3M(TM) Panel Bonding Adhesive, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-CD 507) 04/23/15 ________________________________________________________________________________________________________ Page 1 of 2 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 19-0738-5 Version Number: 3.00 Issue Date: 04/23/15 Supercedes Date: 11/02/12 Product identifier 3M(TM) Panel Bonding Adhesive, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-CD 507) ID Number(s): 41-0003-6679-3, 41-0003-8017-4, 41-3701-2169-5, 60-9801-0901-5 Recommended use Automotive, A two-part structural adhesive used to bond steel or aluminum auto body panels. Supplier's details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included. Please do not separate the component documents from this cover page. The document numbers for components of this product are: 19-0736-9, 34-3781-1 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M(TM) Panel Bonding Adhesive, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-CD 507) 04/23/15 ________________________________________________________________________________________________________ Page 2 of 2 3M USA SDSs are available at www.3M.com 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) 02/02/15 __________________________________________________________________________________________ Page 1 of 14 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 19-0736-9 Version Number: 10.00 Issue Date: 02/02/15 Supercedes Date: 09/27/12 SECTION 1: Identification 1.1. Product identifier 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) Product Identification Numbers LB-K100-0126-5 1.2. Recommended use and restrictions on use Recommended use Automotive, Part A of a two-part structural adhesive used to bond steel or aluminum auto body panels. 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Acute Toxicity (inhalation): Category 3. Acute Toxicity (oral): Category 4. Acute Toxicity (dermal): Category 4. Serious Eye Damage/Irritation: Category 1. Skin Corrosion/Irritation: Category 1B. Skin Sensitizer: Category 1A. Reproductive Toxicity: Category 1B. Specific Target Organ Toxicity (single exposure): Category 2. 2.2. Label elements Signal word Danger 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) 02/02/15 __________________________________________________________________________________________ Page 2 of 14 Symbols Corrosion | Skull and crossbones | Exclamation mark | Health Hazard | Pictograms Hazard Statements Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May damage fertility or the unborn child. May cause damage to organs: blood or blood-forming organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves, protective clothing, and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF exposed or concerned: Call a POISON CENTER or doctor/physician. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified May cause chemical gastrointestinal burns. Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines. 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) 02/02/15 __________________________________________________________________________________________ Page 3 of 14 33% of the mixture consists of ingredients of unknown acute oral toxicity. 37% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Aliphatic Polymer Diamine 68911-25-1 30 - 60 Trade Secret * Fused Silica 60676-86-0 10 - 30 Trade Secret * Butadiene Acrylonitrile Polymer 68683-29-4 7 - 20 Trade Secret * Alkyl Amines 68955-53-3 7 - 13 Trade Secret * Tris(2,4,6-Dimethylaminomonomethyl)Phenol 90-72-2 5 - 10 Trade Secret * Poly(Oxypropylene)Diamine 9046-10-0 3 - 7 Trade Secret * Bis(3-Aminopropyl) Ether Of Diethylene Glycol 4246-51-9 1 - 7 Trade Secret * Dimethyl Siloxane, Reaction Product With Silica 67762-90-7 1 - 5 Trade Secret * Calcium Nitrate 10124-37-5 1 - 5 Trade Secret * Poly(Oxypropylene)Triamine 39423-51-3 0.5 - 1.5 Trade Secret * N-Aminoethylpiperazine 140-31-8 0.1 - 1.5 Trade Secret * Bis[(Dimethylamino)Methyl]Phenol 71074-89-0 0.1 - 1.5 Trade Secret * Toluene 108-88-3 < 0.5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediate medical attention. Wash clothing before reuse. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Rinse mouth. Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) 02/02/15 __________________________________________________________________________________________ Page 4 of 14 5.2. Special hazards arising from the substance or mixture None inherent in this product. 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Store away from acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin Toluene 108-88-3 CMRG STEL:75 ppm Skin Notation SILICA, AMORPHOUS 60676-86-0 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Dimethyl Siloxane, Reaction Product With Silica 67762-90-7 CMRG CEIL:5 mg/m3 SILICA, AMORPHOUS 67762-90-7 OSHA TWA concentration:0.8 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) 02/02/15 __________________________________________________________________________________________ Page 5 of 14 mg/m3;TWA:20 millions of particles/cu. ft. Tris(2,4,6- Dimethylaminomonomethyl)Phen ol 90-72-2 CMRG TWA:5 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. Thermal hazards Wear heat insulating gloves when handling hot material to prevent thermal burns. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Viscous 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) 02/02/15 __________________________________________________________________________________________ Page 6 of 14 Odor, Color, Grade: Amber color; Slight amine odor Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point No Data Available Flash Point >=230 ?F [Test Method: Closed Cup] [Details: Closed Cup SETAFLASH (Based on flammable ingredient at highest %) (ASTM D-3278-96 e-1)] Evaporation rate < 1 [Ref Std: BUOAC=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density No Data Available Density 1.1 g/ml Specific Gravity 1.1 [Test Method: Estimated] [Ref Std: WATER=1] Solubility In Water No Data Available Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity > 100,000 centipoise Hazardous Air Pollutants 0.013 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 0.4 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 4 g/l [Test Method: calculated SCAQMD rule 443.1] VOC Less H2O & Exempt Solvents 4 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Oxides of Nitrogen Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) 02/02/15 __________________________________________________________________________________________ Page 7 of 14 classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Toxic if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Harmful in contact with skin. Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Ingestion: Harmful if swallowed. Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen. Additional Health Effects: Single exposure may cause target organ effects: Methemoglobinemia: Signs/symptoms may include headache, dizziness, nausea, difficulty breathing, and generalized weakness. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Additional Information: Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE 1,000 - 2,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 2 - 10 mg/l Overall product Ingestion No data available; calculated ATE 300 - 2,000 mg/kg Fused Silica Dermal Rabbit LD50 > 5,000 mg/kg Fused Silica Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) 02/02/15 __________________________________________________________________________________________ Page 8 of 14 Fused Silica Ingestion Rat LD50 > 5,110 mg/kg Butadiene Acrylonitrile Polymer Dermal Rabbit LD50 > 3,000 mg/kg Butadiene Acrylonitrile Polymer Ingestion Rat LD50 > 15,300 mg/kg Alkyl Amines Dermal Rat LD50 251 mg/kg Alkyl Amines Inhalation- Vapor (4 hours) Rat LC50 > .94 mg/l Alkyl Amines Ingestion Rat LD50 320 mg/kg Tris(2,4,6-Dimethylaminomonomethyl)Phenol Dermal Rat LD50 1,280 mg/kg Tris(2,4,6-Dimethylaminomonomethyl)Phenol Ingestion Rat LD50 1,000 mg/kg Bis(3-Aminopropyl) Ether Of Diethylene Glycol Dermal Rabbit LD50 2,500 mg/kg Bis(3-Aminopropyl) Ether Of Diethylene Glycol Ingestion Rat LD50 3,160 mg/kg Poly(Oxypropylene)Diamine Dermal Rabbit LD50 > 1,000 mg/kg Poly(Oxypropylene)Diamine Ingestion Rat LD50 >= 475 mg/kg