3M? Rust Fighter-I, PN 08892 02/11/15 __________________________________________________________________________________________ Page 1 of 13 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 27-7230-9 Version Number: 5.00 Issue Date: 02/11/15 Supercedes Date: 05/06/11 SECTION 1: Identification 1.1. Product identifier 3M? Rust Fighter-I, PN 08892 Product Identification Numbers 60-4550-5146-0, 60-4550-5281-5 1.2. Recommended use and restrictions on use Recommended use Automotive, Rust protection coating for internal auto parts. 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 1. Skin Corrosion/Irritation: Category 2. Simple Asphyxiant. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (central nervous system): Category 3. 2.2. Label elements Signal word Danger Symbols Flame | Exclamation mark | Health Hazard | 3M? Rust Fighter-I, PN 08892 02/11/15 __________________________________________________________________________________________ Page 2 of 13 Pictograms Hazard Statements Extremely flammable aerosol. Causes skin irritation. May cause drowsiness or dizziness. May displace oxygen and cause rapid suffocation. Causes damage to organs: cardiovascular system | Precautionary Statements General: Keep out of reach of children. Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Specific treatment (see Notes to Physician on this label). Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. 10% of the mixture consists of ingredients of unknown acute oral toxicity. 10% of the mixture consists of ingredients of unknown acute dermal toxicity. 3M? Rust Fighter-I, PN 08892 02/11/15 __________________________________________________________________________________________ Page 3 of 13 29% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Medium Aliphatic Solvent Naphtha 64742-88-7 40 - 70 Trade Secret * Propane 74-98-6 10 - 30 Trade Secret * Isobutane 75-28-5 5 - 10 Trade Secret * Calcium Dodecylbenzensulfonate 26264-06-2 1 - 10 Trade Secret * Calcium Carbonate 471-34-1 1 - 10 Trade Secret * Hydrotreated Heavy Paraffinic Distillate (Petroleum) 64742-54-7 < 5 Trade Secret * Solvent-Refined Heavy Paraffinic Petroleum Distillates 64741-88-4 < 5 Trade Secret * Light Aromatic Solvent Naphtha (Petroleum) 64742-95-6 1 - 5 Trade Secret * Cumene 98-82-8 < 0.1 Trade Secret * Benzene 71-43-2 < 0.01 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion 3M? Rust Fighter-I, PN 08892 02/11/15 __________________________________________________________________________________________ Page 4 of 13 Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Calcium Carbonate 471-34-1 CMRG TWA:10 mg/m3;STEL:20 mg/m3 Limestone 471-34-1 OSHA TWA(as total dust):15 mg/m3;TWA(respirable 3M? Rust Fighter-I, PN 08892 02/11/15 __________________________________________________________________________________________ Page 5 of 13 fraction):5 mg/m3 PETROLEUM DISTILLATES 64741-88-4 OSHA TWA:2000 mg/m3(500 ppm) Solvent-Refined Heavy Paraffinic Petroleum Distillates 64741-88-4 CMRG TWA:5 mg/m3 Paraffin oil 64741-88-4 OSHA TWA(as mist):5 mg/m3 Medium Aliphatic Solvent Naphtha 64742-88-7 CMRG TWA:100 ppm Light Aromatic Solvent Naphtha (Petroleum) 64742-95-6 CMRG TWA:50 ppm(245 mg/m3) Benzene 71-43-2 ACGIH TWA:0.5 ppm;STEL:2.5 ppm A1: Confirmed human carcin., Skin Notation Benzene 71-43-2 OSHA TWA:1 ppm;TWA:10 ppm;STEL:5 ppm;CEIL:25 ppm 29 CFR 1910.1028 Propane 74-98-6 ACGIH Limit value not established: Propane 74-98-6 OSHA TWA:1800 mg/m3(1000 ppm) Natural gas 75-28-5 ACGIH Limit value not established: Isobutane 75-28-5 ACGIH STEL:1000 ppm Cumene 98-82-8 OSHA TWA:245 mg/m3(50 ppm) Skin Notation Cumene 98-82-8 ACGIH TWA:50 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Neoprene Nitrile Rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: 3M? Rust Fighter-I, PN 08892 02/11/15 __________________________________________________________________________________________ Page 6 of 13 Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Aerosol Odor, Color, Grade: Solvent odor tan Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point Not Applicable Flash Point -50 ?F Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Density 4.70 [Ref Std: AIR=1] Density 0.770 g/ml Specific Gravity 0.770 [Ref Std: WATER=1] Solubility in Water Slight (less than 10%) Solubility- non-water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity Not Applicable Hazardous Air Pollutants 0.0115 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 71.5 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 550 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 71.5 % weight VOC Less H2O & Exempt Solvents 550 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition None known. 3M? Rust Fighter-I, PN 08892 02/11/15 __________________________________________________________________________________________ Page 7 of 13 Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: May be harmful in contact with skin. Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Eye Contact: Sprayed material may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Carcinogenicity: Ingredient CAS No. Class Description Regulation Benzene 71-43-2 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Benzene 71-43-2 Known human carcinogen National Toxicology Program Carcinogens Benzene 71-43-2 Cancer hazard OSHA Carcinogens Cumene 98-82-8 Grp. 2B: Possible human carc. International Agency for Research on Cancer 3M? Rust Fighter-I, PN 08892 02/11/15 __________________________________________________________________________________________ Page 8 of 13 Cumene 98-82-8 Anticipated human carcinogen National Toxicology Program Carcinogens Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE 2,000 - 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 20 - 50 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Medium Aliphatic Solvent Naphtha Inhalation- Vapor LC50 estimated to be 20 - 50 mg/l Medium Aliphatic Solvent Naphtha Dermal Rabbit LD50 > 3,000 mg/kg Medium Aliphatic Solvent Naphtha Ingestion Rat LD50 > 5,000 mg/kg Propane Inhalation- Gas (4 hours) Rat LC50 > 200,000 ppm Isobutane Inhalation- Gas (4 hours) Rat LC50 276,000 ppm Calcium Carbonate Dermal Rat LD50 > 2,000 mg/kg Calcium Carbonate Inhalation- Dust/Mist (4 hours) Rat LC50 3.0 mg/l Calcium Carbonate Ingestion Rat LD50 6,450 mg/kg Hydrotreated Heavy Paraffinic Distillate (Petroleum) Dermal Rabbit LD50 > 5,000 mg/kg Solvent-Refined Heavy Paraffinic Petroleum Distillates Dermal Rabbit LD50 > 2,000 mg/kg Hydrotreated Heavy Paraffinic Distillate (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg Solvent-Refined Heavy Paraffinic Petroleum Distillates Ingestion Rat LD50 > 5,000 Light Aromatic Solvent Naphtha (Petroleum) Dermal Rabbit LD50 > 2,000 mg/kg Light Aromatic Solvent Naphtha (Petroleum) Inhalation- Vapor (4 hours) Rat LC50 > 5.2 mg/l Light Aromatic Solvent Naphtha (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg Cumene Dermal Rabbit LD50 > 3,160 mg/kg Cumene Inhalation- Vapor (4 hours) Rat LC50 39.4 mg/l Cumene Ingestion Rat LD50 1,400 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Medium Aliphatic Solvent Naphtha Rabbit Irritant Propane Rabbit Minimal irritation Isobutane Professio nal judgeme nt No significant irritation Calcium Carbonate Rabbit No significant irritation Hydrotreated Heavy Paraffinic Distillate (Petroleum) Rabbit Minimal irritation Solvent-Refined Heavy Paraffinic Petroleum Distillates Rabbit Minimal irritation Light Aromatic Solvent Naphtha (Petroleum) Rabbit Irritant Cumene Rabbit Minimal irritation Serious Eye Damage/Irritation Name Species Value Medium Aliphatic Solvent Naphtha Rabbit No significant irritation Propane Rabbit Mild irritant Isobutane Professio No significant irritation 3M? Rust Fighter-I, PN 08892 02/11/15 __________________________________________________________________________________________ Page 9 of 13 nal judgeme nt Calcium Carbonate Rabbit No significant irritation Hydrotreated Heavy Paraffinic Distillate (Petroleum) Rabbit Mild irritant Solvent-Refined Heavy Paraffinic Petroleum Distillates Rabbit Mild irritant Light Aromatic Solvent Naphtha (Petroleum) Rabbit Mild irritant Cumene Rabbit Mild irritant Skin Sensitization Name Species Value Medium Aliphatic Solvent Naphtha Guinea pig Not sensitizing Hydrotreated Heavy Paraffinic Distillate (Petroleum) Guinea pig Not sensitizing Solvent-Refined Heavy Paraffinic Petroleum Distillates Guinea pig Not sensitizing Light Aromatic Solvent Naphtha (Petroleum) Guinea pig Not sensitizing Cumene Guinea pig Not sensitizing Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Medium Aliphatic Solvent Naphtha In vivo Not mutagenic Medium Aliphatic Solvent Naphtha In Vitro Some positive data exist, but the data are not sufficient for classification Propane In Vitro Not mutagenic Isobutane In Vitro Not mutagenic Hydrotreated Heavy Paraffinic Distillate (Petroleum) In Vitro Some positive data exist, but the data are not sufficient for classification Solvent-Refined Heavy Paraffinic Petroleum Distillates In Vitro Some positive data exist, but the data are not sufficient for classification Cumene In Vitro Not mutagenic Cumene In vivo Not mutagenic Carcinogenicity Name Route Species Value Medium Aliphatic Solvent Naphtha Dermal Mouse Some positive data exist, but the data are not sufficient for classification Medium Aliphatic Solvent Naphtha Inhalation Human and animal Some positive data exist, but the data are not sufficient for classification Hydrotreated Heavy Paraffinic Distillate (Petroleum) Dermal Mouse Some positive data exist, but the data are not sufficient for classification Solvent-Refined Heavy Paraffinic Petroleum Distillates Dermal Mouse Some positive data exist, but the data are not sufficient for classification Light Aromatic Solvent Naphtha (Petroleum) Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Cumene Inhalation Multiple animal species Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Medium Aliphatic Solvent Naphtha Inhalation Not toxic to development Rat NOAEL 2.4 mg/l during organogenesi 3M? Rust Fighter-I, PN 08892 02/11/15 __________________________________________________________________________________________ Page 10 of 13 s Calcium Carbonate Ingestion Not toxic to development Rat NOAEL 625 mg/kg/day premating & during gestation Light Aromatic Solvent Naphtha (Petroleum) Inhalation Not toxic to female reproduction Rat NOAEL 1,500 ppm 2 generation Light Aromatic Solvent Naphtha (Petroleum) Inhalation Not toxic to male reproduction