PENRAY TOTAL INTAKE SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 06/11/2014 Revision date: 06/11/2014 Version: 1.0 06/11/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PENRAY TOTAL INTAKE SYSTEM CLEANER Product code : 2512 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Intake system cleaner. 1.3. Details of the supplier of the safety data sheet The Penray Companies, Inc. 440 Denniston Ct. Wheeling, IL 60090 T (800) 373-6729 This email address is being protected from spambots. You need JavaScript enabled to view it. 1.4. Emergency telephone number Emergency number : (800) 373-6729 CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527-3887 24 hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable Aerosol 1 Gases Under Pressure - Compressed Gas Acute toxicity 4 (Oral) Acute toxicity 3 (Dermal) Skin corrosion 1B Serious eye damage 1 Reproductive toxicity 1B Specific target organ toxicity - Single exposure 3 Specific target organ toxicity - Repeated exposure 2 Aspiration hazard 1 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS02 GHS04 GHS05 GHS06 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Harmful if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. May damage fertility or the unborn child. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways. Precautionary statements (GHS-US) : Keep away from heat/sparks/open flames/hot surfaces. -No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Use only outdoors or in a well-ventilated area. Do not breathe gas/mist/vapors/spray. If exposed or concerned: Get medical advice/attention. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Immediately call a poison center/doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. If inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a poison center/doctor. If swallowed: Rinse mouth. Do NOT induce vomiting. Immediately call a poison center/doctor. Do not expose to temperatures exceeding 50 ?C/122 ?F. Protect from sunlight. Store in a well-ventilated place. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. PENRAY TOTAL INTAKE SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 2/7 2.3. Other hazards No additional information available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Butane (CAS No) 106-97-8 15 - 40 Flam. Gas 1 Liquefied gas Propane (CAS No) 74-98-6 15 - 40 Flam. Gas 1 Liquefied gas Toluene (CAS No) 108-88-3 7 - 13 Flam. Liq. 2 Skin Irrit. 2 Repr. 2 STOT SE 3 STOT RE 2 Asp. Tox. 1 Acetonitrile (CAS No) 75-05-8 3 - 7 Flam. Liq. 2 Acute Tox. 4 (Oral, Inhalation) Acute Tox. 3 (Dermal) Eye Irrit. 2A 1-Methyl-2-pyrrolidone (CAS No) 872-50-4 3 - 7 Flam. Liq. 4 Skin Irrit. 2 Eye Irrit. 2A Repr. 1B STOT SE 3 Isopropyl alcohol (CAS No) 67-63-0 3 - 7 Flam. Liq. 2 Eye Irrit. 2A STOT SE 3 Morpholine (CAS No) 110-91-8 3 - 7 Flam. Liq. 3 Acute Tox. 4 (Oral, Inhalation) Acute Tox. 3 (Dermal) Skin Corr. 1B * The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical advice/attention. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Get immediate medical advice/attention. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get medical attention immediately. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Rinse mouth. Get immediate medical advice/attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : Irritating to respiratory system. May cause drowsiness, dizziness and central nervous system depression. Intentional misuse of product by inhalation can result in asphyxiation or death. Symptoms/injuries after skin contact : Toxic in contact with skin. Causes severe skin burns. Redness. Pain. Blisters. Symptoms/injuries after eye contact : Causes serious eye damage. May cause serious chemical burns. Redness, pain, tearing. Symptoms/injuries after ingestion : Harmful if swallowed. May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Powder, water spray, foam, carbon dioxide. Unsuitable extinguishing media : None known. PENRAY TOTAL INTAKE SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 3/7 5.2. Special hazards arising from the substance or mixture Fire hazard : Extremely flammable aerosol. Products of combustion may include, and are not limited to: oxides of carbon. Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Vapors may be heavier than air and may travel along the ground to a distant ignition source and flash back. Use water spray to keep fire-exposed containers cool. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition. 6.2. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep away from sources of ignition. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not get in eyes, on skin, or on clothing. Do not swallow. Do not breathe gas, fumes, vapour or spray. When using do not eat, drink or smoke. Use only outdoors or in a well-ventilated area. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep locked up and out of reach of children. Do not expose ot temperatures exceeding 50?C/ 122?F. Store away from direct sunlight or other heat sources. Store in a well-ventilated place. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Butane (106-97-8) USA ACGIH ACGIH STEL (ppm) 1000 ppm Propane (74-98-6) USA ACGIH ACGIH TWA (ppm) 1000 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 1800 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm Toluene (108-88-3) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm Acetonitrile (75-05-8) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 70 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 40 ppm PENRAY TOTAL INTAKE SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 4/7 1-Methyl-2-pyrrolidone (872-50-4) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Isopropyl alcohol (67-63-0) USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (ppm) 400 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 980 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 400 ppm Morpholine (110-91-8) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 70 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 20 ppm 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear chemically resistant protective gloves. Eye protection : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles) and face protection (face shield). Skin and body protection : Wear suitable protective clothing. Respiratory protection : A NIOSH approved respirator is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas/Pressurized Liquid. Appearance : Clear. Colour : Colourless. Odour : Solvent. Odour threshold : No data available. pH : No data available. Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : No data available. Flash point : No data available. Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Flammable. Vapour pressure : No data available. Relative vapour density at 20 ?C : No data available. Relative density : 0.94 - 1.04 Solubility : No data available. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. PENRAY TOTAL INTAKE SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 5/7 Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. Extremely flammable aerosol. Contents under pressure. Container may explode if heated. Do not puncture. Do not burn. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Sources of ignition. 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Harmful if swallowed. Toxic in contact with skin. 2512 LD50 oral rat 1556 mg/kg LD50 dermal rabbit 850 mg/kg LC50 inhalation rat (mg/l) > 5 mg/l/4h Butane (106-97-8) LC50 inhalation rat (mg/l) 658 mg/l/4h Propane (74-98-6) LC50 inhalation rat (mg/l) 658 mg/l/4h Toluene (108-88-3) LD50 oral rat > 5000 mg/kg LD50 dermal rat 12124 mg/kg LD50 dermal rabbit 8390 mg/kg LC50 inhalation rat (mg/l) 28.1 mg/l/4h Acetonitrile (75-05-8) LD50 dermal rabbit 395 - 988 mg/kg LC50 inhalation rat (ppm) 7551 ppm/8h 1-Methyl-2-pyrrolidone (872-50-4) LD50 oral rat 3598 mg/kg LD50 dermal rabbit 8 g/kg LC50 inhalation rat (mg/l) > 5.1 mg/l/4h Isopropyl alcohol (67-63-0) LD50 oral rat 4396 mg/kg LD50 dermal rat 12800 mg/kg LD50 dermal rabbit 12870 mg/kg LC50 inhalation rat (ppm) 72.6 mg/L/4h Morpholine (110-91-8) LD50 oral rat 1050 mg/kg LD50 dermal rabbit 310 mg/kg PENRAY TOTAL INTAKE SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 6/7 Morpholine (110-91-8) LC50 inhalation rat (ppm) 8000 ppm/8h Skin corrosion/irritation : Causes severe skin burns. Serious eye damage/irritation : Causes serious eye damage. Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Based on available data, the classification criteria are not met. Toluene (108-88-3) IARC group 3 - Not classifiable Isopropyl alcohol (67-63-0) IARC group 3 - Not classifiable Morpholine (110-91-8) IARC group 3 - Not classifiable Reproductive toxicity : May damage fertility or the unborn child. Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : May cause damage to organs through prolonged or repeated exposure. Aspiration hazard : May be fatal if swallowed and enters airways. Symptoms/injuries after inhalation : Irritating to respiratory system. May cause drowsiness, dizziness and central nervous system depression. Intentional misuse of product by inhalation can result in asphyxiation or death. Symptoms/injuries after skin contact : Toxic in contact with skin. Causes severe skin burns. Redness. Pain. Blisters. Symptoms/injuries after eye contact : Causes serious eye damage. May cause serious chemical burns. Redness, pain, tearing. Symptoms/injuries after ingestion : Harmful if swallowed. May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 2512 Persistence and degradability Not established. 12.3. Bioaccumulative potential 2512 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on ozone layer : No additional information available Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Additional information : Flammable vapours may accumulate in the container. Do not incinerate closed containers. SECTION 14: Transport information In accordance with DOT 14.1. UN number UN-No. UN1950 PENRAY TOTAL INTAKE SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 06/11/2014 EN (English) 7/7 14.2. UN proper shipping name Proper Shipping Name : Aerosols flammable, containing substances in Class 6.1, packing group III and in Class 8, packing group II Department of Transportation Hazard Classes : 2.1 (6.1, 8) Hazard labels : 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory Toluene (108-88-3) Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 1.0 % Acetonitrile (75-05-8) Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 1.0 % 1-Methyl-2-pyrrolidone (872-50-4) Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 1.0 % Isopropyl alcohol (67-63-0) Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 1.0 % 15.2. US State regulations 2512 State or local regulations This product contains chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 16: Other information Indication of changes : None. Date of issue : 06/11/2014 Other information : None. NFPA health hazard : 3 NFPA fire hazard : 4 NFPA reactivity : 0 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product