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3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 1 of 16 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 10-5259-6 Version Number: 52.00 Issue Date: 11/26/14 Supercedes Date: 11/16/11 SECTION 1: Identification 1.1. Product identifier 3M? Heavy Drip-Chek? Sealer, PN 08531 Product Identification Numbers 41-0003-6740-3, 41-3701-2172-9, 60-9800-2709-2, 60-9800-3751-3, 62-2153-2609-1 1.2. Recommended use and restrictions on use Recommended use Automotive, Sealant 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 2. Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 2. Specific Target Organ Toxicity (central nervous system): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 2 of 16 Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Highly flammable liquid and vapor. Causes serious eye irritation. Causes skin irritation. May cause drowsiness or dizziness. May damage fertility or the unborn child. Suspected of causing cancer. Causes damage to organs through prolonged or repeated exposure: nervous system | sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 3 of 16 Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 12% of the mixture consists of ingredients of unknown acute dermal toxicity. 34% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Toluene 108-88-3 30 - 60 Trade Secret * Acrylonitrile-Butadiene Polymer 9003-18-3 10 - 30 Trade Secret * Formaldehyde, Polymer With 4-(1,1- Dimethylethyl)Phenol, Magnesium Oxide Complex 68037-42-3 5 - 15 Trade Secret * N-Amyl Acetate 628-63-7 7 - 13 Trade Secret * 2-Methylbutyl Acetate 624-41-9 3 - 7 Trade Secret * Synthetic Amorphous Silica, Fumed, Crystalline Free 112945-52-5 3 - 7 Trade Secret * Salicylic Acid 69-72-7 1 - 5 Trade Secret * Titanium Dioxide 13463-67-7 0.5 - 1.5 Trade Secret * Zinc Oxide 1314-13-2 0.5 - 1.5 Trade Secret * Ethylbenzene 100-41-4 < 0.5 Trade Secret * Benzene 71-43-2 < 0.1 Trade Secret * Carbon Black 1333-86-4 < 0.05 Trade Secret * Formaldehyde 50-00-0 < 0.05 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 4 of 16 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Toxic Vapor, Gas, Particulate During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid breathing of vapors created during cure cycle. Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 5 of 16 vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal carcin. Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm) Ethylbenzene 100-41-4 CMRG TWA:25 ppm;STEL:75 ppm Toluene 108-88-3 CMRG STEL:75 ppm Skin Notation Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin SILICA, AMORPHOUS 112945-52- 5 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Zinc Oxide 1314-13-2 OSHA TWA(as fume):5 mg/m3;TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Zinc Oxide 1314-13-2 ACGIH TWA(respirable fraction):2 mg/m3;STEL(respirable fraction):10 mg/m3 Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3 Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. Carbon Black 1333-86-4 CMRG TWA:0.5 mg/m3 Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin Titanium Dioxide 13463-67-7 CMRG TWA(as respirable dust):5 mg/m3 Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3 Formaldehyde 50-00-0 ACGIH CEIL:0.3 ppm A2: Suspected human carcin., Sensitizer Formaldehyde 50-00-0 CMRG TWA:0.5 ppm Formaldehyde 50-00-0 OSHA TWA:0.75 ppm;STEL:2 ppm 29 CFR 1910.1048 2-Methylbutyl Acetate 624-41-9 ACGIH TWA:50 ppm;STEL:100 ppm N-Amyl Acetate 628-63-7 ACGIH TWA:50 ppm;STEL:100 ppm N-Amyl Acetate 628-63-7 OSHA TWA:525 mg/m3(100 ppm) Benzene 71-43-2 OSHA TWA:1 ppm;TWA:10 ppm;STEL:5 ppm;CEIL:25 ppm 29 CFR 1910.1028 Benzene 71-43-2 ACGIH TWA:0.5 ppm;STEL:2.5 ppm A1: Confirmed human carcin., Skin Notation 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 6 of 16 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide ventilated enclosure for heat curing. