TRACER PRODUCTS TP-3400 Effective: 7/1/15 SAFETY DATA SHEET Page 1 Supersedes: 17/10/14 Page 1 of 7 Version 2 Section 1: Identification GHS Product Identifier: TP-3400 Other Names: TP-3400-0001, TP-3400-0008, TP-3400-0016, TP-3400-0032, TP-3400-0100, TP-3400-0500, TP-3400-5500, TP-3400- 0601, TP-3400-2401, TP-3400-12025 Use of Product: Leak Detection Description: Fluorescent dye for oil and oil-based fluids (All-in-One?) Company Information: Tracer Products, a Division of Spectronics Corporation 956 Brush Hollow Road Westbury, New York 11590 800-641-1133 516-333-1254 (for calls originating outside continental U.S.) Emergency Contact: US & Canada 800-424-9300 (24 HOURS) CHEMTREC; Call collect outside continental US & Canada: 703-527-3887. Section 2: Hazardous Identification Classification of Product: Pictogram: Signal Word: Warning Physical Hazards: Not Classified Health Hazard: Hazard Precautionary Statement Class Cat. Statement Prevention Response Storage Acute Tox Inhalation 4 Harmful if inhaled Avoid breathing Mist. Use only outdoors or in a well-ventilated area If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor if you feel unwell. N/A Environmental 2 Toxic to aquatic life with long lasting effects Avoid release into the environment Environmental 2 Disposal: Dispose of contents/container in accordance with local/regional/national/international regulations N/A: Not Applicable Cat: Category HMIS Hazard Rating: Health: 1, Fire: 1, Reactivity: 0. 2.1 GHS Label Elements: Signal Word: Warning Pictogram: Harmful if inhaled. Avoid breathing mist. Use only outdoors or in a well-ventilated area. IF INHALED: remove person to fresh air and keep comfortable for breathing. Call a doctor if you feel unwell. Toxic to aquatic life with long lasting effects. Avoid release into the environment. 2.2 CLP Label Elements: Signal Word: Warning Pictogram: TRACER PRODUCTS TP-3400 Effective: 7/1/15 SAFETY DATA SHEET Page 2 Supersedes: 17/10/14 Page 2 of 7 Version 2 Harmful if inhaled. Avoid breathing mist. Toxic to aquatic life with long lasting effects. Avoid release into the environment. Section 3: Composition/Information on Ingredients Chemical Identity: TP-3400 Synonyms: See Section 1 Above Common Name/ Chemical Name CAS Number ELINCS % W Polyol Ester Oil See Below See Below 40-60 Mineral Oil See Below See Below 10-20 Fluorescent Dye A See Below See Below 10-20 Petroleum Hydrocarbon See Below See Below 5-20 Fluorescent Dye B See Below See Below 0-10 Polyol Ester Oil: The specific identity and composition has been withheld as a trade secret, NJTSRN 80100312-5003 Mineral Oil: The specific identity and composition has been withheld as a trade secret, NJ TSRN 80100312-5001 Fluorescent Dye A: The specific identity and composition has been withheld as a trade secret, NJ TSRN 80100312-50006 Petroleum Hydrocarbon: The specific identity and composition has been withheld as a trade secret, NJ TSRN 80100312-5002 Fluorescent Dye B: The specific identity and composition has been withheld as a trade secret, NJ TSRN 80100312-5007 Section 4: First-Aid Measures Primary Routes of Exposure: Inhalation: Remove to fresh air. If symptoms develop, seek immediate medical attention. If not breathing, give artificial respiration. Eye Contact: Flush eyes with water for 15 minutes. If irritation develops, consult a physician. Skin Contact: Wash affected area with soap and water and rinse thoroughly. If irritation develops, consult a physician. Ingestion: Give water. Call a physician immediately. Do not induce vomiting. Aggravation of Existing Conditions: Exposure to this product is not expected to contribute to, worsen or aggravate any existing medical conditions. Most Important Symptom: Treat symptomatically. Section 5: Fire-Fighting Measures Flash Point: 268?F (131?C) Test Method: Pensky Martens Closed Cup Explosive Limit: LEL (%): No data available; UEL (%): No data available Autoignition Temperature: No data available Unusual Fire and Hazardous Combustion and Decomposition Products: Smoke, soot, and toxic/irritating fumes (i.e., carbon dioxide, carbon monoxide, etc.). Oxides of nitrogen and carbon. Fire and Explosion Hazards: May liberate irritating or toxic vapors during combustion or decomposition. Extinguishing Media: Based on the NFPA guide, use dry chemical, carbon dioxide, water mist, water jet sprays, halogen, or alcohol foam suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray, fog or alcohol foam, thoroughly drenching the burning material. Unsuitable Extinguishing Media: High volume