Dimethyl Siloxane, Reaction Product With Silica Dermal Rabbit LD50 > 5,000 mg/kg Dimethyl Siloxane, Reaction Product With Silica Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Dimethyl Siloxane, Reaction Product With Silica Ingestion Rat LD50 > 5,110 mg/kg Calcium Nitrate Dermal Rat LD50 estimated to be > 5,000 mg/kg Calcium Nitrate Ingestion Rat LD50 9,285 mg/kg Poly(Oxypropylene)Triamine Dermal Rabbit LD50 562 mg/kg Poly(Oxypropylene)Triamine Ingestion Rat LD50 220 mg/kg Bis[(Dimethylamino)Methyl]Phenol Ingestion LD50 estimated to be 300 - 2,000 mg/kg N-Aminoethylpiperazine Dermal Rabbit LD50 865 mg/kg N-Aminoethylpiperazine Ingestion Rat LD50 1,470 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Aliphatic Polymer Diamine Rabbit Irritant Fused Silica Rabbit No significant irritation Alkyl Amines Rabbit Corrosive Tris(2,4,6-Dimethylaminomonomethyl)Phenol Rabbit Corrosive Bis(3-Aminopropyl) Ether Of Diethylene Glycol Rabbit Corrosive Poly(Oxypropylene)Diamine Rabbit Corrosive Dimethyl Siloxane, Reaction Product With Silica Rabbit No significant irritation Bis[(Dimethylamino)Methyl]Phenol similar compoun ds Corrosive N-Aminoethylpiperazine Rabbit Corrosive Toluene Rabbit Irritant Serious Eye Damage/Irritation Name Species Value Aliphatic Polymer Diamine similar health hazards Corrosive Fused Silica Rabbit No significant irritation Alkyl Amines Rabbit Corrosive Tris(2,4,6-Dimethylaminomonomethyl)Phenol Rabbit Corrosive Bis(3-Aminopropyl) Ether Of Diethylene Glycol similar health hazards Corrosive Poly(Oxypropylene)Diamine Rabbit Corrosive Dimethyl Siloxane, Reaction Product With Silica Rabbit No significant irritation Bis[(Dimethylamino)Methyl]Phenol similar compoun ds Corrosive 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) 02/02/15 __________________________________________________________________________________________ Page 9 of 14 N-Aminoethylpiperazine Rabbit Corrosive Toluene Rabbit Moderate irritant Skin Sensitization Name Species Value Aliphatic Polymer Diamine Guinea pig Sensitizing Fused Silica Human and animal Not sensitizing Butadiene Acrylonitrile Polymer Guinea pig Some positive data exist, but the data are not sufficient for classification Alkyl Amines Guinea pig Sensitizing Tris(2,4,6-Dimethylaminomonomethyl)Phenol Guinea pig Some positive data exist, but the data are not sufficient for classification Poly(Oxypropylene)Diamine Guinea pig Not sensitizing Dimethyl Siloxane, Reaction Product With Silica Human and animal Not sensitizing N-Aminoethylpiperazine Guinea pig Sensitizing Toluene Guinea pig Not sensitizing Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Fused Silica In Vitro Not mutagenic Alkyl Amines In vivo Not mutagenic Alkyl Amines In Vitro Some positive data exist, but the data are not sufficient for classification Tris(2,4,6-Dimethylaminomonomethyl)Phenol In Vitro Not mutagenic Poly(Oxypropylene)Diamine In Vitro Not mutagenic Poly(Oxypropylene)Diamine In vivo Not mutagenic Dimethyl Siloxane, Reaction Product With Silica In Vitro Not mutagenic N-Aminoethylpiperazine In vivo Not mutagenic N-Aminoethylpiperazine In Vitro Some positive data exist, but the data are not sufficient for classification Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Carcinogenicity Name Route Species Value Fused Silica Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Dimethyl Siloxane, Reaction Product With Silica Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) 02/02/15 __________________________________________________________________________________________ Page 10 of 14 Fused Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Fused Silica Inhalation Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Fused Silica Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Alkyl Amines Ingestion Not toxic to female reproduction Rat NOAEL 124 mg/kg/day 1 generation Alkyl Amines Ingestion Not toxic to male reproduction Rat NOAEL 107 mg/kg/day 1 generation Alkyl Amines Dermal Not toxic to development Rat NOAEL 45 mg/kg/day during gestation Alkyl Amines Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 21 mg/kg/day 1 generation Poly(Oxypropylene)Diamine