SDS Repository

sds

Collection
Tech Chem/Johnsens
Description
 
Tags
Search Tag
Filename
2942.pdf
Source
 
Full Text
JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 09/15/2014 : Version: 04/11/2014 EN (English US) 1/9 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. Product code : 2942 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Windshield Washer Concentrate 1.3. Details of the supplier of the safety data sheet Technical Chemical Company P.O. BOX 139 Cleburne, Texas 76033 T 817-645-6088 1.4. Emergency telephone number Emergency number : CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Flam. Liq. 2 H225 Acute Tox. 3 (Oral) H301 Acute Tox. 3 (Dermal) H311 Acute Tox. 3 (Inhalation:dust,mist) H331 STOT SE 1 H370 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS02 GHS06 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapor H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H370 - Causes damage to organs Precautionary statements (GHS-US) : P210 - Keep away from heat,sparks,open flames,hot surfaces. - No smoking P233 - Keep container tightly closed P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical, ventilating, lighting equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P260 - Do not breathe dust,fumes,gas,mist,vapor spray P261 - Avoid breathing dust,fume,gas,mist,vapor spray P264 - Wash affected areas thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves,protective clothing,eye protection,face protection P301+P310 - If swallowed: Immediately call a poison control center, doctor,physician, P302+P352 - If on skin: Wash with plenty of soap and water P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P307+P311 - If exposed: Call a poison center/doctor P311 - Call a poison center,doctor P312 - Call a POISON CONTROL CENTER, doctor, if you feel unwell. P321 - Specific treatment: See section 4.1 on SDS P330 - Rinse mouth P361 - Take off immediately all contaminated clothing P363 - Wash contaminated clothing before reuse P370+P378 - In case of fire: See Section 5.1 Extinguishing Media JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/11/2014 EN (English US) 2/9 P403+P233 - Store in a well-ventilated place. Keep container tightly closed P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. 2.3. Other hazards Other hazards not contributing to the classification : None under normal conditions. 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Methanol (CAS No) 67-56-1 >= 95 Flam. Liq. 2, H225 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation:dust,mist), H331 STOT SE 1, H370 Polyethylene Glycol 200-600 (CAS No) 25322-68-3 <= 0.0045 Not classified Nonyl Nonoxynol-5 (CAS No) 9014-93-1 <= 0.003 Not classified Hydrogen [4-[4-(Diethylamino)-2',4'- Disulphonatobenzhydrylidene] Cyclohexa-2,5-Dien-1-ylidene] Diethylammonium, Sodium Salt (CAS No) 129-17-9 ~ 0.000001 Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : IF exposed or concerned: Get medical advice/attention. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Call a POISON CENTER or doctor/physician. First-aid measures after inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Immediately call a POISON CENTER or doctor/physician. Wash with plenty of soap and water. Wash contaminated clothing before reuse. First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. Immediately call a POISON CENTER or doctor/physician. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : May damage fertility or the unborn child. Causes damage to organs. Symptoms/injuries after inhalation : Toxic if inhaled. Danger of serious damage to health by prolonged exposure through inhalation. Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Symptoms/injuries after eye contact : Causes serious eye damage. Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion : Fatal if swallowed. Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Highly flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/11/2014 EN (English US) 3/9 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Safety glasses. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Avoid breathing dust,fume,gas,mist,vapor spray. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : Do not handle until all safety precautions have been read and understood. Obtain special instructions . Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No naked lights. No smoking. Use only non-sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing dust,fume,gas,mist,vapor spray. Do not breathe dust,fumes,gas,mist,vapor spray. Hygiene measures : Do not eat, drink or smoke when using this product. Wash affected areas thoroughly after handling. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating, lighting equipment. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep in fireproof place. Keep container tightly closed. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Methanol (67-56-1) USA ACGIH ACGIH TWA (mg/m?) 262 mg/m? USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (mg/m?) 328 mg/m? USA ACGIH ACGIH STEL (ppm) 250 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 260 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 200 ppm JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/11/2014 EN (English US) 4/9 8.2. Exposure controls Appropriate engineering controls : Local exhaust venilation, vent hoods. Personal protective equipment : Safety glasses. Gloves. Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. Consumer exposure controls : Avoid contact during pregnancy/while nursing. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Blue. Odor : Mild . Odourless. Odor threshold : 4.2 - 5960 ppm pH : ? 7 Relative evaporation rate (butyl acetate=1) : 4.1 Melting point : No data available Freezing point : -97.8 Boiling point : 64.7 ?C Flash point : 11 ?C Critical temperature : 239.4 ?C Auto-ignition temperature : 464 ?C Decomposition temperature : Not Determined Flammability (solid, gas) : No data available Vapor pressure : 12.8 kPa @ 20 deg C Critical pressure : 77.77 bar Relative vapor density at 20 ?C : No data available Relative density : 0.792 Solubility : Soluble in alcohols. Soluble in water. Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : 36.5 vol % Upper Explosive Limit (UEL) 9.2. Other information VOC content : > 98 % SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Highly flammable liquid and vapor. May form flammable/explosive vapor-air mixture. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Open flame. JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/11/2014 EN (English US) 5/9 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Toxic fume. . Carbon monoxide. Carbon dioxide. May release flammable gases. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Polyethylene Glycol 200-600 (25322-68-3) LD50 oral rat > 15000 mg/kg (Rat) LD50 dermal rabbit > 20000 mg/kg (Rabbit) Hydrogen [4-[4-(Diethylamino)-2',4'-Disulphonatobenzhydrylidene] Cyclohexa-2,5-Dien-1-ylidene] Diethylammonium, Sodium Salt (129- 17-9) LD50 oral rat 3001 mg/kg (Rat) Methanol (67-56-1) LD50 oral rat >= 2528 mg/kg body weight application as 50% aqueous solution LD50 dermal rabbit 17100 mg/kg corresponding to 20 ml/kg bw according to the authors LC50 inhalation rat (mg/l) 128.2 mg/l/4h Air Skin corrosion/irritation : Not classified pH: ? 7 Serious eye damage/irritation : Not classified pH: ? 7 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Based on available data, the classification criteria are not met Carcinogenicity : Not classified Hydrogen [4-[4-(Diethylamino)-2',4'-Disulphonatobenzhydrylidene] Cyclohexa-2,5-Dien-1-ylidene] Diethylammonium, Sodium Salt (129- 17-9) IARC group 3 Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Causes damage to organs. Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Fatal if swallowed. Based on available data, the classification criteria are not met. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Symptoms/injuries after inhalation : Toxic if inhaled. Danger of serious damage to health by prolonged exposure through inhalation. Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Symptoms/injuries after eye contact : Causes serious eye damage. Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion : Fatal if swallowed. Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. SECTION 12: Ecological information 12.1. Toxicity Polyethylene Glycol 200-600 (25322-68-3) LC50 fish 1 > 1000 mg/l (96 h; Pisces) LC50 other aquatic organisms 1 > 1000 mg/l (96 h) LC50 fish 2 > 5000 mg/l (24 h; Carassius auratus) Threshold limit other aquatic organisms 1 <= 100 mg/l (96 h; Plankton) Threshold limit other aquatic organisms 2 > 1000 mg/l Threshold limit algae 2 500 mg/l (720 h; Algae; No effect) Methanol (67-56-1) LC50 fish 1 15400 mg/l (96 h; Lepomis macrochirus; Lethal) EC50 Daphnia 1 > 10000 mg/l (48 h; Daphnia magna; Lethal) LC50 fish 2 10800 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/11/2014 EN (English US) 6/9 Methanol (67-56-1) EC50 Daphnia 2 24500 mg/l (48 h; Daphnia magna) Threshold limit other aquatic organisms 1 6600 mg/l (16 h; Pseudomonas putida) Threshold limit algae 1 530 mg/l (192 h; Microcystis aeruginosa) Threshold limit algae 2 8000 mg/l (168 h; Scenedesmus quadricauda) 12.2. Persistence and degradability JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. Persistence and degradability Not established. Polyethylene Glycol 200-600 (25322-68-3) Persistence and degradability Biodegradability in water: no data available. Nonyl Nonoxynol-5 (9014-93-1) Persistence and degradability Not established. Hydrogen [4-[4-(Diethylamino)-2',4'-Disulphonatobenzhydrylidene] Cyclohexa-2,5-Dien-1-ylidene] Diethylammonium, Sodium Salt (129- 17-9) Persistence and degradability Biodegradability in water: no data available. Methanol (67-56-1) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biochemical oxygen demand (BOD) 0.6 - 1.12 g O? /g substance Chemical oxygen demand (COD) 1.42 g O? /g substance ThOD 1.5 g O? /g substance BOD (% of ThOD) 0.8 % ThOD 12.3. Bioaccumulative potential JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. Bioaccumulative potential Not established. Polyethylene Glycol 200-600 (25322-68-3) Log Pow -1.2 Bioaccumulative potential Bioaccumulation: not applicable. Nonyl Nonoxynol-5 (9014-93-1) Bioaccumulative potential Not established. Hydrogen [4-[4-(Diethylamino)-2',4'-Disulphonatobenzhydrylidene] Cyclohexa-2,5-Dien-1-ylidene] Diethylammonium, Sodium Salt (129- 17-9) Log Pow -5.340 (Estimated value) Bioaccumulative potential Bioaccumulation: not applicable. Methanol (67-56-1) BCF fish 1 < 10 (Leuciscus idus) Log Pow -0.77 (Experimental value; Other) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). 