SAFETY DATA SHEET 300000005228 Page: 1 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name: ACDelco Structural Urethane Installation Adhesive Medium Set Pt B Product Use/Class: Urethane Adhesive, Part 2 of 2 Distributor: ACDelco 6200 Grand Pointe Drive Grand Blanc, MI 48439 Telephone: 1-800-223-3536 Chemtrec 24 Hr Transportation Emergency No. 800 424-9300 (Outside Continental U.S. 703 527-3887) EFFECTIVE DATE: 03/12/2015 2. HAZARDS IDENTIFICATION GHS CLASSIFICATION: Acute toxicity Inhalation - Dust and MistCategory 4 . Exposure is not expected during application of this product; possible exposure exists if the dried/cured product is sanded. Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Skin sensitization Category 1 Respiratory sensitization Category 1 Reproductive toxicity Category 2 Specific target organ systemic toxicity (single exposure) Category 2 Nervous system, Respiratory system Specific target organ systemic toxicity (repeated exposure) Category 1 Lungs, Nervous system, Respiratory system Hazardous to the aquatic environment - acute hazard Category 3 Hazardous to the aquatic environment - chronic hazard Category 3 GHS LABEL ELEMENTS: Symbol(s) Signal Word DANGER Hazard Statements Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of damaging fertility or the unborn child. May cause damage to organs.(Nervous system, Respiratory system) Causes damage to organs through prolonged or repeated exposure.(Lungs, Nervous system, Respiratory system) Harmful to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary Statements Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/eye protection/face protection. Use personal protective equipment as required. 10-1012, 12378568 - ACDelco Structural Urethane Installation Adhesive Medium Set - Pt B Product: ACDelco Structural Urethane Installation Adhesive Medium Set Pt B, Effective Date: 03/12/2015 Page: 2 In case of inadequate ventilation wear respiratory protection. Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Response Call a POISON CENTER or doctor/physician if you feel unwell. Call a POISON CENTER or doctor/physician if exposed or you feel unwell. Specific treatment (see supplemental first aid instructions on this label). IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Storage Store locked up. Disposal: Dispose of contents/container in accordance with waste/disposal laws and regulations of your country or particular locality. Other Hazards: This product contains component(s) which have the following warnings; however based on the GHS classification criteria of your country or locale, the product mixture may be outside the respective category(s). Acute: May cause skin and eye burns. Harmful if swallowed. Ingestion is not an expected route of entry in industrial or commercial uses. Chronic: Prolonged or repeated contact may result in dermatitis. 3. COMPOSITION/INFORMATION ON INGREDIENTS ? Chemical Name CAS Number Weight % Less Than Piperazine 110-85-0 5.0 % 4. FIRST AID MEASURES FIRST AID - EYE CONTACT: Flush eyes immediately with large amount of water for at least 15 minutes holding eyelids open while flushing. Get prompt medical attention. FIRST AID - SKIN CONTACT: Flush contaminated skin with large amounts of water while removing contaminated clothing. Wash affected skin areas with soap and water. Get medical attention if symptoms occur. FIRST AID - INHALATION: Move person to fresh air. Restore and support continued breathing. If breathing is difficult, give oxygen. Get immediate medical attention. FIRST AID - INGESTION: If swallowed, do not induce vomiting. Call a physician or poison control center immediately for further instructions. Never give anything by mouth if victim is rapidly losing consciousness, unconscious or convulsing. 5. FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water Fog Product: ACDelco Structural Urethane Installation Adhesive Medium Set Pt B, Effective Date: 03/12/2015 Page: 3 SPECIFIC HAZARDS POSSIBLY ARISING FROM THE CHEMICAL: Keep containers tightly closed. Closed containers may rupture when exposed to extreme heat. Use water spray to keep fire exposed containers cool. During a fire, irritating and/or toxic gases and particulate may be generated by thermal decomposition or combustion. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS: Wear full firefighting protective clothing, including self-contained breathing apparatus (SCBA). If water is used, fog nozzles are preferable. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES: Avoid contact. Avoid breathing vapors. Use self-contained breathing equipment. ENVIRONMENTAL PRECAUTIONS: Do not contaminate bodies of water, waterways, or ditches, with chemical or used container. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANUP: Keep non-essential personnel a safe distance away from the spill area. Notify appropriate authorities if necessary. Avoid contact. Before attempting cleanup, refer to hazard caution information in other sections of the SDS form. Scoop spilled material into an appropriate container for proper disposal. (If necessary, use inert absorbent material to aid in containing the spill). 7. HANDLING AND STORAGE HANDLING: Keep closure tight and container upright to prevent leakage.Avoid skin and eye contact.Wash thoroughly after handling.Avoid breathing of vapor or spray mists.Do not handle until all safety precautions have been read and understood.Empty containers should not be re-used.Use with adequate ventilation. STORAGE: Store only in well-ventilated areas.Keep container closed when not in use. INCOMPATIBILITY: Strong acids, bases, and strong oxidizers. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION COMPONENT EXPOSURE LIMIT Chemical Name ACGIH TLV- TWA ACGIH TLV- STEL OSHA PEL- TWA OSHA PEL- CEILING Skin Piperazine N.E. N.E. N.E. N.E. N.A. N.A. - Not Applicable, N.E. - Not Established, S - Skin Designation Engineering controls: Sufficient ventilation in pattern and volume should be provided in order to maintain air contaminant levels below recommended exposure limits. PERSONAL PROTECTION MEASURES/EQUIPMENT: RESPIRATORY PROTECTION: Use a NIOSH approved air-purifying organic vapor respirator if occupational limits are exceeded. For emergency situations, confined space use, or other conditions where exposure limits may be greatly exceeded, use an approved air-supplied respirator. Observe OSHA regulations (29CFR 1910.134) for respirator use. SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin contact. EYE PROTECTION: Use safety eyewear including safety glasses with side shields and chemical goggles where splashing may occur. OTHER PROTECTIVE EQUIPMENT: Remove and wash contaminated clothing before reuse. HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet facility. Food or beverages should not be consumed anywhere this product is handled or stored. Wash thoroughly after handling. Product: ACDelco Structural Urethane Installation Adhesive Medium Set Pt B, Effective Date: 03/12/2015 Page: 4 9. PHYSICAL AND CHEMICAL PROPERTIES Typical values, not to be used for specification purposes. ODOR: No VAPOR PRESSURE: N.D. APPEARANCE: Off-white VAPOR DENSITY: Heavier than Air PHYSICAL STATE: Liquid LOWER EXPLOSIVE LIMIT: Not Applicable FLASH POINT: ? 201 ?F, 93 ?C Setaflash Closed Cup UPPER EXPLOSIVE LIMIT: Not Applicable BOILING RANGE: N.A. EVAPORATION RATE: Not Applicable AUTOIGNITION TEMPERATURE: N.D. DENSITY: 1.26 g/cm3 - 10.45 lb/gal DECOMPOSITION TEMPERATURE: N.D. VISCOSITY, DYNAMIC: ?7,000 mPa.s @ 25 ?C ODOR THRESHOLD: N.D. VISCOSITY, KINEMATIC: ?5,556 mm2/s @ 25 ?C SOLUBILITY IN H2O: Insoluble VOLATILE BY WEIGHT: 0.00 % pH: N.A. VOLATILE BY VOLUME: 0.00 % FREEZE POINT: N.D. VOC CALCULATED: 0 lb/gal, 0 g/l COEFFICIENT OF WATER/OIL DISTRIBUTION: N.D. LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined 10. STABILITY AND REACTIVITY HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur under normal conditions. STABILITY: Product is stable under normal storage conditions. CONDITIONS TO AVOID: High temperatures. INCOMPATIBILITY: Strong acids, bases, and strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, organic or inorganic nitrogen compounds including traces of hydrogen cyanide 11. TOXICOLOGICAL INFORMATION EXPOSURE PATH: Refer to section 2 of this SDS. SYMPTOMS: Refer to section 2 of this SDS. TOXICITY MEASURES: Chemical Name LD50/LC50 Piperazine Oral LD50: Rat 600 mg/kg Dermal LD50: Rabbit 1,590 mg/kg Germ cell mutagenicity: No classification proposed Carcinogenicity: No classification proposed Reproductive toxicity: Category 2 - Suspected of damaging fertility or the unborn child. Components contributing to classification: Piperazine. Tin catalyst. 12. ECOLOGICAL INFORMATION ECOTOXICITY: Chemical Name Ecotoxicity Piperazine Fish: Lepomis macrochirus > 10,000 mg/l96 h Static Product: ACDelco Structural Urethane Installation Adhesive Medium Set Pt B, Effective Date: 03/12/2015 Page: 5 PERSISTENCE AND DEGRADABILITY: Not determined for this product. BIOACCUMULATIVE: Not determined for this product. MOBILITY IN SOIL: Not determined for this product. OTHER ADVERSE EFFECTS: Not determined for this product. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Dispose of contents/container in accordance with waste/disposal laws and regulations of your country or particular locality. Disposal should be done in accordance with Federal (40CFR Part 261), state and local environmental control regulations. If waste is determined to be hazardous, use licensed hazardous waste transporter and disposal facility. 14. TRANSPORT INFORMATION This product is NOT REGULATED for non-bulk US DOT Road, IATA Cargo or IMDG shipments. For the most accurate shipping information, refer to your transportation/compliance department regarding changes in package size, mode of shipment or other regulatory descriptors. 15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: AS FOLLOWS: SARA SECTION 313 This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372.: NONE TOXIC SUBSTANCES CONTROL ACT: INVENTORY STATUS The chemical substances in this product are on the TSCA Section 8 Inventory. EXPORT NOTIFICATION This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: NONE 16. OTHER INFORMATION Under HazCom 2012 it is optional to continue using the HMIS rating system. It is important to ensure employees have been trained to recognize the different numeric ratings associated with the HazCom 2012 and HMIS schemes. HMIS RATINGS - HEALTH: 1* FLAMMABILITY: 1 PHYSICAL HAZARD: 0 * - Indicates a chronic hazard; see Section 2 Revision: New GHS SDS Format Effective Date: 03/12/2015 DISCLAIMER The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by Product: ACDelco Structural Urethane Installation Adhesive Medium Set Pt B, Effective Date: 03/12/2015 Page: 6 use of this material. It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations.