Safety Data Sheet Kem Krest AC Delco Adhesion Promotor Section 1. Identification Product Identifier Kem Krest AC Delco Adhesion Promotor Synonyms 12378462 Manufacture Stock Numbers 12378462 Recommended use Refer to Technical Data Uses advised against Refer to Technical Data Manufacturer Contact Address Dynatex Inc. 350 Ring Road Elizabethtown, KY, 42701 USA Phone Emergency Phone Fax (270) 769-3385 (800) 424- 9300 Chemtrec N/A Section 2. Hazards Identification Classification ASPIRATION HAZARD - Category 1 CARCINOGENICITY - Category 2 EYE DAMAGE/IRRITATION - Category 2B FLAMMABLE LIQUIDS - Category 2 SENSITIZATION - SKIN - Category 1 SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure) - Category 1 SPECIFIC TARGET ORGAN TOXICITY (Single Exposure) - Category 1 TOXIC TO REPRODUCTION - Category 1A Signal Word Danger Pictogram Hazard Statements Causes damage to nervous system and/or sensory organs through prolonged or repeated exposure. Causes damage to sensory organs. Causes eye irritation Page 1 of 10 10-1018, 12378462 - ACDelco Adhesion Promotor Highly flammable liquid and vapor May be fatal if swallowed and enters airways May cause an allergic skin reaction May damage fertility or the unborn child. Suspected of causing cancer. Precautionary Statements Response Do NOT induce vomiting. Get medical advice/attention if you feel unwell. If exposed or concerned: Get medical advice/attention. If exposed: Call a poison center or doctor. If eye irritation persists: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical advice/attention. If swallowed: Immediately call a poison center or doctor. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Wash contaminated clothing before reuse. Prevention Avoid breathing dust/fume/gas/mist/ vapors/spray. Contaminated work clothing must not be allowed out of the workplace. Do not breathe dust/fume/gas/mist/ vapors/spray. Do not eat, drink or smoke when using this product. Do not handle until all safety precautions have been read and understood. Ground/bond container and receiving equipment. Keep away from heat. Keep container tightly closed. Obtain special instructions before use. Take precautionary measures against static discharge. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Wash thoroughly after handling. Wear protective gloves. Wear protective gloves/eye protection/face protection Wear protective gloves/protective clothing/eye protection/face protection. Storage Store in a well-ventilated place. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Ingredients of unknown toxicity 8% Hazards not Otherwise Classified None known Page 2 of 10 Occupational exposure limits, if available, are listed in Section 8. Section 3. Ingredients CAS Ingredient Name Weight % 108-88-3 Toluene 0.3% - Max 67-56-1 Methyl alcohol 0.4% - Max 25068-38-6 Bisphenol A / Epichlorohydrin Resin 0.5% - Max 68609-36-9 Chlorinated Rubber 1% - 5% Trade Secret Acrylate Polymer (NJTSRN 04499600-5984P) 1% - 5% 100-41-4 Ethyl benzene 11% - Max 1330-20-7 Xylene 30% - 35% 141-78-6 Ethyl acetate 4% - Max 110-82-7 Cyclohexane 45% - 50% 64-17-5 Ethanol 5% - 10% Section 4. First-aid Measures Eye Contact Immediately flush with large amounts of water. If irritation occurs, seek medical attention. Skin Contact Remove contaminated clothing and shoes. Immediately flush skin with large amount of water. Get medical attention. Launder contaminated clothing and clean shoes before reuse. Inhalation Remove to fresh air. If symptoms persist, obtain appropriate medical attention. Ingestion Do not induce vomiting. Immediately drink two glasses of water. Never give anything to an unconscious person. Get medical attention. Page 3 of 10 Section 5. Fire Fighting Measures Suitable Extinguishing Media N/A Unsuitable Extinguishing Media N/A OSHA Flammability Classification Class IB Flammable Liquid Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Special Fire Fighting Procedures Water may not effectively extinguish fire; however, it should be used to keep fire- exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards Flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Page 4 of 10 Section 6. Accidental Release Measures Personal precautions. protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Environmental precautions Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up Methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Seal the container. Note In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state and federal regulations. Section 7. Handling and Storage Handling Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Avoid breathing of vapors, mists or spray. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. For industrial or professional use only. Avoid contact with oxidizing agents. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Storage Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Store away from areas where product may come into contact with food or pharmaceuticals. Store away from oxidizing agents. Page 5 of 10 Section 8. Exposure Controls/Personal Protecction Occupational Exposure Limits Ingredient Name ACGIH TLV OSHA PEL STEL Toluene 100 ppm 100 ppm 150 ppm Methyl alcohol N/A N/A N/A Bisphenol A / Epichlorohydrin Resin 100 ppm 100 ppm 125 ppm Chlorinated Rubber 1000 ppm 1000 ppm 150 ppm Acrylate Polymer (NJTSRN 04499600-5984P) N/A N/A N/A Ethyl benzene 400 ppm 400 ppm N/A Xylene N/A N/A N/A Ethyl acetate 200 ppm 200 ppm 250 ppm Cyclohexane 50 ppm skin 100 ppm skin 150 ppm skin Ethanol N/A N/A N/A Personal Protective Equipment N/A Engineering Controls Use in a well-ventilated area. Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Fluoroelastomer Polymer laminate Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoid breathing of vapors, mists or spray. Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Do not ingest. Exposure Guidelines CYCLOHEXANE ACGIH TWA 100 ppm CYCLOHEXANE OSHA TWA 1050 mg/m3 ETHYL ACETATE ACGIH TWA 400 ppm ETHYL ACETATE OSHA TWA 1400 mg/m3 ETHYL ALCOHOL ACGIH STEL 1000 ppm ETHYL ALCOHOL OSHA TWA 1900 mg/m3 ETHYLBENZENE ACGIH TWA 20 ppm ETHYLBENZENE CMRG TWA 25 ppm ETHYLBENZENE CMRG STEL 75 ppm ETHYLBENZENE OSHA TWA 435 mg/m3 METHYL ALCOHOL ACGIH TWA 200 ppm Skin Notation* METHYL ALCOHOL ACGIH STEL 250 ppm Skin Notation* METHYL ALCOHOL OSHA TWA 260 mg/m3 TOLUENE ACGIH TWA 20 ppm TOLUENE CMRG STEL 75 ppm Skin Notation* TOLUENE OSHA TWA 200 ppm TOLUENE OSHA CEIL 300 ppm XYLENE ACGIH TWA 100 ppm XYLENE ACGIH STEL 150 ppm XYLENE CMRG TWA 50 ppm XYLENE CMRG STEL 75 ppm XYLENE OSHA TWA 435 mg/m3 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Page 6 of 10 NoteThe above information is not intended for use in preparing product specifications. Contact Accumetric LLC before writing specifications. Association Workplace Environmental Exposure Level (WEEL) Section 9. Physical and Chemical Properties Physical State Liquid Color Yellow Odor Solvent odor Odor Threshold N/A Solubility 10% in water Partition coefficient Water/n- octanol N/A Viscosity 30-40 centipoise Specific Gravity 0.82 Density lbs/Gal 6.8 Pounds per Cubic Foot N/A Flash Point 34F FP Method Seta Flash Ph Not applicable Melting Point N/A Boiling Point >= 170F Boiling Range N/A LEL 1 UEL 6 Evaporation Rate N/A Flammability N/A Decomposition Temperature N/A Auto-ignition Temperature 430C Vapor Pressure 122mm Hg @ 20C Vapor Density 1.7 estimated (Air=1) Section 10. Stability and Reactivity Chemical Stability Stable Conditions to Avoid Heat Sparks and/or flames Materials to Avoid Strong acids Strong oxidizing agents Hazardous Polymerization Will not occur Hazardous Decomposition or By- Products Substance Condition Aldehydes During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Chloride During Combustion Page 7 of 10 Section 11. Toxicological Information Target Organ Effects Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination. Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity NOTE: This product contains ethanol. Alcoholic beverages and ethanol in alcoholic beverages have been classified as human carcinogens by the International Agency for Research on Cancer, the U.S. National Toxicology Program, and the California Environmental Protection Agency (for purposes of Proposition 65). Exposure to ethanol during the foreseeable use of this product is not expected to cause cancer. Contains a chemical or chemicals which can cause cancer. Ingredient: ETHYLBENZENE CAS Number: 100-41-4 Class Description: Grp. 2B: Possible human carc. Regulation: International Agency for Research on Cancer Section 12. Ecological Information Ecotoxicological Information Not determined Chemical Fate Information Not determined Section 13. Disposal Waste Diposal Method Incinerate in a permitted hazardous waste incinerator. Combustion products will include HCl. Facility must be capable of handling halogenated materials. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA) D001 (Ignitable) Page 8 of 10 Section 14. Transport Information UN Number N/A UN Proper Shipping Name N/A DOT Classification N/A Packing Group N/A Not regulated per U.S. DOT, IATA or IMO. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. Transportation classifications are based on product formulation, packaging, and our understanding of applicable current regulations. We does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. Page 9 of 10 Section 15. Regulatory Information The contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. 311/312 Hazard Categories Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals and 40 CFR part 372 (EPCRA) Ingredient C.A.S. No % by Wt CYCLOHEXANE 110-82-7 45 - 50 XYLENE 1330-20-7 30 - 35 ETHYLBENZENE 100-41-4 < 11 California Proposition 65 ETHYLBENZENE (100-41-4) **Carcinogen METHYL ALCOHOL (67- 56-1) *Developmental Toxin TOLUENE (108-88-3) *Developmental Toxin TOLUENE (108-88-3) *Female reproductive toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. ** WARNING: contains a chemical which can cause cancer. Chemcial Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Section 16. Other Information Revision Date 2/11/2015 Disclaimer The data contained herein is based upon information that Accumetric LLC believes to be reliable. Users of this product have the responsibility to determine that suitability of use and to adopt all necessary precautions to ensure the safety and protection of property and persons involved in said use. All statements or suggestions are made without warranty, expressed or implied, regarding the accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Page 10 of 10