water solubility Soluble in water None Revision Date 29-Apr-2015 Solubility in other solvents No information available pH Partition coefficient No information available 1.5-2.5 Evaporation rate < 1 Autoignition temperature No information available Decomposition temperature No information available Butyl acetate = 1 _____________________________________________________________________________________________ Skin contact Corrosive. Contact causes severe skin irritation and possible burns. Ingestion Can burn mouth, throat, and stomach. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 WATER 7732-18-5 > 90 mL/kg ( Rat ) - - PHOSPHORIC ACID 7664-38-2 = 1530 mg/kg ( Rat ) = 2740 mg/kg ( Rabbit ) > 850 mg/m3 ( Rat ) 1 h 2-PROPANOL 67-63-0 = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m3 ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA 2-PROPANOL 67-63-0 - Group 1 - X IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Not classifiable as a human carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target Organ Effects Eyes, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 5515 mg/kg ATEmix (dermal) 9997 mg/kg ATEmix (inhalation-dust/mist) 0.8 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 3.7192% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea PHOSPHORIC ACID 7664-38-2 - 3 - 3.5: 96 h Gambusia affinis mg/L LC50 4.6: 12 h Daphnia magna mg/L EC50 2-PROPANOL 67-63-0 1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50 11130: 96 h Pimephales promelas mg/L LC50 static 9640: 96 h Pimephales promelas mg/L LC50 flow-through 1400000: 96 h Lepomis macrochirus ?g/L LC50 13299: 48 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient 2-PROPANOL 67-63-0 0.05 _____________________________________________________________________________________________ Page 6 / 9 81756 - RUST DISSOLVER GEL 8 FL.OZ Revision Date 29-Apr-2015 _____________________________________________________________________________________________ Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number D002 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status PHOSPHORIC ACID 7664-38-2 Corrosive 2-PROPANOL 67-63-0 Toxic Ignitable 14. TRANSPORT INFORMATION DOT UN/ID no 3264 Proper shipping name: Corrosive liquid, acidic, inorganic, n.o.s, (phosphoric acid), Limited Quantity (LQ) Hazard Class 8 Packing Group III Emergency Response Guide Number 154 IATA UN/ID no 3264 Proper shipping name: Corrosive liquid, acidic, inorganic, n.o.s, (phosphoric acid), Limited Quantity (LQ) Hazard Class 8 Packing Group III ERG Code 8L IMDG UN/ID no 3264 Proper shipping name: Corrosive liquid, acidic, inorganic, n.o.s, (phosphoric acid), Limited Quantity (LQ) Hazard Class 8 Packing Group III EmS-No F-A, S-B 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Not Listed. IECSC Complies KECL Complies PICCS Complies AICS Complies _____________________________________________________________________________________________ Page 7 / 9 81756 - RUST DISSOLVER GEL 8 FL.OZ Revision Date 29-Apr-2015 _____________________________________________________________________________________________ Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % 2-PROPANOL - 67-63-0 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances PHOSPHORIC ACID 7664-38-2 5000 lb - - X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) PHOSPHORIC ACID 7664-38-2 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 RHODAMINE - 81-88-9 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania PHOSPHORIC ACID 7664-38-2 X X X 2-PROPANOL 67-63-0 X X X ETHANOLAMINE 141-43-5 X X X RHODAMINE 81-88-9 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable _____________________________________________________________________________________________ Page 8 / 9 Revision Date 29-Apr-201581756 - RUST DISSOLVER GEL 8 FL.OZ _____________________________________________________________________________________________ NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 29-Apr-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 9 / 9 - 81756 - RUST DISSOLVER GEL 8 FL.OZ HMIS NFPA Health hazards 3 Flammability 0 Revision Date 29-Apr-2015 Physical hazards 0 Personal protection B Health hazards 3 Flammability 0 Instability 0