3M? Urethane Seam Sealer, Gray, PN 08361, 08362 06/05/14 __________________________________________________________________________________________ Page 1 of 14 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 08-5018-0 Version Number: 6.00 Issue Date: 06/05/14 Supercedes Date: 08/02/06 SECTION 1: Identification 1.1. Product identifier 3M? Urethane Seam Sealer, Gray, PN 08361, 08362 Product Identification Numbers 60-4550-5460-5, 60-9800-3472-6 1.2. Recommended use and restrictions on use Recommended use Automotive, Adhesive/Sealant 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Respiratory Sensitizer: Category 1. Skin Sensitizer: Category 1. Carcinogenicity: Category 2. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger 3M? Urethane Seam Sealer, Gray, PN 08361, 08362 06/05/14 __________________________________________________________________________________________ Page 2 of 14 Symbols Health Hazard | Pictograms Hazard Statements Causes serious eye irritation. Causes skin irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. Causes damage to organs: sensory organs | Causes damage to organs through prolonged or repeated exposure: nervous system | sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. In case of inadequate ventilation wear respiratory protection. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Get medical advice/attention if you feel unwell. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 3M? Urethane Seam Sealer, Gray, PN 08361, 08362 06/05/14 __________________________________________________________________________________________ Page 3 of 14 2.3. Hazards not otherwise classified Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. 32% of the mixture consists of ingredients of unknown acute dermal toxicity. 118% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Urethane Polymer 68130-40-5 15 - 40 Trade Secret * Poly (Vinyl Chloride) 9002-86-2 10 - 30 Trade Secret * Sulfonic Acids, C10-18-Alkane, Ph Esters 70775-94-9 10 - 30 Trade Secret * Xylene 1330-20-7 4 - 10 Trade Secret * Calcium Oxide 1305-78-8 1 - 5 Trade Secret * Ethylbenzene 100-41-4 1 - 5 Trade Secret * Titanium Dioxide 13463-67-7 1 - 5 Trade Secret * Hydrotreated Light Petroleum Distillates 64742-47-8 0.5 - 1.5 Trade Secret * P,P'-Methylenebis(phenyl isocyanate) 101-68-8 < 0.2 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media DO NOT USE WATER In case of fire: Use a carbon dioxide or dry chemical extinguisher to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. 3M? Urethane Seam Sealer, Gray, PN 08361, 08362 06/05/14 __________________________________________________________________________________________ Page 4 of 14 Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Collect as much of the spilled material as possible. Place in a container approved for transportation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure build-up. Place in a metal container approved for transportation by appropriate authorities. Clean up residue. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Keep away from reactive metals (eg. Aluminum, zinc etc.) to avoid the formation of hydrogen gas that could create an explosion hazard. Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal container. Keep cool. Protect from sunlight. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidizing agents. Store in a dry place. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA:20 ppm Ethylbenzene 100-41-4 CMRG TWA:25 ppm;STEL:75 ppm Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm) FREE ISOCYANATES 101-68-8 Manufacturer determined TWA:0.005 ppm;STEL:0.02 ppm 3M? Urethane Seam Sealer, Gray, PN 08361, 08362 06/05/14 __________________________________________________________________________________________ Page 5 of 14 P,P'-Methylenebis(phenyl isocyanate) 101-68-8 ACGIH TWA:0.005 ppm P,P'-Methylenebis(phenyl isocyanate) 101-68-8 OSHA CEIL:0.2 mg/m3(0.02 ppm) Calcium Oxide 1305-78-8 ACGIH TWA:2 mg/m3 Calcium Oxide 1305-78-8 OSHA TWA:5 mg/m3 Xylene 1330-20-7 ACGIH TWA:100 ppm;STEL:150 ppm Xylene 1330-20-7 CMRG TWA:50 ppm;STEL:75 ppm Xylene 1330-20-7 OSHA TWA:435 mg/m3(100 ppm) Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 Titanium Dioxide 13463-67-7 CMRG TWA(as respirable dust):5 mg/m3 Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3 Hydrotreated Light Petroleum Distillates 64742-47-8 CMRG TWA:165 ppm JET FUELS (NON-AEROSOL), AS TOTAL HYDROCARBON VAPOR 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 Skin Notation Kerosine (petroleum) 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 Skin Notation Poly (Vinyl Chloride) 9002-86-2 ACGIH TWA(respirable fraction):1 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide local exhaust ventilation at transfer points. Provide ventilated enclosure for heat curing. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Provide ventilation adequate to maintain dust concentration below minimum explosive concentrations. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Wear eye/face protection. Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Wear protective gloves. Gloves made from the following material(s) are recommended: Nitrile Rubber Natural Rubber 3M? Urethane Seam Sealer, Gray, PN 08361, 08362 06/05/14 __________________________________________________________________________________________ Page 6 of 14 If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron ? Nitrile Respiratory protection In case of inadequate ventilation wear respiratory protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Solid Specific Physical Form: Paste Odor, Color, Grade: Solvent odor, black paste. Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point 137 ?C Flash Point No flash point Evaporation rate Not Applicable Flammability (solid, gas) Not Classified Flammable Limits(LEL) 0.6 % volume Flammable Limits(UEL) 7 % volume Vapor Pressure No Data Available Vapor Density 4 [Ref Std: AIR=1] Density 1.16 g/ml Specific Gravity 1.17 [Ref Std: WATER=1] Solubility in Water Negligible Autoignition temperature > 200 ?C Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 7.11 % weight [Test Method: Calculated] Hazardous Air Pollutants 0.69 lb HAPS/gal [Test Method: Calculated] Hazardous Air Pollutants 0.112 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 108 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 9.3 % weight [Test Method: calculated per CARB title 2] Percent volatile 9.3 % [Details: Excluding exempt compounds] VOC Less H2O & Exempt Solvents 108 g/l [Test Method: tested per EPA method 24] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 3M? Urethane Seam Sealer, Gray, PN 08361, 08362 06/05/14 __________________________________________________________________________________________ Page 7 of 14 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat High shear and high temperature conditions Sparks and/or flames Temperatures above the boiling point 10.5. Incompatible materials Amines Alcohols Water Reaction with water, alcohols, and amines is not hazardous if container can vent to the atmosphere to prevent pressure buildup. Accelerators Alkali and alkaline earth metals Reactive metals Reducing agents Strong acids Strong bases Strong oxidizing agents Al or Mg powder and high/shear temperature conditions Combustibles Finely divided active metals 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. 3M? Urethane Seam Sealer, Gray, PN 08361, 08362 06/05/14 __________________________________________________________________________________________ Page 8 of 14 Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. May cause target organ effects after inhalation. Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Target Organ Effects: Single exposure may cause: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Prolonged or repeated exposure may cause: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer Additional Information: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE > 50 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Urethane Polymer Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Poly (Vinyl Chloride) Dermal LD50 estimated to be > 5,000 mg/kg Poly (Vinyl Chloride) Ingestion LD50 estimated to be > 5,000 mg/kg Sulfonic Acids, C10-18-Alkane, Ph Esters Dermal Rat LD50 > 1,000 mg/kg Sulfonic Acids, C10-18-Alkane, Ph Esters Ingestion Rat LD50 > 5,000 mg/kg Xylene Dermal Rabbit LD50 > 4,200 mg/kg Xylene Inhalation- Vapor (4 hours) Rat LC50 29 mg/l Xylene Ingestion Rat LD50 3,523 mg/kg Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg Titanium Dioxide Inhalation- Rat LC50 > 6.82 mg/l 3M? Urethane Seam Sealer, Gray, PN 08361, 08362 06/05/14 __________________________________________________________________________________________ Page 9 of 14 Dust/Mist (4 hours) Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg Ethylbenzene Inhalation- Vapor (4 hours) Rat LC50 17.4 mg/l