PENRAY FUEL INJECTOR CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 Date of issue: 12/31/2014 Revision date: 12/31/2014 Version: 1.0 12/31/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PENRAY FUEL INJECTOR CLEANER Product code : 2112 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Fuel System cleaner. 1.3. Details of the supplier of the safety data sheet The Penray Companies, Inc. 440 Denniston Ct. Wheeling, IL 60090 T (800) 373-6729 This email address is being protected from spambots. You need JavaScript enabled to view it. 1.4. Emergency telephone number Emergency number : (800) 373-6729 CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527-3887 24 hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable Liquid 2 Skin irritation 2 Carcinogenicity 2 Specific target organ toxicity - Single exposure 3 Aspiration hazard 1 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS02 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Highly flammable liquid and vapor. Causes skin irritation. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Precautionary statements (GHS-US) : Keep away from heat/sparks/open flames/hot surfaces.? No smoking. Keep container tightly closed. Ground/Bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/eye protection/face protection. Wash hands thoroughly after handling. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. If on skin (or hair): Take off immediately all contaminated clothing and wash it before reuse. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) 4 percent of the mixture consists of ingredient(s) of unknown acute toxicity. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable PENRAY FUEL INJECTOR CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/31/2014 EN (English) 2/9 3.2. Mixture Name Product identifier % GHS-US classification Kerosine, petroleum (CAS No) 8008-20-6 60 - 100 Flam. Liq. 3 Skin Irrit. 2 STOT SE 3 Asp. Tox. 1 Polyolefin alkyl phenol alkyl amine Propriatary 1 - 2 Skin Irrit. 2 Eye Irrit. 2A Benzene, 1,2,4-trimethyl- (CAS No) 95-63-6 0.5 - 1.5 Flam. Liq. 3 Acute Tox. 4 (Inhalation) Skin Irrit. 2 Eye Irrit. 2A STOT SE 3 Naphthalene (CAS No) 91-20-3 < 0.5 Acute Tox. 4 (Oral) Carc. 2 Cumene (CAS No) 98-82-8 < 0.1 Flam. Liq. 3 Acute Tox. 4 (Oral) Carc. 2 STOT SE 3 Asp. Tox. 1 Ethylbenzene (CAS No) 100-41-4 < 0.1 Flam. Liq. 2 Acute Tox. 4 (Inhalation) Skin Irrit. 2 Carc. 2 Toluene (CAS No) 108-88-3 < 0.1 Flam. Liq. 2 Skin Irrit. 2 Repr. 2 (developmental) STOT SE 3 STOT RE 2 Asp. Tox. 1 Benzene (CAS No) 71-43-2 < 0.1 Flam. Liq. 2 Acute Tox. 4 (Oral) Skin Irrit. 2 Eye Irrit. 2A Muta. 1B Carc. 1A STOT RE 1 Asp. Tox. 1 Furan (CAS No) 110-00-9 < 0.1 Flam. Liq. 1 Acute Tox. 4 (Oral) Acute Tox. 3 (Inhalation) Skin Irrit. 2 Muta. 2 Carc. 1B STOT RE 2 Propylene oxide (CAS No) 75-56-9 < 0.1 Flam. Liq. 1 Acute Tox. 3 (Inhalation) Acute Tox. 4 (Oral, Dermal) Eye Irrit. 2A Muta. 1B Carc. 2 STOT SE 3 Acetaldehyde (CAS No) 75-07-0 < 0.1 Flam. Liq. 1 Eye Irrit. 2A Carc. 2 STOT SE 3 * The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water. Remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get immediate medical advice/attention. PENRAY FUEL INJECTOR CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/31/2014 EN (English) 3/9 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause respiratory tract irritation. May cause drowsiness, dizziness and central nervous system depression. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Powder, water spray, foam, carbon dioxide. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, aldehydes, hydrocarbons. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Vapors may be heavier than air and may travel along the ground to a distant ignition source and flash back. Use water spray to keep fire-exposed containers cool. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition. 6.2. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep away from sources of ignition - No smoking. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not swallow. Handle and open container with care. Use only non-sparking tools. When using do not eat, drink or smoke. Use only outdoors or in a well-ventilated area. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed and in a well-ventilated place. Store locked up. Keep cool. Keep away from heat, sparks, and flame. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Kerosine, petroleum (8008-20-6) USA ACGIH ACGIH TWA (mg/m?) 200 mg/m? Polyolefin alkyl phenol alkyl amine (Propriatary) ACGIH Not applicable OSHA Not applicable PENRAY FUEL INJECTOR CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/31/2014 EN (English) 4/9 Benzene, 1,2,4-trimethyl- (95-63-6) ACGIH Not applicable OSHA Not applicable Naphthalene (91-20-3) USA ACGIH ACGIH TWA (ppm) 10 ppm USA ACGIH ACGIH STEL (ppm) 15 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 50 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 10 ppm Cumene (98-82-8) USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 245 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 50 ppm Ethylbenzene (100-41-4) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 435 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Toluene (108-88-3) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm Benzene (71-43-2) USA ACGIH ACGIH TWA (ppm) 0.5 ppm USA ACGIH ACGIH STEL (ppm) 2.5 ppm USA OSHA OSHA PEL (TWA) (ppm) 1 ppm USA OSHA OSHA PEL (STEL) (ppm) 5 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 25 ppm Furan (110-00-9) ACGIH Not applicable OSHA Not applicable Propylene oxide (75-56-9) USA ACGIH ACGIH TWA (ppm) 2 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 240 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Acetaldehyde (75-07-0) USA OSHA OSHA PEL (TWA) (mg/m?) 360 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 200 ppm 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear chemically resistant protective gloves. Eye protection : Safety glasses or goggles are recommended when using product. Skin and body protection : Wear suitable protective clothing. PENRAY FUEL INJECTOR CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/31/2014 EN (English) 5/9 Respiratory protection : A NIOSH approved respirator is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear Color : Amber Odor : Petroleum odor Odor threshold : No data available pH : No data available Relative evaporation rate (butylacetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : 22 ?C (71 ?F) Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : Flammable Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : 0.864 - 0.869 Solubility : No data available Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidising properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. May form flammable/explosive vapor-air mixture. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Open flame. 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon, aldehydes, hydrocarbons. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified. PENRAY FUEL INJECTOR CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/31/2014 EN (English) 6/9 2112 LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat No data available Kerosine, petroleum (8008-20-6) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 5.28 mg/l/4h Benzene, 1,2,4-trimethyl- (95-63-6) LD50 oral rat 3280 mg/kg LD50 dermal rabbit > 3160 mg/kg LC50 inhalation rat 18 g/m?/4h Naphthalene (91-20-3) LD50 oral rat 490 mg/kg LD50 dermal rabbit > 20 g/kg Cumene (98-82-8) LD50 oral rat 1400 mg/kg LD50 dermal rabbit >3160 mg/kg LC50 inhalation rat 39000 mg/m3/4h Ethylbenzene (100-41-4) LD50 oral rat 3500 mg/kg LD50 dermal rabbit 15354 mg/kg LC50 inhalation rat 17.2 mg/l/4h Toluene (108-88-3) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit 8390 mg/kg LD50 dermal rat 12124 mg/kg LC50 inhalation rat 28.1 mg/l/4h Benzene (71-43-2) LD50 oral rat 930 mg/kg LD50 dermal rabbit > 9.4 ml/kg LC50 inhalation rat 13050-14380 ppm/4h Furan (110-00-9) LC50 inhalation rat 3398 ppm/1h Propylene oxide (75-56-9) LD50 oral rat 520 mg/kg LD50 dermal rabbit 1244 mg/kg LC50 inhalation rat 4000 ppm/4h Acetaldehyde (75-07-0) LD50 oral rat 1930 mg/kg LC50 inhalation rat 13300 ppm/4h Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Based on available data, the classification criteria are not met. Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Suspected of causing cancer. Naphthalene (91-20-3) IARC group 2B - Possibly carcinogenic to humans National Toxicology Program (NTP) Status 1 - Evidence of Carcinogenicity, 3 - Reasonably anticipated to be Human Carcinogen Cumene (98-82-8) IARC group 2B - Possibly carcinogenic to humans National Toxicology Program (NTP) Status 1 - Evidence of Carcinogenicity PENRAY FUEL INJECTOR CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/31/2014 EN (English) 7/9 Ethylbenzene (100-41-4) IARC group 2B - Possibly carcinogenic to humans National Toxicology Program (NTP) Status 1 - Evidence of Carcinogenicity Toluene (108-88-3) IARC group 3 - Not classifiable Benzene (71-43-2) IARC group 1 - Carcinogenic to humans National Toxicology Program (NTP) Status 1 - Evidence of Carcinogenicity, 2 - Known Human Carcinogens In OSHA Specifically Regulated Carcinogen list Furan (110-00-9) IARC group 2B - Possibly carcinogenic to humans National Toxicology Program (NTP) Status 1 - Evidence of Carcinogenicity, 3 - Reasonably anticipated to be Human Carcinogen Propylene oxide (75-56-9) IARC group 2B - Possibly carcinogenic to humans National Toxicology Program (NTP) Status 1 - Evidence of Carcinogenicity, 3 - Reasonably anticipated to be Human Carcinogen Acetaldehyde (75-07-0) IARC group 1 - Carcinogenic to humans (associated with consumption of alcoholic beverages), 2B - Possibly carcinogenic to humans National Toxicology Program (NTP) Status 3 - Reasonably anticipated to be Human Carcinogen Reproductive toxicity : Based on available data, the classification criteria are not met. Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : May be fatal if swallowed and enters airways. Symptoms/injuries after inhalation : May cause respiratory tract irritation. May cause drowsiness, dizziness and central nervous system depression. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 2112 Persistence and degradability Not established. 12.3. Bioaccumulative potential 2112 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Additional information : Handle empty containers with care because residual vapors are flammable. PENRAY FUEL INJECTOR CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/31/2014 EN (English) 8/9 SECTION 14: Transport information In accordance with DOT UN-No.(DOT) : UN1993 Proper Shipping Name (DOT) : Flammable liquids, n.o.s. (Petroleum, Benzene, 1,2,4-trimethyl-) Department of Transportation (DOT) Hazard Classes : 3 Hazard labels (DOT) : Packing group (DOT) : II Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory. Benzene, 1,2,4-trimethyl- (95-63-6) Listed on United States SARA Section 313 SARA Section 313 - Emission Reporting 1.0 % Naphthalene (91-20-3) Listed on United States SARA Section 313 EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 0.1 % Cumene (98-82-8) Listed on United States SARA Section 313 EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 1.0 % Ethylbenzene (100-41-4) Listed on United States SARA Section 313 SARA Section 313 - Emission Reporting 0.1 % Toluene (108-88-3) Listed on United States SARA Section 313 SARA Section 313 - Emission Reporting 1.0 % Benzene (71-43-2) Listed on United States SARA Section 313 SARA Section 313 - Emission Reporting 0.1 % Furan (110-00-9) Listed on the United States SARA Section 302 Listed on United States SARA Section 313 SARA Section 302 Threshold Planning Quantity (TPQ) 500 SARA Section 313 - Emission Reporting 0.1 % Propylene oxide (75-56-9) Listed on the United States SARA Section 302 Listed on United States SARA Section 313 EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 302 Threshold Planning Quantity (TPQ) 10000 SARA Section 313 - Emission Reporting 0.1 % PENRAY FUEL INJECTOR CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 12/31/2014 EN (English) 9/9 Acetaldehyde (75-07-0) Listed on United States SARA Section 313 EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 0.1 % 15.2. US State regulations 2112 State or local regulations This product contains chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 16: Other information Indication of changes : None. Date of issue : 12/31/2014 Other information : None. NFPA health hazard : 2 NFPA fire hazard : 3 NFPA reactivity : 0 Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use. PENRAY INTAKE VALVE DEPOSIT CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 07/24/2014 Revision date: 07/24/2014 Version: 1.0 07/24/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PENRAY INTAKE VALVE DEPOSIT CLEANER CAS No : 2312 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Fuel System cleaner. 1.3. Details of the supplier of the safety data sheet The Penray Companies, Inc. 440 Denniston Ct. Wheeling, IL 60090 T (800) 373-6729 This email address is being protected from spambots. You need JavaScript enabled to view it. 1.4. Emergency telephone number Emergency number : (800) 373-6729 CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527-3887 24 hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable Liquid 2 Acute toxicity 4 (Dermal, Inhalation) Skin irritation 2 Carcinogenicity 2 Reproductive toxicity 2 (developmental) Specific target organ toxicity - Repeated exposure 2 Aspiration hazard 1 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS02 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Highly flammable liquid and vapor. Harmful in contact with skin or if inhaled. Causes skin irritation. Suspected of damaging the unborn child. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways. Precautionary statements (GHS-US) : Keep away from heat/sparks/open flames/hot surfaces.? No smoking. Keep container tightly closed. Ground/Bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Use only outdoors or in a well- ventilated area. Wash hands thoroughly after handling. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe gas/mist/vapors/spray. If exposed or concerned: Get medical advice/attention. If on skin (or hair): Take off immediately all contaminated clothing and wash it before reuse. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Other hazards No additional information available PENRAY INTAKE VALVE DEPOSIT CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 07/24/2014 EN (English) 2/9 SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Xylenes (o-, m-, p- isomers) (CAS No) 1330-20-7 60 - 100 Flam. Liq. 3 Acute Tox. 4 (Dermal, Inhalation) Skin Irrit. 2 Ethylbenzene (CAS No) 100-41-4 7 - 30 Flam. Liq. 2 Acute Tox. 4 (Inhalation) Skin Irrit. 2 Carc. 2 Asp. Tox. 1 Toluene (CAS No) 108-88-3 7 - 13 Flam. Liq. 2 Skin Irrit. 2 Repr. 2 STOT SE 3 STOT RE 2 Asp. Tox. 1 Solvent naphtha, petroleum, light aromatic (CAS No) 64742-95-6 0.5 - 1.5 Flam. Liq. 3 Skin Irrit. 2 Eye Irrit. 2A Asp. Tox. 1 Cumene (CAS No) 98-82-8 < 0.1 Flam. Liq. 3 Carc. 2 STOT SE 3 Asp. Tox. 1 Benzene (CAS No) 71-43-2 < 0.1 Flam. Liq. 2 Acute Tox. 4 (Oral) Skin Irrit. 2 Eye Irrit. 2A Muta. 1B Carc. 1A STOT RE 1 Asp. Tox. 1 Naphthalene (CAS No) 91-20-3 < 0.1 Acute Tox. 4 (Oral) Carc. 2 Furan (CAS No) 110-00-9 < 0.1 Flam. Liq. 1 Acute Tox. 3 (Inhalation) Acute Tox. 4 (Oral) Skin Irrit. 2 Muta. 2 Carc. 1B STOT RE 2 Propylene oxide (CAS No) 75-56-9 < 0.1 Flam. Liq. 1 Acute Tox. 3 (Inhalation) Acute Tox. 4 (Oral, Dermal) Eye Irrit. 2A Muta. 1B Carc. 2 STOT SE 3 Acetaldehyde (CAS No) 75-07-0 < 0.1 Flam. Liq. 1 Eye Irrit. 2A Carc. 2 STOT SE 3 * The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get immediate medical advice/attention. PENRAY INTAKE VALVE DEPOSIT CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 07/24/2014 EN (English) 3/9 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : Harmful if inhaled. May cause drowsiness, dizziness and central nervous system depression. May cause respiratory tract irritation. Symptoms/injuries after skin contact : Harmful in contact with skin. Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Powder, water spray, foam, carbon dioxide. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, aldehydes, hydrocarbons. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Vapors may be heavier than air and may travel along the ground to a distant ignition source and flash back. Use water spray to keep fire-exposed containers cool. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition. 6.2. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep away from sources of ignition - No smoking. Avoid contact with skin and eyes. Do not breathe gas/mist/vapors/spray. Do not swallow. Handle and open container with care. Use only non-sparking tools. When using do not eat, drink or smoke. Use only outdoors or in a well- ventilated area. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed and in a well-ventilated place. Store locked up. Keep cool. Keep away from heat, sparks, and flame. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Xylenes (o-, m-, p- isomers) (1330-20-7) USA ACGIH ACGIH TWA (ppm) 100 ppm USA ACGIH ACGIH STEL (ppm) 150 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 435 mg/m? PENRAY INTAKE VALVE DEPOSIT CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 07/24/2014 EN (English) 4/9 Xylenes (o-, m-, p- isomers) (1330-20-7) USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Ethylbenzene (100-41-4) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 435 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Toluene (108-88-3) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (STEL) (ppm) 150 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm Solvent naphtha, petroleum, light aromatic (64742-95-6) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Cumene (98-82-8) USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 245 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 50 ppm Benzene (71-43-2) USA ACGIH ACGIH TWA (ppm) 0.5 ppm USA ACGIH ACGIH STEL (ppm) 2.5 ppm USA OSHA OSHA PEL (TWA) (ppm) 1 ppm USA OSHA OSHA PEL (STEL) (ppm) 5 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 25 ppm Naphthalene (91-20-3) USA ACGIH ACGIH TWA (ppm) 10 ppm USA ACGIH ACGIH STEL (ppm) 15 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 50 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 10 ppm Furan (110-00-9) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Propylene oxide (75-56-9) USA ACGIH ACGIH TWA (ppm) 2 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 240 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Acetaldehyde (75-07-0) USA ACGIH ACGIH Ceiling (ppm) 25 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 360 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 200 ppm PENRAY INTAKE VALVE DEPOSIT CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 07/24/2014 EN (English) 5/9 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear chemically resistant protective gloves. Eye protection : Safety glasses or goggles are recommended when using product. Skin and body protection : Wear suitable protective clothing. Respiratory protection : A NIOSH approved respirator is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid. Appearance : Clear. Color : Amber. Odor : Petroleum odor. Odor threshold : No data available. pH : No data available. Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : No data available. Flash point : ~ 22 ?C (~ 71 ?F) Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Flammable. Vapor pressure : No data available. Relative vapor density at 20 ?C : No data available. Relative density : 0.864 - 0.869 Solubility : No data available. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. May form flammable/explosive vapor-air mixture. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Open flame. PENRAY INTAKE VALVE DEPOSIT CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 07/24/2014 EN (English) 6/9 10.5. Incompatible materials Acids. Bases. Strong oxidizing agents. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon, aldehydes, hydrocarbons. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Harmful in contact with skin or if inhaled. 2312 LD50 oral rat > 2000 mg/kg LD50 dermal rabbit >1000 but ?2000 mg/kg LC50 inhalation rat >10.0 but ?20.0 mg/l/4h (Calculated using ATE values) Xylenes (o-, m-, p- isomers) (1330-20-7) LD50 oral rat 4300 mg/kg LD50 dermal rabbit > 1700 mg/kg LC50 inhalation rat 5000 ppm/4 h Ethylbenzene (100-41-4) LD50 oral rat 3500 mg/kg LD50 dermal rabbit 15354 mg/kg LC50 inhalation rat 17.2 mg/l/4h Toluene (108-88-3) LD50 oral rat > 5000 mg/kg LD50 dermal rat 12124 mg/kg LD50 dermal rabbit 8390 mg/kg LC50 inhalation rat 28.1 mg/l/4h Solvent naphtha, petroleum, light aromatic (64742-95-6) LD50 oral rat 8400 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat 3400 ppm/4h LC50 inhalation rat > 5.2 mg/l/4h Cumene (98-82-8) LD50 oral rat 1400 mg/kg LD50 dermal rabbit > 3160 mg/kg LC50 inhalation rat 39000 mg/m 3 /4 h Benzene (71-43-2) LD50 oral rat 930 mg/kg LD50 dermal rabbit > 9.4 mL/kg LC50 inhalation rat 13050 - 14380 ppm/4h Naphthalene (91-20-3) LD50 oral rat 490 mg/kg LD50 dermal rabbit > 20 g/kg LC50 inhalation rat >340 mg/m 3 /4 h Furan (110-00-9) LC50 inhalation rat 3398 ppm/1h Propylene oxide (75-56-9) LD50 oral rat 520 mg/kg LD50 dermal rabbit 1244 mg/kg LC50 inhalation rat 4000 ppm/4h Acetaldehyde (75-07-0) LD50 oral rat 1930 mg/kg LC50 inhalation rat 13300 ppm/4h PENRAY INTAKE VALVE DEPOSIT CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 07/24/2014 EN (English) 7/9 Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Based on available data, the classification criteria are not met. Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Suspected of causing cancer. Xylenes (o-, m-, p- isomers) (1330-20-7) IARC group 3 - Not classifiable Ethylbenzene (100-41-4) IARC group 2B - Possibly carcinogenic to humans National Toxicity Program (NTP) Status 1 - Evidence of Carcinogenicity Toluene (108-88-3) IARC group 3 - Not classifiable Cumene (98-82-8) IARC group 2B - Possibly carcinogenic to humans National Toxicity Program (NTP) Status 1 - Evidence of Carcinogenicity Benzene (71-43-2) IARC group 1 - Carcinogenic to humans National Toxicity Program (NTP) Status 1 - Evidence of Carcinogenicity, 2 - Known Human Carcinogens In OSHA Specifically Regulated Carcinogen list Naphthalene (91-20-3) IARC group 2B - Possibly carcinogenic to humans National Toxicity Program (NTP) Status 1 - Evidence of Carcinogenicity, 3 - Reasonably anticipated to be Human Carcinogen Furan (110-00-9) IARC group 2B - Possibly carcinogenic to humans National Toxicity Program (NTP) Status 1 - Evidence of Carcinogenicity, 3 - Reasonably anticipated to be Human Carcinogen Propylene oxide (75-56-9) IARC group 2B - Possibly carcinogenic to humans National Toxicity Program (NTP) Status 1 - Evidence of Carcinogenicity, 3 - Reasonably anticipated to be Human Carcinogen Acetaldehyde (75-07-0) IARC group 1 - Carcinogenic to humans, 2B - Possibly carcinogenic to humans National Toxicity Program (NTP) Status 3 - Reasonably anticipated to be Human Carcinogen Reproductive toxicity : Suspected of damaging the unborn child. Specific target organ toxicity (single exposure) : Based on available data, the classification criteria are not met. Specific target organ toxicity (repeated exposure) : May cause damage to organs through prolonged or repeated exposure. Aspiration hazard : May be fatal if swallowed and enters airways. Symptoms/injuries after inhalation : Harmful if inhaled. May cause drowsiness, dizziness and central nervous system depression. May cause respiratory tract irritation. Symptoms/injuries after skin contact : Harmful in contact with skin. Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 2312 Persistence and degradability Not established. PENRAY INTAKE VALVE DEPOSIT CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 07/24/2014 EN (English) 8/9 12.3. Bioaccumulative potential 2312 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on ozone layer : No additional information available Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Additional information : Handle empty containers with care because residual vapors are flammable. SECTION 14: Transport information In accordance with DOT 14.1. UN number UN-No. : 3295 14.2. UN proper shipping name Proper Shipping Name : Hydrocarbons, liquid, n.o.s. (Xylene, Ethylbenzene, Toluene) Department of Transportation Hazard Classes : 3 Hazard labels : Packing group : II 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory. Xylenes (o-, m-, p- isomers) (1330-20-7) Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 1.0 % Ethylbenzene (100-41-4) Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 0.1 % Toluene (108-88-3) Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 1.0 % Cumene (98-82-8) Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 1.0 % PENRAY INTAKE VALVE DEPOSIT CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 07/24/2014 EN (English) 9/9 Benzene (71-43-2) Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 0.1 % Naphthalene (91-20-3) Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 0.1 % Furan (110-00-9) Listed on SARA Section 302 (Specific toxic chemical listings) Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 302 Threshold Planning Quantity (TPQ) 500 SARA Section 313 - Emission Reporting 0.1 % Propylene oxide (75-56-9) Listed on SARA Section 302 (Specific toxic chemical listings) Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 302 Threshold Planning Quantity (TPQ) 10000 SARA Section 313 - Emission Reporting 0.1 % Acetaldehyde (75-07-0) Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 0.1 % 15.2. US State regulations 2312 State or local regulations This product contains chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 16: Other information Indication of changes : None. Date of issue : 07/24/2014 Other information : None. NFPA health hazard : 2 NFPA fire hazard : 3 NFPA reactivity : 0 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product PENRAY F.I. AIR INTAKE CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 04/30/2014 Revision date: 04/30/2014 Version: 1.0 04/30/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PENRAY F.I. AIR INTAKE CLEANER Product code : 2412 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Fuel system cleaner. 1.3. Details of the supplier of the safety data sheet The Penray Companies, Inc. 440 Denniston Ct. 60090 Wheeling, IL T (800) 373-6729 This email address is being protected from spambots. You need JavaScript enabled to view it. 1.4. Emergency telephone number Emergency number : (800) 373-6729 CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527-3887 24 hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable Liquid 3 Skin irritation 2 Serious eye damage 1 Carcinogenicity 2 Specific target organ toxicity - Single exposure 3 Aspiration hazard 1 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS02 GHS05 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Flammable liquid and vapor. Causes skin irritation. Causes serious eye damage. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Precautionary statements (GHS-US) : Keep away from heat/sparks/open flames/hot surfaces.? No smoking. Keep container tightly closed. Ground/Bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/eye protection/face protection. Wash hands thoroughly after handling. Avoid breathing gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. If on skin (or hair): Take off immediately all contaminated clothing and wash it before reuse. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Other hazards No additional information available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable PENRAY F.I. AIR INTAKE CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 2/8 3.2. Mixture Name Product identifier % GHS-US classification Kerosene, petroleum (CAS No) 8008-20-6 30 - 60 Flam. Liq. 3 Skin Irrit. 2 STOT SE 3 Asp. Tox. 1 Isopropyl alcohol (CAS No) 67-63-0 15 - 40 Flam. Liq. 2 Eye Irrit. 