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MSDS_237_Drum_Brake_Lining_NA_En.pdf
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ABEX, FA, FERODO, FM, GNBX, TQ, WE, BBS (see section 16) 24-Mar-2011 NORTH AMERICAN MSDS 1 / 10 MATERIAL SAFETY DATA SHEET 1 PRODUCT AND COMPANY IDENTIFICATION Product Name: ABEX, FA, FERODO, FM, GNBX, TQ, WE, BBS (see section 16) Product No.: 237 Manufacturer Name: Federal-Mogul World Headquarters 26555 Northwestern Highway Southfield, Michigan 48033 Emergency Telephone: 24hr EP (INFOTRAC): 1-800-535-5053 International: (001) 352-323-3500 Non-emergency Telephone: 1-248-354-9844 Intended Use: Drum brake lining. Friction Material Contact Person: MSDS Request (voicemail) 1-248-354-9844 2 HAZARDS IDENTIFICATION Physical State: Linings Emergency Overview Color: Gray Odor: Resin WARNING! Dust can be created by the machining of finished products. Cancer hazard - can cause cancer. Causes skin, eye and respiratory tract irritation. Harmful if inhaled. May cause allergic skin reaction. Potential Health Effects Inhalation: The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. Harmful if inhaled. Dust irritating to respiratory tract. Inhalation of powder or fumes may cause metal fume fever. Inhalation may lead to deposition in lung and in sufficient quantities produce baritosis. Eye Contact: Dust in the eyes will cause irritation. Exposed individuals may experience eye tearing, redness, and discomfort. Skin Contact: The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. Dust: Causes skin irritation. May cause allergic skin reaction. Ingestion: The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. May cause discomfort if swallowed. Chronic Health Effects: The ingredients may be released as general dust from the product by ABEX, FA, FERODO, FM, GNBX, TQ, WE, BBS (see section 16) 24-Mar-2011 NORTH AMERICAN MSDS 2 / 10 operations such as overheating, burning, machining, abrading, or riveting. Cancer hazard - can cause cancer. May cause lung damage. Prolonged and repeated overexposure to dust can lead to benign pneumoconiosis. May cause damage to the liver and kidneys. Target Organ(s): | Eye | Skin | Respiratory system | Lung | Liver | Kidney | Potential Physical / Chemical Effects: This product is not flammable or combustible. OSHA Regulatory Status: This product is hazardous according to OSHA 29CFR 1910.1200. Environment: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 3 COMPOSITION / INFORMATION ON INGREDIENTS General Information: This product contains a variety of ingredients all of which have become part of a bound system both physically and chemically and do not necessarily exhibit the properties of the individual components. The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. The formulations listed in Section 1 do not contain all of the ingredients listed below. Chemical Name CAS-No. Concentration* ?Acrylic Fibers 24980-62-9 > 1% ?Aluminium oxide 1344-28-1 > 1% ?Aluminum powder (stabilized) 7429-90-5 > 1% ?Barium sulphate 7727-43-7 > 1% ?Calcium carbonate 471-34-1 > 1% ?Calcium hydroxide 1305-62-0 > 1% ?Carbon black 1333-86-4 > 1% ?Cashew, nutshell liq. 8007-24-7 > 1% ?Cellulose 9004-34-6 > 1% ?Ceramic fiber 142844-00-6 > 1% ?Copper 7440-50-8 > 1% ?Crystalline silica 1317-95-9 > 1% ?Diantimony trioxide 1309-64-4 > 1% ?Glass fiber 65997-17-3 > 1% ?Graphite 7782-42-5 > 1% ?Limestone 1317-65-3 > 1% ?Mica 12001-26-2 > 1% ?Para-aramid polymer 26125-61-1 > 1% ?Silicon oxide 7631-86-9 > 1% ?Sulfur 7704-34-9 > 1% ?Talc 14807-96-6 > 1% ?Wollastonite 13983-17-0 > 1% ?Zinc Oxide 1314-13-2 > 1% ? This chemical is hazardous according to OSHA/WHMIS criteria. 4 FIRST AID MEASURES ABEX, FA, FERODO, FM, GNBX, TQ, WE, BBS (see section 16) 24-Mar-2011 NORTH AMERICAN MSDS 3 / 10 Inhalation: Move injured person into fresh air and keep person calm under observation. If necessary, seek hospital and take along these instructions. Eye Contact: Do not rub eye. Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention promptly if symptoms occur after washing. Skin Contact: Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms persist or occur after washing. Ingestion: If swallowed, rinse mouth with water (only if the person is conscious). Get medical attention if any discomfort continues. 5 FIRE-FIGHTING MEASURES Extinguishing Media: This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials. Unsuitable Extinguishing Media: None. Special Fire Fighting Procedures: Use standard firefighting procedures and consider the hazards of other involved materials. Unusual Fire & Explosion Hazards: The product is non-combustible. If heated, toxic vapors may be formed. Hazardous Combustion Products: Antimony oxides, Calcium oxides, Carbon Dioxide, Carbon Monoxide, Metallic fumes, Sulfur Oxides, Zinc oxides Protective Measures: Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace. Flammability Class: Dust: NFPA Rating Fire = 1. Materials that must be preheated before ignition can occur. 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Use explosion-proof electrical equipment if airborne dust levels are high. Avoid dust formation. Avoid inhalation of dust and contact with skin and eyes. Wear necessary protective equipment. See Section 8 of the MSDS for Personal Protective Equipment. Spill Cleanup Methods: Collect powder using special dust vacuum cleaner with particle filter or carefully sweep into closed container. Do not vacuum clean unless vacuum cleaners are equipped with HEPA filter. For waste disposal, see section 13 of the MSDS. Environmental Precautions: Do not allow to enter drains, sewers or watercourses. Collect and dispose of spillage as indicated in section 13 of the MSDS. ABEX, FA, FERODO, FM, GNBX, TQ, WE, BBS (see section 16) 24-Mar-2011 NORTH AMERICAN MSDS 4 / 10 Notification Procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. 7 HANDLING AND STORAGE Handling: Provide adequate ventilation. Avoid dust formation. Avoid inhalation of dust and contact with skin and eyes. Use work methods which minimize dust production. See Section 8 of the MSDS for Personal Protective Equipment. Observe good industrial hygiene practices. Storage: Store in tightly closed original container. Avoid conditions which create dust. Protect against direct sunlight. Store away from incompatible materials. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits: Chemical Name Source Type Exposure Limits Notes Aluminium oxide (Respirable fraction.) US. OSHA Z-1 PEL TWA 5 mg/m? Aluminum powder (stabilized) (Respirable fraction.) US. ACGIH TLV TWA 1 mg/m? Aluminum powder (stabilized) (Respirable dust.) US. OSHA Z-1 PEL TWA 5 mg/m? as Al Aluminum powder (stabilized) (Total dust.) US. OSHA Z-1 PEL TWA 15 mg/m? as Al Barium sulphate US. ACGIH TLV TWA 10 mg/m? Barium sulphate (Respirable fraction.) US. OSHA Z-1 PEL TWA 5 mg/m? Calcium carbonate (Total dust.) US. OSHA Z-1 PEL TWA 15 mg/m? Calcium carbonate (Respirable fraction.) US. OSHA Z-1 PEL TWA 5 mg/m? Calcium hydroxide US. ACGIH TLV TWA 5 mg/m? Calcium hydroxide (Respirable fraction.) US. OSHA Z-1 PEL TWA 5 mg/m? Carbon black US. ACGIH TLV TWA 3.5 mg/m? Carbon black US. NIOSH Guide IDLH 1750 mg/m? Carbon black US. OSHA Z-1 PEL TWA 3.5 mg/m? Cellulose US. ACGIH TLV TWA 10 mg/m? Cellulose US. NIOSH Guide IDLH - Cellulose (Respirable fraction.) US. OSHA Z-1 PEL TWA 5 mg/m? Ceramic fiber US. ACGIH TLV TWA 0.2 fibers/cm? Copper (Fume.) US. ACGIH TLV TWA 0.2 mg/m? Copper US. NIOSH Guide IDLH 100 mg/m? Copper (Fume.) US. OSHA Z-1 PEL TWA 0.1 mg/m? as Cu Crystalline silica (Respirable fraction.) US. ACGIH TLV TWA 0.1 mg/m? as quartz Diantimony trioxide US. ACGIH TLV TWA 0.5 mg/m? as Sb Diantimony trioxide US. NIOSH Guide IDLH 50 mg/m? Diantimony trioxide US. OSHA Z-1 PEL TWA 0.5 mg/m? as Sb Glass fiber (Inhalable fraction.) US. ACGIH TLV TWA 5 mg/m? Glass fiber US. NIOSH Guide IDLH - Graphite (Respirable fraction.) US. ACGIH TLV TWA 2 mg/m? Graphite