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3M? High Strength Red Threadlocker, 08730 10/07/14 __________________________________________________________________________________________ Page 1 of 10 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 07-7789-6 Version Number: 6.00 Issue Date: 10/07/14 Supercedes Date: 03/08/13 SECTION 1: Identification 1.1. Product identifier 3M? High Strength Red Threadlocker, 08730 Product Identification Numbers LB-K000-0570-0, 60-4550-6752-4, 60-9800-2824-9 1.2. Recommended use and restrictions on use Recommended use Automotive, Adhesive 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Skin Sensitizer: Category 1. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Exclamation mark | Health Hazard | 3M? High Strength Red Threadlocker, 08730 10/07/14 __________________________________________________________________________________________ Page 2 of 10 Pictograms Hazard Statements Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction. Causes damage to organs through prolonged or repeated exposure: nervous system | respiratory system | Precautionary Statements General: Keep out of reach of children. Prevention: Do not breathe dust/fume/gas/mist/vapors/spray. Wear eye/face protection. Wear protective gloves. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Get medical advice/attention if you feel unwell. Storage: Keep cool. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 18% of the mixture consists of ingredients of unknown acute oral toxicity. 22% of the mixture consists of ingredients of unknown acute dermal toxicity. 73% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Polyethylene Glycol Dimethacrylate 25852-47-5 60 - 90 Trade Secret * Polyester Resin Trade Secret* 10 - 30 Trade Secret * 3M? High Strength Red Threadlocker, 08730 10/07/14 __________________________________________________________________________________________ Page 3 of 10 Cumene Hydroperoxide 80-15-9 1 - 5 Trade Secret * Saccharin 81-07-2 1 - 5 Trade Secret * Polyethylene 9002-88-4 1 - 5 Trade Secret * Synthetic Amorphous Silica, Fumed, Crystalline Free 112945-52-5 1 - 5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a carbon dioxide or dry chemical extinguisher to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially 3M? High Strength Red Threadlocker, 08730 10/07/14 __________________________________________________________________________________________ Page 4 of 10 available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Keep away from reactive metals (eg. Aluminum, zinc etc.) to avoid the formation of hydrogen gas that could create an explosion hazard. 7.2. Conditions for safe storage including any incompatibilities Protect from sunlight. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidizing agents. Store in a dry place. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments SILICA, AMORPHOUS 112945-52- 5 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Cumene Hydroperoxide 80-15-9 AIHA TWA:6 mg/m3(1 ppm) Skin Notation ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the 3M? High Strength Red Threadlocker, 08730 10/07/14 __________________________________________________________________________________________ Page 5 of 10 substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber Fluoroelastomer Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: Red paste, mild organic odor Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point > 300 ?F Flash Point >=212 ?F [Test Method: Cleveland Open Cup] Flash Point Flash point > 93 ?C (200 ?F) Evaporation rate Nil Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure > 5 mmHg Vapor Density 1.01 [Ref Std: AIR=1] Density 1.07 - 1.15 g/ml Specific Gravity 1.07 - 1.15 [Ref Std: WATER=1] Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 0.09 % weight [Test Method: Calculated] Volatile Organic Compounds 0.28 lb/gal [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 3.1 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 33 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 3.17 % VOC Less H2O & Exempt Solvents 33 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 3M? High Strength Red Threadlocker, 08730 10/07/14 __________________________________________________________________________________________ Page 6 of 10 10.3. Possibility of hazardous reactions Hazardous polymerization may occur. 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Strong acids Strong oxidizing agents Aluminum Al or Mg powder and high/shear temperature conditions Alkali and alkaline earth metals Metal powder Reducing agents Strong bases Zinc 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Oxides of Nitrogen Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: 3M? High Strength Red Threadlocker, 08730 10/07/14 __________________________________________________________________________________________ Page 7 of 10 May be harmful if swallowed. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Target Organ Effects: Prolonged or repeated exposure may cause: Prolonged or repeated exposure by inhalation may cause: Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 20 - 50 mg/l Overall product Ingestion No data available; calculated ATE 2,000 - 5,000 mg/kg Polyethylene Glycol Dimethacrylate Dermal LD50 estimated to be > 5,000 mg/kg Polyethylene Glycol Dimethacrylate Ingestion Rat LD50 > 5,000 mg/kg Saccharin Ingestion Mouse LD50 17,000 mg/kg Polyethylene Dermal LD50 estimated to be > 5,000 mg/kg Polyethylene Ingestion Rat LD50 > 2,000 mg/kg Cumene Hydroperoxide Dermal Rat LD50 500 mg/kg Cumene Hydroperoxide Inhalation- Vapor (4 hours) Rat LC50 1.4 mg/l Cumene Hydroperoxide Ingestion Rat LD50 382 mg/kg Synthetic Amorphous Silica, Fumed, Crystalline Free Dermal Rabbit LD50 > 5,000 mg/kg Synthetic Amorphous Silica, Fumed, Crystalline Free Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Rat LD50 > 5,110 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Overall product Irritant Polyethylene No significant irritation Cumene Hydroperoxide Rabbit Corrosive Synthetic Amorphous Silica, Fumed, Crystalline Free Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Cumene Hydroperoxide Rabbit Corrosive Synthetic Amorphous Silica, Fumed, Crystalline Free Rabbit No significant irritation Skin Sensitization Name Species Value Synthetic Amorphous Silica, Fumed, Crystalline Free Human and animal Not sensitizing Respiratory Sensitization 3M? High Strength Red Threadlocker, 08730 10/07/14 __________________________________________________________________________________________ Page 8 of 10 Name Species Value Germ Cell Mutagenicity Name Route Value Cumene Hydroperoxide In vivo Not mutagenic Cumene Hydroperoxide In Vitro Some positive data exist, but the data are not sufficient for classification Synthetic Amorphous Silica, Fumed, Crystalline Free In Vitro Not mutagenic Carcinogenicity Name Route Species Value Polyethylene Not Specified Multiple animal species Some positive data exist, but the data are not sufficient for classification Synthetic Amorphous Silica, Fumed, Crystalline Free Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Cumene Hydroperoxide Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available occupational exposure Cumene Hydroperoxide Inhalation respiratory irritation May cause respiratory irritation Human NOAEL Not available occupational exposure Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Cumene Hydroperoxide Inhalation nervous system | respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.2 mg/l 7 days Cumene Hydroperoxide Inhalation heart | liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.03 mg/l 90 days Synthetic Amorphous Silica, Fumed, Crystalline Free Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information 3M? High Strength Red Threadlocker, 08730 10/07/14 __________________________________________________________________________________________ Page 9 of 10 Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Saccharin 81-07-2 1 - 5 Cumene Hydroperoxide 80-15-9 1 - 5 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. 3M? High Strength Red Threadlocker, 08730 10/07/14 __________________________________________________________________________________________ Page 10 of 10 SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 07-7789-6 Version Number: 6.00 Issue Date: 10/07/14 Supercedes Date: 03/08/13 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com