2A STOT SE 3 Solvent naphtha, petroleum, light aromatic (CAS No) 64742-95-6 7 - 13 Asp. Tox. 1 Alkylphenol polyoxyalkyl alkylamine Proprietary 7 - 13 Eye Dam. 1 Xylenes (o-, m-, p- isomers) (CAS No) 1330-20-7 1 - 5 Flam. Liq. 3 Acute Tox. 4 (Dermal, Inhalation) Skin Irrit. 2 Benzene, 1,2,4-trimethyl- (CAS No) 95-63-6 1 - 5 Flam. Liq. 3 Acute Tox. 4 (Inhalation) Skin Irrit. 2 Eye Irrit. 2A STOT SE 3 1,3,5-Trimethylbenzene (CAS No) 108-67-8 1 - 5 Flam. Liq. 3 Skin Irrit. 2 Eye Irrit. 2A STOT SE 3 Asp. Tox. 1 n-Propylbenzene (CAS No) 103-65-1 1 - 5 Flam. Liq. 3 STOT SE 3 Asp. Tox. 1 Cumene (CAS No) 98-82-8 0.1 - 1 Flam. Liq. 3 Acute Tox. 4 (Oral) Carc. 2 Naphthalene (CAS No) 91-20-3 0.1 - 1 Acute Tox. 4 (Oral, Dermal) Carc. 2 The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get medical attention immediately. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get immediate medical advice/attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause drowsiness, dizziness and central nervous system depression. May cause respiratory tract irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. May cause burns. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Powder, water spray, foam, carbon dioxide. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Vapors may be heavier than air and may travel along the ground to a distant ignition source and flash back. Use water spray to keep fire-exposed containers cool. PENRAY F.I. AIR INTAKE CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 3/8 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition. 6.2. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep away from sources of ignition - No smoking. Avoid contact with skin and eyes. Avoid breathing gas/mist/vapors/spray. Do not swallow. Handle and open container with care. Use only non-sparking tools. When using do not eat, drink or smoke. Use only outdoors or in a well- ventilated area. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed and in a well-ventilated place. Store locked up. Keep cool. Keep away from heat, sparks, and flame. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Kerosene, petroleum (8008-20-6) USA ACGIH ACGIH TWA (mg/m?) 200 mg/m? Isopropyl alcohol (67-63-0) USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (ppm) 400 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 980 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 400 ppm Solvent naphtha, petroleum, light aromatic (64742-95-6) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Alkylphenol polyoxyalkyl alkylamine (Proprietary) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Xylenes (o-, m-, p- isomers) (1330-20-7) USA ACGIH ACGIH TWA (ppm) 100 ppm USA ACGIH ACGIH STEL (ppm) 150 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 435 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Benzene, 1,2,4-trimethyl- (95-63-6) USA ACGIH ACGIH TWA (ppm) 25 ppm 1,3,5-Trimethylbenzene (108-67-8) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. PENRAY F.I. AIR INTAKE CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 4/8 n-Propylbenzene (103-65-1) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Cumene (98-82-8) USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 245 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 50 ppm Naphthalene (91-20-3) USA ACGIH ACGIH TWA (ppm) 10 ppm USA ACGIH ACGIH STEL (ppm) 15 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 50 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 10 ppm 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear chemically resistant protective gloves. Eye protection : Wear approved eye (properly fitted dust- or splash-proof chemical safety goggles) / face (face shield) protection. Skin and body protection : Wear suitable protective clothing. Respiratory protection : A NIOSH approved respirator is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid. Appearance : Clear. Colour : No data available. Odour : Petroleum odor. Odour threshold : No data available. pH : No data available. Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : No data available. Flash point : ~ 26 ?C (~ 78 ?F) Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Flammable. Vapour pressure : No data available. Relative vapour density at 20 ?C : No data available. Relative density : 0.811 - 0.823 Solubility : No data available. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. PENRAY F.I. AIR INTAKE CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 5/8 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. May form flammable/explosive vapour-air mixture. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Open flame. 