Ethylbenzene Ingestion Rat LD50 4,769 mg/kg Calcium Oxide Ingestion Rat LD50 500-2000 mg/kg Hydrotreated Light Petroleum Distillates Dermal Rabbit LD50 > 3,160 mg/kg Hydrotreated Light Petroleum Distillates Inhalation- Dust/Mist (4 hours) Rat LC50 > 3.0 mg/l Hydrotreated Light Petroleum Distillates Ingestion Rat LD50 > 5,000 mg/kg P,P'-Methylenebis(phenyl isocyanate) Inhalation- Vapor LC50 estimated to be 10 - 20 mg/l P,P'-Methylenebis(phenyl isocyanate) Dermal Rabbit LD50 > 5,000 mg/kg P,P'-Methylenebis(phenyl isocyanate) Inhalation- Dust/Mist (4 hours) Rat LC50 0.369 mg/l P,P'-Methylenebis(phenyl isocyanate) Ingestion Rat LD50 31,600 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Poly (Vinyl Chloride) No significant irritation Xylene Rabbit Mild irritant Titanium Dioxide Rabbit No significant irritation Ethylbenzene Rabbit Mild irritant Calcium Oxide official classifica tion Corrosive Hydrotreated Light Petroleum Distillates Rabbit Mild irritant P,P'-Methylenebis(phenyl isocyanate) official classifica tion Irritant Serious Eye Damage/Irritation Name Species Value Xylene Rabbit Mild irritant Titanium Dioxide Rabbit No significant irritation Ethylbenzene Rabbit Moderate irritant Calcium Oxide Rabbit Corrosive Hydrotreated Light Petroleum Distillates Rabbit Mild irritant P,P'-Methylenebis(phenyl isocyanate) official classifica tion Severe irritant Skin Sensitization Name Species Value Titanium Dioxide Human and animal Not sensitizing Ethylbenzene Human Not sensitizing Hydrotreated Light Petroleum Distillates Guinea pig Not sensitizing P,P'-Methylenebis(phenyl isocyanate) official classifica tion Sensitizing Respiratory Sensitization Name Species Value P,P'-Methylenebis(phenyl isocyanate) Human Sensitizing Germ Cell Mutagenicity 3M? Urethane Seam Sealer, Gray, PN 08361, 08362 06/05/14 __________________________________________________________________________________________ Page 10 of 14 Name Route Value Poly (Vinyl Chloride) In Vitro Not mutagenic Xylene In Vitro Not mutagenic Xylene In vivo Not mutagenic Titanium Dioxide In Vitro Not mutagenic Titanium Dioxide In vivo Not mutagenic Ethylbenzene In vivo Not mutagenic Ethylbenzene In Vitro Some positive data exist, but the data are not sufficient for classification Calcium Oxide In Vitro Not mutagenic Hydrotreated Light Petroleum Distillates In Vitro Not mutagenic P,P'-Methylenebis(phenyl isocyanate) In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Poly (Vinyl Chloride) Not Specified Rat Some positive data exist, but the data are not sufficient for classification Xylene Dermal Rat Not carcinogenic Xylene Ingestion Multiple animal species Not carcinogenic Xylene Inhalation Human Some positive data exist, but the data are not sufficient for classification Titanium Dioxide Ingestion Multiple animal species Not carcinogenic Titanium Dioxide Inhalation Rat Carcinogenic Ethylbenzene Inhalation Multiple animal species Carcinogenic Hydrotreated Light Petroleum Distillates Dermal Mouse Some positive data exist, but the data are not sufficient for classification P,P'-Methylenebis(phenyl isocyanate) Inhalation Rat Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Poly (Vinyl Chloride) Not Specified Not toxic to development Mouse NOAEL Not available during gestation Xylene Ingestion Not toxic to female reproduction Mouse NOAEL 1,000 mg/kg/day 103 weeks Xylene Ingestion Not toxic to male reproduction Mouse NOAEL 1,000 mg/kg/day 103 weeks Xylene Inhalation Some positive female reproductive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Xylene Ingestion Some positive developmental data exist, but the data are not sufficient for classification Mouse NOAEL Not available during organogenesi s Xylene Inhalation Some positive developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available during gestation Ethylbenzene Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 4.3 mg/l premating & during gestation P,P'-Methylenebis(phenyl isocyanate) Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 0.004 mg/l during organogenesi s Lactation 3M? Urethane Seam Sealer, Gray, PN 08361, 08362 06/05/14 __________________________________________________________________________________________ Page 11 of 14 Name Route Species Value Xylene Ingestion Mouse Does not cause effects on or via lactation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Xylene Inhalation auditory system Causes damage to organs Rat LOAEL 6.3 mg/l 8 hours