water with full jet. Oxidizers and reducers. Fire-Fighting Procedures/Equipment: Fire fighters and others who may be exposed to the products of combustion should be equipped with NIOSH-approved, positive-pressure, self-contained breathing apparatus (SCBA) and full protective clothing. Water can be used to cool and protect containers and surroundings. Section 6: Accidental Release Measures Non-Emergency Personnel: TRACER PRODUCTS TP-3400 Effective: 7/1/15 SAFETY DATA SHEET Page 3 Supersedes: 17/10/14 Page 3 of 7 Version 2 General Advice: Avoid inhalation and contact with skin, eyes, or clothing. Wash hands and face before eating, drinking, or using tobacco products. Personal Protective Equipment Needed: Wear impervious gloves, shoes, and protective clothing Emergency Personnel: Suitable Protective Gear: Wear impervious gloves, shoes and protective clothing. Unsuitable Protective Gear: Not Applicable Environmental Precautions: Prevent any contamination of local soils and water supply. Prevent ground water infiltration or any ground penetration. Avoid the spreading or entering into watercourses by using sand, soil, or other types of barriers. If contamination into water course or sewage system, alert appropriate authorities. Containment/Clean-up Methods: Containment & Recovery of Product: Contain with absorbent material, such as clay, soil, universal binding medium, or any commercially available absorbent. Shovel reclaimed dye and absorbent into a recovery or salvage drums for disposal. For larger spills, transfer to a salvage tank for recovery or safe disposal. Any residues should be treated like a small spill. This is not a RCRA hazardous waste per Title 40 CFR 261. Stop material from contaminating soil, or from entering sewers or bodies of water. For larger spills, transfer to a salvage tank for safe recovery/disposal. Residues are treated as small spills. Disposal: Either incinerate or land fill in accordance with applicable local, state and federal regulations. Section 7: Handling and Storage Handling Precautions: Use product only in well ventilated areas. Avoid breathing in mists or vapors from a heated product. Avoid formation of mists. Avoid heating product near flash point. Avoid prolonged or repeated contact with skin. Handle in ambient temperature. Storage Conditions: Store in a cool, dry, well-ventilated area away from heat, ignition sources, and direct sunlight. Always keep containers tightly closed. Store away from oxidizing and reducing agents. Personal Hygiene: Wash hands before breaks and at the end of the work day. Do not carry cleaning clothes used to absorb product in clothing. General hygiene measures for chemicals apply. Empty Container Precautions: Do not reuse empty container for any purpose. Section 8: Exposure Controls/Personal Protection Occupational Exposure Limits: No exposure limits have been established for this product. Biological Exposure Limits: No data available Engineering Controls/Ventilation: Maintain airborne concentrations below the established exposure limits by providing adequate ventilation. General (dilution) ventilation should be acceptable. Additional local exhaust ventilation is recommended where dusts, mists or vapors may be released. Airborne Oil Mist Exposure Limits: Mineral Oil, Petroleum Hydrocarbon, and Polyol Ester Oil ACGIH TLV: 5mg/m3, 8 hr. ACGIH STEL: 10mg/m3 OSHA PEL: 5mg/m3, 8 hr. Personal Protective Equipment: Respiratory Protection: Avoid breathing vapor and/or mist. If occupational exposure limits are exceeded wear NIOSH/OSHA approved equipment. Use a respiratory protection fitted with a combination filter A-P3 for short term use. High airborne concentrations may necessitate the use of self-contained breathing apparatus (SCBA) or a supplied air respirator. Respiratory protection programs must be in compliance with 29 CFR 1910.134. Skin Protection: Wear protective clothing and appropriate impervious gloves. Eye Protection: Wear safety goggles with peripheral coverage approved to EU Standard EN 166, AS/NZS 1337. An eye wash facility should be readily available. Hand Protection: When in contact with material, be sure to use proper gloves approved to standards (Europe: EN 374, U.S.: F739, & AS/NZS: 2161). Gloves made from neoprene, nitrile or butyl rubber may provide suitable chemical protection. Hygiene Measures: Wash thoroughly after handling, especially before eating, drinking, smoking, or using restroom facilities. Section 9: Physical and Chemical Properties Physical State: Liquid TRACER PRODUCTS TP-3400 