JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 10/31/2014 : Version: 25/03/2015 EN (English US) 1/10 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. Product code : 2232 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Brake Fluid 1.3. Details of the supplier of the safety data sheet Technical Chemical Company P.O. BOX 139 Cleburne, Texas 76033 T 817-645-6088 1.4. Emergency telephone number Emergency number : CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Acute Tox. 4 (Oral) H302 Skin Irrit. 2 H315 Eye Dam. 1 H318 Repr. 2 H361 STOT RE 2 H373 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS05 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H302 - Harmful if swallowed H315 - Causes skin irritation H318 - Causes serious eye damage H361 - Suspected of damaging fertility or the unborn child H373 - May cause damage to organs through prolonged or repeated exposure Precautionary statements (GHS-US) : P201 - Obtain special instructions P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe dust,fumes,gas,mist,vapor spray P264 - Wash affected areas thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear protective gloves,protective clothing,eye protection,face protection P301+P312 - If swallowed: Call a poison center, doctor if you feel unwell P302+P352 - If on skin: Wash with plenty of soap and water P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - If exposed or concerned: Get medical advice/attention P310 - Immediately call a poison center,doctor, physician P314 - Get medical advice/attention if you feel unwell P321 - Specific treatment: See section 4.1 on SDS P330 - Rinse mouth P332+P313 - If skin irritation occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P405 - Store locked up P501 - Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. 2.3. Other hazards Other hazards not contributing to the : None under normal conditions. JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 25/03/2015 EN (English US) 2/10 classification 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Triethylene Glycol Monomethyl Ether (CAS No) 112-35-6 5 - 50 Not classified Triethyleneglycol Monoethyl Ether (CAS No) 112-50-5 5 - 50 Not classified Triethylene Glycol Monobutyl Ether (CAS No) 143-22-6 5 - 50 Eye Dam. 1, H318 3,6,9,12-Tetraoxahexadecane-1-ol (CAS No) 1559-34-8 5 - 20 Not classified Polyethylene Glycol 200-600 (CAS No) 25322-68-3 5 - 20 Not classified 2-(2-Butoxyethoxy) Ethanol (CAS No) 112-34-5 5 - 20 Eye Irrit. 2A, H319 Tetraethylene Glycol Monomethyl Ether (CAS No) 23783-42-8 5 - 20 Not classified Oxirane, 2-Methyl-, Polymer with Oxirane, Monobutyl Ether (CAS No) 9038-95-3 5 - 20 Not classified Polyalkylene Glycol Monobutyl Ether (CAS No) 9004-77-7 5 - 20 Not classified Diethylene Glycol (CAS No) 111-46-6 5 - 15 Acute Tox. 4 (Oral), H302 STOT RE 2, H373 Diethylene Glycol Monomethyl Ether (CAS No) 111-77-3 < 5 Flam. Liq. 4, H227 Repr. 2, H361 Diethyleneglycolmonoethyl Ether (CAS No) 111-90-0 < 5 Eye Irrit. 2A, H319 The exact percentage is a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a POISON CENTER or doctor/physician if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Suspected of damaging fertility or the unborn child. Causes damage to organs. Symptoms/injuries after inhalation : May cause irritation or asthma-like symptoms. Symptoms/injuries after skin contact : Itching. Skin rash/inflammation. Red skin. Causes skin irritation. Symptoms/injuries after eye contact : Inflammation/damage of the eye tissue. Irritation of the eye tissue. Redness of the eye tissue. Causes serious eye damage. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways. Swallowing a small quantity of this material will result in serious health hazard. