1 Safety Data Sheet SDS No. Date : Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE SECTION 1: IDENTIFICATION 1.1 Product identifier Product : Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE Synonyms : None Product Part Number : 252-1002 1.2 Relevant identified uses of the substance or mixture and advised against Antifreeze/Coolant 1.3 Detail of the supplier of the safety data sheet Supplier Name: Beck/Arnley Inc. Address: 2375 Midway Lane Smyrna, TN 37167 Telephone: 615-220-3200 1.4 Emergency telephone number INFOTRAC 1-800-535-5053 SECTION 2: HAZARDOUS IDENTIFICATION 2.1 Classification of the substance or mixture Classification : Health Hazard Classification: Acute Toxicity(Oral) Not Classified Acute Toxicity(Dermal) Not Classified Acute Toxicity(Inhalation-Gases) - Acute Toxicity(Inhalation-Vapors) Classification Not Possible Acute Toxicity(Inhalation-Dusts) Classification Not Possible Acute Toxicity(Inhalation-Mists) Classification Not Possible Skin Corrosion/Irritation Category 2 Serious eye damage/Eye irritation Category 2 Respiratory or skin sensitization Classification Not Possible Germ cell mutagenicity Classification Not Possible Carcinogenicity Classification Not Possible Reproductive toxicity Classification Not Possible Specific target organ toxicity single exposure Category 1, 3 Specific target organ toxicity repeated or prolonged exposure Category 2 Aspiration hazard Classification Not Possible Physical Hazard Criteria Explosives - 5/28/2015 2 Safety Data Sheet SDS No. Date : Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE 5/28/2015 Flammable gases - Flammable aerosols - Oxidizing gases - Gases under pressure - Flammable liquids Not Classified Flammable solids - Self-reactive chemicals - Pyrophoric liquids Not Classified Pyrophoric solids - Self-heating chemicals Classification Not Possible Chemicals which, in contact with water, emit flammable gases - Oxidizing liquids Classification Not Possible Oxidizing solids - Organic peroxides - Corrosive to metals Not Classified 2.2 Label elements Hazardous Pictograms Signal word Danger Hazard statements Causes serious eye irritation Causes skin irritation Causes damage to organs May cause respiratory irritation: or May cause drowsiness or dizziness May cause damage to organs through prolonged or repeated exposure Precautionary statements Prevention Wash contact areas thoroughly after handling. Wear eye protection/face protection. Wear protective gloves. Do not breathe mist/vapors/spray. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Response If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If on skin: Wash with plenty of water. 3 Safety Data Sheet SDS No. Date : Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE 5/28/2015 If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. If exposed: Call a poison center/doctor. Get medical advice/attention if you feel unwell. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. Storage Store locked up. Store in a well ventilated place. Keep container tightly closed. Disposal 2.3 Other hazardous Other hazards Data not available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2 Mixtures Components CAS No. Nominal % Hazard PEL/TLV Hazard Code Ethylene 107-21-1 85 - 94 % A Ceiling : Respiratory irritant Glycol 100mg/m Ingestion may produce [Aerosol only] liver, brain and kidney damage. Diethylene 111-46-6 Less than 5% A None Ingestion may produce Glycol kidney damage. Hydrated pro- Less than 7% N/A None None noted. inorganic prietary acid, organic acid salts Water 7732-18-5 Less than 5% N/A None None noted SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measurers A Not Skin, eye and Swallowing : Proprietary items on this SDS are designated as trade secrets. Requests for disclosure of trade secret information will be made in accordance with the provisions contained in OSHA 29 CFR 1910.1200(i). If victim is conscious and able to swallow, quickly have victim drink water or milk to dilute. Do NOT give sodium bicarbonate, fruit juices or vinegar. NEVER give anything by mouth if victim is unconscious or having convulsions. Induce vomiting only if advised by physician or Poison Control Center. CALL PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. Dispose of contents/container in accordance with applicable federal, state and local regulations. 4 Safety Data Sheet SDS No. Date : Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE 5/28/2015 Skin Contact : Immediately flush skin with plenty of water while removing contaminated clothing. Eye Contact : Inhalation : 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11. 4.3 Indication of any immediately medical attention and special treatment needed No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY! SECTION 5 : FIREFIGHTING MEASURES 5.1 Extinguishing media 5.2 Special hazards arising from the substance or mixture Data not available 5.3 Advice for firefighters SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures For personal protection, see section 8. In case of spills, beware of slippery floors and surfaces. 