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PM19500-1000_lacquer_touch-up_paint_primer_msds.pdf
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WARN Specified stream length 6928 is wrong. Fall back to reading stream until 'endstream'. WARN Specified stream length 29231 is wrong. Fall back to reading stream until 'endstream'. WARN Specified stream length 25193 is wrong. Fall back to reading stream until 'endstream'. WARN Did not found XRef object at specified startxref position 208008 WARN /Length of COSObject{5, 0} corrected from 3323 to 3368 WARN /Length of COSObject{10, 0} corrected from 7166 to 7262 WARN /Length of COSObject{11, 0} corrected from 338 to 344 WARN /Length of COSObject{15, 0} corrected from 2378 to 2411 WARN /Length of COSObject{17, 0} corrected from 7166 to 7262 WARN /Length of COSObject{20, 0} corrected from 3475 to 3522 WARN /Length of COSObject{22, 0} corrected from 7166 to 7262 WARN /Length of COSObject{25, 0} corrected from 2866 to 2905 WARN /Length of COSObject{27, 0} corrected from 7166 to 7262 WARN /Length of COSObject{30, 0} corrected from 2875 to 2914 WARN /Length of COSObject{35, 0} corrected from 2119 to 2148 WARN /Length of COSObject{32, 0} corrected from 7166 to 7262 WARN /Length of COSObject{37, 0} corrected from 7166 to 7262 WARN /Length of COSObject{42, 0} corrected from 7166 to 7262 WARN /Length of COSObject{40, 0} corrected from 3008 to 3049 WARN /Length of COSObject{47, 0} corrected from 7166 to 7262 WARN /Length of COSObject{45, 0} corrected from 2389 to 2422 WARN /Length of COSObject{50, 0} corrected from 3641 to 3690 WARN /Length of COSObject{55, 0} corrected from 2931 to 2971 WARN /Length of COSObject{52, 0} corrected from 7166 to 7262 WARN /Length of COSObject{57, 0} corrected from 7166 to 7262 WARN /Length of COSObject{62, 0} corrected from 7166 to 7262 WARN /Length of COSObject{60, 0} corrected from 2875 to 2914 WARN /Length of COSObject{70, 0} corrected from 1406 to 1426 WARN /Length of COSObject{65, 0} corrected from 3311 to 3356 WARN /Length of COSObject{67, 0} corrected from 7166 to 7262 WARN /Length of COSObject{72, 0} corrected from 7166 to 7262 WARN /Length of COSObject{75, 0} corrected from 275 to 280 WARN /Length of COSObject{85, 0} corrected from 615 to 625 WARN /Length of COSObject{80, 0} corrected from 686 to 697 OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 040056 US-US-10 Level: 3 Release Date: 2013-02-26 Page: 1 / FIR No.: 13 1. Product and Company Identification Product Name: Product Code: Application: Supplier: Emergency Telephone: Lacquer Touch-Up Paint - Primer See Attachment Automotive exterior touch-up paint Ford Motor Company Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 1-800-392-3673 Poison Control Center: 1-800-959-3673 CHEMTREC: U.S. and Canada: 1-800-424-9300 CHEMTREC: International: 1-703-527-3887 Chemical Name CAS Number Percent Concentration Hazard Classification METHYL ETHYL KETONE TITANIUM DIOXIDE TALC METHYL ALCOHOL 78-93-3 13463-67-7 14807-96-6 67-56-1 30-60 5-10 5-10 1-5 LOCAL REV 1 HAZCOM DSL LISTED CANPRECURS OR WHMIS 1 PEL/TLV-US RQ RSMS_D_ALL ACGIH/OSHA PEL/TLV-US IARC 2B (NA) HAZCOM DSL LISTED ACGIH/OSHA RSMS_D_ALL ACGIH/OSHA PEL/TLV-US HAZCOM DSL LISTED LOCAL REV 1 PEL/TLV-US RQ RSMS_D_ALL SARA 313 HAZCOM WHMIS 1 2. Composition/Information on Ingredients This chemical product is a preparation. OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 040056 US-US-10 Level: 3 Release Date: 2013-02-26 Page: 2 / FIR No.: 13 ISOPROPANOL ISOBUTYL ALCOHOL METHYL ISOBUTYL KETONE TOLUENE CALCIUM CARBONATE 67-63-0 78-83-1 108-10-1 108-88-3 471-34-1 1-5 1-5 1-5 1-5 1-5 