PENRAY ENGINE OIL TREATMENT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 04/30/2014 Revision date: 04/30/2014 Version: 1.0 04/30/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PENRAY ENGINE OIL TREATMENT Product code : 3112 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Engine oil treatment. 1.3. Details of the supplier of the safety data sheet The Penray Companies, Inc. 440 Denniston Ct. 60090 Wheeling, IL T (800) 373-6729 This email address is being protected from spambots. You need JavaScript enabled to view it. 1.4. Emergency telephone number Emergency number : (800) 373-6729 CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527-3887 24 hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Eye irritation 2A Skin sensitization 1 Reproductive toxicity 1B Aspiration hazard 1 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Causes serious eye irritation. May cause an allergic skin reaction. May damage fertility or the unborn child. May be fatal if swallowed and enters airways. Precautionary statements (GHS-US) : Wash hands thoroughly after handling. Avoid breathing gas/mist/vapors/spray. Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. If exposed or concerned: Get medical advice/attention. If on skin: Wash with plenty of water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Other hazards No additional information available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Distillates, petroleum, solvent-refined heavy paraffinic (CAS No) 64741-88-4 30 - 60 Not classified Distillates, petroleum, hydrotreated light naphthenic (CAS No) 64742-53-6 15 - 40 Not classified Distillates, petroleum, hydrotreated heavy naphthenic (CAS No) 64742-52-5 10 - 30 Asp. Tox. 1 Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS No) 68649-42-3 1 - 5 Skin Irrit. 2 Eye Dam. 1 Phenol, (tetrapropenyl) derivatives (CAS No) 74499-35-7 0.1 - 1 Skin Irrit. 2 Eye Irrit. 2A Repr. 2 Phenol, (tetrapropenyl) derivatives, calcium salts (CAS No) 132752-19-3 0.1 - 1 Repr. 1B PENRAY ENGINE OIL TREATMENT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 2/6 Name Product identifier % GHS-US classification Benzenesulfonic acid, methyl-, mono-C20-24-branched alkyl derivatives, calcium salts (CAS No) 722503-68-6 0.1 - 1 Skin Sens. 1 Methyl alcohol (CAS No) 67-56-1 < 0.1 Flam. Liq. 2 Acute Tox. 3 (Oral, Dermal, Inhalation) Eye Irrit. 2B STOT SE 1 The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If inhaled and if breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get immediate medical advice/attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause respiratory tract irritation. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. May cause sensitization by skin contact. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Powder, water spray, foam, carbon dioxide. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Use water spray to keep fire-exposed containers cool. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. 6.2. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Avoid contact with skin and eyes. Avoid breathing gas/mist/vapors/spray. Do not swallow. Handle and open container with care. When using do not eat, drink or smoke. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store locked up. 7.3. Specific end use(s) Not available. PENRAY ENGINE OIL TREATMENT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 3/6 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) USA ACGIH ACGIH TWA (mg/m?) 5 mg/m? USA OSHA OSHA PEL (TWA) (mg/m?) 5 mg/m? Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) USA ACGIH ACGIH TWA (mg/m?) 5 mg/m? USA OSHA OSHA PEL (TWA) (mg/m?) 5 mg/m? Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) USA ACGIH ACGIH TWA (mg/m?) 5 mg/m? USA OSHA OSHA PEL (TWA) (mg/m?) 5 mg/m? Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Phenol, (tetrapropenyl) derivatives (74499-35-7) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Phenol, (tetrapropenyl) derivatives, calcium salts (132752-19-3) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Benzenesulfonic acid, methyl-, mono-C20-24-branched alkyl derivatives, calcium salts (722503-68-6) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Methyl alcohol (67-56-1) USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (ppm) 250 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 260 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 200 ppm 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear chemically resistant protective gloves. Eye protection : Safety glasses or goggles are recommended when using product. Skin and body protection : Wear suitable protective clothing. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid. Appearance : Clear. Colour : Amber. Odour : Petroleum odor. Odour threshold : No data available. pH : No data available. PENRAY ENGINE OIL TREATMENT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 4/6 Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : No data available. Flash point : > 100 ?C (> 212 ?F) Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Not flammable. Vapour pressure : No data available. Relative vapour density at 20 ?C : No data available. Relative density : 0.876 - 0.886 Solubility : No data available. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Direct sunlight. 