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TRACER PRODUCTS TP-9870 Effective: 20/2/15 SAFETY DATA SHEET Page 1 Supersedes: 24/6/13 Page 1 of 6 Version 2 Section 1: Identification GHS Product Identifier: TP-9870 Other Names: TP-9870-0001, TP-9870-0601, TP-9870-0601/J, TP-9870CS Use of Product: Leak Detection Description: Fluorescent Dye for Mobile Air Conditioning Systems Company Information: Tracer Products, a Division of Spectronics Corporation 956 Brush Hollow Road Westbury, New York 11590 800-641-1133 516-333-1254 (for calls originating outside continental U.S.) Emergency Contact: US & Canada 800-424-9300 (24 HOURS) CHEMTREC; Call collect outside continental US & Canada: 703-527-3887. Section 2: Hazardous Identification Pictogram: No Pictogram required Signal Word: None Physical Hazards: Not Classified Health Hazard: This product is not classified as hazardous according to OSHA 1910.1200. Environmental Hazard: No known significant effects or critical hazards HMIS Hazard Rating: Health: 1, Fire: 1, Reactivity: 0. 2.1 GHS Label Elements: This product is not classified as hazardous according to the GHS. 2.2 CLP Label Elements: This product is not classified as hazardous according to Regulation EC 1272/2008 (CLP) Section 3: Composition/Information on Ingredients Chemical Identity: TP-9870 Synonyms: See Section 1 Above Common Name/ Chemical Name CAS Number ELINCS % W Polyol Ester Oil See Below See Below 40-60 Fluorescent Dye See Below See Below 40-60 Polyol Ester Oil: The specific identity and composition has been withheld as a trade secret. NJTSRN: 80100312-5003 Fluorescent Dye: The specific identity and composition has been withheld as a trade secret. NJTSRN: 80100312-5007 Section 4: First-Aid Measures Primary Routes of Exposure: Inhalation: Remove to fresh air. If symptoms develop, seek immediate medical attention. If not breathing, give artificial respiration. Eye Contact: Flush eyes with water for 15 minutes. If irritation develops, consult a physician. Skin Contact: Wash affected area with soap and water and rinse thoroughly. If irritation develops, consult a physician. Ingestion: Give water. Call a physician immediately. Do not induce vomiting. Aggravation of Existing Conditions: Exposure to this product is not expected to contribute to, worsen or aggravate any existing medical conditions. Most Important Symptom: Treat symptomatically. TRACER PRODUCTS TP-9870 Effective: 20/2/15 SAFETY DATA SHEET Page 2 Supersedes: 24/6/13 Page 2 of 6 Version 2 Section 5: Fire-Fighting Measures Flash Point: 500?F (260?C) Test Method: Pensky-Martens Closed Cup Explosive Limit: LEL (%): No data available; UEL (%): No data available Autoignition Temperature: No data available Unusual Fire and Hazardous Combustion and Decomposition Products: Smoke, soot, and toxic/irritating fumes (i.e., carbon dioxide, carbon monoxide, etc.). Oxides of nitrogen and carbon. Fire and Explosion Hazards: May liberate irritating or toxic vapors during combustion or decomposition. Extinguishing Media: Based on the NFPA guide, use dry chemical, carbon dioxide, water mist, water jet sprays, halogen, or alcohol foam suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray, fog or alcohol foam, thoroughly drenching the burning material. Unsuitable Extinguishing Media: High volume water with full jet. Oxidizers and reducers. Fire-Fighting Procedures/Equipment: Fire fighters and others who may be exposed to the products of combustion should be equipped with NIOSH-approved, positive-pressure, self-contained breathing apparatus (SCBA) and full protective clothing. Water can be used to cool and protect containers and surroundings. Section 6: Accidental Release Measures Non-Emergency Personnel: General Advice: Avoid inhalation and contact with skin, eyes, or clothing. Wash hands and face before eating, drinking, or using tobacco products. Personal Protective Equipment Needed: Wear impervious gloves, shoes, and protective