Dermal Not toxic to female reproduction Rat NOAEL 30 mg/kg/day premating & during gestation Poly(Oxypropylene)Diamine Dermal Not toxic to male reproduction Rat NOAEL 30 mg/kg/day premating & during gestation Poly(Oxypropylene)Diamine Dermal Not toxic to development Rat NOAEL 30 mg/kg/day premating & during gestation Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s N-Aminoethylpiperazine Ingestion Not toxic to female reproduction Rat NOAEL 598 mg/kg/day premating & during gestation N-Aminoethylpiperazine Ingestion Not toxic to male reproduction Rat NOAEL 409 mg/kg/day 32 days N-Aminoethylpiperazine Ingestion Not toxic to development Rat NOAEL 899 mg/kg/day premating & during gestation Toluene Inhalation Some positive female reproductive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Inhalation Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Alkyl Amines Inhalation respiratory irritation May cause respiratory irritation Rat NOAEL .019 mg/l 4 weeks Tris(2,4,6- Dimethylaminomonomethy l)Phenol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Bis(3-Aminopropyl) Ether Of Diethylene Glycol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Poly(Oxypropylene)Diami ne Inhalation respiratory irritation May cause respiratory irritation NOAEL Not available N-Aminoethylpiperazine Inhalation respiratory irritation Some positive data exist, but the NOAEL Not 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) 02/02/15 __________________________________________________________________________________________ Page 11 of 14 data are not sufficient for classification available Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Fused Silica Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Alkyl Amines Dermal endocrine system | hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 60 mg/kg/day 4 weeks Alkyl Amines Dermal liver | muscles | nervous system | kidney and/or bladder All data are negative Rat NOAEL 60 mg/kg/day 4 weeks Alkyl Amines Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL .129 mg/l 4 weeks Alkyl Amines Inhalation heart | endocrine system | liver | muscles | nervous system | kidney and/or bladder All data are negative Rat NOAEL .129 mg/l 4 weeks Tris(2,4,6- Dimethylaminomonometh yl)Phenol Dermal skin | liver | nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 125 mg/kg/day 28 days Tris(2,4,6- Dimethylaminomonometh yl)Phenol Dermal auditory system | hematopoietic system | eyes All data are negative Rat NOAEL 125 mg/kg/day 28 days Dimethyl Siloxane, Reaction Product With Silica Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure N-Aminoethylpiperazine Ingestion heart | endocrine system | hematopoietic system | liver | nervous system | kidney and/or bladder All data are negative Rat NOAEL 598 mg/kg/day 28 days Toluene Inhalation auditory system | nervous system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 8 weeks 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) 02/02/15 __________________________________________________________________________________________ Page 12 of 14 Toluene Inhalation hematopoietic system | vascular system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 4 weeks Aspiration Hazard Name Value Poly(Oxypropylene)Diamine Some positive data exist, but the data are not sufficient for classification Toluene Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) 02/02/15 __________________________________________________________________________________________ Page 13 of 14 SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Calcium Nitrate (NITRATE COMPOUNDS (WATER DISSOCIABLE; REPORTABLE ONLY WHEN IN AQUEOUS SOLUTION)) 10124-37-5 1 - 5 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification SILICA, CRYSTALLINE (AIRBORNE PARTICLES OF RESPIRABLE SIZE) None Carcinogen Toluene 108-88-3 Female reproductive toxin Toluene 108-88-3 Developmental Toxin WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 3 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification 3M? Panel Bonding Adhesive - Part A, PN 08116 (Meets GM 6449G and Daimler Chrysler MS-COD 507) 02/02/15 __________________________________________________________________________________________ Page 14 of 14 Health: *3 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS? III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS? III ratings are to be used with a fully implemented HMIS? III program. HMIS? is a registered mark of the American Coatings Association (ACA). Document Group: 19-0736-9 Version Number: 10.00 Issue Date: 02/02/15 Supercedes Date: 09/27/12 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com 3M? Panel Bonding Adhesive 08116 (Base) Part B 02/06/15 __________________________________________________________________________________________ Page 1 of 13 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 34-3781-1 Version Number: 1.00 Issue Date: 02/06/15 Supercedes Date: Initial Issue SECTION 1: Identification 1.1. Product identifier 3M? Panel Bonding Adhesive 08116 (Base) Part B Product Identification Numbers LB-K100-1679-5 1.2. Recommended use and restrictions on use Recommended use Automotive, Panel Bonding Adhesive 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2A. Skin Sensitizer: Category 1. Carcinogenicity: Category 2. 2.2. Label elements Signal word Warning Symbols Exclamation mark | Health Hazard | Pictograms 3M? Panel Bonding Adhesive 08116 (Base) Part B 02/06/15 __________________________________________________________________________________________ Page 2 of 13 Hazard Statements Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. Precautionary Statements Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves and eye/face protection. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 5% of the mixture consists of ingredients of unknown acute oral toxicity. 5% of the mixture consists of ingredients of unknown acute dermal toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt 4,4'-ISOPROPYLIDENEDIPHENOL- EPICHLOROHYDRIN POLYMER 25068-38-6 30 - 60 Trade Secret * GLASS BEADS 65997-17-3 10 - 30 Trade Secret * 1,4-BIS[(2,3- EPOXYPROPOXY)METHYL]CYCLOHEXANE 14228-73-0 7 - 13 Trade Secret * FUSED SILICA 60676-86-0 7 - 13 Trade Secret * ACRYLATE POLYMER Trade Secret* 5 - 10 Trade Secret * GLASS Trade Secret* 3 - 7 Trade Secret * SILICA 7631-86-9 1 - 5 Trade Secret * 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL 2530-83-8 0.5 - 1.5 Trade Secret * 3M? Panel Bonding Adhesive 08116 (Base) Part B 02/06/15 __________________________________________________________________________________________ Page 3 of 13 ETHER CARBON BLACK 1333-86-4 <= 0.5 Trade Secret * EPICHLOROHYDRIN 106-89-8 < 0.012 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially 3M? Panel Bonding Adhesive 08116 (Base) Part B 02/06/15 __________________________________________________________________________________________ Page 4 of 13 available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities No special storage requirements. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments EPICHLOROHYDRIN 106-89-8 ACGIH TWA:0.5 ppm A3: Confirmed animal carcin., Skin Notation EPICHLOROHYDRIN 106-89-8 OSHA TWA:19 mg/m3(5 ppm) Skin Notation CARBON BLACK 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. CARBON BLACK 1333-86-4 CMRG TWA:0.5 mg/m3 CARBON BLACK 1333-86-4 OSHA TWA:3.5 mg/m3 3- (TRIMETHOXYSILYL)PROPY L GLYCIDYL ETHER 2530-83-8 CMRG TWA:5 ppm SILICA, AMORPHOUS 60676-86-0 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. GLASS BEADS 65997-17-3 Manufacturer determined TWA(as dust):10 mg/m3 SILICA 7631-86-9 CMRG TWA(as respirable dust):3 mg/m3 SILICA, AMORPHOUS 7631-86-9 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls 3M? Panel Bonding Adhesive 08116 (Base) Part B 02/06/15 __________________________________________________________________________________________ Page 5 of 13 Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Viscous Odor, Color, Grade: Black Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point > 300 ?F Flash Point Flash point > 93 ?C (200 ?F) Evaporation rate < 1 [Ref Std: BUOAC=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure < 5 mmHg [@ 20 ?C] Vapor Density No Data Available Density 1.2 g/ml Specific Gravity 1.2 [Ref Std: WATER=1] Solubility In Water No Data