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SAFETY DATA SHEET Revision Date 30-Jan-2015 Version 1 1. IDENTIFICATION Product identifier Product Name 81844 REARVIEW MIRROR ADHESIVE KIT PART 1 Other means of identification Product Code PTX194319X Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Adhesives Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 1 Sub-category B Serious eye damage/eye irritation Category 2A Skin sensitization Category 1 Specific target organ toxicity (repeated exposure) Category 2 Label elements Emergency Overview Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA _____________________________________________________________________________________________ Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Danger Page 1 / 9 Causes severe skin burns and eye damage May cause an allergic skin reaction May cause damage to organs through prolonged or repeated exposure Combustible liquid _____________________________________________________________________________________________ PTX194319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 1 Revision Date 30-Jan-2015 Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Contaminated work clothing should not be allowed out of the workplace Precautionary Statements - Response Immediately call a POISON CENTER or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse If skin irritation or rash occurs: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a POISON CENTER or doctor/physician IF SWALLOWED: Rinse mouth. DO NOT induce vomiting Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information May be harmful if swallowed. May be harmful in contact with skin. Unknown acute toxicity 46.49% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Chemical Name CAS No Weight-% Trade Secret POLYURETHANE METHACRYLATE RESIN (MIXTURE) _ 30 - 60 * HYDROXYALKYL METHACRYLATE 27813-02-1 15 - 40 * ALIPHATIC URETHANE METHACRYLATE 3290-92-4 5 - 10 * ACRYLIC ACID 79-10-7 3 - 7 * DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 1 - 5 * SACCHARIN 81-07-2 1 - 5 * 2-HYDROXYETHYL METHACRYLATE 868-77-9 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. _____________________________________________________________________________________________ Appearance Yellow Page 2 / 9 Physical state Liquid Odor Irritating _____________________________________________________________________________________________ PTX194319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 1 Revision Date 30-Jan-2015 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. _____________________________________________________________________________________________ Environmental precautions Environmental precautions Page 3 / 9 Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. _____________________________________________________________________________________________ PTX194319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 1 Revision Date 30-Jan-2015 Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible materials Strong oxidizing agents. Strong bases. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ACRYLIC ACID 79-10-7 TWA: 2 ppm S* (vacated) TWA: 10 ppm (vacated) TWA: 30 mg/m3 (vacated) S* TWA: 2 ppm TWA: 6 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES _____________________________________________________________________________________________ Information on basic physical and chemical properties Physical state Liquid Page 4 / 9 Appearance Yellow _____________________________________________________________________________________________ PTX194319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 1 Revision Date 30-Jan-2015 Odor Irritating Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 5.3% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents, Strong bases Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Property Values Remarks ? Method pH Does not apply Melting point / freezing point No information available Boiling point / boiling range > 149 ?C / 300 ?F Flash point > 93 ?C / > 199 ?F Cleveland Open Cup Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure <5 mmHg @ 75?F Vapor density No information available Relative density 1.1 @ 80?F Water solubility No information available Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity _____________________________________________________________________________________________ No information available Dynamic viscosity No information available Page 5 / 9 No data available _____________________________________________________________________________________________ PTX194319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 1 Revision Date 30-Jan-2015 Eye contact Irritating to eyes. May cause redness and tearing of the eyes. Skin contact Contact causes severe skin irritation and possible burns. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 HYDROXYALKYL METHACRYLATE 27813-02-1 = 11200 mg/kg ( Rat ) > 3000 mg/kg ( Rabbit ) - ALIPHATIC URETHANE METHACRYLATE 3290-92-4 = 5660 ?L/kg ( Rat ) = 16 mL/kg ( Rabbit ) - ACRYLIC ACID 79-10-7 = 193 mg/kg ( Rat ) = 33500 ?g/kg ( Rat ) = 280 ?L/kg ( Rabbit ) = 295 mg/kg ( Rabbit ) = 11.1 mg/L ( Rat ) 1 h = 3.6 mg/L ( Rat ) 4 h DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 = 382 mg/kg ( Rat ) = 0.126 mL/kg ( Rabbit ) = 220 ppm ( Rat ) 4 h 2-HYDROXYETHYL METHACRYLATE 868-77-9 = 5050 mg/kg ( Rat ) > 3000 mg/kg ( Rabbit ) - Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA ACRYLIC ACID 79-10-7 - Group 3 - - SACCHARIN 81-07-2 - Group 3 - - IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen Target Organ Effects Eyes, Respiratory system, Skin. