1. IDENTIFICATION Product identifier Product Name 82 BLACK SUPER WEATHERSTRIP ADHESIVE 5 FL.OZ Other means of identification Product Code 81850 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Contact adhesives Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Reproductive toxicity Category 2 Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 2 Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 10 Revision Date 02-Mar-2015 SAFETY DATA SHEET Version 1 Danger Flammable liquids Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Category 2 Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 _____________________________________________________________________________________________ Precautionary Statements - Prevention Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. ? No smoking Keep container tightly closed Ground/bond container and receiving equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention If skin irritation occurs: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Not applicable. Unknown acute toxicity 31.28% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS _____________________________________________________________________________________________ Page 2 / 10 81850 - 82 BLACK SUPER WEATHERSTRIP ADHESIVE 5 FL.OZ Causes skin irritation Causes serious eye irritation Suspected of damaging fertility or the unborn child May cause drowsiness or dizziness May cause damage to organs through prolonged or repeated exposure Revision Date 02-Mar-2015 Highly flammable liquid and vapor Odor SolventAppearance Black Physical state Liquid _____________________________________________________________________________________________ substance(s) Chemical Name CAS No Weight-% Trade Secret TOLUENE 108-88-3 10 - 30 * METHYL ETHYL KETONE (BUTANONE) 78-93-3 10 - 30 * ACETONE 67-64-1 10 - 30 * N-HEXANE 110-54-3 10 - 30 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Extremely flammable. May be ignited by heat, sparks or flames. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES _____________________________________________________________________________________________ Page 3 / 10 Revision Date 02-Mar-201581850 - 82 BLACK SUPER WEATHERSTRIP ADHESIVE 5 FL.OZ _____________________________________________________________________________________________ Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Take precautionary measures against static discharges. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Take precautionary measures against static discharges. Handle in accordance with good industrial hygiene and safety practice. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Incompatible materials Strong oxidizing agents, Bases, Acids 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH TOLUENE 108-88-3 TWA: 20 ppm TWA: 200 ppm (vacated) TWA: 100 ppm (vacated) TWA: 375 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 560 mg/m3 Ceiling: 300 ppm IDLH: 500 ppm TWA: 100 ppm TWA: 375 mg/m3 STEL: 150 ppm STEL: 560 mg/m3 METHYL ETHYL KETONE (BUTANONE) 78-93-3 STEL: 300 ppm TWA: 200 ppm TWA: 200 ppm TWA: 590 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 590 mg/m3 (vacated) STEL: 300 ppm (vacated) STEL: 885 mg/m3 IDLH: 3000 ppm TWA: 200 ppm TWA: 590 mg/m3 STEL: 300 ppm STEL: 885 mg/m3 _____________________________________________________________________________________________ Page 4 / 10 81850 - 82 BLACK SUPER WEATHERSTRIP ADHESIVE 5 FL.OZ Revision Date 02-Mar-2015 _____________________________________________________________________________________________ ACETONE 67-64-1 STEL: 750 ppm TWA: 500 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 N-HEXANE 110-54-3 TWA: 50 ppm S* TWA: 500 ppm TWA: 1800 mg/m3 (vacated) TWA: 50 ppm (vacated) TWA: 180 mg/m3 IDLH: 1100 ppm TWA: 50 ppm TWA: 180 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Black Odor Solvent Odor threshold No information available _____________________________________________________________________________________________ Page 5 / 10 Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: 13.0% Values Lower flammability limit: 1.2% Vapor pressure 175 mmHg @ 68?F Boiling point / boiling range 55 ?C / 131 ?F Vapor density >1 Remarks ? Method Air = 1 Relative density 0.91 81850 - 82 BLACK SUPER WEATHERSTRIP ADHESIVE 5 FL.OZ Flash point Water solubility Negligible -26 ?C / -15 ?F Solubility in other solvents No information available Tag Closed Cup pH Partition coefficient No information available Does not apply Evaporation rate < 1 Revision Date 02-Mar-2015 Butyl acetate = 1 Flammability (solid, gas) No information available _____________________________________________________________________________________________ Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 52% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents, Bases, Acids Hazardous Decomposition Products Carbon oxides Nitrogen oxides (NOx) 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May be harmful if inhaled. May cause drowsiness or dizziness. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion May be harmful if swallowed. Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 TOLUENE 108-88-3 = 2600 mg/kg ( Rat ) = 12000 mg/kg ( Rabbit ) = 12.5 mg/L ( Rat ) 4 h METHYL ETHYL KETONE (BUTANONE) 78-93-3 = 2483 mg/kg ( Rat ) = 2737 mg/kg ( Rat ) = 5000 mg/kg ( Rabbit ) = 6480 mg/kg ( Rabbit ) = 11700 ppm ( Rat ) 4 h ACETONE 67-64-1 = 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h N-HEXANE 110-54-3 = 25 g/kg ( Rat ) = 3000 mg/kg ( Rabbit ) = 48000 ppm ( Rat ) 4 h Information on toxicological effects Symptoms No information available. _____________________________________________________________________________________________ Page 6 / 10 Autoignition temperature Kinematic viscosity No data available No information available No information available Revision Date 02-Mar-2015 Dynamic viscosity No information available Decomposition temperature No information available 81850 - 82 BLACK SUPER WEATHERSTRIP ADHESIVE 5 FL.OZ _____________________________________________________________________________________________ Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA TOLUENE 108-88-3 - Group 3 - - IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen Chronic toxicity May cause adverse liver effects. Target Organ Effects Central nervous system, Eyes, kidney, Liver, Peripheral Nervous System (PNS), Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 3702 mg/kg ATEmix (dermal) 6968 mg/kg ATEmix (inhalation-dust/mist) 39.3 mg/l ATEmix (inhalation-vapor) 36620 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 31.28% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea TOLUENE 108-88-3 433: 96 h Pseudokirchneriella subcapitata mg/L EC50 12.5: 72 h Pseudokirchneriella subcapitata mg/L EC50 static 15.22 - 19.05: 96 h Pimephales promelas mg/L LC50 flow-through 12.6: 96 h Pimephales promelas mg/L LC50 static 5.89 - 7.81: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 14.1 - 17.16: 96 h Oncorhynchus mykiss mg/L LC50 static 5.8: 96 h Oncorhynchus mykiss mg/L LC50 semi-static 11.0 - 15.0: 96 h Lepomis macrochirus mg/L LC50 static 54: 96 h Oryzias latipes mg/L LC50 static 28.2: 96 h Poecilia reticulata mg/L LC50 semi-static 50.87 - 70.34: 96 h Poecilia reticulata mg/L LC50 static 5.46 - 9.83: 48 h Daphnia magna mg/L EC50 Static 11.5: 48 h Daphnia magna mg/L EC50 METHYL ETHYL KETONE (BUTANONE) 78-93-3 - 3130 - 3320: 96 h Pimephales promelas mg/L LC50 flow-through 520: 48 h Daphnia magna mg/L EC50 5091: 48 h Daphnia magna mg/L EC50 4025 - 6440: 48 h Daphnia magna mg/L EC50 Static ACETONE 67-64-1 - 4.74 - 6.33: 96 h Oncorhynchus mykiss mL/L LC50 6210 - 8120: 96 h Pimephales promelas mg/L LC50 static 8300: 96 h Lepomis macrochirus mg/L LC50 10294 - 17704: 48 h Daphnia magna mg/L EC50 Static 12600 - 12700: 48 h Daphnia magna mg/L EC50 N-HEXANE 110-54-3 - 2.1 - 2.98: 96 h Pimephales promelas mg/L LC50 flow-through 1000: 24 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient _____________________________________________________________________________________________ Page 7 / 10 Revision Date 02-Mar-201581850 - 82 BLACK SUPER WEATHERSTRIP ADHESIVE 5 FL.OZ _____________________________________________________________________________________________ TOLUENE 108-88-3 2.65 METHYL ETHYL KETONE (BUTANONE) 78-93-3 0.29 ACETONE 67-64-1 -0.24 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes TOLUENE 108-88-3 U220 Included in waste streams: F005, F024, F025, F039, K015, K036, K037, K149, K151 - U220 METHYL ETHYL KETONE (BUTANONE) 78-93-3 U159 Included in waste streams: F005, F039 200.0 mg/L regulatory level U159 ACETONE 67-64-1 - Included in waste stream: F039 - U002 Chemical Name RCRA - Halogenated Organic Compounds RCRA - P Series Wastes RCRA - F Series Wastes RCRA - K Series Wastes TOLUENE 108-88-3 - - Toxic waste waste number F025 Waste description: Condensed light ends, spent filters and filter aids, and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons, by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from one to and including five, with varying amounts and positions of chlorine substitution. - This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status TOLUENE 108-88-3 Toxic Ignitable METHYL ETHYL KETONE (BUTANONE) 78-93-3 Toxic Ignitable ACETONE 67-64-1 Ignitable N-HEXANE 110-54-3 Toxic Ignitable _____________________________________________________________________________________________ Page 8 / 10 81850 - 82 BLACK SUPER WEATHERSTRIP ADHESIVE 5 FL.OZ Revision Date 02-Mar-2015 _____________________________________________________________________________________________ 14. TRANSPORT INFORMATION DOT UN/ID no UN 1133 Proper shipping name: Adhesives, Limited Quantity (LQ) Hazard Class 3 Packing Group II Emergency Response Guide Number 128 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 3L IMDG UN/ID no UN 1133 Proper shipping name: Adhesives, Limited Quantity (LQ) Hazard Class 3 Packing Group II EmS-No F-E, S-D 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % TOLUENE - 108-88-3 1.0 N-HEXANE - 110-54-3 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No _____________________________________________________________________________________________ Page 9 / 10 Revision Date 02-Mar-201581850 - 82 BLACK SUPER WEATHERSTRIP ADHESIVE 5 FL.OZ _____________________________________________________________________________________________ CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances TOLUENE 108-88-3 1000 lb X X X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) TOLUENE 108-88-3 1 lb - RQ 1 lb final RQ RQ 0.454 kg final RQ METHYL ETHYL KETONE (BUTANONE) 78-93-3 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ N-HEXANE 110-54-3 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 TOLUENE - 108-88-3 Developmental Female Reproductive U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania TOLUENE 108-88-3 X X X METHYL ETHYL KETONE (BUTANONE) 78-93-3 X X X ACETONE 67-64-1 X X X N-HEXANE 110-54-3 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 02-Mar-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet_____________________________________________________________________________________________ Page 10 / 10 Instability 0 - HMIS NFPA Health hazards 2 Flammability 3 81850 - 82 BLACK SUPER WEATHERSTRIP ADHESIVE 5 FL.OZ Physical hazards 0 Personal protection B Health hazards 2 Flammability 3 Revision Date 02-Mar-2015