clothing Emergency Personnel: Suitable Protective Gear: Wear impervious gloves, shoes and protective clothing. Unsuitable Protective Gear: Not Applicable Environmental Precautions: Prevent any contamination of local soils and water supply. Prevent ground water infiltration or any ground penetration. Avoid the spreading or entering into watercourses by using sand, soil, or other types of barriers. If contamination into water course or sewage system, alert appropriate authorities. Containment/Clean-up Methods: Containment & Recovery of Product: Contain with absorbent material, such as clay, soil, universal binding medium, or any commercially available absorbent. Shovel reclaimed dye and absorbent into a recovery or salvage drums for disposal. For larger spills, transfer to a salvage tank for recovery or safe disposal. Any residues should be treated like a small spill. This is not a RCRA hazardous waste per Title 40 CFR 261. Stop material from contaminating soil, or from entering sewers or bodies of water. For larger spills, transfer to a salvage tank for safe recovery/disposal. Residues are treated as small spills. Disposal: Either incinerate or land fill in accordance with applicable local, state and federal regulations. Section 7: Handling and Storage Handling Precautions: Use product only in well ventilated areas. Avoid breathing in mists or vapors from a heated product. Avoid formation of mists. Avoid heating product near flash point. Avoid prolonged or repeated contact with skin. Handle in ambient temperature. Storage Conditions: Store in a cool, dry, well-ventilated area away from heat, ignition sources, and direct sunlight. Always keep containers tightly closed. Store away from oxidizing and reducing agents. Personal Hygiene: Wash hands before breaks and at the end of the work day. Do not carry cleaning clothes used to absorb product in clothing. General hygiene measures for chemicals apply. Empty Container Precautions: Do not reuse empty container for any purpose. Special Warnings: Hot organic chemical vapors or mists can suddenly and without warning combust when mixed with air. Section 8: Exposure Controls/Personal Protection Occupational Exposure Limits: No exposure limits have been established for this product. TRACER PRODUCTS TP-9870 Effective: 20/2/15 SAFETY DATA SHEET Page 3 Supersedes: 24/6/13 Page 3 of 6 Version 2 Biological Exposure Limits: No data available Engineering Controls/Ventilation: Maintain airborne concentrations below the established exposure limits by providing adequate ventilation. General (dilution) ventilation should be acceptable. Additional local exhaust ventilation is recommended where dusts, mists or vapors may be released. Airborne Oil Mist Exposure Limits: Polyol Ester Oil ACGIH TLV: 5 mg/m3, 8 hr ACGIH STEL: 10 mg/m3 OSHA PEL: 5mg/m3, 8 hr Personal Protective Equipment: Respiratory Protection: Avoid breathing vapor and/or mist. If occupational exposure limits are exceeded wear NIOSH/OSHA approved equipment. Use a respiratory protection fitted with a combination filter A-P3 for short term use. High airborne concentrations may necessitate the use of self-contained breathing apparatus (SCBA) or a supplied air respirator. Respiratory protection programs must be in compliance with 29 CFR 1910.134. Skin Protection: Wear protective clothing and appropriate impervious gloves. Eye Protection: Wear safety goggles with peripheral coverage approved to EU Standard EN 166, AS/NZS 1337. An eye wash facility should be readily available. Hand Protection: When in contact with material, be sure to use proper gloves approved to standards (Europe: EN 374, U.S.: F739, & AS/NZS: 2161). Gloves made from neoprene, nitrile or butyl rubber may provide suitable chemical protection. Hygiene Measures: Wash thoroughly after handling, especially before eating, drinking, smoking, or using restroom facilities. Section 9: Physical and Chemical Properties Physical State: Liquid