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 3112 LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) No data available. Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) 2.18 mg/l/4h Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) 2.18 mg/l/4h Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 5000 mg/kg LC50 inhalation rat (mg/l) > 5 mg/l/4h Methyl alcohol (67-56-1) LD50 oral rat 5628 mg/kg PENRAY ENGINE OIL TREATMENT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 5/6 Methyl alcohol (67-56-1) LD50 dermal rabbit 15800 mg/kg LC50 inhalation rat (mg/l) 83.2 mg/l/4h Skin corrosion/irritation : Based on available data, the classification criteria are not met. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitisation : May cause an allergic skin reaction. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Based on available data, the classification criteria are not met. Reproductive toxicity : May damage fertility or the unborn child. Specific target organ toxicity (single exposure) : Based on available data, the classification criteria are not met. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : May be fatal if swallowed and enters airways. Symptoms/injuries after inhalation : May cause respiratory tract irritation. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. May cause sensitisation by skin contact. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 3112 Persistence and degradability Not established. 12.3. Bioaccumulative potential 3112 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. SECTION 14: Transport information In accordance with DOT 14.1. UN number Not applicable 14.2. UN proper shipping name Not applicable 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory PENRAY ENGINE OIL TREATMENT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 6/6 Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Phenol, (tetrapropenyl) derivatives (74499-35-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory Phenol, (tetrapropenyl) derivatives, calcium salts (132752-19-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Methyl alcohol (67-56-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 1.0 % 15.2. US State regulations 3112 State or local regulations This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: IARC International Agency for Research on Cancer. 1 - Carcinogenic to humans; 2A - Probably carcinogenic to humans; 2B - Possibly carcinogenic to humans; 3 - Not classifiable; 4 - Probably not carcinogenic to humans. NTP National Toxicology Program. 1 - Evidence of Carcinogenicity; 2 - Known Human Carcinogens; 3 - Reasonably anticipated to be Human Carcinogen; 4 - Substances delisted from report on Carcinogens; 5 - Twelfth Report - Items under consideration. SECTION 16: Other information Indication of changes : None. Date of issue : 04/30/2014 Other information : None. NFPA health hazard : 2 NFPA fire hazard : 1 NFPA reactivity : 0 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product PENRAY OIL SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 08/05/2014 Revision date: 08/05/2014 Version: 1.0 08/05/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PENRAY OIL SYSTEM CLEANER Product code : 7512 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Motor flush. 1.3. Details of the supplier of the safety data sheet The Penray Companies, Inc. 440 Denniston Ct. Wheeling, IL 60090 T (800) 373-6729 This email address is being protected from spambots. You need JavaScript enabled to view it. 1.4. Emergency telephone number Emergency number : (800) 373-6729 CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527-3887 24 hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable Liquid 3 Skin irritation 2 Carcinogenicity 2 Specific target organ toxicity - Single exposure 3 Aspiration hazard 1 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS02 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Flammable liquid and vapor. Causes skin irritation. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Precautionary statements (GHS-US) : Keep away from heat/sparks/open flames/hot surfaces.? No smoking. Keep container tightly closed. Ground/Bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash hands thoroughly after handling. Wear protective gloves/eye protection/face protection. Avoid breathing gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. If on skin (or hair): Take off immediately all contaminated clothing and wash it before reuse. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. Store in a well-ventilated place. Keep cool. Store locked up. Keep container tightly closed. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Other hazards No additional information available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable PENRAY OIL SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 08/05/2014 EN (English) 2/6 3.2. Mixture Name Product identifier % GHS-US classification Kerosine, petroleum (CAS No) 8008-20-6 60 - 100 Flam. Liq. 3 Skin Irrit. 2 STOT SE 3 Asp. Tox. 1 Naphthalene (CAS No) 91-20-3 0.1 - 1 Acute Tox. 4 (Oral) Carc. 2 * The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get immediate medical advice/attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause drowsiness, dizziness and central nervous system depression. May cause respiratory tract irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Powder, water spray, foam, carbon dioxide. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, aldehydes, hydrocarbons. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Vapors may be heavier than air and may travel along the ground to a distant ignition source and flash back. Use water spray to keep fire-exposed containers cool. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition. 6.2. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. PENRAY OIL SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 08/05/2014 EN (English) 3/6 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep away from sources of ignition - No smoking. Avoid contact with skin and eyes. Avoid breathing gas/mist/vapors/spray. Do not swallow. Handle and open container with care. Use only non-sparking tools. When using do not eat, drink or smoke. Use only outdoors or in a well- ventilated area. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed and in a well-ventilated place. Store locked up. Keep cool. Keep away from heat, sparks, and flame. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Kerosine, petroleum (8008-20-6) USA ACGIH ACGIH TWA (mg/m?) 200 mg/m? Naphthalene (91-20-3) USA ACGIH ACGIH TWA (ppm) 10 ppm USA ACGIH ACGIH STEL (ppm) 15 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 50 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 10 ppm 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear chemically resistant protective gloves. Eye protection : Safety glasses or goggles are recommended when using product. Skin and body protection : Wear suitable protective clothing. Respiratory protection : A NIOSH approved respirator is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid. Appearance : Clear. Color : Red. Odor : Solvent. Odor threshold : No data available. pH : Neutral. Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : 182 - 288 ?C (360 - 550 ?F) Flash point : 49 - 88 ?C (120 - 190 ?F) Self ignition temperature : ~ 254 ?C (~ 489 ?F) Decomposition temperature : No data available. Flammability (solid, gas) : Flammable. Vapor pressure : 1 - 10 mm Hg @ 38 ?C (100 ?F) PENRAY OIL SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 08/05/2014 EN (English) 4/6 Relative vapor density at 20 ?C : 4 - 5 Relative density : ~ 0.8 Solubility : Negligible. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : 1.3 - 2.1 @ 50 ?C (122 ?F) Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : 0.7 - 5 vol % 9.2. Other information VOC content : 10 % SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. May form flammable/explosive vapor-air mixture. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Open flame. 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon, aldehydes, hydrocarbons. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 7512 LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat No data available. Kerosine, petroleum (8008-20-6) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 5.28 mg/l/4h Naphthalene (91-20-3) LD50 oral rat 490 mg/kg LD50 dermal rabbit > 20 g/kg LC50 inhalation rat >340 mg/m3/1h LC50 inhalation rat >0.4 mg/l/4h Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Based on available data, the classification criteria are not met. Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Suspected of causing cancer. Naphthalene (91-20-3) IARC group 2B - Possibly carcinogenic to humans National Toxicity Program (NTP) Status 1 - Evidence of Carcinogenicity, 3 - Reasonably anticipated to be Human Carcinogen Reproductive toxicity : Based on available data, the classification criteria are not met. PENRAY OIL SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 08/05/2014 EN (English) 5/6 Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : May be fatal if swallowed and enters airways. Symptoms/injuries after inhalation : May cause drowsiness, dizziness and central nervous system depression. May cause respiratory tract irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 7512 Persistence and degradability Not established. 12.3. Bioaccumulative potential 7512 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on ozone layer : No additional information available Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Additional information : Handle empty containers with care because residual vapors are flammable. SECTION 14: Transport information In accordance with DOT 14.1. UN number UN-No. : UN1223 14.2. UN proper shipping name Proper Shipping Name : Kerosene Department of Transportation Hazard Classes : 3 Hazard labels : Packing group : III 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. PENRAY OIL SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 08/05/2014 EN (English) 6/6 SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory. Naphthalene (91-20-3) Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 0.1 % 15.2. US State regulations 7512 State or local regulations This product contains a chemical known to the State of California to cause cancer. SECTION 16: Other information Indication of changes : None. Date of issue : 08/05/2014 Other information : None. NFPA health hazard : 2 NFPA fire hazard : 2 NFPA reactivity : 1 Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use. 3112 US OSHA GHS SDS (English) 2014-04-30 7512 US OSHA GHS SDS (English) 2014-08-05