US. NIOSH Guide IDLH 1250 mg/m? ABEX, FA, FERODO, FM, GNBX, TQ, WE, BBS (see section 16) 24-Mar-2011 NORTH AMERICAN MSDS 5 / 10 Graphite US. OSHA Z-3 PEL TWA 15 Mppcf Limestone US. NIOSH Guide IDLH - Limestone (Respirable fraction.) US. OSHA Z-1 PEL TWA 5 mg/m? Mica (Respirable fraction.) US. ACGIH TLV TWA 3 mg/m? Mica US. NIOSH Guide IDLH 1500 mg/m? Mica US. OSHA Z-3 PEL TWA 20 Mppcf Silicon oxide US. NIOSH Guide IDLH 3000 mg/m? Silicon oxide US. OSHA Z-3 PEL TWA 20 Mppcf Talc (Respirable fraction.) US. ACGIH TLV TWA 2 mg/m? Talc US. NIOSH Guide IDLH 1000 mg/m? Talc US. OSHA Z-3 PEL TWA 20 Mppcf Talc (Respirable.) US. OSHA Z-3 PEL TWAC 0.1 mg/m? 2.4 Mppcf Talc (Total dust.) US. OSHA Z-3 PEL OSHA Z3 (TWA) 0.3 mg/m? Zinc Oxide (Respirable fraction.) US. ACGIH TLV TWA 2 mg/m? Zinc Oxide (Respirable fraction.) US. ACGIH TLV STEL 10 mg/m? Zinc Oxide US. NIOSH Guide IDLH 500 mg/m? Zinc Oxide (Fume.) US. OSHA Z-1 PEL TWA 5 mg/m? Zinc Oxide (Respirable fraction.) US. OSHA Z-1 PEL TWA 5 mg/m? Consult Canadian Provincial Regulations and/or Mexican Regulations on exposure limits, if applicable. Engineering Controls: Use explosion-proof electrical equipment if airborne dust levels are high. Provide adequate ventilation. Observe occupational exposure limits and minimize the risk of inhalation of dust. Respiratory Protection: During dust-raising work: Respirator type: Air-purifying respirator with a high efficiency particulate filter. Eye Protection: Wear approved safety goggles. Hand Protection: Wear protective gloves. Suitable gloves can be recommended by the glove supplier. Skin Protection: Wear suitable protective clothing. Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Observe any medical surveillance requirements. Environmental Exposure Controls: Environmental manager must be informed of all major spillages. 9 PHYSICAL AND CHEMICAL PROPERTIES Color: Gray Odor: Resin Odor Threshold: No data available. Physical State: Linings pH: No data available Melting Point: No data available. ABEX, FA, FERODO, FM, GNBX, TQ, WE, BBS (see section 16) 24-Mar-2011 NORTH AMERICAN MSDS 6 / 10 Freezing Point: Not applicable. Boiling Point: No data available. Flash Point: No data available. Evaporation Rate: No data available. Flammability Limit - Upper (%): No data available. Flammability Limit - Lower (%): No data available. Vapor Pressure: No data available. Vapor Density (Air=1): No data available. Specific Gravity: 2.2 - 3.2 (20?C) Solubility in Water: No data available. Solubility (Other): No data available. Partition Coefficient (n-Octanol/water): No data available. Autoignition Temperature: No data available. Decomposition Temperature: No data available. Volatile Organic Compounds (VOC): Not applicable. Viscosity: Not applicable. 10 STABILITY AND REACTIVITY Stability: Material is stable under normal conditions. Conditions to Avoid: None known. Incompatible Materials: Oxidizing agents. Acids. Hazardous Decomposition Products: At Elevated Temperatures: Calcium oxides, Carbon Dioxide, Carbon Monoxide, Metallic fumes, Sulfur Oxides, Zinc oxides Possibility of Hazardous Reactions: Will not occur. 11 TOXICOLOGICAL INFORMATION Acute Toxicity: Specified Substance(s) Chemical Name Test Results Aluminium oxide Inhalation TCLo-Lowest Toxic Conc. (5 hour(s), Rat): 200 mg/m? Aluminium oxide Intraperitoneal LD50 (Mouse): >3600 mg/kg Calcium carbonate Oral LD50 (Rat): 6450 mg/kg Calcium hydroxide Oral LD50 (Rat): 7340 mg/kg Diantimony trioxide Oral LD50 (Rat): >34600 mg/kg Carbon black Dermal LD50 (Rabbit): > 3000 mg/kg Carbon black Oral LD50 (Rat): > 15400 mg/kg Sulfur Dermal LD50 (Rat): > 2020 mg/kg Sulfur Oral LD50 (Rat): > 5050 mg/kg Cellulose Inhalation LC50 (4 hour(s), Rat): >5800 mg/m? Zinc Oxide Inhalation LC50 (Mouse): 2500 mg/m? Zinc Oxide Oral LD50 (Rat): 8437 mg/kg ABEX, FA, FERODO, FM, GNBX, TQ, WE, BBS (see section 16) 24-Mar-2011 NORTH AMERICAN MSDS 7 / 10 Listed Carcinogens: Chemical Name IARC NTP OSHA ACGIH