Appearance: Amber Odor: Aromatic hydrocarbon Odor Threshold: no data available pH: no data available Melting Point: No data available Freezing Point: No data available Initial Boiling Point: 399?F (204?C) Boiling Range: no data available Flash Point (COC): Greater than 305? F (152? C) Evaporative Rate: No data available Solid Flammability: No data available Gas Flammability: No data available Upper Explosive Limit: No data available Lower Explosive Limit: No data available Vapor Pressure 68? F (20? C) : <0.01 mmHg Vapor Density (Air= 1) : >1 Relative Density: 0.98 Solubility in Water: < 0.1 % Partition Coefficient: n-octanol/water: No data available Auto-ignition Temperature: No data available Decomposition Temperature: No data available Viscosity at 40oC: 48.8 Viscosity at 100oC: no data available Percent Volatile by Volume (%): 0 Evaporation Rate (Butyl Acetate=1): < 0.01 Volatile Organic Content (VOC) Component: None Note: The physical data presented above are typical values and should not be construed as a specification. Section 10: Stability and Reactivity TRACER PRODUCTS TP-9870 Effective: 20/2/15 SAFETY DATA SHEET Page 4 Supersedes: 24/6/13 Page 4 of 6 Version 2 Reactivity: This product is non-reactive under ambient conditions Stability: Stable under normal conditions of use. Conditions to Avoid: High temperatures & a source of ignition. Toxic fumes may be released if product is heated above decomposition point. Incompatible Materials: Strong Acids, Strong oxidizing agents, and Reducing agents Hazardous Decomposition Products: In the event of combustion, CO and CO2 will be formed. Hazardous Polymerization: Will not occur Section 11: Toxicological Information Fluorescent Dye Polyol Ester Oil Oral LD50 Rat >5,000 mg/kg >2,000 mg/kg Dermal LD50 Rabbit >2,000 mg/kg >2,000 mg/kg Inhalation LC50 Rat >12 mg/l >5.1 mg/l Eye Irritation Rabbit Not Irritating Not Irritating Skin Irritation Rabbit >4 No data available Carcinogenicity: Carcinogenicity ACGIH IARC NTP OSHA Polyol Ester Oil No No No No Fluorescent Dye No No No No Summary Comments: According to ACGIH, IARC, NTP, and OSHA, the polyol ester oil and the fluorescent dye are not considered to be a hazardous carcinogen to humans. Reproductive Toxicity: No data available STOT-single exposure: No data available STOT-repeated exposure: Fluorescent Dye Polyol Ester Oral mg/kg Rat No data available 1613 Dermal mg/kg Rat No data available No data available Inhalation mg/l/4h Rat No data available No data available Aspiration Hazard: No Likely Routes of Exposure: Eyes, skin and respiratory tract Symptoms: Eye Contact: May cause mild irritation Skin Contact: May cause mild irritation Inhalation: May cause mild respiratory irritation Ingestion: May cause gastrointestinal irritation Section 12: Ecological Information Toxicity: Fluorescent Dye Polyol Ester Oil Fish LL50 96hr mg/l No data available >100mg/l Crustacean LL50 96hr. mg/l No data available > 10000 mg/L Algae NOEL 72hr. mg/l No data available >100mg/l Persistence & Degradability: Readily biodegradable Bioaccumulation Potential: Does not readily bioaccumulate Mobility in Soil: No data available TRACER PRODUCTS TP-9870 Effective: 20/2/15 SAFETY DATA SHEET Page 5 Supersedes: 24/6/13 Page 5 of 6 Version 2 Behavior in Sewage Plants: No data available PBT vPvB: This substance is not a PBT vPvB Section 13: Disposal Considerations General Statements: Federal regulations may apply to empty container. State and/or local regulations may be different. Disposal: Recover or recycle if possible, otherwise, dispose of in accordance with all local, state, and federal regulations. Sewage disposal is discouraged Special Instructions: Be sure to contact the appropriate government environmental agencies if further guidance is required. Do not remove labels from container until container is cleaned properly. Containers can be reused or disposed of by landfill or incineration if appropriate to local