3M? Matrix Resin 5831 02/03/15 __________________________________________________________________________________________ Page 1 of 9 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 29-5776-9 Version Number: 2.00 Issue Date: 02/03/15 Supercedes Date: 08/03/11 SECTION 1: Identification 1.1. Product identifier 3M? Matrix Resin 5831 Product Identification Numbers 70-0067-2257-6, 70-0067-3004-1 1.2. Recommended use and restrictions on use Recommended use Resin 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Aerospace and Commercial Transportation Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2B. Skin Sensitizer: Category 1. 2.2. Label elements Signal word Warning Symbols Exclamation mark | Pictograms 3M? Matrix Resin 5831 02/03/15 __________________________________________________________________________________________ Page 2 of 9 Hazard Statements Causes eye irritation. May cause an allergic skin reaction. Precautionary Statements Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Storage: Keep container tightly closed. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 50% of the mixture consists of ingredients of unknown acute oral toxicity. 50% of the mixture consists of ingredients of unknown acute dermal toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Engineered Nanoparticle (NJTS Reg No 04499600- 6857) Trade Secret* 35 - 65 Epoxy Resin 25068-38-6 35 - 65 Trade Secret * Epoxy Resin 14228-73-0 1 - 15 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures 3M? Matrix Resin 5831 02/03/15 __________________________________________________________________________________________ Page 3 of 9 Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Irritant Vapors or Gases During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not 3M? Matrix Resin 5831 02/03/15 __________________________________________________________________________________________ Page 4 of 9 remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Decontaminate work surfaces frequently to avoid exposure by contact. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage including any incompatibilities Keep container tightly closed. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits No occupational exposure limit values exist for any of the components listed in Section 3 of this SDS. 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: 3M? Matrix Resin 5831 02/03/15 __________________________________________________________________________________________ Page 5 of 9 Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Paste Odor, Color, Grade: White, minimal epoxy resin odor Odor threshold No Data Available pH No Data Available Melting point Not Applicable Boiling Point Not Applicable Flash Point >=201 ?F [Test Method: Closed Cup] Evaporation rate Not Applicable Flammability (solid, gas) Not Applicable Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure Not Applicable Vapor Density Not Applicable Density 1.48 - 1.57 g/ml Specific Gravity 1.48 - 1.57 [Ref Std: WATER=1] Solubility in Water Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water Not Applicable Autoignition temperature Not Applicable Decomposition temperature No Data Available Viscosity 12,000 - 37,000 centipoise [@ 73.4 ?F ] Hazardous Air Pollutants 0 % weight [Test Method: Calculated] Volatile Organic Compounds < 10 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile <= 0.5 % weight VOC Less H2O & Exempt Solvents < 10 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition 3M? Matrix Resin 5831 02/03/15 __________________________________________________________________________________________ Page 6 of 9 None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Epoxy Resin Dermal Rat LD50 > 1,600 mg/kg Epoxy Resin Ingestion Rat LD50 > 1,000 mg/kg Epoxy Resin Dermal Rabbit LD50 2,500 mg/kg Epoxy Resin Ingestion Rat LD50 2,450 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Epoxy Resin Rabbit Mild irritant Epoxy Resin Mild irritant Serious Eye Damage/Irritation Name Species Value Epoxy Resin Rabbit Moderate irritant Epoxy Resin Mild irritant 3M? Matrix Resin 5831 02/03/15 __________________________________________________________________________________________ Page 7 of 9 Skin Sensitization Name Species Value Epoxy Resin Human and animal Sensitizing Epoxy Resin similar compoun ds Sensitizing Respiratory Sensitization Name Species Value Epoxy Resin Human Some positive data exist, but the data are not sufficient for classification Germ Cell Mutagenicity Name Route Value Epoxy Resin In vivo Not mutagenic Epoxy Resin In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Epoxy Resin Dermal Mouse Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Epoxy Resin Ingestion Not toxic to female reproduction Rat NOAEL 750 mg/kg/day 2 generation Epoxy Resin Ingestion Not toxic to male reproduction Rat NOAEL 750 mg/kg/day 2 generation Epoxy Resin Dermal Not toxic to development Rabbit NOAEL 300 mg/kg/day during organogenesi s Epoxy Resin Ingestion Not toxic to development Rat NOAEL 750 mg/kg/day 2 generation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Epoxy Resin Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Epoxy Resin Dermal liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,000 mg/kg/day 2 years Epoxy Resin Dermal nervous system All data are negative Rat NOAEL 1,000 mg/kg/day 13 weeks Epoxy Resin Ingestion auditory system | heart | endocrine system | All data are negative Rat NOAEL 1,000 mg/kg/day 28 days 3M? Matrix Resin 5831 02/03/15 __________________________________________________________________________________________ Page 8 of 9 hematopoietic system | liver | eyes | kidney and/or bladder Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): Not regulated SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories 3M? Matrix Resin 5831 02/03/15 __________________________________________________________________________________________ Page 9 of 9 Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 29-5776-9 Version Number: 2.00 Issue Date: 02/03/15 Supercedes Date: 08/03/11 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com