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Fluoroelastomer Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: Solvent odor; Gray viscous liquid Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point 232 ?F [Details: Toluene] Flash Point 40 ?F [Test Method: Tagliabue Closed Cup] Evaporation rate 6.00 [Ref Std: ETHER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.00 % volume Flammable Limits(UEL) 7.00 % volume Vapor Pressure 25.19 mmHg [@ 68 ?F] 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 7 of 16 Vapor Density 4.0 [Ref Std: AIR=1] Density 0.97 g/ml Specific Gravity 0.97 [Ref Std: WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity Approximately 100,000 centipoise [@ 73.4 ?F ] Hazardous Air Pollutants 1.59 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 649 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 66.9 % weight [Test Method: calculated per CARB title 2] Percent volatile 66.9 % weight VOC Less H2O & Exempt Solvents 649 g/l [Test Method: calculated SCAQMD rule 443.1] Solids Content 33.9 % weight SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames 10.5. Incompatible materials Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 8 of 16 Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause target organ effects after ingestion. Target Organ Effects: Single exposure may cause: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Benzene 71-43-2 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Benzene 71-43-2 Known human carcinogen National Toxicology Program Carcinogens Benzene 71-43-2 Cancer hazard OSHA Carcinogens Carbon Black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Formaldehyde 50-00-0 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Formaldehyde 50-00-0 Known human carcinogen National Toxicology Program Carcinogens Formaldehyde 50-00-0 Cancer hazard OSHA Carcinogens Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 9 of 16 Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 20 - 50 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Acrylonitrile-Butadiene Polymer Dermal Rabbit LD50 > 15,000 mg/kg Acrylonitrile-Butadiene Polymer Ingestion Rat LD50 > 30,000 mg/kg Formaldehyde, Polymer With 4-(1,1-Dimethylethyl)Phenol, Magnesium Oxide Complex Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg N-Amyl Acetate Dermal Rabbit LD50 8,200 mg/kg N-Amyl Acetate Inhalation- Vapor (4 hours) Rat LC50 > 24.1 mg/l N-Amyl Acetate Ingestion Rat LD50 5,000 mg/kg Synthetic Amorphous Silica, Fumed, Crystalline Free Dermal Rabbit LD50 > 5,000 mg/kg Synthetic Amorphous Silica, Fumed, Crystalline Free Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Rat LD50 > 5,110 mg/kg 2-Methylbutyl Acetate Dermal Rabbit LD50 8,200 mg/kg 2-Methylbutyl Acetate Inhalation- Vapor (4 hours) Rat LC50 > 24.1 mg/l 2-Methylbutyl Acetate Ingestion Rat LD50 5,000 mg/kg Salicylic Acid Dermal Rat LD50 > 2,000 mg/kg Salicylic Acid Ingestion Rat LD50 891 mg/kg Zinc Oxide Dermal LD50 estimated to be > 5,000 mg/kg Zinc Oxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 5.7 mg/l Zinc Oxide Ingestion Rat LD50 > 5,000 mg/kg Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg Titanium Dioxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 6.82 mg/l Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg Ethylbenzene Inhalation- Vapor (4 hours) Rat LC50 17.4 mg/l Ethylbenzene Ingestion Rat LD50 4,769 mg/kg Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg Carbon Black Ingestion Rat LD50 > 8,000 mg/kg Formaldehyde Dermal Rabbit LD50 270 mg/kg Formaldehyde Inhalation- Gas (4 hours) Rat LC50 470 ppm Formaldehyde Ingestion Rat LD50 800 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Toluene Rabbit Irritant Acrylonitrile-Butadiene Polymer No significant irritation N-Amyl Acetate Rabbit Mild irritant Synthetic Amorphous Silica, Fumed, Crystalline Free Rabbit No significant irritation 2-Methylbutyl Acetate Rabbit Mild irritant Salicylic Acid Rabbit No significant irritation Zinc Oxide Human and No significant irritation 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 10 of 16 animal Titanium Dioxide Rabbit No significant irritation Ethylbenzene Rabbit Mild irritant Carbon Black Rabbit No significant irritation Formaldehyde official classifica tion Corrosive Serious Eye Damage/Irritation Name Species Value Toluene Rabbit Moderate irritant Acrylonitrile-Butadiene Polymer No significant irritation N-Amyl Acetate Rabbit Moderate irritant Synthetic Amorphous Silica, Fumed, Crystalline Free Rabbit No significant irritation 2-Methylbutyl Acetate Rabbit Moderate irritant Salicylic Acid Rabbit Corrosive Zinc Oxide Rabbit Mild irritant Titanium Dioxide Rabbit No significant irritation Ethylbenzene Rabbit Moderate irritant Carbon Black Rabbit No significant