FA512 919628 Version #: 01 Revision date: - Issue date: 24-March-2014 CPH MSDS NA 1 / 9 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name FA512 Version # 01 Issue date 24-March-2014 Revision date - Supersedes date - CAS # Mixture Product code 338 Product use Friction material, disc brake pad. Manufacturer information Manufacturer/Supplier Federal-Mogul World Headquarters 26555 Northwestern Highway Southfield, Michigan 48033 USA Contact person: This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency Telephone: 24hr EP (INFOTRAC): 1-800-535-5053 International: (001) 352-323-3500 2. Hazards Identification Physical state Solid. Appearance Solid (article). Emergency overview Low hazard for recommended handling by trained personnel. Dust can be created by the machining of finished products. OSHA regulatory status Under some use conditions, this material may be considered to be hazardous in accordance with OSHA 29 CFR 1910.1200. Potential health effects Routes of exposure Not relevant, due to the form of the product in its manufactured and shipped state. Eyes Dust may irritate the eyes. Skin The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. Dust may irritate skin. Inhalation The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. Dust may irritate the respiratory system. Inhalation of powder or fumes may cause metal fume fever. Inhalation may lead to deposition in lung and in sufficient quantities produce baritosis. Ingestion The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. May cause discomfort if swallowed. Target organs Eyes. Respiratory system. Skin. Lung. Kidneys. Liver. Chronic effects The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. May cause lung damage. May cause damage to the liver and kidneys. Signs and symptoms Exposed individuals may experience eye tearing, redness, and discomfort. Potential environmental effects Not relevant, due to the form of the product in its manufactured and shipped state. 3. Composition / Information on Ingredients Components CAS # Percent Barium sulphate Zirconium dioxide Graphite Calcium carbonate 7727-43-7 10 - 30 1314-23-4 10 - 30 7782-42-5 5 - 10 471-34-1 3 - 7 FA512 919628 Version #: 01 Revision date: - Issue date: 24-March-2014 CPH MSDS NA 2 / 9 Components CAS # Percent Copper Mica Wollastonite Antimony sulfide Aramid fiber Calcium hydroxide 7440-50-8 3 - 7 12001-26-2 3 - 7 13983-17-0 1 - 5 1345-04-6 1 - 5 26125-61-1 1 - 5 1305-62-0 0.01 - 1 Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First Aid Measures First aid procedures The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. This product contains a variety of ingredients all of which have become part of a bound system both physically and chemically and do not necessarily exhibit the properties of the individual components. Eye contact Dust in the eyes: Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids wide apart. Get medical attention if irritation develops and persists. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if irritation develops and persists. Inhalation Move injured person into fresh air and keep person calm under observation. If necessary, seek hospital and take along these instructions. Ingestion If swallowed, rinse mouth with water (only if the person is conscious). Get medical attention if any discomfort continues. Notes to physician Treat symptomatically. General advice Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire Fighting Measures Flammable properties This product is not flammable. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment and precautions for firefighters Fire fighting equipment/instructions Hazardous combustion products Use fire-extinguishing media appropriate for surrounding materials. None. By heating and fire, toxic vapors/gases may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Use standard firefighting procedures and consider the hazards of other involved materials. Carbon dioxide. Carbon monoxide. Metallic fumes. General fire hazards This product is not flammable. Will burn if involved in a fire. 6. Accidental Release Measures Personal precautions Use explosion-proof electrical equipment if airborne dust levels are high. Avoid dust formation. Avoid inhalation of dust and contact with skin and eyes. Wear necessary protective equipment. See Section 8 of the MSDS for Personal Protective Equipment. Environmental precautions Avoid discharge