law. Water with cleaning agents is required Hazardous Waste Number: Not a RCRA hazardous waste Section 14: Transport Information General Comments: This product is not classed as hazardous or regulated for transport under 49 CFR, IATA/ICAO, or IMDG 49 CFR: DOT Shipping Name: Not Regulated DOT Label: N/A DOT Identification No.: Not Applicable; Nonregulated shipments by air under 49 CFR, IATA/ICAO AND IMO Transport by Road/Rail (ADR/RID): UN Proper Shipping Name: Not Applicable Transport Hazard Class: Not Applicable Packing Group: Not Applicable Classification Code: Not Applicable LQ (ADR 2013): Not Applicable LQ (ADR 2009): Not Applicable Environmental Hazard: Not Applicable Tunnel Restriction Code: Not Applicable Transport by Sea (IMDG): UN Proper Shipping Name: Not Applicable Transport Hazard Class: Not Applicable Packing Group: Not Applicable Marine Pollutant: Not Applicable Environmental Hazard: Not Applicable Transport by Air (IATA): UN Shipping Name: Not Applicable Transport Hazard Class: Not Applicable Packing Group Number: Not Applicable Environmental Hazards: Not Applicable Special Precautions for User: Unless otherwise specified, general measures for safe transport must be followed Transport in Bulk: Non-dangerous material according to transport regulations Section 15: Regulatory Information Inventory Status: Polyol Ester Oil: is listed or are excluded from listing on TSCA, DSL, & AICS inventories Fluorescent Dye: is listed or are excluded from listing on TSCA, DSL, AICS, IECSC, & ENCS inventories SARA Title III Information: This product contains no chemicals subject to the reporting requirements of Section 313 of the emergency planning and community right to know act. SARA - Section 302-Extremely Hazardous Substances: No regulated ingredients. SARA - Section 302-Reportable Quantity: None. TRACER PRODUCTS TP-9870 Effective: 20/2/15 SAFETY DATA SHEET Page 6 Supersedes: 24/6/13 Page 6 of 6 Version 2 SARA - Section 311/312-Hazard Categories: Fire Hazard: No Sudden Release of Pressure Hazard: No Reactivity Hazard: No Immediate (Acute) Health Hazard: No Delayed (Chronic) Health Hazard: No Section 313-Toxic Chemicals: No regulated ingredients. State Right-To-Know: Pennsylvania - New Jersey R-T-K: NAME CAS NO. or NJ TSRN %W Polyol Ester Oil NJ TSRN 80100312-5003 40-60 Fluorescent Dye NJ TSRN 80100312-5007 40-60 Clean Air Act Amendments - Ozone-Depleting Chemicals: No regulated ingredients. CONEG: This product is in compliance with CONEG (total cadmium, chromium, lead and mercury <100ppm TSCA: The chemical components of this product are listed or excluded on the Section 8(B) Chemical Substance Inventory List (40 CFR 710). CERCLA: No regulated ingredients. California - California Proposition 65: This product contains no chemical(s) known to the state of California to cause cancer. Canada ? CEPA DSL/NDSL: Not regulated Section 16: Other Information _ USER?S RESPONSIBILITY: A bulletin such as this cannot be expected to cover all possible individual situations. As the user has the responsibility to provide a safe workplace, all aspects of an individual operation should be examined to determine if, or where, precautions (in addition to those described herein) are required. Any health hazard and safety information contained herein should be passed on to your customers or employees, as the case may be. DISCLAIMER OF LIABILITY: The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this material. All chemicals may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Final determination of suitability of the chemical is the sole responsibility of the user. No representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose or any other nature are made hereunder with respect to the information contained herein or the chemical to which the information refers. It is the responsibility of the users to comply with all applicable federal, state and local laws and regulations. END OF SAFETY DATA SHEET