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 25/03/2015 EN (English US) 3/10 6.1.1. For non-emergency personnel Protective equipment : Gloves. Safety glasses. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Obtain special instructions . Do not handle until all safety precautions have been read and understood. Avoid breathing dust,fume,gas,mist,vapor spray. Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Wash affected areas thoroughly after handling. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Comply with applicable regulations. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 2-(2-Butoxyethoxy) Ethanol (112-34-5) USA ACGIH ACGIH TWA (ppm) 10 ppm USA ACGIH ACGIH STEL (ppm) 10 ppm 8.2. Exposure controls Appropriate engineering controls : Local exhaust venilation, vent hoods . Ensure good ventilation of the work station. Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Color : Colourless to light yellow. JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 25/03/2015 EN (English US) 4/10 Odor : Mild. Odor threshold : No data available pH : 7.5 - 11.5 Relative evaporation rate (butyl acetate=1) : < 0.01 Melting point : No data available Freezing point : No data available Boiling point : 232 - 273 ?C Flash point : > 135 ?C Auto-ignition temperature : 310 ?C Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : < 0.01 mm Hg Relative vapor density at 20 ?C : > 1 (air=1) Relative density : 1.025 - 1.075 Solubility : Soluble in water. Log Pow : No data available Log Kow : No data available Viscosity, kinematic : 2 mm?/s @ 100 deg C Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information VOC content : 0 % SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid None. Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Toxic fume. . Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Harmful if swallowed. JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. LD50 oral rat > 2000 mg/kg Triethylene Glycol Monomethyl Ether (112-35-6) LD50 oral rat 11865 mg/kg (Rat) LD50 dermal rabbit 7455 mg/kg (Rabbit) Triethyleneglycol Monoethyl Ether (112-50-5) LD50 oral rat 7750 mg/kg (Rat) LD50 dermal rabbit 8168 mg/kg (Rabbit) Triethylene Glycol Monobutyl Ether (143-22-6) LD50 oral rat > 5000 mg/kg (Rat) LD50 dermal rabbit 3480 mg/kg (Rabbit) JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 25/03/2015 EN (English US) 5/10 3,6,9,12-Tetraoxahexadecane-1-ol (1559-34-8) LD50 oral rat > 5000 mg/kg (Rat) LD50 dermal rat > 4000 mg/kg (Rat) Polyethylene Glycol 200-600 (25322-68-3) LD50 oral rat > 15000 mg/kg (Rat) LD50 dermal rabbit > 20000 mg/kg (Rabbit) 2-(2-Butoxyethoxy) Ethanol (112-34-5) LD50 oral rat 5660 mg/kg (Rat) LD50 dermal rabbit 2764 mg/kg (Rabbit; Experimental value; OECD 402: Acute Dermal Toxicity) Diethylene Glycol (111-46-6) LD50 dermal rabbit 11890 mg/kg (Rabbit) Diethylene Glycol Monomethyl Ether (111-77-3) LD50 oral rat 4140 mg/kg (Rat) LD50 dermal rabbit > 2000 mg/kg (Rabbit) LC50 inhalation rat (mg/l) > 20 mg/l/4h (Rat) Diethyleneglycolmonoethyl Ether (111-90-0) LD50 oral rat 5445 mg/kg (Rat) LD50 dermal rat 5940 mg/kg (Rat) LD50 dermal rabbit > 5000 mg/kg (Rabbit) LC50 inhalation rat (mg/l) > 5.2 mg/l/4h (Rat) Tetraethylene Glycol Monomethyl Ether (23783-42-8) LD50 oral rat > 15000 mg/kg (Rat) Oxirane, 2-Methyl-, Polymer with Oxirane, Monobutyl Ether (9038-95-3) LD50 oral rat > 2000 mg/kg body weight (Rat) LD50 dermal rabbit > 2000 mg/kg body weight (Rabbit) Skin corrosion/irritation : Causes skin irritation. pH: 7.5 - 11.5 Serious eye damage/irritation : Causes serious eye damage. pH: 7.5 - 11.5 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Polyalkylene Glycol Monobutyl Ether (9004-77-7) IARC group 4 Reproductive toxicity : Suspected of damaging fertility or the unborn child. Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : May cause damage to organs through prolonged or repeated exposure. Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Harmful if swallowed. Symptoms/injuries after inhalation : May cause irritation or asthma-like symptoms. Symptoms/injuries after skin contact : Itching. Skin rash/inflammation. Red skin. Causes skin irritation. Symptoms/injuries after eye contact : Inflammation/damage of the eye tissue. Irritation of the eye tissue. Redness of the eye tissue. Causes serious eye damage. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways. Swallowing a small quantity of this material will result in serious health hazard. SECTION 12: Ecological information 12.1. Toxicity Triethylene Glycol Monomethyl Ether (112-35-6) LC50 fish 1 > 5000 mg/l (96 h; Brachydanio rerio; Measured concentration) EC50 other aquatic organisms 1 > 5000 mg/l (16 h; Activated sludge; Cell numbers) LC50 fish 2 > 10000 mg/l (96 h; Pimephales promelas) TLM fish 1 > 1000 ppm (96 h; Pisces) JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 25/03/2015 EN (English US) 6/10 Triethylene Glycol Monomethyl Ether (112-35-6) TLM other aquatic organisms 1 > 1000 ppm (96 h) Threshold limit algae 1 > 500 mg/l (72 h; Scenedesmus subspicatus) Triethyleneglycol Monoethyl Ether (112-50-5) LC50 fish 1 > 10000 mg/l (96 h; Pimephales promelas) LC50 fish 2 > 5000 mg/l (24 h; Pisces) Triethylene Glycol Monobutyl Ether (143-22-6) LC50 fish 1 2400 mg/l (96 h; Pimephales promelas) EC50 Daphnia 1 3200 mg/l (24 h; Daphnia magna) LC50 fish 2 2200 mg/l (96 h; Leuciscus idus) EC50 Daphnia 2 > 500 mg/l (48 h; Daphnia magna) Threshold limit algae 1 > 500 mg/l (72 h; Scenedesmus subspicatus) 3,6,9,12-Tetraoxahexadecane-1-ol (1559-34-8) LC50 fish 1 > 1409 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 1 > 1000 mg/l (48 h; Daphnia magna) Polyethylene Glycol 200-600 (25322-68-3) LC50 fish 1 > 1000 mg/l (96 h; Pisces) LC50 other aquatic organisms 1 > 1000 mg/l (96 h) LC50 fish 2 > 5000 mg/l (24 h; Carassius auratus) Threshold limit other aquatic organisms 1 <= 100 mg/l (96 h; Plankton) Threshold limit other aquatic organisms 2 > 1000 mg/l Threshold limit algae 2 500 mg/l (720 h; Algae; No effect) 2-(2-Butoxyethoxy) Ethanol (112-34-5) LC50 fish 1 1300 mg/l (96 h; Lepomis macrochirus) LC50 other aquatic organisms 1 10 - 100 mg/l (96 h) EC50 Daphnia 1 2850 mg/l (24 h; Daphnia magna; GLP) LC50 fish 2 1805 mg/l (48 h; Leuciscus idus) EC50 Daphnia 2 > 100 mg/l (48 h; Daphnia magna) TLM fish 1 10 - 100,96 h; Pisces TLM other aquatic organisms 1 10 - 100,96 h Threshold limit other aquatic organisms 1 10 - 100,96 h Threshold limit algae 1 53 mg/l (192 h; Microcystis aeruginosa) Threshold limit algae 2 >= 100 mg/l (96 h; Scenedesmus subspicatus) Diethylene Glycol (111-46-6) LC50 fish 1 > 5000 ppm (24 h; Carassius auratus) LC50 other aquatic organisms 1 1174 mg/l (Xenopus laevis) EC50 Daphnia 1 > 10000 mg/l (24 h; Daphnia magna) LC50 fish 2 61072 ppm (168 h; Poecilia reticulata) EC50 Daphnia 2 > 10000 mg/l (24 h; Daphnia magna) TLM fish 1 > 32000 mg/l (96 h; Gambusia affinis) TLM other aquatic organisms 1 > 1000 ppm (96 h) Threshold limit other aquatic organisms 1 1174 mg/l (72 h; Xenopus laevis; Toxicity test) Threshold limit other aquatic organisms 2 10745 mg/l (16 h; Protozoa; Toxicity test) Threshold limit algae 1 2700 mg/l (168 h; Scenedesmus quadricauda) Threshold limit algae 2 100 mg/l (Selenastrum capricornutum) Diethylene Glycol Monomethyl Ether (111-77-3) LC50 fish 1 1000 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Static system) EC50 Daphnia 1 > 500 mg/l (48 h; Daphnia magna) LC50 fish 2 7500 ppm (96 h; Lepomis macrochirus) Threshold limit algae 1 > 500 mg/l (72 h; Scenedesmus