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Material Safety Data Sheet 1. PRODUCT IDENTIFICATION Product Name: 66MA POWERBEAD CLEAR RTV SILICONE ADHESIVE 7.25 OZ AE Item No: 81913 Product Type: Silicone (Barrier Pack) 2. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight% ACGIH; TLV-TWA OSHA PEL POLY (DIMETHYLSILOXANE), HYDROXY TERMINATED 70131-67-8 >60 Not listed Not listed AMORPHOUS SILICA 7631-86-9 <10 Not listed 20 mppcf DISTILLATES (PETROLEUM), HYDROTREATED MIDDLE 64742-46-7 <7 5 mg/m3 Not listed ETHYLTRIACETOXYSILANE 17689-77-9 <3 Not listed Not listed METHYLTRIACETOXYSILANE 4253-34-3 <3 Not listed Not listed ACETIC ACID 64-19-7 0.5-2.0 5 mg/m3 10 ppm; 25 mg/m3 NITROGEN 7727-37-9 **** Not listed Not listed 3. HAZARDS IDENTIFICATION Toxicity: May cause eye and skin irritation. May irritate lips, gums, tongue, mouth, nose and throat. May irritate respiratory system upon frequent or prolonged use. ****When this product is exposed to moisture, acetic acid may be formed. Note: This product does not contain microcyrstalline silica. Primary Routes of Entry: Eye and skin contact, ingestion, inhalation Signs and Symptoms of Exposure: Acetic acid produced during curing irritates eyes, nose and throat.. Component Weight% NTP ACGIH Carcinogens IARC Carcinogen AMORPHOUS SILICA 7631-86-9 <10 Group 3 Monograph 68, 1997 Aggravated Medical Condition: Methyltriacetoxysilane: Eye, skin and pulmonary disorders. 4. FIRST AID MEASURES Ingestion: Rinse mouth. If swallowed, DO NOT induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Move to fresh air in case of accidental inhalation of vapours. If symptoms persist, call a physician. Skin Contact: Wipe off material with paper towel or cloth. Wash off with soap and water. If skin irritation persists, call a physician. Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. 5. FIRE FIGHTING MEASURES Flash Point ?F(C?): >200?F TCC Recommended Extinguishing Media: Carbon Dioxide, Dry Chemicals, Foam. Special Fire-Fighting Procedures: ***Warning: This container is pressurized with nitrogen. Do not remove rubber plug. Keep containers cool. Use equipment or shielding required to protect against bursting or venting of containers. Use water spray to cool exposed containers. Hazardous Products of Combustion: Oxides of carbon, Acetic acid, Silica fume, Formaldehyde 1 of 3 ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Telephone: 1-87-Permatex (877) 376-2839 Emergency: 800-255-3924 (ChemTel) International Emergency: +01-813-248-0585 5. FIRE FIGHTING MEASURES Unusual Fire/Explosion Hazards: Contents under pressure. Heated cans may burst. Use equipment or shielding to protect personnel from bursting containers. Lower Explosive Limit: Not determined Upper Explosive Limit: Not determined 6. ACCIDENTAL RELEASE MEASURES Spill Procedures: Wipe or scrape up spill material. Maintain good ventilation for large spills. Place scrap material in a well- ventilated area and allow to cure to rubber. Clean up spills thoroughly as residue is slippery. 7. HANDLING AND STORAGE Storage: Store away from heat, sparks or open flame. Do not store at temperatures above 100?F (38?C). Exposure to high temperatures may cause container to burst. Keep away from oxidizers. Store away from water or moisture. Handling: Do not take internally. Use only in a well ventilated area. Avoid contact with skin and eyes. Do not wear contact lenses. Wash hands before eating and smoking. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses. Skin: Neoprene or nitrile gloves recommended. Ventilation: General; local exhaust ventilation as necessary to control any air contaminants to within their exposure limits (or to the lowest feasible levels when limits have not been established) during the use of this product. Respiratory Protection: An approved organic vapor respirator should be worn when exposures are expected to exceed the applicable limits. Comments: When heated to temperatures above 300 degrees F. in the presence of air, this product can form formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and respiratory sensitizer. Safe handling conditions may be maintained by keeping vapor concentrations below the OSHA permissible limit for formaldehyde 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear paste Odor: Acetic acid Boiling Point: Not applicable, polymeric material pH: Does not apply Solubility in Water: Polymerized Specific Gravity: 1.01 VOC(Wt.