Material Safety Data Sheet 1. PRODUCT IDENTIFICATION Product Name: VR-1A VINYL & LEATHER REPAIR KIT Item No: 80902 Product Type: Sealant 2. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight% ACGIH; TLV-TWA OSHA PEL ACETONE 67-64-1 40-50 500 ppm 1000 ppm; 2400 mg/m3 TETRAHYDROFURAN 109-99-9 20-30 50 ppm 200 ppm; 590 mg/m3 VINYL COPOLYMER 9003-22-9 15-25 Not listed Not listed BENZOATE ESTERS MIXTURE <10 Not listed Not listed SILICON DIOXIDE, AMORPHOUS 112945-52-5 <5 5 mg/m3, TWA Not listed 3. HAZARDS IDENTIFICATION Toxicity: This material is irritating to skin, eyes and mucous membranes. Note: This product does not contain microcyrstalline silica. Primary Routes of Entry: Eye and skin contact, ingestion, inhalation Signs and Symptoms of Exposure: Skin: Exposure may cause mild skin irritation. Prolonged or repeated exposure may dry the skin. Symptoms may include redness, burning, drying, cracking and skin burns. Preexisting skin disorders may be aggravated by exposure. . Excessive overexposure may cause giddiness, dizziness, headache, nausea and in extreme cases, unconsciousness and respiratory depression. Inhaling may cause mild irritation to the nose, throat and respiratory tract and may result in central nervous system (CNS) depression. Component Weight% NTP ACGIH Carcinogens IARC Carcinogen ACETONE 67-64-1 40-50 Not known A4 - Not Classifiable as a Human Carcinogen TETRAHYDROFURAN 109-99-9 20-30 male rat-some evidence; female rat- no evidence; male mice-no evidence; female mice-clear evidence A3 Confirmed animal carcinogen with unknown relevance to humans VINYL COPOLYMER 9003-22-9 15-25 Group 3 Supplement 7, 1987; Monograph 19, 1979 SILICON DIOXIDE, AMORPHOUS 112945-52-5 <5 Amorphous Silica, Group 3: Vol. 68: 1997 Aggravated Medical Condition: Preexisting pulmonary and dermatological disorders. 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Move to fresh air in case of accidental inhalation of vapours. Oxygen or artificial respiration if needed. Obtain medical attention. Skin Contact: Wash off with soap and water. If skin irritation persists, call a physician. Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. 1 of 3 ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Telephone: 1-87-Permatex (877) 376-2839 Emergency: 800-255-3924 (ChemTel) International Emergency: +01-813-248-0585 5. FIRE FIGHTING MEASURES Flash Point ?F(C?): 0?F TCC Recommended Extinguishing Media: Carbon Dioxide, Dry Chemicals, Foam. Special Fire-Fighting Procedures: Firefighters should wear self-contained breathing apparatus. Water spray may be ineffective on flames but should be used to keep fire-exposed containers cool. Hazardous Products of Combustion: Hydrogen chloride, Irritating vapors, Oxides of carbon, Oxides of phosphorus Unusual Fire/Explosion Hazards: Vapors may travel from container toward sources of ignition and flashback. Lower Explosive Limit: Acetone: 2.6; tetrahydrofuran: 2 Upper Explosive Limit: Acetone: 12.8; tetrahydrofuran: 11.8 6. ACCIDENTAL RELEASE MEASURES Spill Procedures: Eliminate all sources of ignition. Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal. 7. HANDLING AND STORAGE Storage: Store away from heat, sparks or open flame. Do not store at temperatures above 100?F (38?C). Handling: Do not use near heat, sparks or open flame. Use only in a well ventilated area. Avoid breathing vapors, if exposed to high vapor concentration, leave area at once. Avoid contact with skin and eyes. Wash hands before eating and smoking. Keep container closed when not in use. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses. Skin: Neoprene or nitrile gloves recommended. Ventilation: General; local exhaust ventilation as necessary to control any air contaminants to within their exposure limits (or to the lowest feasible levels when limits have not been established) during the use of this product. Respiratory Protection: An approved organic vapor respirator should be worn when exposures are expected to exceed the applicable limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear liquid Odor: Pungent Boiling Point: 135?F pH: Does not apply Solubility in Water: Slight Specific Gravity: 0.94 VOC(Wt.