Available Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available 3M? Panel Bonding Adhesive 08116 (Base) Part B 02/06/15 __________________________________________________________________________________________ Page 6 of 13 Decomposition temperature No Data Available Viscosity > 100,000 centipoise Hazardous Air Pollutants 0.00000289 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 1.4 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 17 g/l [Test Method: calculated SCAQMD rule 443.1] VOC Less H2O & Exempt Solvents 17 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition Aldehydes Not Specified Carbon monoxide Not Specified Carbon dioxide Not Specified Hydrogen Chloride Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. 3M? Panel Bonding Adhesive 08116 (Base) Part B 02/06/15 __________________________________________________________________________________________ Page 7 of 13 Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Additional Health Effects: Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Generic: GLASS FILAMENTS 65997-17-3 Anticipated human carcinogen National Toxicology Program Carcinogens CARBON BLACK 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer EPICHLOROHYDRIN 106-89-8 Grp. 2A: Probable human carc. International Agency for Research on Cancer EPICHLOROHYDRIN 106-89-8 Anticipated human carcinogen National Toxicology Program Carcinogens Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg 4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN POLYMER Dermal Rat LD50 > 1,600 mg/kg 4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN POLYMER Ingestion Rat LD50 > 1,000 mg/kg GLASS BEADS Dermal LD50 estimated to be > 5,000 mg/kg GLASS BEADS Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg 1,4-BIS[(2,3-EPOXYPROPOXY)METHYL]CYCLOHEXANE Dermal Rabbit LD50 2,500 mg/kg FUSED SILICA Dermal Rabbit LD50 > 5,000 mg/kg 1,4-BIS[(2,3-EPOXYPROPOXY)METHYL]CYCLOHEXANE Ingestion Rat LD50 2,450 mg/kg FUSED SILICA Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l FUSED SILICA Ingestion Rat LD50 > 5,110 mg/kg ACRYLATE POLYMER Dermal Rabbit LD50 > 5,000 mg/kg ACRYLATE POLYMER Ingestion Rat LD50 > 5,000 mg/kg SILICA Dermal Rabbit LD50 > 5,000 mg/kg SILICA Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l SILICA Ingestion Rat LD50 > 5,110 mg/kg 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Dermal Rabbit LD50 4,000 mg/kg 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Inhalation- Dust/Mist (4 hours) Rat LC50 > 5.3 mg/l 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Ingestion Rat LD50 7,010 mg/kg CARBON BLACK Dermal Rabbit LD50 > 3,000 mg/kg CARBON BLACK Ingestion Rat LD50 > 8,000 mg/kg EPICHLOROHYDRIN Dermal Rabbit LD50 755 mg/kg EPICHLOROHYDRIN Inhalation- Vapor (4 hours) Rat LC50 1.7 mg/l EPICHLOROHYDRIN Ingestion Rat LD50 260 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation 3M? Panel Bonding Adhesive 08116 (Base) Part B 02/06/15 __________________________________________________________________________________________ Page 8 of 13 Name Species Value 4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN POLYMER Rabbit Mild irritant GLASS BEADS Professio nal judgeme nt No significant irritation 1,4-BIS[(2,3-EPOXYPROPOXY)METHYL]CYCLOHEXANE Professio nal judgeme nt Mild irritant FUSED SILICA Rabbit No significant irritation ACRYLATE POLYMER Professio nal judgeme nt Minimal irritation SILICA Rabbit No significant irritation 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Rabbit Mild irritant CARBON BLACK Rabbit No significant irritation EPICHLOROHYDRIN Human and animal Corrosive Serious Eye Damage/Irritation Name Species Value 4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN POLYMER Rabbit Moderate irritant GLASS BEADS Professio nal judgeme nt No significant irritation 1,4-BIS[(2,3-EPOXYPROPOXY)METHYL]CYCLOHEXANE Professio nal judgeme nt Mild irritant FUSED SILICA Rabbit No significant irritation ACRYLATE POLYMER Professio nal judgeme nt Mild irritant SILICA Rabbit No significant irritation 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Rabbit Corrosive CARBON BLACK Rabbit No significant