Prod.Name: GM 12345493 HIGH STRENGTH HIGH TEMPERATURE THREADLOCKER RED Manufacturer: ITW Permatex HMCS ID: 353600 SUC: 05 - Adhesives - Solvent -Based Polyurethanes, Epoxies, and Sealers MATERIAL SAFETY DATA SHEET Revision: 13.Jan.2011 Effective: 13.Jan.2011 Print Date: 06.May.2013 Page: 1 of 5 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT INFORMATION Product Name: GM 12345493 HIGH STRENGTH HIGH TEMPERATURE THREADLOCKER RED External Keys: 89021297 Distributable Material (Part #) HIGH STRENGTH HIGH TEMPERATURE THREADLOCKE R - RED Primary Tradename - Distributable Material MANUFACTURER INFORMATION Manufacturer: ITW Permatex Address: 10 Columbus Blvd. USA Connecticut 06106 Hartford MAILING Communication Lines: Phone 877-376-2839 EMERGENCY Phone 877-376-2839 INFO Phone 800-255-3924 EMERGENCY Phone 813-348-0585 International Emergency Internet www.permatex.com Website (with MSDS) Comment: Process MSDS as OSHA Compliant. 2 INGREDIENT INFORMATION FORMULATION Ingredients: Chemical Name CAS Number Prefix Value Unit Exposure Limits 2-Propenoic acid, 2-methyl-, (1- methylethylidene)bis(4,1- phenyleneoxy-2,1-ethanediyl) ester 24448-20-2 Range 55 - 75 %Wt No 2-Propenoic acid, 2-methyl-, monoester with 1,2-propanediol 27813-02-1 Range 10 - 30 %Wt No MALEIMIDE, N,N'-(m- PHENYLENE)DI- 3006-93-7 Range 10 - 30 %Wt No Siloxanes and Silicones, di-Me, reaction products with silica 67762-90-7 < 3 %Wt No HYDROPEROXIDE, alpha,alpha- DIMETHYLBENZYL- 80-15-9 < 3 %Wt No 3 HAZARDS IDENTIFICATION Hazards Overview: Toxicity: At elevated temperatures may cause irritation of the respiratory tract. Irritates mucous membranes. Ingestion may irritate digestive tract and cause nausea, vomiting and diarrhea. High concentrations may cause central nervous system (CNS) depression. May cause eye and skin irritation. May cause skin sensitization. Note: This product does not contain microcyrstalline silica. Specific Hazards: Primary Routes of Entry: Eye and skin contact, ingestion, inhalation Effects Of Overexposure: Repeated skin contact may cause allergic skin reactions. Skin redness. Ingestion may cause nausea and vomiting. Inhalation overexposure may cause irritation, coughing and flu-like symptoms. May cause pain, redness or swelling of the eyes and excessive blinking and tear production. Prod.Name: GM 12345493 HIGH STRENGTH HIGH TEMPERATURE THREADLOCKER RED Manufacturer: ITW Permatex HMCS ID: 353600 SUC: 05 - Adhesives - Solvent -Based Polyurethanes, Epoxies, and Sealers MATERIAL SAFETY DATA SHEET Revision: 13.Jan.2011 Effective: 13.Jan.2011 Print Date: 06.May.2013 Page: 2 of 5 3 HAZARDS IDENTIFICATION Medical Conditions Aggravated By Exposure: Preexisting skin disorders. Comment: Additional Health Hazard Data: AT ELEVATED TEMPERATURES MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT. IRRITATES MUCOUS MEMBRANES. MAY CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. 4 FIRST AID MEASURES First Aid By:: Inhalation Move to fresh air in case of accidental Inhalation of vapours. Obtain medical attention. Skin Contact Wash off with soap and water. If skin irritation persists, call a physician. Eye Contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. Ingestion If swallowed, DO NOT induce vomiting. Keep individual calm. Obtain medical attention. 5 FIRE FIGHTING MEASURES Flash Point: > 200 ?F Explosive Limits: Lower Explosive Limit (LEL) Not Determined Upper Explosive Limit (UEL) Not Determined Extinguishing Media: Recommended Extinguishing Media: Dry chemical, Carbon dioxide, Foam Fire and Explosion Hazards: Hazardous Products of Combustion: Oxides of carbon Unusual Fire/Explosion Hazards: Closed containers may rupture or explode when exposed to extreme heat. May polymerize exothermically. Special Fire Fighting Procedures: Water spray may be ineffective on flames but should be used to keep fire-exposed containers cool. Comment: Firefighters should wear self-contained breathing apparatus. 6 ACCIDENTAL RELEASE MEASURES SPILL OR LEAK PROCEDURES Recovery: Spill Procedures: Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal. Disposal: Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations. US EPA Waste Number: NH - Not a RCRA Hazardous Waste Material 7 HANDLING AND STORAGE HANDLING Safe Handling Procedures: Avoid prolonged skin contact. Keep away from eyes. Wash thoroughly after handling. STORAGE Storage Conditions: Store in a cool, dry area. Additional Information on Storage Conditions: Prod.Name: GM 12345493 HIGH STRENGTH HIGH TEMPERATURE THREADLOCKER RED Manufacturer: ITW Permatex HMCS ID: 353600 SUC: 05 - Adhesives - Solvent -Based Polyurethanes, Epoxies, and Sealers MATERIAL SAFETY DATA SHEET Revision: 13.Jan.2011 Effective: 13.Jan.2011 Print Date: 06.May.2013 Page: 3 of 5 7 HANDLING AND STORAGE STORAGE Additional Information on Storage Conditions: Precautions to be Taken in Handling and Storage: DO NOT STORE AT OR BELOW 32 DEGREES F, AS INHIBITOR CAN SEPARATE AS A SOLID. PREVENT MOISTURE CONTACT. STORE IN TIGHTLY CLOSED CONTAINERS AWAY FROM HEAT, SPARKS, OPEN FLAME, OXIDIZERS, RADIATION AND OTHER INITIATORS. PREVENT CONTAMINATION BY FOREIGN MATERIALS. USE ONLY NON-SPARKING TOOLS. AVOID PROLONGED SKIN CONTACT. KEEP AWAY FROM EYES. UNLESS INHIBITED, PRODUCT CAN POLYMERIZE, RAISING TEMPERATURE AND PRESSURE AND POSSIBLY RUPTURING THE CONTAINER. DO NOT BLANKET OR MIX WITH OXYGEN-FREE GAS AS IT RENDERS THE INHIBITOR INEFFECTIVE. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: Ventilation: General; local exhaust ventilation as necessary to control any air contaminants to within their exposure limits (or to the lowest feasible levels when limits have not been established) during the use of this product. PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment (PPE): Eye Protection Safety glasses. Respiratory Protection An approved organic vapor respirator should be worn when exposures are expected to exceed the applicable limits. Hand Protection Neoprene or nitrile gloves recommended. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Color: RED Odor: MUSTY Comment: Physical State: Liquid PHYSICAL PROPERTIES pH Value: Concentrate Does not apply Changes of State: Boiling Point Not Determined Vapor Pressure: Not Determined Vapor Density: > 1 Air=1 Evaporation Rate: Not Determined Specific Gravity: = 1.1 = 20 ?C Solubility: Water Negligible VOC: Theoretical VOC (by. Calculated from MSDS data by Prod.Name: GM 12345493 HIGH STRENGTH HIGH TEMPERATURE THREADLOCKER RED Manufacturer: ITW Permatex HMCS ID: 353600 SUC: 05 - Adhesives - Solvent -Based Polyurethanes, Epoxies, and Sealers MATERIAL SAFETY DATA SHEET Revision: 13.Jan.2011 Effective: 13.Jan.2011 Print Date: 06.May.2013 Page: 4 of 5 9 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL PROPERTIES VOC: wt.) < 0.18 lb/gal General Motors Technical review. Theoretical VOC (by. wt.) < 2 %Wt 10 STABILITY AND REACTIVITY STABILITY INFORMATION Stability Under Normal Conditions: Stable Conditions to Avoid: Heat Incompatible Materials: Strong oxidizers, free radical initiators, inert gases, Peroxides, Reducing agents, Oxygen scavengers Hazardous Polymerization: May occur Comment: Chemical Stability: Stable at normal conditions HAZARDOUS DECOMPOSITION Reactions: Type of Reaction Reaction Products Decomposition Hazardous Products of Combustion: Oxides of carbon 11 TOXICOLOGICAL INFORMATION 12 ECOLOGICAL INFORMATION ENVIRONMENTAL IMPACT Comment: NO DATA AVAILABLE 13 DISPOSAL CONSIDERATIONS Waste Disposal Information: Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations. US EPA Waste Number: NH - Not a RCRA Hazardous Waste Material 14 TRANSPORT INFORMATION DOT Shipping Name: Not regulated DOT Hazard Class: None DOT UN Code: None Comment: IATA Proper Shipping Name: Not regulated Class or Division: None UN/ID Number: None IMDG Proper Shipping: Not regulated Hazard Class: None UN Number: None Prod.Name: GM 12345493 HIGH STRENGTH HIGH TEMPERATURE THREADLOCKER RED Manufacturer: ITW Permatex HMCS ID: 353600 SUC: 05 - Adhesives - Solvent -Based Polyurethanes, Epoxies, and Sealers MATERIAL SAFETY DATA SHEET Revision: 13.Jan.2011 Effective: 13.Jan.2011 Print Date: 06.May.2013 Page: 5 of 5 14 TRANSPORT INFORMATION Comment: Marine Pollutant: None 15 REGULATORY INFORMATION LABELLING Hazard Codes: HMIS Reactivity 0 HMIS Health 2 HMIS Flammability 1 NFPA Flammability 1 NFPA Health 2 NFPA Reactivity 0 NATIONAL REGULATIONS SARA 311/312: No SARA 313: Yes Immediate Health: No Delayed Health: No Fire: No Sudden Pressure Release: No Reactive: No Other Regulation: SARA 313 Chemicals The following component(s) is listed as a SARA Section 313 Toxic Chemical. DIMETHYLBENZYL HYDROPEROXIDE TSCA Inventory Status All components of this product are listed (or exempt) on the EPA TSCA inventory. STATE/LOCAL REGULATIONS Comment: California Proposition 65: No California Prop 65 chemicals are known to be present at or above the No Significant Risk Level 16 OTHER INFORMATION Comments: Additional Exposure Limits: GM Occupational Exposure Guidelines (OEG) and State-TWA's were provided by General Motors. 1 PRODUCT AND COMPANY IDENTIFICATION 2 INGREDIENT INFORMATION 3 HAZARDS IDENTIFICATION 4 FIRST AID MEASURES 5 FIRE FIGHTING MEASURES 6 ACCIDENTAL RELEASE MEASURES 7 HANDLING AND STORAGE 8 EXPOSURE CONTROLS/PERSONAL PROTECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 10 STABILITY AND REACTIVITY 11 TOXICOLOGICAL INFORMATION 12 ECOLOGICAL INFORMATION 13 DISPOSAL CONSIDERATIONS 14 TRANSPORT INFORMATION 15 REGULATORY INFORMATION 16 OTHER INFORMATION