Xylene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Xylene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Xylene Inhalation eyes Some positive data exist, but the data are not sufficient for classification Rat NOAEL 3.5 mg/l not available Xylene Inhalation liver Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available Xylene Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available Xylene Ingestion eyes Some positive data exist, but the data are not sufficient for classification Rat NOAEL 250 mg/kg not applicable Ethylbenzene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Calcium Oxide Inhalation respiratory irritation May cause respiratory irritation Not available NOAEL Not available occupational exposure Hydrotreated Light Petroleum Distillates Inhalation central nervous system depression May cause drowsiness or dizziness NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available P,P'-Methylenebis(phenyl isocyanate) Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Poly (Vinyl Chloride) Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL .013 mg/l 22 months Xylene Inhalation nervous system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.4 mg/l 4 weeks Xylene Inhalation auditory system May cause damage to organs though prolonged or repeated exposure Rat LOAEL 7.8 mg/l 5 days Xylene Inhalation liver Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available Xylene Inhalation heart | endocrine system | hematopoietic system | muscles | kidney and/or bladder | respiratory system All data are negative Multiple animal species NOAEL 3.5 mg/l 13 weeks 3M? Urethane Seam Sealer, Gray, PN 08361, 08362 06/05/14 __________________________________________________________________________________________ Page 12 of 14 Xylene Ingestion auditory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 900 mg/kg/day 2 weeks Xylene Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,500 mg/kg/day 90 days Xylene Ingestion liver Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available Xylene Ingestion heart | skin | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | immune system | nervous system | respiratory system All data are negative Mouse NOAEL 1,000 mg/kg/day 103 weeks Titanium Dioxide Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.010 mg/l 2 years Titanium Dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not available occupational exposure Ethylbenzene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 2 years Ethylbenzene Inhalation liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 103 weeks Ethylbenzene Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 3.4 mg/l 28 days Ethylbenzene Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2.4 mg/l 5 days Ethylbenzene Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 3.3 mg/l 103 weeks Ethylbenzene Inhalation bone, teeth, nails, and/or hair | muscles All data are negative Multiple animal species NOAEL 4.2 mg/l 90 days Ethylbenzene Inhalation heart | immune system | respiratory system All data are negative Multiple animal species NOAEL 3.3 mg/l 2 years Ethylbenzene Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 680 mg/kg/day 6 months P,P'-Methylenebis(phenyl isocyanate) Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.004 mg/l 13 weeks Aspiration Hazard Name Value Xylene Aspiration hazard Ethylbenzene Aspiration hazard Hydrotreated Light Petroleum Distillates Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material 3M? Urethane Seam Sealer, Gray, PN 08361, 08362 06/05/14 __________________________________________________________________________________________ Page 13 of 14 and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Xylene 1330-20-7 4 - 10 Xylene (Benzene, 1,2-dimethyl-) 1330-20-7 4 - 10 Xylene (Benzene, 1,3-dimethyl-) 1330-20-7 4 - 10 Xylene (Benzene, 1,4-dimethyl-) 1330-20-7 4 - 10 Xylene (Benzene, dimethyl-) 1330-20-7 4 - 10 Ethylbenzene 100-41-4 1 - 5 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Ethylbenzene 100-41-4 Carcinogen Titanium Dioxide 13463-67-7 Carcinogen 3M? Urethane Seam Sealer, Gray, PN 08361, 08362 06/05/14 __________________________________________________________________________________________ Page 14 of 14 WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 2 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 08-5018-0 Version Number: 6.00 Issue Date: 06/05/14 Supercedes Date: 08/02/06 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com