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 2412 LD50 oral rat > 2000 mg/kg LD50 dermal rat > 2000 mg/kg LC50 inhalation rat (mg/l) > 20 mg/l/4h Kerosene, petroleum (8008-20-6) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) > 5.28 mg/l/4h Isopropyl alcohol (67-63-0) LD50 oral rat 4396 mg/kg LD50 dermal rat 12800 mg/kg LD50 dermal rabbit 12870 mg/kg LC50 inhalation rat (mg/l) 72.6 mg/l/4h Solvent naphtha, petroleum, light aromatic (64742-95-6) LD50 oral rat 8400 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (ppm) 3400 ppm/4h LC50 inhalation rat (mg/l) > 5.2 mg/l/4h Xylenes (o-, m-, p- isomers) (1330-20-7) LD50 oral rat 4300 mg/kg LD50 dermal rabbit > 1700 mg/kg LC50 inhalation rat (ppm) 5000 ppm/4h LC50 inhalation rat (mg/l) 47635 mg/l/4h Benzene, 1,2,4-trimethyl- (95-63-6) LD50 oral rat 3400 mg/kg LD50 dermal rabbit > 3160 mg/kg LC50 inhalation rat (mg/l) 18 g/m?/4h 1,3,5-Trimethylbenzene (108-67-8) LC50 inhalation rat (mg/l) 24 g/m?/4 h n-Propylbenzene (103-65-1) LD50 oral rat 6040 mg/kg LC50 inhalation rat (ppm) 65000 ppm/2h Cumene (98-82-8) LD50 oral rat 1400 mg/kg LD50 dermal rabbit > 3160 mg/kg LC50 inhalation rat (mg/m3) 39000 mg/m3/4 h PENRAY F.I. AIR INTAKE CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 6/8 Naphthalene (91-20-3) LD50 oral rat 490 mg/kg LD50 dermal rabbit > 20 g/kg Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye damage. Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Suspected of causing cancer. Isopropyl alcohol (67-63-0) IARC group 3 Xylenes (o-, m-, p- isomers) (1330-20-7) IARC group 3 Cumene (98-82-8) IARC group 2B National Toxicity Program (NTP) Status 1 Naphthalene (91-20-3) IARC group 2B National Toxicity Program (NTP) Status 1, 3 Reproductive toxicity : Based on available data, the classification criteria are not met. Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : May be fatal if swallowed and enters airways. Symptoms/injuries after inhalation : May cause drowsiness, dizziness and central nervous system depression. May cause respiratory tract irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. May cause burns. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 2412 Persistence and degradability Not established. 12.3. Bioaccumulative potential 2412 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Additional information : Handle empty containers with care because residual vapours are flammable. SECTION 14: Transport information In accordance with DOT 14.1. UN number UN-No. : UN1993 PENRAY F.I. AIR INTAKE CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 7/8 14.2. UN proper shipping name Proper Shipping Name : Flammable liquids, n.o.s. (Petroleum, Isopropanol) Department of Transportation Hazard Classes : 3 Hazard labels : Packing group (DOT) : III 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations Kerosene, petroleum (8008-20-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory Isopropyl alcohol (67-63-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 1.0 % Solvent naphtha, petroleum, light aromatic (64742-95-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory Xylenes (o-, m-, p- isomers) (1330-20-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 1.0 % Benzene, 1,2,4-trimethyl- (95-63-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 1.0 % 1,3,5-Trimethylbenzene (108-67-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. n-Propylbenzene (103-65-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory Cumene (98-82-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 1.0 % Naphthalene (91-20-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 0.1 % 15.2. US State regulations 2412 State or local regulations This product contains chemicals known to the State of California to cause cancer. PENRAY F.I. AIR INTAKE CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 8/8 SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: IARC International Agency for Research on Cancer. 1 - Carcinogenic to humans; 2A - Probably carcinogenic to humans; 2B - Possibly carcinogenic to humans; 3 - Not classifiable; 4 - Probably not carcinogenic to humans. NTP National Toxicology Program. 1 - Evidence of Carcinogenicity; 2 - Known Human Carcinogens; 3 - Reasonably anticipated to be Human Carcinogen; 4 - Substances delisted from report on Carcinogens; 5 - Twelfth Report - Items under consideration. SECTION 16: Other information Indication of changes : None. Date of issue : 04/30/2014 Other information : None. NFPA health hazard : 3 NFPA fire hazard : 2 NFPA reactivity : 0 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 2112 US OSHA GHS SDS (English) 2014-12-31 2312 US OSHA GHS SDS (English) 2014-07-24 2412 US OSHA GHS SDS (English) 2014-04-30