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 2504 mg/kg ATEmix (dermal) 2750 mg/kg ATEmix (inhalation-dust/mist) 6.4 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity None known 80.99% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea HYDROXYALKYL METHACRYLATE 27813-02-1 - _____________________________________________________________________________________________ 493: 48 h Leuciscus idus melanotus mg/L LC50 static - ALIPHATIC URETHANE METHACRYLATE 3290-92-4 - Page 6 / 9 144: 96 h Oncorhynchus mykiss mg/L LC50 160: 96 h Pimephales promelas mg/L LC50 112: 96 h Lepomis macrochirus mg/L LC50 - _____________________________________________________________________________________________ PTX194319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 1 Revision Date 30-Jan-2015 ACRYLIC ACID 79-10-7 0.17: 96 h Pseudokirchneriella subcapitata mg/L EC50 0.04: 72 h Desmodesmus subspicatus mg/L EC50 222: 96 h Brachydanio rerio mg/L LC50 semi-static 95: 48 h Daphnia magna mg/L EC50 270: 24 h Daphnia magna mg/L LC50 Static DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 - 3.9: 96 h Oncorhynchus mykiss mg/L LC50 static 7: 24 h Daphnia magna mg/L EC50 SACCHARIN 81-07-2 - 18300: 96 h Pimephales promelas mg/L LC50 - 2-HYDROXYETHYL METHACRYLATE 868-77-9 - 213 - 242: 96 h Pimephales promelas mg/L LC50 flow-through 227: 96 h Pimephales promelas mg/L LC50 - Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient HYDROXYALKYL METHACRYLATE 27813-02-1 0.97 ACRYLIC ACID 79-10-7 0.38 - 0.46 2-HYDROXYETHYL METHACRYLATE 868-77-9 0.47 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes ACRYLIC ACID 79-10-7 - - - U008 DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 - - - U096 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 Toxic Ignitable _____________________________________________________________________________________________ 14. TRANSPORT INFORMATION Page 7 / 9 DOT _____________________________________________________________________________________________ PTX194319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 1 Revision Date 30-Jan-2015 Proper shipping name Not regulated TDG Proper shipping name Not regulated ICAO (air) Proper shipping name Not regulated IATA Proper shipping name Not regulated IMDG Proper shipping name Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Does not comply ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % ACRYLIC ACID - 79-10-7 1.0 DIMETHYLBENZYL HYDROPEROXIDE - 80-15-9 1.0 SACCHARIN - 81-07-2 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard No Sudden release of pressure hazard No _____________________________________________________________________________________________ Reactive Hazard No Page 8 / 9 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) _____________________________________________________________________________________________ PTX194319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 1 Revision Date 30-Jan-2015 CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACRYLIC ACID 79-10-7 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 10 lb - RQ 10 lb final RQ RQ 4.54 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania ACRYLIC ACID 79-10-7 X X X DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 X X X SACCHARIN 81-07-2 X X X PROPYLENE GLYCOL 57-55-6 X - X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 30-Jan-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 2 Flammability 1 Instability 0 _____________________________________________________________________________________________ - HMIS Health hazards 2 Flammability 1 Page 9 / 9 Physical hazards 0 Personal protection B SAFETY DATA SHEET Revision Date 03-Feb-2015 Version 1 1. IDENTIFICATION Product identifier Product Name 81844 REARVIEW MIRROR ADHESIVE KIT PART 2 Other means of identification Product Code PTX394319X Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Activator Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 4 Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 1 Label elements Emergency Overview Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Flammable liquids _____________________________________________________________________________________________ Category 2 Danger Page 1 / 9 Harmful if swallowed Causes serious eye irritation May cause drowsiness or dizziness Causes damage to organs through prolonged or repeated exposure Highly flammable liquid and vapor _____________________________________________________________________________________________ PTX394319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 2 Revision Date 03-Feb-2015 Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Wear eye/face protection Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. ? No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/ .? /equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0,1 % w/w benzene (EINECS No 200-753-7). Copper compounds. Unknown acute toxicity 2.38% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Chemical Name CAS No Weight-% Trade Secret _____________________________________________________________________________________________ Appearance Green Page 2 / 9 Physical state Liquid Odor Alcoholic _____________________________________________________________________________________________ PTX394319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 2 Revision Date 03-Feb-2015 2-PROPANOL 67-63-0 60 - 100 * MINERAL SPIRITS 8052-41-3 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If symptoms persist, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire. Specific hazards arising from the chemical Flammable. May be ignited by heat, sparks or flames. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES _____________________________________________________________________________________________ Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Page 3 / 9 Environmental precautions _____________________________________________________________________________________________ PTX394319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 2 Revision Date 03-Feb-2015 Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Use a non-combustible material like vermiculite or sand to soak up the product and place into a container for later disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Incompatible materials Strong oxidizing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH 2-PROPANOL 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 MINERAL SPIRITS 8052-41-3 TWA: 100 ppm TWA: 500 ppm TWA: 2900 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 525 mg/m3 IDLH: 20000 mg/m3 Ceiling: 1800 mg/m3 15 min TWA: 350 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment _____________________________________________________________________________________________ Eye/face protection Wear safety glasses with side shields (or goggles). Page 4 / 9 Skin and body protection Wear protective gloves and protective clothing. _____________________________________________________________________________________________ PTX394319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 2 Revision Date 03-Feb-2015 Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Green Odor Alcoholic Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 96.5 Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Take precautionary measures against static discharges. Property Values Remarks ? Method pH Does not apply Melting point / freezing point No information available Boiling point / boiling range 82 ?C / 180 ?F Flash point 12 ?C / 53 ?F Tag Closed Cup Evaporation rate 7.7 Butyl acetate = 1 Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: 12.0% Lower flammability limit: 2.0% Vapor pressure 32 mm Hg @ 68?F Vapor density 2.1 Air = 1 Relative density 0.79 @ 77?F Water solubility Soluble in water Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity _____________________________________________________________________________________________ No information available Dynamic viscosity No information available Page 5 / 9 No data available _____________________________________________________________________________________________ PTX394319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 2 Revision Date 03-Feb-2015 Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May be harmful by inhalation. Eye contact May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion May be harmful if swallowed. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 2-PROPANOL 67-63-0 = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m3 ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA 2-PROPANOL 67-63-0 - Group 1 - X IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target Organ Effects Central nervous system, Eyes, kidney, Respiratory system, Skin. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 1938 mg/kg ATEmix (dermal) 4206 mg/kg ATEmix (inhalation-dust/mist) 75.2 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity None known 3.5% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea 2-PROPANOL 67-63-0 _____________________________________________________________________________________________ 1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50 11130: 96 h Pimephales promelas mg/L LC50 static 9640: 96 h Pimephales promelas mg/L LC50 flow-through 1400000: 96 h Lepomis macrochirus ?g/L LC50 13299: 48 h Daphnia magna mg/L EC50 Page 6 / 9 Persistence and degradability No information available. _____________________________________________________________________________________________ PTX394319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 2 Revision Date 03-Feb-2015 Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient 2-PROPANOL 67-63-0 0.05 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status 2-PROPANOL 67-63-0 Toxic Ignitable 14. TRANSPORT INFORMATION DOT Proper shipping name Isopropyl alcohol, Limited Quantity (LQ) Hazard Class 3 Packing Group II TDG UN/ID no UN 1219 Proper shipping name Isopropyl alcohol, Limited Quantity (LQ) Hazard Class 3 Packing Group II ICAO (air) UN/ID no ID 8000 Proper shipping name Consumer commodity Hazard Class 9 IATA UN/ID no ID 8000 Proper shipping name Consumer commodity Hazard Class 9 IMDG _____________________________________________________________________________________________ UN/ID no UN 1219 Page 7 / 9 Proper shipping name Isopropyl alcohol, Limited Quantity (LQ) _____________________________________________________________________________________________ PTX394319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 2 Revision Date 03-Feb-2015 Hazard Class 3 Packing Group II EmS-No F-E, S-D 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % 2-PROPANOL - 67-63-0 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations _____________________________________________________________________________________________ California Proposition 65 This product does not contain any Proposition 65 chemicals Page 8 / 9 U.S. State Right-to-Know Regulations _____________________________________________________________________________________________ PTX394319X - 81844 REARVIEW MIRROR ADHESIVE KIT PART 2 Revision Date 03-Feb-2015 Chemical Name New Jersey Massachusetts Pennsylvania 2-PROPANOL 67-63-0 X X X MINERAL SPIRITS 8052-41-3 X X X ORGANO-COPPER COMPOUND 85737-14-0 X - X ORGANO-COPPER COMPOUND 68084-48-0 X - X ORGANO-COPPER COMPOUND 22221-10-9 X - X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 03-Feb-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 2 Flammability 3 Instability 0 _____________________________________________________________________________________________ - HMIS Health hazards 2 Flammability 3 Page 9 / 9 Physical hazards 0 Personal protection B