PENRAY CHLORINATED BRAKE CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 08/05/2014 Revision date: 08/05/2014 Version: 1.0 08/05/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PENRAY CHLORINATED BRAKE CLEANER Product code : 4855 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Chlorinated brake cleaner. 1.3. Details of the supplier of the safety data sheet The Penray Companies, Inc. 440 Denniston Ct. Wheeling, IL 60090 T (800) 373-6729 Manufactured for: AIOD P.O. Box 1861 Montrose, CO 81402 970-240-4176 1.4. Emergency telephone number Emergency number : (800) 373-6729 CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527-3887 24 hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Skin irritation 2 Carcinogenicity 1B Specific target organ toxicity - Single exposure 3 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Causes skin irritation. May cause cancer. May cause drowsiness or dizziness. Precautionary statements (GHS-US) : Wash hands thoroughly after handling. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Avoid breathing gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. If exposed or concerned: Get medical advice/attention. If on skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Other hazards No additional information available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Tetrachloroethylene (CAS No) 127-18-4 60 - 100 Skin Irrit. 2 Carc. 1B STOT SE 3 PENRAY CHLORINATED BRAKE CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 08/05/2014 EN (English) 2/6 Name Product identifier % GHS-US classification Xylenes (o-, m-, p- isomers) (CAS No) 1330-20-7 3 - 7 Flam. Liq. 3 Acute Tox. 4 (Dermal, Inhalation) Skin Irrit. 2 Phenylethane (CAS No) 100-41-4 0.5 - 2 Flam. Liq. 2 Acute Tox. 4 (Inhalation) Skin Irrit. 2 Carc. 2 Asp. Tox. 1 * The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water. Remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May be harmful by inhaled. May cause nervous system depression, headache, and weakness leading to unconsciousness. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Treat for surrounding material. Unsuitable extinguishing media : Not available. 5.2. Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, hydrogen chloride. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. 6.2. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Avoid contact with skin and eyes. Avoid breathing gas/mist/vapors/spray. Do not swallow. Handle and open container with care. When using do not eat, drink or smoke. Use only outdoors or in a well-ventilated area. PENRAY CHLORINATED BRAKE CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 08/05/2014 EN (English) 3/6 Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed and in a well-ventilated place. Store locked up. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Tetrachloroethylene (127-18-4) USA ACGIH ACGIH TWA (ppm) 25 ppm USA ACGIH ACGIH STEL (ppm) 100 ppm USA OSHA OSHA PEL (TWA) (ppm) 100 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 200 ppm Xylenes (o-, m-, p- isomers) (1330-20-7) USA ACGIH ACGIH TWA (ppm) 100 ppm USA ACGIH ACGIH STEL (ppm) 150 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 435 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Phenylethane (100-41-4) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 435 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 100 ppm 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear chemically resistant protective gloves. Eye protection : Safety glasses or goggles are recommended when using product. Skin and body protection : Wear suitable protective clothing. Respiratory protection : A NIOSH approved respirator is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid. Appearance : Clear. Color : Colorless. Odor : Solvent. Odor threshold : No data available. pH : No data available. Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : No data available. Flash point : > 93 ?C (> 200 ?F) PENRAY CHLORINATED BRAKE CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 08/05/2014 EN (English) 4/6 Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Not flammable. Vapor pressure : No data available. Relative vapor density at 20 ?C : No data available. Relative density : 1.52 - 1.62 Solubility : No data available. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. 10.5. Incompatible materials Amines. Bases. Strong oxidizing agents. Metals. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon, hydrogen chloride. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 4855 LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 20 mg/l/4h Tetrachloroethylene (127-18-4) LD50 oral rat 2629 mg/kg LD50 dermal rabbit > 3228 mg/kg LC50 inhalation rat 4000 ppm/4h Xylenes (o-, m-, p- isomers) (1330-20-7) LD50 oral rat 4300 mg/kg LD50 dermal rabbit > 1700 mg/kg LC50 inhalation rat 47635 mg/l/4h Phenylethane (100-41-4) LD50 oral rat 3500 mg/kg LD50 dermal rabbit 15354 mg/kg LC50 inhalation rat 17.2 mg/l/4h Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Based on available data, the classification criteria are not met. Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. PENRAY CHLORINATED BRAKE CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 08/05/2014 EN (English) 5/6 Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : May cause cancer. Tetrachloroethylene (127-18-4) IARC group 2A - Probably carcinogenic to humans National Toxicity Program (NTP) Status 1 - Evidence of Carcinogenicity, 3 - Reasonably anticipated to be Human Carcinogen Xylenes (o-, m-, p- isomers) (1330-20-7) IARC group 3 - Not classifiable Phenylethane (100-41-4) IARC group 2B - Possibly carcinogenic to humans National Toxicity Program (NTP) Status 1 - Evidence of Carcinogenicity Reproductive toxicity : Based on available data, the classification criteria are not met. Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : May be harmful by inhaled. May cause nervous system depression, headache, and weakness leading to unconsciousness. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 4855 Persistence and degradability Not established. 12.3. Bioaccumulative potential 4855 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on ozone layer : No additional information available Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. SECTION 14: Transport information In accordance with DOT 14.1. UN number UN-No. : UN1897 14.2. UN proper shipping name Proper Shipping Name : Tetrachloroethylene Mixture Department of Transportation Hazard Classes : 6.1 PENRAY CHLORINATED BRAKE CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 08/05/2014 EN (English) 6/6 Hazard labels : Packing group : III 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory. Tetrachloroethylene (127-18-4) Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 0.1 % Xylenes (o-, m-, p- isomers) (1330-20-7) Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 1.0 % Phenylethane (100-41-4) Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 0.1 % 15.2. US State regulations 4855 State or local regulations This product contains chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 16: Other information Indication of changes : None. Date of issue : 08/05/2014 Other information : None. NFPA health hazard : 2 NFPA fire hazard : 0 NFPA reactivity : 0 Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use.