CAA-HAP ACGIH/OSHA DSL LISTED ACGIH/OSHA DSL LISTED HAZCOM PEL/TLV-US RSMS_D_ALL SARA 313 WHMIS 1 DSL LISTED ACGIH/OSHA WHMIS 1 RSMS_D_ALL RQ PEL/TLV-US HAZCOM RSMS_D_ALL SARA 313 RQ PEL/TLV-US LOCAL REV 1 HAZCOM DSL LISTED CAA-HAP ACGIH/OSHA WHMIS 1 ACGIH/OSHA CAA-HAP WHMIS 1 SARA 313 RSMS_P_SOM CANPRECURS OR DSL LISTED HAZCOM LOCAL REV 1 PEL/TLV-US RQ RSMS_D_ALL DSL LISTED ACGIH/OSHA HAZCOM PEL/TLV-US OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 040056 US-US-10 Level: 3 Release Date: 2013-02-26 Page: 3 / FIR No.: 13 Health: Environment: Inhalation: Skin Contact: Eye Contact: Ingestion: Most Important Symptoms Effects: Notes to a Physician: Extinguishing Media: Specific Methods: Specific Hazards: Extreme overexposure may result in unconsciousness and possibly death. Inhalation of mist and vapors may irritate the nose, throat, and lungs. May cause skin, eye and respiratory tract irritation. Overexposure may cause central nervous system depression. Overexposure may cause liver, kidney and heart damage. Material contains a chemical which is a Hazardous Air Pollutant (HAP), regulated by the United States Clean Air Act. If gas/fume/vapor/dust/mist from the material is inhaled, remove the affected person immediately to fresh air. If irritation persists, get medical attention. Wash skin with soap and water. If irritation persists, get medical attention. In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes and seek medical attention. If irritation persists, get medical attention. If the material is swallowed, get immediate medical attention or advice -- Do not induce vomiting. Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. This material, if aspirated into the lungs, may cause chemical pneumonitis; treat the affected person appropriately. Dry chemical, foam, carbon dioxide. Water may be an ineffective extinguishing medium. Water may be used to cool exposed containers to prevent pressure build-up and explosion when exposed to extreme heat. Due to pressure buildup, closed containers exposed to excess heat may explode. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 3. Hazards Identification 4. First-Aid Measures 5. Fire-Fighting Measures FLAMMABLE OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 040056 US-US-10 Level: 3 Release Date: 2013-02-26 Page: 4 / FIR No.: 13 Protection of Firefighters: Personal Precautions: Environmental Precautions: Methods for Cleaning Up: Handling: Storage: Fire fighters should be equipped with NIOSH-approved, self-contained breathing apparatus (SCBA) and full protective clothing. Avoid inhalation of vapors and contact with skin and eyes. Eliminate all sources of ignition or flammables that may come into contact with a spill of this material. Ventilate the contaminated area. Wear appropriate protective equipment and clothing during clean-up. Do not allow the spilled product to enter public drainage system or open water courses. Do not allow this material to drain into sewers/water supplies. Absorb the spilled material with an inert absorbent (nonflammable) material. Keep this product from heat, sparks, or open flame. Avoid breathing vapor or mist. Avoid contact with skin, eyes and clothing. Keep area ventilated. Do not smoke. Extinguish all flames, pilot lights, and heaters. Turn off stoves, electric tools and appliances, and any other sources of ignition. Eliminate all sources of ignition. Ground all containers of this material. Keep the container tightly closed and in a cool, well-ventilated place. Keep away from children. Technical Measures: Precautions and Advice for Safe Handling: Technical Measures: Storage Conditions: 