12.4. Mobility in soil Methanol (67-56-1) Surface tension 0.023 N/m (20 ?C) 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. Hazardous waste due to toxicity. JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/11/2014 EN (English US) 7/9 SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN US DOT (ground): UN1230, Methanol Solution, 3, II, Limited Quantity ICAO/IATA (air): UN1230, Methanol Solution, 3 (6.1), II, Limited Quantity IMO/IMDG (water): UN1230, Methanol Solution, 3 (6.1), II, Limited Quantity Special Provisions: IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. T7 - 4 178.274(d)(2) Normal............. 178.275(d)(3) TP2 - a. The maximum degree of filling must not exceed the degree of filling determined by the following: (image) Where: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and a is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For liquids transported under ambient conditions may be calculated using the formula: (image) Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C (59 F) and 50 C (122 F), respectively. Not applicable 14.2. UN proper shipping name Proper Shipping Name (DOT) : Methanol Solution Department of Transportation (DOT) Hazard Classes : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 Hazard labels (DOT) : 3 - Flammable liquid DOT Symbols : + - Fixes (cannot be altered) proper shipping name, hazard class, and packing group,I - Proper shipping name appropriate for international and domestic transportation Packing group (DOT) : II - Medium Danger DOT Special Provisions (49 CFR 172.102) : IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. T7 - 4 178.274(d)(2) Normal............. 178.275(d)(3) TP2 - a. The maximum degree of filling must not exceed the degree of filling determined by the following: (image) Where: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and a is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For liquids transported under ambient conditions may be calculated using the formula: (image) Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C (59 F) and 50 C (122 F), respectively. DOT Packaging Exceptions (49 CFR 173.xxx) : 150 DOT Packaging Non Bulk (49 CFR 173.xxx) : 202 DOT Packaging Bulk (49 CFR 173.xxx) : 242 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea DOT Vessel Stowage Location : B - (i) The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) ??On deck only?? on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. DOT Vessel Stowage Other : 40 - Stow ??clear of living quarters?? Subsidiary risks (IMDG) : 6.1 Air transport DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 1 L DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 60 L Subsidiary risks (IATA) : 6.1 JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/11/2014 EN (English US) 8/9 SECTION 15: Regulatory information 15.1. US Federal regulations JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Fire hazard Methanol (67-56-1) Listed on United States SARA Section 313 Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Fire hazard 15.2. International regulations CANADA JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects Methanol (67-56-1) WHMIS Classification Class B Division 2 - Flammable Liquid Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] F; R11 T; R23/24/25 T; R39/23/24/25 Full text of R-phrases: see section 16 15.2.2. National regulations No additional information available 15.3. US State regulations No additional information available SECTION 16: Other information Indication of changes : Revision - See : *. Other information : None. Full text of H-phrases: see section 16: ------ Acute Tox. 3 (Dermal) Acute toxicity (dermal) Category 3 ------ Acute Tox. 3 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 3 ------ Acute Tox. 3 (Oral) Acute toxicity (oral) Category 3 ------ Flam. Liq. 2 Flammable liquids Category 2 ------ STOT SE 1 Specific target organ toxicity (single exposure) Category 1 ------ H225 Highly flammable liquid and vapor ------ H301 Toxic if swallowed ------ H311 Toxic in contact with skin ------ H331 Toxic if inhaled ------ H370 Causes damage to organs NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/11/2014 EN (English US) 9/9 NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all ambient conditions. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 3 Serious Hazard Physical : 0 Minimal Hazard Personal Protection : B SDS US (GHS HazCom 2012) - TCC The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.