into drains, water courses or onto the ground. Collect and dispose of spillage as indicated in Section 13 of the MSDS. Methods for containment In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. FA512 919628 Version #: 01 Revision date: - Issue date: 24-March-2014 CPH MSDS NA 3 / 9 Methods for cleaning up Collect powder using special dust vacuum cleaner with particle filter or carefully sweep into closed container. Do not vacuum clean unless vacuum cleaners are equipped with HEPA filter. For waste disposal, see Section 13 of the MSDS. 7. Handling and Storage Handling Provide adequate ventilation. Avoid dust formation. Avoid inhalation of dust and contact with skin and eyes. Use work methods which minimize dust production. See Section 8 of the MSDS for Personal Protective Equipment. Observe good industrial hygiene practices. Storage Store in tightly closed original container. Avoid conditions which create dust. Protect against direct sunlight. Store away from incompatible materials. 8. Exposure Controls / Personal Protection Occupational exposure limits US. ACGIH Threshold Limit Values Components Type Value Form Antimony sulfide (CAS 1345-04-6) Barium sulphate (CAS 7727-43-7) Calcium hydroxide (CAS 1305-62-0) Copper (CAS 7440-50-8) Graphite (CAS 7782-42-5) Mica (CAS 12001-26-2) Zirconium dioxide (CAS 1314-23-4) TWA 0.5 mg/m3 TWA 10 mg/m3 TWA 5 mg/m3 TWA 1 mg/m3 Dust and mist. 0.2 mg/m3 Fume. TWA 2 mg/m3 Respirable fraction. TWA 3 mg/m3 Respirable fraction. STEL 10 mg/m3 TWA 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Form Antimony sulfide (CAS 1345-04-6) Barium sulphate (CAS 7727-43-7) Calcium carbonate (CAS 471-34-1) Calcium hydroxide (CAS 1305-62-0) Copper (CAS 7440-50-8) Graphite (CAS 7782-42-5) Zirconium dioxide (CAS 1314-23-4) US. OSHA Table Z-3 (29 CFR 1910.1000) PEL 0.5 mg/m3 PEL 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. PEL 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. PEL 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. PEL 1 mg/m3 Dust and mist. 0.1 mg/m3 Fume. PEL 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. PEL 5 mg/m3 Components Type Value Graphite (CAS 7782-42-5) Mica (CAS 12001-26-2) TWA 15 millions of particle TWA 20 mppcf Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Components Type Value Form Antimony sulfide (CAS 1345-04-6) Barium sulphate (CAS 7727-43-7) TWA 0.5 mg/m3 TWA 10 mg/m3 FA512 919628 Version #: 01 Revision date: - Issue date: 24-March-2014 CPH MSDS NA 4 / 9 Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Components Type Value Form Calcium carbonate (CAS 471-34-1) Calcium hydroxide (CAS 1305-62-0) Copper (CAS 7440-50-8) Graphite (CAS 7782-42-5) Mica (CAS 12001-26-2) Zirconium dioxide (CAS 1314-23-4) TWA 10 mg/m3 TWA 5 mg/m3 TWA 1 mg/m3 Dust and mist. 0.2 mg/m3 Fume. TWA 2 mg/m3 Respirable. TWA 3 mg/m3 Respirable. STEL 10 mg/m3 TWA 5 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Components Type Value Form Antimony sulfide (CAS 1345-04-6) Barium sulphate (CAS 7727-43-7) Calcium carbonate (CAS 471-34-1) Calcium hydroxide (CAS 1305-62-0) Copper (CAS 7440-50-8) Graphite (CAS 7782-42-5) Mica (CAS 12001-26-2) Zirconium dioxide (CAS 1314-23-4) TWA 0.5 mg/m3 TWA 3 mg/m3 Respirable fraction. 10 mg/m3 Total dust. STEL 20 mg/m3 Total dust. TWA 3 mg/m3 Respirable fraction. 10 mg/m3 Total dust. TWA 5 mg/m3 TWA 1 mg/m3 Dust and mist. 0.2 mg/m3 Fume. TWA 2 mg/m3 Respirable. TWA 3 mg/m3 Respirable. STEL 10 mg/m3 TWA 5 mg/m3 Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act) Components Type Value Form Antimony sulfide (CAS 1345-04-6) Barium sulphate (CAS 7727-43-7) Calcium hydroxide (CAS 1305-62-0) Copper (CAS 7440-50-8) Graphite (CAS 7782-42-5) Mica (CAS 12001-26-2) Zirconium dioxide (CAS 1314-23-4) TWA 0.5 mg/m3 TWA 10 mg/m3 TWA 5 mg/m3 TWA 1 mg/m3 Dust and mist. 0.2 mg/m3 Fume. TWA 2 mg/m3 Respirable fraction. TWA 3 mg/m3 Respirable fraction. STEL 10 mg/m3 TWA 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Components Type Value Form Antimony sulfide (CAS 1345-04-6) Barium sulphate (CAS 7727-43-7) Calcium hydroxide (CAS 1305-62-0) Copper (CAS 7440-50-8) Graphite (CAS 7782-42-5) TWA 0.5 mg/m3 TWA 10 mg/m3 TWA 5 mg/m3 TWA 0.2 mg/m3 Fume. TWA 2 mg/m3 Respirable fraction. FA512 919628 Version #: 01 Revision date: - Issue date: 24-March-2014 CPH MSDS NA 5 / 9 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Components Type Value Form Mica (CAS 