6. Accidental Release Measures 7. Handling and Storage OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 040056 US-US-10 Level: 3 Release Date: 2013-02-26 Page: 5 / FIR No.: 13 8. Exposure Controls/Personal Protection Use local exhaust.Engineering Measures: Exposure Limits: 200(ppm) 400(ppm) 100(ppm) 200(ppm) 100(ppm) 200(ppm) Note 15(mg/m3) Note 300(ppm) 75(ppm) C 300(ppm) 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) 20 mppcf TWA (if 1% quartz or more, use quartz limit) OSHA OSHA OSHA OSHA OSHA OSHA OSHA OSHA OSHA METHYL ALCOHOL ISOPROPANOL ISOBUTYL ALCOHOL METHYL ETHYL KETONE METHYL ISOBUTYL KETONE TOLUENE CALCIUM CARBONATE TITANIUM DIOXIDE TALC 200(ppm) 200(ppm) 50(ppm) 200(ppm) 20(ppm) 20(ppm) Note 10(mg/m3) Note 250(ppm) 400(ppm) 300(ppm) 75(ppm) 10 mg/m3 TWA (total dust/particulate) 2 mg/m3 TWA (respirable fraction, particulate matter containing no asbestos and <1% crystalline silica) ACGIH ACGIH ACGIH ACGIH ACGIH ACGIH ACGIH ACGIH ACGIH Chemical Name TWA STEL/C NotesReferences OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 040056 US-US-10 Level: 3 Release Date: 2013-02-26 Page: 6 / FIR No.: 13 When using this material, do not eat, drink or smoke. Personal Protective Equipment: Hygiene Measures: If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Use appropriate dust/mist/fume respirator for operations involving sanding/grinding or welding/flame cutting. The use of butyl rubber gloves is recommended. Wear safety glasses with side shields. Remove contaminated clothing and wash before reuse. Wash thoroughly after handling. Respiratory Protection: Hand Protection: Eye Protection: Skin and Body Protection: OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 040056 US-US-10 Level: 3 Release Date: 2013-02-26 Page: 7 / FIR No.: 13 9. Physical and Chemical Properties 10. Stability and Reactivity 1.07 H2O=1 @4?C LIQUID PAINT LACQUER PAINT GREY N.AP N.AV 2.22 ?C PMCC N.AV N.AV >1 (AIR=1) N.AV N.AV N.AP <1 Ether = 1 This is a stable material. Hazardous polymerization will not occur. Static discharge, friction, sparks, open flames, heat and other sources of ignition. Carbon monoxide, carbon dioxide. Specific Gravity: Physical State: Form: Odor: Color: pH: Temperature Range During which Changes in Physical State Occur: Decomposition Temperature: Flash Point: Auto-ignition Temperature: Explosion Properties: Vapor Pressure: Vapor Density: Octanol Water Partition Coefficient: Solubility: Viscosity: Evaporation Rate: Stability: Conditions and Materials to Avoid: Hazardous Decomposition Products: 64.4-172.2 ?C (148-342F) N.AV N.AP 36.5 % 1 % Boiling Point: Freezing Point: Melting Point: UEL: LEL: OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 040056 US-US-10 Level: 3 Release Date: 2013-02-26 Page: 8 / FIR No.: 13 11. Toxicological Information 67-56-1 METHYL ALCOHOL Inhalation, adult rat, LC50 = 64000 ppm (4 Hours) 108-88-3 TOLUENE Oral, adult rat, LD50 = 5000 mg/kg 67-63-0 ISOPROPANOL Oral, adult rat, LD50 = 5045 mg/kg 108-10-1 METHYL ISOBUTYL KETONE Inhalation, adult rat, LC50 = 8000 ppm (4 Hours) 108-88-3 TOLUENE Inhalation, mouse, LC50 = 5320 ppm (8 Hours) 108-88-3 TOLUENE Skin, adult rabbit, LD50 = 12124 mg/kg 67-56-1 METHYL ALCOHOL Skin, adult rabbit, LD50 = 15800 mg/kg 78-83-1 ISOBUTYL ALCOHOL Skin, adult rabbit, LD50 = 3400 mg/kg 108-10-1 METHYL ISOBUTYL KETONE Oral, adult rat, LD50 = 2080 mg/kg 1330-78-5 TRICRESYL PHOSPHATE Skin, adult cat, LD50 = 1500 mg/kg 763-69-9 ETHYL 3-ETHOXYPROPANOATE Skin, adult rabbit, LD50 = 10 gm/kg 78-93-3 METHYL ETHYL KETONE Inhalation, mouse, LC50 = 40 gm/m3 (2 Hours) 78-93-3 METHYL ETHYL KETONE Oral, adult