Effective: 7/1/15 SAFETY DATA SHEET Page 4 Supersedes: 17/10/14 Page 4 of 7 Version 2 Appearance: Red Odor: Mineral Oil Odor Threshold: No data available pH: no data available Melting Point: No data available Freezing Point: No data available Initial Boiling Point: No data available Boiling Range: TBD Flash Point (PMCC): 268?F (131?C) Evaporative Rate: No data available Solid Flammability: No data available Gas Flammability: No data available Upper Explosive Limit: No data available Lower Explosive Limit: No data available Vapor Pressure 68? F (20? C): No data available Vapor Density (Air=1): No data available Relative Density: .9331 Solubility in Water: Insoluble Partition Coefficient: n-octanol/water: No data available Auto-ignition Temperature: No data available Decomposition Temperature: No data available Viscosity at 40oC: 22.18 Viscosity at 100oC: 3.479 Percent Volatile by Volume (%): 0 Evaporation Rate (Butyl Acetate=1): < 0.01 Volatile Organic Content (VOC) Component: None Note: The physical data presented above are typical values and should not be construed as a specification. Section 10: Stability and Reactivity Reactivity: This product is non-reactive under ambient conditions Stability: Stable under normal conditions of use. Can decompose slowly with localized heating over 300oC Conditions to Avoid: High temperatures & a source of ignition. Toxic fumes may be released if product is heated above decomposition point. Incompatible Materials: strong Acids, strong oxidizing agents, and reducing agents Hazardous Decomposition Products: In the event of combustion, CO and CO2 will be formed. Hazardous Polymerization: Will not occur Section 11: Toxicological Information Fluorescent Dye A Fluorescent Dye B Petroleum Hydrocarbon Polyol Ester Oil Mineral Oil Oral LD50 Rat >5000 mg/kg >5000 mg/kg >5000 mg/kg >2000 mg/kg >5000 mg/kg Dermal LD50 Rabbit >2000 mg/kg Not available >2000 mg/kg >2000 mg/kg >2000 mg/kg Inhalation LC50 Rat 2.18 mg/l Not available 5.28 mg/l 5.1 mg/l 2.18 mg/l Eye Irritation Rabbit Not Irritating Not Irritating Not irritating Not available Not irritating Skin Irritation Rabbit Not irritating Not available Not irritating Not available Mild Irritation *Results are based on test of similar products Carcinogenicity: TRACER PRODUCTS TP-3400 Effective: 7/1/15 SAFETY DATA SHEET Page 5 Supersedes: 17/10/14 Page 5 of 7 Version 2 Carcinogenicity ACGIH IARC NTP OSHA Polyol Ester Oil No No No No Mineral Oil No No No No Fluorescent Dye A No No No No Petroleum Hydrocarbon No No No No Fluorescent Dye B No No No No Summary Comments: According to ACGIH, IARC, NTP, and OSHA, the Polyol Ester oil, Mineral oil, fluorescent dye A, Petroleum Hydrocarbon and fluorescent dye B are not considered to be a hazardous carcinogen to humans. Reproductive Toxicity: No data available STOT-single exposure: May cause respiratory irritation STOT-repeated exposure: Fluorescent Dye A Fluorescent Dye B Petroleum Hydrocarbon Polyol Ester Mineral Oil Oral mg/kg Rat No data available No data available 1500 1613 No data available Dermal mg/kg Rat 980 No data available >600 No data available >1000 Inhalation mg/l/4h Rat 1000 No data available 1000 No data available >980 Aspiration Hazard: No Likely Routes of Exposure: Eyes, skin and respiratory tract Symptoms: Eye Contact: May cause mild irritation Skin Contact: May cause mild irritation Inhalation: May cause respiratory irritation Ingestion: May cause gastrointestinal irritation Section 12: Ecological Information Toxicity: Fluorescent Dye A* Fluorescent Dye B* Petroleum Hydrocarbon* Polyol Ester Oil Mineral Oil Fish LL50 96hr mg/l >100 Not Available 2 >150 >100 Crustacean LL50 96hr. mg/l >10000 Not Available 1.4 >1000 >10000 Algae NOEL 72hr. mg/l >100 Not Available 2 >100 >100 NOEL: No observed adverse effect level Persistence & Degradability: Isolate as much as possible with an oil separator. Bioaccumulation Potential: No data available Mobility in Soil: No data available Behavior in Sewage Plants: No data available PBT vPvB: The substance is not PBT / vPvB Section 13: Disposal Considerations General Statements: Federal regulations may apply to empty container. State and/or local regulations may be different. Disposal: Recover or recycle if possible, otherwise, dispose of in accordance with all local, state, and federal regulations. Sewage disposal is discouraged Special Instructions: Be sure to contact the appropriate government environmental agencies if further guidance is required. Do not remove labels from container until