12001-26-2) Zirconium dioxide (CAS 1314-23-4) TWA 3 mg/m3 Respirable fraction. STEL 10 mg/m3 TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Components Type Value Form Antimony sulfide (CAS 1345-04-6) Barium sulphate (CAS 7727-43-7) Calcium carbonate (CAS 471-34-1) Calcium hydroxide (CAS 1305-62-0) Copper (CAS 7440-50-8) Graphite (CAS 7782-42-5) Mica (CAS 12001-26-2) Wollastonite (CAS 13983-17-0) Zirconium dioxide (CAS 1314-23-4) TWA 0.5 mg/m3 TWA 5 mg/m3 Respirable dust. 10 mg/m3 Total dust. TWA 10 mg/m3 Total dust. TWA 5 mg/m3 TWA 1 mg/m3 Dust and mist. 0.2 mg/m3 Fume. TWA 2 mg/m3 Respirable dust. TWA 3 mg/m3 Respirable dust. TWA 10 mg/m3 Fiber. STEL 10 mg/m3 TWA 5 mg/m3 Mexico. Occupational Exposure Limit Values Components Type Value Form Antimony sulfide (CAS 1345-04-6) Calcium carbonate (CAS 471-34-1) Calcium hydroxide (CAS 1305-62-0) Copper (CAS 7440-50-8) Graphite (CAS 7782-42-5) Mica (CAS 12001-26-2) Zirconium dioxide (CAS 1314-23-4) TWA 0.5 mg/m3 STEL 20 mg/m3 TWA 10 mg/m3 TWA 5 mg/m3 STEL 2 mg/m3 Fume. 2 mg/m3 Dust and mist. TWA 1 mg/m3 Dust and mist. 0.2 mg/m3 Fume. TWA 10 mg/m3 TWA 3 mg/m3 STEL 10 mg/m3 TWA 5 mg/m3 Engineering controls Use explosion-proof electrical equipment if airborne dust levels are high. Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of inhalation of dust. Personal protective equipment Eye / face protection Wear approved safety goggles. Skin protection Wear protective gloves (i.e. latex, nitrile). Wear suitable protective clothing. Suitable gloves can be recommended by the glove supplier. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. During dust-raising work: In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 1910.134. Respirator type: Any powered, air-purifying respirator with a high-efficiency particulate filter. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. FA512 919628 Version #: 01 Revision date: - Issue date: 24-March-2014 CPH MSDS NA 6 / 9 9. Physical & Chemical Properties Appearance Solid (article). Physical state Solid. Form Solid (Disc pad). Color Gray. Odor None. Odor threshold Not applicable. pH Not applicable. Vapor pressure Not applicable. Vapor density Not applicable. Boiling point Not applicable. Melting point/Freezing point Not applicable. Solubility (water) Not available. Specific gravity 2 - 3 (20 ?C) Flash point Not applicable. Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Not applicable. Not applicable. Auto-ignition temperature Not applicable. 10. Chemical Stability & Reactivity Information Chemical stability Material is stable under normal conditions. Conditions to avoid None known. Incompatible materials None. Hazardous decomposition products Possibility of hazardous reactions Carbon dioxide. Carbon monoxide. Metallic fumes. Will not occur. 11. Toxicological Information Toxicological data Components Species Calcium carbonate (CAS 471-34-1) Acute Oral LD50 Rat Calcium hydroxide (CAS 1305-62-0) Acute Oral LD50 Rat Sensitization Not a skin sensitizer. Test Results 6450 mg/kg 7340 mg/kg Acute effects The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. Dust may cause eye, skin and respiratory tract irritation. Inhalation may lead to deposition in lung and in sufficient quantities produce baritosis. Inhalation of powder or fumes may cause metal fume fever. Chronic effects The ingredients may be released as general dust from the product by operations such as overheating, burning, machining, abrading, or riveting. May cause lung damage. May cause damage to the liver and kidneys. Carcinogenicity Not classified. ACGIH Carcinogens Zirconium dioxide (CAS 1314-23-4) A4 Not classifiable as a human carcinogen. FA512 919628 Version #: 01 Revision date: - Issue date: 24-March-2014 CPH MSDS NA 7 / 9 IARC Monographs. Overall Evaluation of Carcinogenicity Antimony sulfide (CAS 1345-04-6) 3 Not classifiable as to carcinogenicity to humans. Aramid fiber (CAS 26125-61-1) 3 Not classifiable as to carcinogenicity to humans. Wollastonite (CAS 13983-17-0) 3 Not classifiable as to carcinogenicity to humans. Mutagenicity No data available. Reproductive effects No data available. Symptoms and target organs Exposed individuals may experience eye tearing, redness, and discomfort. 