rat, LD50 = 2737 mg/kg 763-69-9 ETHYL 3-ETHOXYPROPANOATE Oral, adult rat, LD50 = 5000 mg/kg 67-63-0 ISOPROPANOL Skin, adult rabbit, LD50 = 12800 mg/kg 78-83-1 ISOBUTYL ALCOHOL Oral, adult rat, LD50 = 2460 mg/kg 1330-78-5 TRICRESYL PHOSPHATE Oral, adult rat, LD50 = 5190 mg/kg 78-93-3 METHYL ETHYL KETONE Skin, adult rabbit, LD50 = 13 gm/kg 67-56-1 METHYL ALCOHOL Oral, adult rat, LD50 = 5628 mg/kg 471-34-1 CALCIUM CARBONATE Oral, adult rat, LD50 = 6450 mg/kg Excessive inhalation of this material causes headache, dizziness, nausea and incoordination. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis. Inhalation: Skin Contact: OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 040056 US-US-10 Level: 3 Release Date: 2013-02-26 Page: 9 / FIR No.: 13 12. Ecological Information 13. Disposal Considerations No specific aquatic data available for this product. Based on animal studies, exposure to methyl ethyl ketone (MEK) increases the onset of peripheral neuropathy caused by exposure to methyl butyl ketone (MBK), and/or n-hexane, and/or ethyl butyl ketone. MEK alone has not been shown to cause peripheral neuropathy. Ethyl benzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. There is no evidence that ethylbenzene causes cancer in humans. Methanol has produced fetotoxicity in rats and teratogenicity in mice exposed by inhalation to high concentrations that did not produce significant maternal toxicity. Prolonged and repeated exposure of pregnant animals to toluene (concentrations greater than 1500 ppm) has been reported to cause adverse fetal developmental effects. It has also been reported that variable growth deficiencies have occurred in human infants born to mothers who intentionally inhaled toluene containing products (e.g., glue). Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. The National Toxicology Program (NTP) conducted a two year inhalation study of ethylbenzene vapor on laboratory animals. The study revealed that ethylbenzene vapor at 750 ppm produced kidney and testicular tumors in rats and lung and liver tumors in mice. Human data is not available at this time. This material contains an ingredient which is a possible cancer hazard based on tests with laboratory animals. Overexposure may create a cancer risk. This material contains an ingredient which is a possible reproductive hazard based on tests with laboratory animals. This product contains TITANIUM DIOXIDE. Animals inhaling massive quantities of TITANIUM DIOXIDE dust in a long term study developed lung tumors. Studies with humans involved in the manufacture of this pigment indicate no increased risk of cancer from exposure. Potential for inhaltion of TITANIUM DIOXIDE dusts from coatings is very limited. Since overexposures are not expected, there is no significant hazard for man. Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulation. No consideration given when disposed of according to local, state, and Federal regulations. Chronic (Long Term) Toxicity: Waste from Residues: Contaminated Packaging: OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 040056 US-US-10 Level: 3 Release Date: 2013-02-26 Page: 10 / FIR No.: 13 14. Transport Information U.S. Department of Transportation (DOT) 49 - CFR 172.101 Canadian Transportation of Dangerous Goods (T.D.G.) - TDGR Schedule II Proper Shipping Name: UN Number: Hazard Class / Division: Packing Group: Reportable Quantity (per packaging): Proper Shipping Name: UN Number: Hazard Class / Division: Packing Group: Paint UN1263 3 II PAINT UN1263 3 II Regulated Quantity: Regulated Quantity: Bulk Bulk Non-Bulk Non-Bulk Limited Quantity Limited Quantity X X