%): 3.0%; 30 g/l Vapor Pressure: 66 mm Hg @ 70?F Vapor Density (Air=1): Not determined Evaporation Rate: Not determined 10. STABILITY AND REACTIVITY Chemical Stability: Stable at normal conditions Hazardous Polymerization: Will not occur Incompatabilities: Polymerized by contact with moisture. Acetic acid liberated. Conditions to Avoid: Moisture while storing. Do not expose to heat or store at temperatures above 120 F. Hazardous Products of Combustion: Oxides of carbon, Acetic acid, Silica fume, Formaldehyde 11. TOXICOLOGICAL INFORMATION See Section 3 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations. US EPA Waste Number: NH - Not a RCRA Hazardous Waste Material Item No. 8191366MA POWERBEAD CLEAR RTV SILICONE ADHESIVE 7.25 OZ AE Product Name: 14. TRANSPORTATION INFORMATION DOT (49CFR 172) U.S. Department of Transportation - DOT - 49 CFR (Ground) DOT Shipping Name: Aerosols, Limited Quantity Hazard Class: Class 2.2 UN/ID Number: UN 1950 IATA (Air) Proper Shipping Name: Consumer Commodity (Not more than 1 liter) Class or Division: Class 9 UN/ID Number: ID 8000 IMDG (Vessel) Proper Shipping Name: Aerosols, Limited Quantity Hazard Class: Class 2.2 UN Number: UN 1950 Marine Pollutant: None 15. REGULATORY INFORMATION SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical. NONE California Proposition 65: No California Prop 65 chemicals are known to be present at or above the No Significant Risk Level TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory. 16. OTHER INFORMATION Estimated NFPA Rating: HEALTH 2, FLAMMABILITY 1 , REACTIVITY 0. Estimated HMIS Classification: HEALTH 2, FLAMMABILILTY 1, PHYSICAL HAZARD 0 (NFPA is a registered trademark of the National Fire Protection Association) HMIS is a registered trademark of the National Paint and Coatings Association 66MA POWERBEAD CLEAR RTV SILICONE ADHESIVE 7.25 OZ AE Company: ITW Permatex 10 Columbus Blvd. Hartford, CT USA 06106 Product Name: Revision Number: 8 Telephone No.: 1-87-Permatex (877) 376-2839 Prepared By: Denise Boyd, Manager-Environmental, Health & Safety Item No. 81913 Revision Date: March 08, 2012 << /ASCII85EncodePages false /AllowTransparency false /AutoPositionEPSFiles true /AutoRotatePages /All /Binding /Left /CalGrayProfile (Dot Gain 20%) /CalRGBProfile (sRGB IEC61966-2.1) /CalCMYKProfile (U.S. Web Coated \050SWOP\051 v2) /sRGBProfile (sRGB IEC61966-2.1) /CannotEmbedFontPolicy /Warning /CompatibilityLevel 1.6 /CompressObjects /Tags /CompressPages true /ConvertImagesToIndexed true /PassThroughJPEGImages true /CreateJDFFile false /CreateJobTicket false /DefaultRenderingIntent /Default /DetectBlends true /DetectCurves 0.0000 /ColorConversionStrategy /LeaveColorUnchanged /DoThumbnails false /EmbedAllFonts true /EmbedOpenType false /ParseICCProfilesInComments true /EmbedJobOptions true /DSCReportingLevel 0 /EmitDSCWarnings false /EndPage -1 /ImageMemory 1048576 /LockDistillerParams false /MaxSubsetPct 100 /Optimize true /OPM 1 /ParseDSCComments true /ParseDSCCommentsForDocInfo true /PreserveCopyPage true /PreserveDICMYKValues true /PreserveEPSInfo true /PreserveFlatness true /PreserveHalftoneInfo false /PreserveOPIComments false /PreserveOverprintSettings true /StartPage 1 /SubsetFonts true /TransferFunctionInfo /Apply /UCRandBGInfo /Preserve /UsePrologue false /ColorSettingsFile () /AlwaysEmbed [ true ] /NeverEmbed [ true ] /AntiAliasColorImages false /CropColorImages true /ColorImageMinResolution 300 /ColorImageMinResolutionPolicy /OK /DownsampleColorImages true /ColorImageDownsampleType /Bicubic /ColorImageResolution 300 /ColorImageDepth -1 /ColorImageMinDownsampleDepth 1 /ColorImageDownsampleThreshold 1.50000 /EncodeColorImages true /ColorImageFilter /DCTEncode /AutoFilterColorImages true /ColorImageAutoFilterStrategy /JPEG /ColorACSImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /ColorImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /JPEG2000ColorACSImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /JPEG2000ColorImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /AntiAliasGrayImages false /CropGrayImages true /GrayImageMinResolution 300 /GrayImageMinResolutionPolicy /OK /DownsampleGrayImages true /GrayImageDownsampleType /Bicubic /GrayImageResolution 300 /GrayImageDepth -1 /GrayImageMinDownsampleDepth 2 /GrayImageDownsampleThreshold 1.50000 /EncodeGrayImages true /GrayImageFilter /DCTEncode /AutoFilterGrayImages true /GrayImageAutoFilterStrategy /JPEG /GrayACSImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /GrayImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /JPEG2000GrayACSImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /JPEG2000GrayImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /AntiAliasMonoImages false /CropMonoImages true /MonoImageMinResolution 1200 /MonoImageMinResolutionPolicy /OK /DownsampleMonoImages true /MonoImageDownsampleType /Bicubic /MonoImageResolution 1200 /MonoImageDepth -1 /MonoImageDownsampleThreshold 1.50000 /EncodeMonoImages true /MonoImageFilter /CCITTFaxEncode /MonoImageDict << /K -1 >> /AllowPSXObjects false /CheckCompliance [ /None ] /PDFX1aCheck false /PDFX3Check false /PDFXCompliantPDFOnly false /PDFXNoTrimBoxError true /PDFXTrimBoxToMediaBoxOffset [ 0.00000 0.00000 0.00000 0.00000 ] /PDFXSetBleedBoxToMediaBox true /PDFXBleedBoxToTrimBoxOffset [ 0.00000 0.00000 0.00000 0.00000 ] /PDFXOutputIntentProfile () /PDFXOutputConditionIdentifier () /PDFXOutputCondition () /PDFXRegistryName () /PDFXTrapped /False /Description << /CHS /CHT /DAN /DEU /ESP /FRA /ITA /JPN /KOR /NLD (Gebruik deze instellingen om Adobe PDF-documenten te maken voor kwaliteitsafdrukken op desktopprinters en proofers. 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