subspicatus) Diethyleneglycolmonoethyl Ether (111-90-0) LC50 fish 1 12900 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Flow-through system) EC50 Daphnia 1 3940 mg/l (48 h; Daphnia magna) EC50 other aquatic organisms 1 10661 mg/l (Echinoidea; Growth) LC50 fish 2 9650 mg/l (96 h; Pimephales promelas; Flow-through system) JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 25/03/2015 EN (English US) 7/10 Tetraethylene Glycol Monomethyl Ether (23783-42-8) LC50 fish 1 > 10000 mg/l (96 h; Brachydanio rerio) Threshold limit other aquatic organisms 1 > 12500 mg/l (3 h; Activated sludge) Oxirane, 2-Methyl-, Polymer with Oxirane, Monobutyl Ether (9038-95-3) LC50 fish 1 > 10000 mg/l (96 h; Pisces) LC50 other aquatic organisms 1 > 10000 mg/l (96 h) Threshold limit other aquatic organisms 1 > 10000 mg/l (96 h) 12.2. Persistence and degradability JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. Persistence and degradability Not established. Triethylene Glycol Monomethyl Ether (112-35-6) Persistence and degradability Inherently biodegradable. Non degradable in the soil. Photodegradation in the air. Triethyleneglycol Monoethyl Ether (112-50-5) Persistence and degradability Readily biodegradable in water. Triethylene Glycol Monobutyl Ether (143-22-6) Persistence and degradability Readily biodegradable in water. Biochemical oxygen demand (BOD) 0.02 g O? /g substance Chemical oxygen demand (COD) 1.83 g O? /g substance 3,6,9,12-Tetraoxahexadecane-1-ol (1559-34-8) Persistence and degradability Not readily biodegradable in water. Inherently biodegradable. ThOD 2.05 g O? /g substance Polyethylene Glycol 200-600 (25322-68-3) Persistence and degradability Biodegradability in water: no data available. 2-(2-Butoxyethoxy) Ethanol (112-34-5) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. No (test)data on mobility of the substance available. Photodegradation in the air. Biochemical oxygen demand (BOD) 0.25 g O? /g substance Chemical oxygen demand (COD) 2.08 g O? /g substance ThOD 2.173 g O? /g substance BOD (% of ThOD) 0.11 % ThOD Diethylene Glycol (111-46-6) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Photolysis in the air. Biochemical oxygen demand (BOD) 0.02 g O? /g substance Chemical oxygen demand (COD) 1.51 g O? /g substance ThOD 1.51 g O? /g substance BOD (% of ThOD) 0.015 % ThOD Diethylene Glycol Monomethyl Ether (111-77-3) Persistence and degradability Readily biodegradable in water. Photolysis in the air. Photodegradation in the air. Chemical oxygen demand (COD) 1.71 g O? /g substance ThOD 1.73 g O? /g substance Diethyleneglycolmonoethyl Ether (111-90-0) Persistence and degradability Readily biodegradable in water. Biochemical oxygen demand (BOD) 0.20 g O? /g substance Chemical oxygen demand (COD) 1.85 g O? /g substance ThOD 1.9078849 g O? /g substance BOD (% of ThOD) 0.11 % ThOD Tetraethylene Glycol Monomethyl Ether (23783-42-8) Persistence and degradability Inherently biodegradable. Photolysis in the air. Oxirane, 2-Methyl-, Polymer with Oxirane, Monobutyl Ether (9038-95-3) Persistence and degradability Not readily biodegradable in water. Trade Secret Inhibitor Package (TRADE SECRET) Persistence and degradability Not established. Polyalkylene Glycol Monobutyl Ether (9004-77-7) Persistence and degradability Not established. JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 25/03/2015 EN (English US) 8/10 12.3. Bioaccumulative potential JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. Bioaccumulative potential Not established. Triethylene Glycol Monomethyl Ether (112-35-6) Log Pow -1.13 Bioaccumulative potential Bioaccumulation: not applicable. Triethyleneglycol Monoethyl Ether (112-50-5) Bioaccumulative potential Not bioaccumulative. Triethylene Glycol Monobutyl Ether (143-22-6) Log Pow 0.51 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). 