Rat NOAEL 1,500 ppm 2 generation Light Aromatic Solvent Naphtha (Petroleum) Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 500 ppm 2 generation Cumene Inhalation Not toxic to female reproduction Rat NOAEL 59 mg/l 13 weeks Cumene Ingestion Not toxic to male reproduction Rat NOAEL 769 mg/kg/day 6 months Cumene Inhalation Not toxic to male reproduction Rat NOAEL 59 mg/l 13 weeks Cumene Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rabbit NOAEL 11.3 mg/l during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Medium Aliphatic Solvent Naphtha Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Medium Aliphatic Solvent Naphtha Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Medium Aliphatic Solvent Naphtha Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Dog NOAEL 6.5 mg/l 4 hours Propane Inhalation cardiac sensitization Causes damage to organs Human NOAEL Not available Propane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Propane Inhalation respiratory irritation All data are negative Human NOAEL Not available Isobutane Inhalation cardiac sensitization Causes damage to organs Multiple animal species NOAEL Not available Isobutane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Isobutane Inhalation respiratory irritation All data are negative Mouse NOAEL Not available Calcium Carbonate Inhalation respiratory system All data are negative Rat NOAEL 0.812 mg/l 90 minutes Hydrotreated Heavy Paraffinic Distillate (Petroleum) Inhalation central nervous system depression May cause drowsiness or dizziness NOAEL Not available Solvent-Refined Heavy Paraffinic Petroleum Distillates Inhalation central nervous system depression Some positive data exist, but the data are not sufficient for classification NOAEL Not available Light Aromatic Solvent Naphtha (Petroleum) Inhalation central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Light Aromatic Solvent Naphtha (Petroleum) Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Professio nal judgeme nt NOAEL Not available Light Aromatic Solvent Naphtha (Petroleum) Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal NOAEL Not available 3M? Rust Fighter-I, PN 08892 02/11/15 __________________________________________________________________________________________ Page 11 of 13 judgeme nt Cumene Inhalation central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available not available Cumene Inhalation respiratory irritation May cause respiratory irritation Human LOAEL 0.2 mg/l occupational exposure Cumene Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL Not available not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Medium Aliphatic Solvent Naphtha Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 4.6 mg/l 6 months Medium Aliphatic Solvent Naphtha Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 1.9 mg/l 13 weeks Medium Aliphatic Solvent Naphtha Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.6 mg/l 90 days Medium Aliphatic Solvent Naphtha Inhalation bone, teeth, nails, and/or hair | blood | liver | muscles All data are negative Rat NOAEL 5.6 mg/l 12 weeks Medium Aliphatic Solvent Naphtha Inhalation heart All data are negative Multiple animal species NOAEL 1.3 mg/l 90 days Isobutane Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 4,500 ppm 13 weeks Calcium Carbonate Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Hydrotreated Heavy Paraffinic Distillate (Petroleum) Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.21 mg/l 28 days Solvent-Refined Heavy Paraffinic Petroleum Distillates Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.21 mg/l 28 days Cumene Inhalation auditory system | endocrine system | hematopoietic system | liver | nervous system | eyes Some positive data exist, but the data are not sufficient for classification Rat NOAEL 59 mg/l 13 weeks Cumene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 4.9 mg/l 13 weeks Cumene Inhalation respiratory system All data are negative Rat NOAEL 59 mg/l 13 weeks Cumene Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 769 mg/kg/day 6 months Cumene Ingestion heart | endocrine system | hematopoietic system | liver | respiratory system All data are negative Rat NOAEL 769 mg/kg/day 6 months Aspiration Hazard Name Value Medium Aliphatic Solvent Naphtha Aspiration hazard Solvent-Refined Heavy Paraffinic Petroleum Distillates Aspiration hazard Light Aromatic Solvent Naphtha (Petroleum) Aspiration hazard Cumene Aspiration hazard 3M? Rust Fighter-I, PN 08892 02/11/15 __________________________________________________________________________________________ Page 12 of 13 Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Benzene 71-43-2 Male reproductive toxin Benzene 71-43-2 Carcinogen Benzene 71-43-2 Developmental Toxin Cumene 98-82-8 Carcinogen WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. 3M? Rust Fighter-I, PN 08892 02/11/15 __________________________________________________________________________________________ Page 13 of 13 WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None Aerosol Storage Code: 3 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 27-7230-9 Version Number: 5.00 Issue Date: 02/11/15 Supercedes Date: 05/06/11 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com