%): 25% Vapor Pressure: Not Determined Vapor Density (Air=1): >1 Evaporation Rate: Not Determined 10. STABILITY AND REACTIVITY Chemical Stability: Stable at normal conditions Hazardous Polymerization: Will not occur Incompatabilities: Strong oxidizers, Acids, Reducing agents Conditions to Avoid: Keep away from heat, sparks and open flame. - No smoking. Hazardous Products of Combustion: Hydrogen chloride, Irritating vapors, Oxides of carbon, Oxides of phosphorus 11. TOXICOLOGICAL INFORMATION See Section 3 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations. US EPA Waste Number: D001 as per 40CFR 261.21 Product Name: Item No. 80902VR-1A VINYL & LEATHER REPAIR KIT 14. TRANSPORTATION INFORMATION DOT (49CFR 172) U.S. Department of Transportation - DOT - 49 CFR (Ground) DOT Shipping Name: Adhesives, Limited Quantity Hazard Class: Class 3, PG II UN/ID Number: UN 1133 IATA (Air) Proper Shipping Name: Consumer Commodity (Not more than 1 liter) Class or Division: Class 9 UN/ID Number: ID 8000 IMDG (Vessel) Proper Shipping Name: Adhesives, Limited Quantity Hazard Class: Class 3, PG II UN Number: UN 1133 Marine Pollutant: None 15. REGULATORY INFORMATION SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical. None California Proposition 65: No California Prop 65 chemicals are known to be present at or above the No Significant Risk Level TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory. 16. OTHER INFORMATION Estimated NFPA Rating: HEALTH 2, FLAMMABILITY 3 , REACTIVITY 1. Estimated HMIS Classification: HEALTH 2, FLAMMABILITY 3, PHYSICAL HAZARD 0 (NFPA is a registered trademark of the National Fire Protection Association) HMIS is a registered trademark of the National Paint and Coatings Association VR-1A VINYL & LEATHER REPAIR KIT Company: ITW Permatex 10 Columbus Blvd. Hartford, CT USA 06106 Product Name: Revision Number: 3 Telephone No.: 1-87-Permatex (877) 376-2839 Prepared By: Denise Boyd, Manager-Environmental, Health & Safety Item No. 80902 Revision Date: January 26, 2012 << /ASCII85EncodePages false /AllowTransparency false /AutoPositionEPSFiles true /AutoRotatePages /All /Binding /Left /CalGrayProfile (Dot Gain 20%) /CalRGBProfile (sRGB IEC61966-2.1) /CalCMYKProfile (U.S. Web Coated \050SWOP\051 v2) /sRGBProfile (sRGB IEC61966-2.1) /CannotEmbedFontPolicy /Warning /CompatibilityLevel 1.4 /CompressObjects /Tags /CompressPages true /ConvertImagesToIndexed true /PassThroughJPEGImages true /CreateJDFFile false /CreateJobTicket false /DefaultRenderingIntent /Default /DetectBlends true /DetectCurves 0.0000 /ColorConversionStrategy /LeaveColorUnchanged /DoThumbnails false /EmbedAllFonts true /EmbedOpenType false /ParseICCProfilesInComments true /EmbedJobOptions true /DSCReportingLevel 0 /EmitDSCWarnings false /EndPage -1 /ImageMemory 1048576 /LockDistillerParams false /MaxSubsetPct 100 /Optimize true /OPM 1 /ParseDSCComments true /ParseDSCCommentsForDocInfo true /PreserveCopyPage true /PreserveDICMYKValues true /PreserveEPSInfo true /PreserveFlatness true /PreserveHalftoneInfo false /PreserveOPIComments false /PreserveOverprintSettings true /StartPage 1 /SubsetFonts true /TransferFunctionInfo /Apply /UCRandBGInfo /Preserve /UsePrologue false /ColorSettingsFile () /AlwaysEmbed [ true ] /NeverEmbed [ true ] /AntiAliasColorImages false /CropColorImages true /ColorImageMinResolution 300 /ColorImageMinResolutionPolicy /OK /DownsampleColorImages true /ColorImageDownsampleType /Bicubic /ColorImageResolution 300 /ColorImageDepth -1 /ColorImageMinDownsampleDepth 1 /ColorImageDownsampleThreshold 1.50000 /EncodeColorImages true /ColorImageFilter /DCTEncode /AutoFilterColorImages true /ColorImageAutoFilterStrategy /JPEG /ColorACSImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /ColorImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /JPEG2000ColorACSImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /JPEG2000ColorImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /AntiAliasGrayImages false /CropGrayImages true /GrayImageMinResolution 300 /GrayImageMinResolutionPolicy /OK /DownsampleGrayImages true /GrayImageDownsampleType /Bicubic /GrayImageResolution 300 /GrayImageDepth -1 /GrayImageMinDownsampleDepth 2 /GrayImageDownsampleThreshold 1.50000 /EncodeGrayImages true /GrayImageFilter /DCTEncode /AutoFilterGrayImages true /GrayImageAutoFilterStrategy /JPEG /GrayACSImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /GrayImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /JPEG2000GrayACSImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /JPEG2000GrayImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /AntiAliasMonoImages false /CropMonoImages true /MonoImageMinResolution 1200 /MonoImageMinResolutionPolicy /OK /DownsampleMonoImages true /MonoImageDownsampleType /Bicubic /MonoImageResolution 1200 /MonoImageDepth -1 /MonoImageDownsampleThreshold 1.50000 /EncodeMonoImages true /MonoImageFilter /CCITTFaxEncode /MonoImageDict << /K -1 >> /AllowPSXObjects false /CheckCompliance [ /None ] /PDFX1aCheck false /PDFX3Check false /PDFXCompliantPDFOnly false /PDFXNoTrimBoxError true /PDFXTrimBoxToMediaBoxOffset [ 0.00000 0.00000 0.00000 0.00000 ] /PDFXSetBleedBoxToMediaBox true /PDFXBleedBoxToTrimBoxOffset [ 0.00000 0.00000 0.00000 0.00000 ] /PDFXOutputIntentProfile () /PDFXOutputConditionIdentifier () /PDFXOutputCondition () /PDFXRegistryName () /PDFXTrapped /False /Description << /CHS /CHT /DAN /DEU /ESP /FRA /ITA /JPN /KOR /NLD (Gebruik deze instellingen om Adobe PDF-documenten te maken voor kwaliteitsafdrukken op desktopprinters en proofers. 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