X X Label: Label: FLAMMABLE LIQUID FLAMMABLE LIQUID NameRQCAS METHYL ETHYL KETONE ETHYLBENZENE MALEIC ACID METHYL ISOBUTYL KETONE METHYL ALCOHOL TOLUENE ISOBUTYL ALCOHOL 16129 >100000 >100000 100000 >100000 33333 >100000 78-93-3 100-41-4 110-16-7 108-10-1 67-56-1 108-88-3 78-83-1 OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 040056 US-US-10 Level: 3 Release Date: 2013-02-26 Page: 11 / FIR No.: 13 Secretary of Communication and Transportation (SCT) - NOM-002-SCT2/1994 (Mexico) International and Domestic Air Transportation - ICAO & IATA Section 4.2 International Water Transportation - IMDG Code Amendment 31-02 Proper Shipping Name: UN Number: Hazard Class/Division: Packing Group: Proper Shipping Name: UN Number: Hazard Class/Division: Packing Group: Label: Proper Shipping Name: UN Number: Hazard Class/Division: Flashpoint: Packing Group: Ems Number: PINTURA UN1263 3 II PAINT UN1263 3 II FLAMMABLE LIQUID PAINT UN1263 3 14.4 ?C TCC II 3-05 Regulated Quantity: Regulated Quantity: Bulk Bulk Non-Bulk Non-Bulk Limited Quantity Limited Quantity X X X X Label: Label: FLAMMABLE LIQUID FLAMMABLE LIQUID The components of this product are listed on the TSCA Inventory This product contains a toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 15. Regulatory Information OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 040056 US-US-10 Level: 3 Release Date: 2013-02-26 Page: 12 / FIR No.: 13 California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer. This product contains an ingredient(s) considered to be a hazardous substance by the State of Pennsylvania (Pennsylvania Worker and Community Right to Know Act). This product contains an ingredient(s) considered to be an environmental hazardous substance(s) by the State of New Jersey. This product contains an ingredients(s) considered to be a hazardous substance(s) by the State of New Jersey. Material contains a chemical which is a Ford Motor Company Material of Concern. Use and release of this material should be minimized to the greatest extent possible. 16. Other Information Key/Legend: N.AP = Not applicable; N.AV = Not available; ND = Not determined or No data; TLV = Threshold limit value; TWA = Time-weighted average; STEL = Short-term exposure limit; C = Ceiling limit 8 2 16 15 The chemical identification and properties for this material were provided by the manufacturer. Health and safety information has been evaluated by the Occupational and Environmental Health Sciences Department, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. The following sections contain revisions OR NEW statements. Preparation Information: Disclaimer: HMIS and NFPA Hazard Class Information: HMIS Hazard Class: NFPA Hazard Class: Health: 2 (Moderate) Flammability: 3 (Serious) Physical Hazard: 0 (Least) Health: 2 (Moderate) Flammability: 3 (Serious) Instability: 0 (Least) OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 040056 US-US-10 Level: 3 Release Date: 2013-02-26 Page: 13 / FIR No.: 13 Product Code Container Size Part of Kit Kit Product Code ALBZ-19500-1000 (Obsolete) PMP-19500-1000 0.5 fl. oz. (14.7 mL) 0.5 fl. oz. (14.7 mL) Attachment US-040056-US 1. Product and Company Identification 2. Composition/Information on Ingredients 3. Hazards Identification 4. First-Aid Measures 5. Fire-Fighting Measures 6. Accidental Release Measures 7. Handling and Storage 8. Exposure Controls/Personal Protection 9. Physical and Chemical Properties 10. Stability and Reactivity 11. Toxicological Information 12. Ecological Information 13. Disposal Considerations 14. Transport Information 15. Regulatory Information 16. Other Information Attachment