12. Ecological Information Ecotoxicological data Components Barium sulphate (CAS 7727-43-7) Aquatic Crustacea EC50 Species Tubificid worm (Tubifex tubifex) Test Results 28.61 - 38.03 mg/l, 48 hours Calcium hydroxide (CAS 1305-62-0) Aquatic Fish Copper (CAS 7440-50-8) Aquatic Crustacea Fish LC50 EC50 LC50 LC50 Zambezi barbel (Clarias gariepinus) Water flea (Daphnia magna) Water flea (Daphnia magna) Chinook salmon (Oncorhynchus tshawytscha) Oncorhynchus mykiss 33.8844 mg/l, 96 hours 0.0318 mg/l, 48 hours 0.04 - 0.05 mg/l, 48 hours 0.02 mg/l, 96 hours 200 ?g/l, 96 hours Ecotoxicity Not relevant, due to the form of the product in its manufactured and shipped state. Persistence and degradability The product contains inorganic compounds which are not biodegradable. Bioaccumulation / Accumulation Mobility in environmental media No data available. The product is insoluble in water and will sediment in water systems. 13. Disposal Considerations Disposal instructions Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Waste from residues / unused products Dispose of waste and residues in accordance with local authority requirements. Contaminated packaging Since emptied containers retain product residue, follow label warnings even after container is emptied. 14. Transport Information DOT Not regulated as a hazardous material by DOT. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. TDG Not regulated as dangerous goods. 15. Regulatory Information US federal regulations Under some use conditions, this material may be considered to be hazardous in accordance with OSHA 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. FA512 919628 Version #: 01 Revision date: - Issue date: 24-March-2014 CPH MSDS NA 8 / 9 Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Antimony sulfide (CAS 1345-04-6) US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration Antimony sulfide (CAS 1345-04-6) 1.0 % N010 Copper (CAS 7440-50-8) 1.0 % US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Antimony sulfide (CAS 1345-04-6) N010 Listed. Copper (CAS 7440-50-8) Listed. CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4) Barium sulphate: 1000 Copper: 5000 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical Drug Enforcement Administration (DEA) (21 CFR 1308.11-15) No Not controlled Canadian regulations This product has been classified according to the hazard criteria of the Canadian Controlled Products Regulations, Section 33, and the MSDS contains all required information. WHMIS status Non-controlled Inventory status Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US - California Hazardous Substances (Director's): Listed substance Antimony sulfide (CAS 1345-04-6) Listed. Calcium hydroxide (CAS 1305-62-0) Listed. Copper (CAS 7440-50-8) Listed. Graphite (CAS 7782-42-5) Listed. Mica (CAS 12001-26-2) Listed. Wollastonite (CAS 13983-17-0) Listed. Zirconium dioxide (CAS 1314-23-4) Listed. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed. US. Massachusetts RTK - Substance List Barium sulphate (CAS 7727-43-7) Listed. Calcium carbonate (CAS 471-34-1) Listed. Calcium hydroxide (CAS 1305-62-0) Listed. Copper (CAS 7440-50-8) Listed. Graphite (CAS 7782-42-5) Listed. Mica (CAS 12001-26-2) Listed. Zirconium dioxide (CAS 1314-23-4) Listed. US. New Jersey Worker and Community Right-to-Know Act Antimony sulfide (CAS 1345-04-6) Barium sulphate (CAS 7727-43-7) Calcium carbonate (CAS 471-34-1) Calcium hydroxide (CAS 1305-62-0) Copper (CAS 7440-50-8) Graphite (CAS 7782-42-5) FA512 919628 Version #: 01 Revision date: - Issue date: 24-March-2014 CPH MSDS NA 9 / 9 Mica (CAS 12001-26-2) US. Pennsylvania Worker and Community Right-to-Know Law Barium sulphate (CAS 7727-43-7) Calcium carbonate (CAS 471-34-1) Calcium hydroxide (CAS 1305-62-0) Copper (CAS 7440-50-8) Graphite (CAS 7782-42-5) Mica (CAS 12001-26-2) 16. Other Information Further information HMIS? is a registered trade and service mark of the NPCA. Dash ?-?next to each of the entries for the HMIS and NFPA ratings indicates Not Applicable. HMIS? ratings Health: - Flammability: - Physical hazard: - NFPA Ratings - - - Disclaimer The information provided on this data sheet was abstracted from supplier material safety data sheets and standard references in occupational health and toxicology. Federal-Mogul makes no representation or warranty with respect to the information obtained from such references. The information is however, as of the date provided, true and accurate to the best of Federal-Mogul's knowledge, and should be used to make an independent determination of the methods to safeguard workers and the environment.