Silicon oxide 3 Not Listed Not Listed Not Listed Ceramic fiber 2B Not Listed Not Listed A2 Crystalline silica 1 Listed Not Listed Not Listed Wollastonite 3 Not Listed Not Listed Not Listed Talc Not Listed Not Listed Not Listed A4 Diantimony trioxide 2B Not Listed Not Listed A2 Para-aramid polymer 3 Not Listed Not Listed Not Listed Carbon black 2B Not Listed Not Listed A4 IARC: 1 = Carcinogenic to Humans; 2A = Probably Carcinogenic to Humans; 2B = Possibly Carcinogenic to Humans; 3 = Not classifiable as to carcinogenicity to humans; 4 = Probably not carcinogenic to humans; Not listed = Not evaluated by IARC. ACGIH: A1 = Confirmed Human Carcinogen; A2 = Suspected Human Carcinogen; A3 = Confirmed Animal Carcinogen; A4 = Not classifiable as a human carcinogen; A5 = Not suspected to be a human carcinogen; Not listed = Not evaluated by ACGIH. Acute Toxicity: Product Information Test Results: No test data available for the product. Other Acute: The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. Harmful if inhaled. Causes skin, eye and respiratory tract irritation. May cause allergic skin reaction. Inhalation of powder or fumes may cause metal fume fever. Chronic Toxicity: The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. Cancer hazard - can cause cancer. May cause lung damage. Prolonged and repeated overexposure to dust can lead to benign pneumoconiosis. May cause damage to the liver and kidneys. 12 ECOLOGICAL INFORMATION Ecotoxicity: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Specified Substance(s) Chemical Name Test Calcium hydroxide LC50 (96 hour(s), Fish): 33.9 mg/l Carbon black EC50 (24 hour(s), Daphnia magna): >5600 mg/l Carbon black EC50 (72 hour(s), Green alga): >10000 mg/l Carbon black LC50 (96 hour(s), Zebra Fish): >1000 mg/l Mobility: The product is insoluble in water and will sediment in water systems. Persistence and Degradability: The product contains inorganic compounds which are not biodegradable. Bioaccumulation Potential: No data available. Other Adverse Effects: No data available. ABEX, FA, FERODO, FM, GNBX, TQ, WE, BBS (see section 16) 24-Mar-2011 NORTH AMERICAN MSDS 8 / 10 13 DISPOSAL CONSIDERATIONS General Information: Dispose of waste and residues in accordance with local authority requirements. Disposal Methods: Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Container: Since emptied containers retain product residue, follow label warnings even after container is emptied. 14 TRANSPORT INFORMATION DOT Not regulated. TDG Not regulated. IATA Not regulated. IMDG Not regulated. 15 REGULATORY INFORMATION Canadian Controlled Products Regulations: This product has been classified according to the hazard criteria of the Canadian Controlled Products Regulations, Section 33, and the MSDS contains all required information. WHMIS Classification: D2A, D2B Mexican Dangerous Statement: This product is dangerous according to Mexican regulations. US Regulations CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Name RQ Copper 5000 lbs Barium sulphate 1000 lbs Diantimony trioxide 1000 lbs Zinc Oxide - - : No reportable quantity. Section 302 Extremely Hazardous Substances (40 CFR 355, Appendix A): Not regulated. SARA Title III Section 311/312 (40 CFR 370): X Acute (Immediate) X Chronic (Delayed) Fire Reactive Pressure Generating Section 313 Toxic Release Inventory (40 CFR 372): Chemical Name CAS-No. Reporting threshold for other users Reporting threshold for manufacturing ABEX, FA, FERODO, FM, GNBX, TQ, WE, BBS (see section 16) 24-Mar-2011 NORTH AMERICAN MSDS 9 / 10 and processing Copper 7440-50-8 10000 lbs 25000 lbs Diantimony trioxide 1309-64-4 10000 lbs 25000 lbs Aluminum (Fume or dust) 7429-90-5 10000 lbs 25000 lbs Aluminium oxide 1344-28-1 10000 lbs 25000 lbs Zinc Oxide 1314-13-2 10000 lbs 25000 lbs For reporting purposes: the De Minimis Concentration for a toxic chemical in a mixture is 0.1% for carcinogens as defined in 29 CFR 1910.1200(d)(4) or 1% for others. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3): Diantimony trioxide Drug Enforcement Act: Not regulated. TSCA TSCA Section 4(a) Final Test Rules & Testing Consent Orders: Not regulated. TSCA Section 5(a)(2) Final Significant New Use Rules (SNURs) (40CFR 721, Subpt. E): Not regulated. TSCA Section 5(e) PMN-Substance Consent Orders: Not regulated. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D): Ceramic fiber State Regulations California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): Carbon black; Crystalline silica; Diantimony trioxide Massachusetts Right-To-Know List: Aluminium oxide; Aluminum powder (stabilized); Barium sulphate; Calcium carbonate; Calcium hydroxide; Carbon black; Cellulose; Copper; Crystalline silica; Diantimony trioxide; Glass fiber; Graphite; Limestone; Mica; Silicon oxide; Sulfur; Talc; Zinc Oxide Michigan Critical Materials List (Michigan Natural Resources and Environmental Protection Act (Act. 451 of 1994)): Copper Minnesota Hazardous Substances List: Aluminium oxide; Aluminum powder (stabilized); Barium sulphate; Calcium hydroxide; Carbon black; Cellulose; Copper; Crystalline silica; Diantimony trioxide; Glass fiber; Graphite; Limestone; Mica; Silicon oxide; Zinc Oxide New Jersey Right-To-Know List: Aluminium oxide; Aluminum powder (stabilized); Barium sulphate; Calcium hydroxide; Carbon black; Copper; Crystalline silica; Diantimony trioxide; Glass fiber; Mica; Silicon oxide; Sulfur; Talc; Zinc Oxide Pennsylvania Right-To-Know List: Aluminium oxide; Aluminum powder (stabilized); Barium sulphate; Calcium carbonate; Calcium hydroxide; Carbon black; Cellulose; Copper; Crystalline silica; Diantimony trioxide; Glass fiber; Graphite; Limestone; Mica; Silicon oxide; Sulfur; Talc; Zinc Oxide ABEX, FA, FERODO, FM, GNBX, TQ, WE, BBS (see section 16) 24-Mar-2011 NORTH AMERICAN MSDS 10 / 10 Rhode Island Right-To-Know List: Aluminium oxide; Calcium hydroxide; Carbon black; Cellulose; Copper; Crystalline silica; Diantimony trioxide; Glass fiber; Graphite; Limestone; Mica; Sulfur; Talc; Zinc Oxide 16 OTHER INFORMATION HAZARD RATINGS Health Hazard Fire Hazard Instability Special Hazard NFPA 2 1 0 -- Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe NFPA Label colored diamond code: Blue - Health; Red - Flammability; Yellow - Instability; White - Special Hazards Health Hazard Flammability Physical Hazard Personal Protection HMIS 2* 1 0 E Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe *- Chronic Health Effect Personal Protection codes: E - Safety Glasses, Gloves, Dust Respirator HMIS Label colored bar code: Blue - Health; Red - Flammability; Orange - Physical Hazards; White - Special General Information: ABEX (6020, 6035, 6037, 6047, 6048, 6068, 6079, 6080, 6082, 6097, 6103, 6110, 6125, 6126, 6127, 6135, 6150, 6206, 6224, 685, 697) FA (903, 904, 906, 908, 910, 912, 916, NB-1, PM23-1) FERODO (3038, 3057, 3074, 3075, 3076, 3102, 3135, 3137, 3165, 3169, 3172, 3177, 3184, 3185, 3187, 3190, 3198, 372, 373, 374, 3219) FM (2031, 2041, 2058, 2059, 2088, 2089, 2090, 2100, 2116, 2151, 2153, 2181, 2185, 2188, 2189, 2200, 2202, 2203, 2204, 2206, 2216, 2237) BBS 34, GNBX (3) TQ (201, 202, 204, 205, 206, 207, 208, 209, 210, 211, 212, 213, 214) WE (103,105, 106,130, 133, 134,147,153, 155, 156,157, 158, 159,160,161, 162, 163, 164, 167, 168, 169, 170, 171, 172, 173, 174, 175) Issued by: Federal-Mogul Corporation Issue Date: 24-Mar-2011 Supercedes Date: 23-Mar-2011 SDS No.: 1029914 Disclaimer: The information provided on this data sheet was abstracted from supplier material safety data sheets and standard references in occupational health and toxicology. Federal-Mogul makes no representation or warranty with respect to the information obtained from such references. The information is however, as of the date provided, true and accurate to the best of Federal-Mogul's knowledge, and should be used to make an independent determination of the methods to safeguard workers and the environment.