irritation EPICHLOROHYDRIN Rabbit Corrosive Skin Sensitization Name Species Value 4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN POLYMER Human and animal Sensitizing 1,4-BIS[(2,3-EPOXYPROPOXY)METHYL]CYCLOHEXANE similar compoun ds Sensitizing FUSED SILICA Human and animal Not sensitizing SILICA Human and animal Not sensitizing 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Guinea pig Some positive data exist, but the data are not sufficient for classification EPICHLOROHYDRIN Human and animal Sensitizing Respiratory Sensitization 3M? Panel Bonding Adhesive 08116 (Base) Part B 02/06/15 __________________________________________________________________________________________ Page 9 of 13 Name Species Value 4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN POLYMER Human Some positive data exist, but the data are not sufficient for classification Germ Cell Mutagenicity Name Route Value 4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN POLYMER In vivo Not mutagenic 4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN POLYMER In Vitro Some positive data exist, but the data are not sufficient for classification GLASS BEADS In Vitro Some positive data exist, but the data are not sufficient for classification FUSED SILICA In Vitro Not mutagenic SILICA In Vitro Not mutagenic 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER In vivo Not mutagenic 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER In Vitro Some positive data exist, but the data are not sufficient for classification CARBON BLACK In Vitro Not mutagenic CARBON BLACK In vivo Some positive data exist, but the data are not sufficient for classification EPICHLOROHYDRIN In Vitro Some positive data exist, but the data are not sufficient for classification EPICHLOROHYDRIN In vivo Mutagenic Carcinogenicity Name Route Species Value 4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN POLYMER Dermal Mouse Some positive data exist, but the data are not sufficient for classification GLASS BEADS Inhalation Multiple animal species Some positive data exist, but the data are not sufficient for classification FUSED SILICA Not Specified Mouse Some positive data exist, but the data are not sufficient for classification SILICA Not Specified Mouse Some positive data exist, but the data are not sufficient for classification 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Dermal Mouse Not carcinogenic CARBON BLACK Dermal Mouse Not carcinogenic CARBON BLACK Ingestion Mouse Not carcinogenic CARBON BLACK Inhalation Rat Carcinogenic EPICHLOROHYDRIN Dermal Mouse Not carcinogenic EPICHLOROHYDRIN Ingestion Rat Carcinogenic EPICHLOROHYDRIN Inhalation Rat Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration 4,4'-ISOPROPYLIDENEDIPHENOL- EPICHLOROHYDRIN POLYMER Ingestion Not toxic to female reproduction Rat NOAEL 750 mg/kg/day 2 generation 4,4'-ISOPROPYLIDENEDIPHENOL- EPICHLOROHYDRIN POLYMER Ingestion Not toxic to male reproduction Rat NOAEL 750 mg/kg/day 2 generation 4,4'-ISOPROPYLIDENEDIPHENOL- EPICHLOROHYDRIN POLYMER Dermal Not toxic to development Rabbit NOAEL 300 mg/kg/day during organogenesi s 4,4'-ISOPROPYLIDENEDIPHENOL- EPICHLOROHYDRIN POLYMER Ingestion Not toxic to development Rat NOAEL 750 mg/kg/day 2 generation FUSED SILICA Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation FUSED SILICA Inhalation Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation FUSED SILICA Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s 3M? Panel Bonding Adhesive 08116 (Base) Part B 02/06/15 __________________________________________________________________________________________ Page 10 of 13 SILICA Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation SILICA Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation SILICA Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Ingestion Not toxic to female reproduction Rat NOAEL 1,000 mg/kg/day 1 generation 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Ingestion Not toxic to male reproduction Rat NOAEL 1,000 mg/kg/day 1 generation 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 3,000 mg/kg/day during organogenesi s EPICHLOROHYDRIN Inhalation Not