container is cleaned properly. Containers can be reused or disposed of by landfill or incineration if appropriate to local law. Water with cleaning agents is required Hazardous Waste Number: Not a RCRA hazardous waste TRACER PRODUCTS TP-3400 Effective: 7/1/15 SAFETY DATA SHEET Page 6 Supersedes: 17/10/14 Page 6 of 7 Version 2 Section 14: Transport Information General Comments: This product is not classed as hazardous or regulated for transport under 49 CFR, IATA/ICAO, or IMDG 49 CFR: DOT Shipping Name: Not Regulated DOT Label: N/A DOT Identification No.: Not Applicable; Nonregulated shipments by air under 49 CFR, IATA/ICAO AND IMO Transport by Road/Rail (ADR/RID): UN Proper Shipping Name: Not Applicable Transport Hazard Class: Not Applicable Packing Group: Not Applicable Classification Code: Not Applicable LQ (ADR 2013): Not Applicable LQ (ADR 2009): Not Applicable Environmental Hazard: Not Applicable Tunnel Restriction Code: Not Applicable Transport by Sea (IMDG): UN Proper Shipping Name: Not Applicable Transport Hazard Class: Not Applicable Packing Group: Not Applicable Marine Pollutant: Not Applicable Environmental Hazard: Not Applicable Transport by Air (IATA): UN Shipping Name: Not Applicable Transport Hazard Class: Not Applicable Packing Group Number: Not Applicable Environmental Hazards: Not Applicable Special Precautions for User: Unless otherwise specified, general measures for safe transport must be followed Transport in Bulk: Non-dangerous material according to transport regulations. Section 15: Regulatory Information Inventory Status: Polyol Ester Oil can be found on TSCA, DSL, IECSC, & ENCS inventories Mineral Oil can be found on TSCA, DSL, AICS, IECSC, KECI, & ENCS inventories Fluorescent Dye A can be found on TSCA, DSL, AICS, IECSC, & ENCS inventories Petroleum Hydrocarbon can be found on TSCA, DSL, AICS, IECSC, KECI, & ENCS inventories Fluorescent Dye B can be found on TSCA, DSL, & ENCS inventories SARA Title III Information: This product contains no chemicals subject to the reporting requirements of Section 313 of the emergency planning and community right to know act. SARA - Section 302-Extremely Hazardous Substances: No regulated ingredients. SARA - Section 302-Reportable Quantity: None. SARA - Section 311/312-Hazard Categories: Fire Hazard: No Sudden Release of Pressure Hazard: No Reactivity Hazard: No Immediate (Acute) Health Hazard: No Delayed (Chronic) Health Hazard: No Section 313-Toxic Chemicals: No regulated ingredients. TRACER PRODUCTS TP-3400 Effective: 7/1/15 SAFETY DATA SHEET Page 7 Supersedes: 17/10/14 Page 7 of 7 Version 2 State Right-To-Know: Pennsylvania - New Jersey R-T-K: NAME CAS NO. or NJ TSRN %W Polyol Ester NJ TSRN 80100312-5003 40-60 Mineral Oil NJ TSRN 80100312-5001 10-20 Fluorescent Dye A NJ TSRN 80100312-5006 10-20 Petroleum Hydrocarbon NJ TSRN 80100312-5002 5-20 Fluorescent Dye B NJ TSRN 80100312-5007 0-10 Clean Air Act Amendments - Ozone-Depleting Chemicals: No regulated ingredients. CONEG: This product is in compliance with CONEG (total cadmium, chromium, lead and mercury <100ppm) TSCA: The chemical components of this product are listed on the Section 8(B) Chemical Substance Inventory List (40 CFR 710). CERCLA: No regulated ingredients. California - California Proposition 65: This product contains no chemical(s) known to the state of California to cause cancer. Canada ? CEPA DSL/NDSL: All DSL except fluorescent dye B which is NDSL Section 16: Other Information _ USER?S RESPONSIBILITY: A bulletin such as this cannot be expected to cover all possible individual situations. As the user has the responsibility to provide a safe workplace, all aspects of an individual operation should be examined to determine if, or where, precautions (in addition to those described herein) are required. Any health hazard and safety information contained herein should be passed on to your customers or employees, as the case may be. DISCLAIMER OF LIABILITY: The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this material. All chemicals may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Final determination of suitability of the chemical is the sole responsibility of the user. No representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose or any other nature are made hereunder with respect to the information contained herein or the chemical to which the information refers. It is the responsibility of the users to comply with all applicable federal, state and local laws and regulations. NA = Not Available END OF SAFETY DATA SHEET