irritation Formaldehyde official classifica tion Corrosive Skin Sensitization Name Species Value Toluene Guinea pig Not sensitizing N-Amyl Acetate Human Not sensitizing Synthetic Amorphous Silica, Fumed, Crystalline Free Human and animal Not sensitizing 2-Methylbutyl Acetate Human Not sensitizing Salicylic Acid Mouse Not sensitizing Zinc Oxide Guinea pig Some positive data exist, but the data are not sufficient for classification Titanium Dioxide Human and animal Not sensitizing Ethylbenzene Human Not sensitizing Formaldehyde Guinea pig Sensitizing Photosensitization Name Species Value N-Amyl Acetate Human Not sensitizing 2-Methylbutyl Acetate Human Not sensitizing Salicylic Acid Mouse Not sensitizing Respiratory Sensitization Name Species Value Formaldehyde Human Some positive data exist, but the data are not sufficient for classification Germ Cell Mutagenicity Name Route Value Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic N-Amyl Acetate In Vitro Not mutagenic Synthetic Amorphous Silica, Fumed, Crystalline Free In Vitro Not mutagenic 2-Methylbutyl Acetate In Vitro Not mutagenic Salicylic Acid In Vitro Not mutagenic Salicylic Acid In vivo Not mutagenic 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 11 of 16 Zinc Oxide In Vitro Some positive data exist, but the data are not sufficient for classification Zinc Oxide In vivo Some positive data exist, but the data are not sufficient for classification Titanium Dioxide In Vitro Not mutagenic Titanium Dioxide In vivo Not mutagenic Ethylbenzene In vivo Not mutagenic Ethylbenzene In Vitro Some positive data exist, but the data are not sufficient for classification Carbon Black In Vitro Not mutagenic Carbon Black In vivo Some positive data exist, but the data are not sufficient for classification Formaldehyde In Vitro Some positive data exist, but the data are not sufficient for classification Formaldehyde In vivo Mutagenic Carcinogenicity Name Route Species Value Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Synthetic Amorphous Silica, Fumed, Crystalline Free Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Titanium Dioxide Ingestion Multiple animal species Not carcinogenic Titanium Dioxide Inhalation Rat Carcinogenic Ethylbenzene Inhalation Multiple animal species Carcinogenic Carbon Black Dermal Mouse Not carcinogenic Carbon Black Ingestion Mouse Not carcinogenic Carbon Black Inhalation Rat Carcinogenic Formaldehyde Not Specified Human and animal Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Toluene Inhalation Some positive female reproductive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Inhalation Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse N-Amyl Acetate Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 2.7 mg/l during organogenesi s Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s 2-Methylbutyl Acetate Inhalation Some positive developmental data exist, Rat NOAEL 2.7 during 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 12 of 16 but the data are not sufficient for classification mg/l organogenesi s Salicylic Acid Ingestion Toxic to development Rat NOAEL 75 mg/kg/day during organogenesi s Zinc Oxide Ingestion Some positive reproductive/developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL 125 mg/kg/day premating & during gestation Ethylbenzene Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 4.3 mg/l premating & during gestation Formaldehyde Ingestion Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 100 mg/kg not applicable Formaldehyde Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 10 ppm during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse N-Amyl Acetate Inhalation central nervous system depression May cause drowsiness or dizziness NOAEL Not available N-Amyl Acetate Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL not available 2-Methylbutyl Acetate Inhalation central nervous system depression May cause drowsiness or dizziness NOAEL Not available 2-Methylbutyl Acetate Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Ethylbenzene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Formaldehyde Inhalation respiratory system Causes damage to organs Rat LOAEL 128 ppm 6 hours Formaldehyde Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Toluene Inhalation auditory system | nervous system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney Some positive data exist, but the Rat NOAEL 11.3 15 weeks 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 13 of 16 and/or bladder data are not sufficient for classification mg/l Toluene Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 105 mg/kg/day 4 weeks Synthetic Amorphous Silica, Fumed, Crystalline Free Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Salicylic Acid Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 500 mg/kg/day 3 days Zinc Oxide Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 600 mg/kg/day 10 days Zinc Oxide Ingestion endocrine system | hematopoietic system | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Other NOAEL 500 mg/kg/day 6 months Titanium Dioxide Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.010 mg/l 2 years Titanium Dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not available occupational exposure Ethylbenzene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 2 years Ethylbenzene Inhalation liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 103 weeks Ethylbenzene Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 3.4 mg/l 28 days Ethylbenzene Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2.4 mg/l 5 days Ethylbenzene Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 3.3 mg/l 103 weeks Ethylbenzene Inhalation bone, teeth, nails, and/or hair | muscles All data are negative Multiple animal species NOAEL 4.2 mg/l 90 days 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 14 of 16 Ethylbenzene Inhalation heart | immune system | respiratory system All data are negative Multiple animal species NOAEL 3.3 mg/l 2 years Ethylbenzene Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 680 mg/kg/day 6 months Carbon Black Inhalation pneumoconiosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Formaldehyde Dermal respiratory system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 80 mg/kg/day 60 weeks Formaldehyde Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat NOAEL 0.3 ppm 28 months Formaldehyde Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 20 ppm 13 weeks Formaldehyde Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 15 ppm 3 weeks Formaldehyde Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 10 ppm 13 weeks Formaldehyde Inhalation endocrine system | immune system | muscles | kidney and/or bladder All data are negative Rat NOAEL 15 ppm 28 months Formaldehyde Inhalation eyes | vascular system All data are negative Rat NOAEL 14.3 ppm 2 years Formaldehyde Inhalation heart All data are negative Mouse NOAEL 14.3 ppm 2 years Formaldehyde Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 300 mg/kg/day 2 years Formaldehyde Ingestion immune system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 20 mg/kg/day 4 weeks Formaldehyde Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 15 mg/kg/day 24 months Formaldehyde Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 109 mg/kg/day 2 years Formaldehyde Ingestion heart | endocrine system | hematopoietic system | respiratory system | vascular system All data are negative Rat NOAEL 300 mg/kg/day 2 years Formaldehyde Ingestion skin | muscles | eyes All data are negative Rat NOAEL 109 mg/kg/day 2 years Aspiration Hazard Name Value Toluene Aspiration hazard Ethylbenzene Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 15 of 16 Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Toluene 108-88-3 30 - 60 Zinc Oxide (ZINC COMPOUNDS) 1314-13-2 0.5 - 1.5 Ethylbenzene 100-41-4 < 0.5 Benzene 71-43-2 < 0.1 Benzene (Benzene) 71-43-2 < 0.1 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Acrylonitrile 107-13-1 Carcinogen Cumene 98-82-8 Carcinogen Ethylbenzene 100-41-4 Carcinogen Toluene 108-88-3 Female reproductive toxin Toluene 108-88-3 Developmental Toxin Carbon Black 1333-86-4 Carcinogen Titanium Dioxide 13463-67-7 Carcinogen 3M? Heavy Drip-Chek? Sealer, PN 08531 11/26/14 __________________________________________________________________________________________ Page 16 of 16 Formaldehyde 50-00-0 Carcinogen Benzene 71-43-2 Male reproductive toxin Benzene 71-43-2 Carcinogen Benzene 71-43-2 Developmental Toxin WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 10-5259-6 Version Number: 52.00 Issue Date: 11/26/14 Supercedes Date: 11/16/11 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com