toxic to female reproduction Rat NOAEL 0.2 mg/l 10 weeks EPICHLOROHYDRIN Inhalation Not toxic to development Multiple animal species NOAEL 0.09 mg/l during organogenesi s EPICHLOROHYDRIN Ingestion Some positive developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL 160 mg/kg/day during gestation EPICHLOROHYDRIN Ingestion Toxic to male reproduction Rat LOAEL 6.25 mg/kg/day 23 days EPICHLOROHYDRIN Inhalation Toxic to male reproduction Rat NOAEL 0.02 mg/l 10 weeks Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 1,4-BIS[(2,3- EPOXYPROPOXY)MET HYL]CYCLOHEXANE Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available EPICHLOROHYDRIN Inhalation respiratory irritation May cause respiratory irritation Human NOAEL not available occupational exposure EPICHLOROHYDRIN Inhalation liver Some positive data exist, but the data are not sufficient for classification Human NOAEL not available occupational exposure Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 4,4'- ISOPROPYLIDENEDIPH ENOL- EPICHLOROHYDRIN POLYMER Dermal liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,000 mg/kg/day 2 years 4,4'- ISOPROPYLIDENEDIPH ENOL- EPICHLOROHYDRIN POLYMER Dermal nervous system All data are negative Rat NOAEL 1,000 mg/kg/day 13 weeks 4,4'- ISOPROPYLIDENEDIPH ENOL- EPICHLOROHYDRIN POLYMER Ingestion auditory system | heart | endocrine system | hematopoietic system | liver | eyes | kidney and/or bladder All data are negative Rat NOAEL 1,000 mg/kg/day 28 days GLASS BEADS Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Human NOAEL not available occupational exposure FUSED SILICA Inhalation respiratory system | All data are negative Human NOAEL Not occupational 3M? Panel Bonding Adhesive 08116 (Base) Part B 02/06/15 __________________________________________________________________________________________ Page 11 of 13 silicosis available exposure SILICA Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure 3- (TRIMETHOXYSILYL)P ROPYL GLYCIDYL ETHER Ingestion heart | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | liver | immune system | nervous system | kidney and/or bladder | respiratory system All data are negative Rat NOAEL 1,000 mg/kg/day 28 days CARBON BLACK Inhalation pneumoconiosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure EPICHLOROHYDRIN Inhalation liver Causes damage to organs through prolonged or repeated exposure Rat NOAEL 0.21 mg/l 19 days EPICHLOROHYDRIN Inhalation kidney and/or bladder May cause damage to organs though prolonged or repeated exposure Rat NOAEL 0.04 mg/l 136 weeks EPICHLOROHYDRIN Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.377 mg/l 4 weeks EPICHLOROHYDRIN Inhalation immune system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.211 mg/l 4 weeks EPICHLOROHYDRIN Inhalation heart Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.02 mg/l 98 days EPICHLOROHYDRIN Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL .002 mg/l 98 days EPICHLOROHYDRIN Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.02 mg/l 13 weeks EPICHLOROHYDRIN Inhalation blood All data are negative Rat NOAEL 0.189 mg/l 90 days EPICHLOROHYDRIN Ingestion heart | blood Some positive data exist, but the data are not sufficient for classification Rat NOAEL 80 mg/kg/day 12 weeks EPICHLOROHYDRIN Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 25 mg/kg/day 90 days Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. 3M? Panel Bonding Adhesive 08116 (Base) Part B 02/06/15 __________________________________________________________________________________________ Page 12 of 13 SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification EPICHLOROHYDRIN 106-89-8 Male reproductive toxin EPICHLOROHYDRIN 106-89-8 Carcinogen CARBON BLACK 1333-86-4 Carcinogen WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. 3M? Panel Bonding Adhesive 08116 (Base) Part B 02/06/15 __________________________________________________________________________________________ Page 13 of 13 SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 34-3781-1 Version Number: 1.00 Issue Date: 02/06/15 Supercedes Date: Initial Issue DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com