6.2 Environmental precautions 6.3 Method and material for containment cleaning up 6.4 Reference to other sections Water spray may cause foaming of hot glycol so indirect application of water spray or use of other extinguishing media should be used on hot glycol. Immediately flush eyes with plenty of cool water for at least 15 minutes. Do NOT permit victim to rub eyes. GET MEDICAL ATTENTION IMMEDIATELY. Immediately remove victim to fresh air. If victim has stopped breathing give artificial respiration, preferably mouth-to-mouth. GET MEDICAL ATTENTION IMMEDIATELY. Individuals should perform only those firefighting procedures for which they have been trained. Use water spray, dry chemical, foam or carbon dioxide. Use water to keep fire-exposed containers cool. If a spill or leak has not ignited, use water spray to disperse the vapors. Water spray may be used to flush spills away from fire and diluted spills to noncombustible proportions(see warning on water spray on hot glycol below.) To prevent possible storage container rupture, do not permit to freeze. Incompatible with strong acids, oxidizers, bases and chromium trioxide, potassium permanganate, and sodium peroxide. The product should not be dumped in nature but collected and delivered according to agreement with the local authorities. Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. 5 Safety Data Sheet SDS No. Date : Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE 5/28/2015 For disposal see section 13. SECTION 7: HANDLING AND STORAGE 7.1 Precautions and safe handling - Do not expose children and pets to this material. - After handling product, wash thoroughly with soap and water before drinking, eating, or smoking. - Keep away from open flames. 7.2 Conditions for safe storage, including any incompatibilities - To prevent possible storage container rupture, do not permit to freeze. Incompatible with strong acids, oxidizers, bases and chromium trioxide, potassium permanganate, and sodium peroxide. 7.3 Specific end use(s) The identified uses for this product are detailed in section 1.2. SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters 8.2 Exposure controls Control Measures : Respiratory Protection : US AIHA (WEEL) 10 mg/m 3 TWA Handle in the presence of adequate ventilation. Engineering controls should be used whenever feasible to maintain concentrations below acceptable exposure criteria, including enclosures and local exhaust ventilation. Where exposure is likely to exceed acceptable criteria and engineering controls are not feasible, use NIOSH/MSHA approved respiratory protection equipment. Respirators should be selected based on the form and concentration of contaminants in air and in accordance with OSHA (29 CFR 1910.134) 100 mg/m3 TLVUS ACGIH None None SourceComponent 107-21-1 US OSHA CAS No. None None US ACGIH None Diethylene Glycol 111-46-6 US OSHA Ethylene glycol Exposure Limit Notes None Ceiling Limit for Aerosols Only; A4 - Not classifiable as a human carcinogen 6 Safety Data Sheet SDS No. Date : Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE 5/28/2015 Protective Clothing : Eye Protection : SECTION 9: PHYSICAL AND CHEMICAL PROPATIES 9.1 Information of basis physical and chemical properties Appearance : Clear, slightly viscous, dark red dyed liquid Odor : No characteristic odor Odor threshold: Data not available pH: 7.5 (50v/v%) Freezing point: Lower than -15oC (5?F) Initial boiling point and boiling range: Higher than 149oC (300 ?F) Flash point: 126oC (259oF) Evaporation rate: Data not available Flammability(Solid, gas): Data not available Upper/Lower flammability or explosive limits: Data not available Vapor pressure : Data not available Vapor Density (Air = 1) : Data not available Density (20?C) : 1.13 g/cm3 Solubility in Water : Infinite miscibility Partition coefficient n-octanol/water: Data not available Auto ignition temperature: Data not available Decomposition temperature: Data not available Viscosity: Data not available 9.2 Other information None SECTION 10 : STABILITY AND REACTIVITY 10.1 Reactivity Hazardous Polymerization : Not likely to occur Conditions and Materials to Avoid : 10.2 Chemical stability Generally stable Wear safety glasses meeting the specifications of ANSI Standard Z87.1 where no contact with the eye is anticipated. Chemical safety goggles meeting the specification of ANSI Standard Z87.1 should be worn whenever there is the possibility of splashing or other contact with the eyes. Wear gloves and protective clothing which are impervious to the product for the duration of exposure if there is potential for skin contact. Avoid concentrated strong acids, oxidizing agents and bases. Do not expose to open flame. 7 Safety Data Sheet SDS No. Date : Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE 5/28/2015 10.3 Possibility of hazardous reactions Data not available 10.4 Conditions to avoid Avoid heat, flames and other sources of ignition. 