3,6,9,12-Tetraoxahexadecane-1-ol (1559-34-8) Log Pow -0.26 (Calculated) Bioaccumulative potential Bioaccumulation: not applicable. Polyethylene Glycol 200-600 (25322-68-3) Log Pow -1.2 Bioaccumulative potential Bioaccumulation: not applicable. 2-(2-Butoxyethoxy) Ethanol (112-34-5) BCF fish 1 0.46 (QSAR) Log Pow 0.56 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Diethylene Glycol (111-46-6) BCF fish 1 100 (3 h; Leuciscus melatonus) Log Pow -1.98 (Calculated; Other) Bioaccumulative potential Bioaccumulation: not applicable. Diethylene Glycol Monomethyl Ether (111-77-3) Log Pow -1.14 - -0.68 Bioaccumulative potential Bioaccumulation: not applicable. Diethyleneglycolmonoethyl Ether (111-90-0) Log Pow -1.19 - -0.08 Bioaccumulative potential Bioaccumulation: not applicable. Tetraethylene Glycol Monomethyl Ether (23783-42-8) Log Pow -0.6 Bioaccumulative potential Bioaccumulation: not applicable. Oxirane, 2-Methyl-, Polymer with Oxirane, Monobutyl Ether (9038-95-3) Bioaccumulative potential Not bioaccumulative. Trade Secret Inhibitor Package (TRADE SECRET) Bioaccumulative potential Not established. Polyalkylene Glycol Monobutyl Ether (9004-77-7) Bioaccumulative potential Not established. 12.4. Mobility in soil Triethylene Glycol Monomethyl Ether (112-35-6) Surface tension 0.0314 N/m 2-(2-Butoxyethoxy) Ethanol (112-34-5) Surface tension 0.034 N/m (25 ?C) Diethylene Glycol (111-46-6) Surface tension 0.0485 N/m Diethylene Glycol Monomethyl Ether (111-77-3) Surface tension 0.035 N/m (25 ?C) Diethyleneglycolmonoethyl Ether (111-90-0) Surface tension 0.032 N/m (25 ?C) JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 25/03/2015 EN (English US) 9/10 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN US DOT (ground): Not Regulated, ICAO/IATA (air): Not Regulated, IMO/IMDG (water): Not Regulated, Not applicable 14.2. UN proper shipping name Proper Shipping Name (DOT) : Not Regulated 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Immediate (acute) health hazard 2-(2-Butoxyethoxy) Ethanol (112-34-5) SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Reactive hazard 15.2. International regulations CANADA 2-(2-Butoxyethoxy) Ethanol (112-34-5) Listed on the Canadian DSL (Domestic Sustances List) WHMIS Classification Class B Division 3 - Combustible Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Repr.Cat.3; R63 Xi; R41 Full text of R-phrases: see section 16 15.2.2. National regulations No additional information available JOHNSEN'S PREMIUM DOT 3 BRAKE FLUID 450 DEG 32 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 25/03/2015 EN (English US) 10/10 15.3. US State regulations No additional information available SECTION 16: Other information Other information : None. Full text of H-phrases: see section 16: ------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 ------ Eye Dam. 1 Serious eye damage/eye irritation Category 1 ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Flam. Liq. 4 Flammable liquids Category 4 ------ Repr. 2 Reproductive toxicity Category 2 ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ STOT RE 2 Specific target organ toxicity (repeated exposure) Category 2 ------ H227 Combustible liquid ------ H302 Harmful if swallowed ------ H315 Causes skin irritation ------ H318 Causes serious eye damage ------ H319 Causes serious eye irritation ------ H361 Suspected of damaging fertility or the unborn child ------ H373 May cause damage to organs through prolonged or repeated exposure NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 1 Slight Hazard Physical : 0 Minimal Hazard Personal Protection : B SDS US (GHS HazCom 2012) - TCC The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.