10.5 Incompatible materials Data not available 10.6 Hazardous decomposition products Hazardous Decomposition Products : SECTION 11:TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Inhalation : Ingestion: Eye Contact : Skin Contact : Chronic Diethylene Glycol Acute oral LD50's = 12,600 mg/kg (rat) 23,700 mg/kg (mouse) Acute oral LD50's = 4,700 mg/kg (rats) 5,500 mg/kg (mouse) No chronic or delayed effects have been identified IARC: No component of this product is present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. NTP: No component of this product is present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. If pyrolyzed, thermal decomposition products of residue may include C, CO, CO2, H2O, NH3, organic vapors and nitrogen-containing. The acute dermal LD50 of the major component (ethylene glycol) of this product is 10,600mg/kg(rabbits). Based on the pH and the irritation potential of this mixture?s constituents, the mist or liquid can be expected to cause mild to moderate irritation of the skin. Based on the pH and irritation potential of this mixture?s constituents, the mist or liquid can be expected to cause mild to moderate irritation or inflammation of the eyes Breathing excessive levels of the vapor or mist can irritate the respiratory tract. Excessive vapor concentrations of the major component (ethylene glycol), as might be generated during heating of this material, have occasionally been reported to cause adverse effects on the blood-forming system and the nervous system. The acute oral toxicities of the main components of this mixture are as follows : Ethylene Glycol : The lowest dose reported to produce death in humans was estimated to be 1,560 mg/kg body weight; for a person weighing 150 pounds, this would be equivalent to drinking about three fluid ounces of pure ethylene glycol in a short period of time. 8 Safety Data Sheet SDS No. Date : Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE 5/28/2015 SECTION 12: ECOROGICAL INFORMATION 12.1 Toxicity Ecological information of the product : Data not available Diethylene Glycol : LC50 - Pimephales promelas (fathead minnow) - 75,200 mg/l - 96 h 12.2 Persistence and degradability Degradation half life Readily biodegradable 12.3 Bioaccumulative potential Bioaccumulative potential Bioconcentration potential is low. Comments to bioaccumulation Log Pow: -0,30 12.4 Mobility in soil Mobility The product is miscible with water. May spread in water systems. 12.5 Results of PBT and vPvB assessment PBT assessment results This substance is not classified as PBT or vPvB. 12.6 Other adverse effects Other adverse effects / Remarks None known. Waste Disposal : SECTION 14 : TRANSPORT INFORMATION 14.1 UN number UN3082 14.2 UN proper shipping name Environmentally Hazardous Substance Liquid n.o.s. (ethylene glycol), 9, UN3082, III 14.3 Transport hazard class(es) DOT Classification (Bulk) : Class 9 miscellaneous DOT Classification (Non-bulk) : Not regulated IATA (Non-bulk) : Not regulated IMDG Code (Non-bulk) : Not regulated 14.4 Packaging group III Ethylene Glycol : LC50 - Oncorhynchus mykiss (rainbow trout) - 18,500 mg/l - 96 h Disposal should be made in accordance with applicable federal, state and local regulations. All recovered material should be packaged, labeled, transported, and disposed of or reclaimed in conformance with good engineering practices. Avoid land filling of liquids. Reclaim where possible. Ecological information of the main ingredient of the product SECTION 13: DISPOSAL CONSIDERATIONS OSHA: No component of this product is present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. 9 Safety Data Sheet SDS No. Date : Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE Beck/Arnley Premium Antifreeze / Coolant RED CONCENTRATE 5/28/2015 14.5 Environmental hazards Marine pollutant: No Poison Inhalation Hazard: No 14.6 Special precautions for user Data not available 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Data not available SECTION 15 : REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Toxic Substance Control Act : SARA Hazard Categories (as defined in Section 311/312) Health Immediate (Acute) and Delayed (Chronic) Physical None California Proposition 65 SECTION 16 : OTHER INFORMATION NFPA Rating : Health (1) Fire (1) Reactivity (0) Preparation information: Issue date The product contains greater than 85% ethylene glycol (CAS# 107-21-1) which is subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372. This product is a mixture : therefore, it is not listed in the TSCA Inventory of Chemical Substances. All of the components of the mixture are listed in the TSCA Inventory of Chemical Substances. This product does not contain any substances currently listed under California Proposition 65. The information presented herein is believed to be factual as it has been derived from the works and opinions of people believed to be qualified experts; however, nothing contained in this information is to be taken as a warranty or representation for which bears legal responsibility. The user should review any recommendation in the specific context of intended use to determine whether they are appropriate. 5/28/2015 Beck Arnley