3M? Heavy Duty Wheel Cleaner, 38374, 38375 10/02/14 __________________________________________________________________________________________ Page 1 of 11 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 29-7822-9 Version Number: 2.00 Issue Date: 10/02/14 Supercedes Date: 07/20/11 SECTION 1: Identification 1.1. Product identifier 3M? Heavy Duty Wheel Cleaner, 38374, 38375 Product Identification Numbers 60-4550-5833-3, 60-4550-5834-1 1.2. Recommended use and restrictions on use Recommended use Automotive, Wheel Cleaner 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Corrosive to metal: Category 1. Acute Toxicity (oral): Category 4. Serious Eye Damage/Irritation: Category 1. Skin Corrosion/Irritation: Category 1B. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols 3M? Heavy Duty Wheel Cleaner, 38374, 38375 10/02/14 __________________________________________________________________________________________ Page 2 of 11 Corrosion | Exclamation mark | Health Hazard | Pictograms Hazard Statements May be corrosive to metals. Harmful if swallowed. Causes serious eye damage. Causes severe skin burns and eye damage. Causes damage to organs: cardiovascular system | respiratory system | Causes damage to organs through prolonged or repeated exposure: musculoskeletal system | kidney/urinary tract | Precautionary Statements General: Keep out of reach of children. Prevention: Keep only in original container. Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves, protective clothing, and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. IF exposed: Call a POISON CENTER or doctor/physician. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Specific treatment (see Notes to Physician on this label). Get medical advice/attention if you feel unwell. Absorb spillage to prevent material damage. Storage: Store in a corrosive resistant container with a resistant inner liner. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified 3M? Heavy Duty Wheel Cleaner, 38374, 38375 10/02/14 __________________________________________________________________________________________ Page 3 of 11 May cause chemical gastrointestinal burns. 14% of the mixture consists of ingredients of unknown acute dermal toxicity. 5% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Water 7732-18-5 60 - 100 Trade Secret * Ammonium Bifluoride 1341-49-7 7 - 13 Trade Secret * Sodium Xylene Sulfonate 1300-72-7 1 - 5 Trade Secret * Ethoxylated C9-11 Alcohols 68439-46-3 < 2 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediate medical attention. Wash clothing before reuse. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Rinse mouth. Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture Exposure to extreme heat can give rise to thermal decomposition. None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Fluoride During Combustion Irritant Vapors or Gases During Combustion 3M? Heavy Duty Wheel Cleaner, 38374, 38375 10/02/14 __________________________________________________________________________________________ Page 4 of 11 5.3. Special protective actions for fire-fighters When fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. For large spills, if necessary, get assistance from professional spill clean up team. For small spills, carefully neutralize spill by adding appropriate dilute acid such as vinegar. Work slowly to avoid boiling or spattering. Continue to add neutralizing agent until reaction stops. Let cool before collecting. Or use a commercially available caustic (alkaline or basic) spill clean-up kit. Follow kit directions exactly. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a metal container approved for use in transportation by appropriate authorities. The container must be lined with polyethylene plastic or contain a plastic drum liner made of polyethylene. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Cover, but do not seal for 48 hours. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not breathe thermal decomposition products. Keep out of reach of children. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Store away from heat. Keep only in original container. Store in a corrosive resistant container with a resistant inner liner. Store away from acids. Store away from strong bases. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments FLUORIDES 1341-49-7 ACGIH TWA(as F):2.5 mg/m3 A4: Not class. as human carcin FLUORIDES 1341-49-7 OSHA TWA(as dust):2.5 3M? Heavy Duty Wheel Cleaner, 38374, 38375 10/02/14 __________________________________________________________________________________________ Page 5 of 11 mg/m3;TWA(as F):2.5 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide appropriate local exhaust when product is heated. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber Nitrile Rubber If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Boots - Nitrile Apron ? Butyl rubber Apron ? Nitrile Boots - Rubber Respiratory protection Use a positive pressure supplied-air respirator if there is a potential for over exposure from an uncontrolled release, exposure levels are not known, or under any other circumstances where air-purifying respirators may not provide adequate protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: Water-thin purple liquid with sweet odor. 3M? Heavy Duty Wheel Cleaner, 38374, 38375 10/02/14 __________________________________________________________________________________________ Page 6 of 11 Odor threshold No Data Available pH 4.5 - 5.5 Melting point No Data Available Boiling Point 210 ?F Flash Point Flash point > 93 ?C (200 ?F) [Test Method: Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density No Data Available Density 1.04 g/ml Specific Gravity 1.04 [Ref Std: WATER=1] Solubility in Water Complete Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 1 centipoise [Details: Approximate] Hazardous Air Pollutants 0 % weight [Test Method: Calculated] Volatile Organic Compounds 2 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 0.1 % weight [Test Method: calculated per CARB title 2] Percent volatile 78.8 % weight VOC Less H2O & Exempt Solvents 6 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Strong acids Strong bases Strong oxidizing agents Reacts with metal/glass to form Hydrofluoric acid 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. Extreme heat arising from situations such as misuse or equipment failure can generate hydrogen fluoride as a decomposition 3M? Heavy Duty Wheel Cleaner, 38374, 38375 10/02/14 __________________________________________________________________________________________ Page 7 of 11 product. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Skin Contact: Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. Allergic Skin Reaction (non-photo induced) in sensitive people: Signs/symptoms may include redness, swelling, blistering, and itching. May cause target organ effects after skin contact. Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Ingestion: Harmful if swallowed. Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen. May cause target organ effects after ingestion. Target Organ Effects: Allergic Skin Reaction (non-photo induced) in sensitive people: Signs/symptoms may include redness, swelling, blistering, and itching. Single exposure may cause: Cardiac Effects: Signs/symptoms may include irregular heartbeat (arrhythmia), changes in heart rate, damage to heart muscle, heart attack, and may be fatal. Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Prolonged or repeated exposure may cause: Hard Tissue Effects: Signs/symptoms may include color changes in the teeth and nails; changes in development of bone, teeth or nails; weakening of the bones; and/or hair loss. 3M? Heavy Duty Wheel Cleaner, 38374, 38375 10/02/14 __________________________________________________________________________________________ Page 8 of 11 Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Dust/Mist(4 hr) No data available; calculated ATE 5 - 12.5 mg/l Overall product Ingestion No data available; calculated ATE 300 - 2,000 mg/kg Ammonium Bifluoride Inhalation- Dust/Mist (4 hours) Rat LC50 0.74 mg/l Ammonium Bifluoride Ingestion Rat LD50 60 mg/kg Sodium Xylene Sulfonate Ingestion Rat LD50 > 5,000 mg/kg Ethoxylated C9-11 Alcohols Dermal Rabbit LD50 > 2,000 mg/kg Ethoxylated C9-11 Alcohols Ingestion Rat LD50 1,378 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Ethoxylated C9-11 Alcohols Rabbit Irritant Serious Eye Damage/Irritation Name Species Value Ethoxylated C9-11 Alcohols Corrosive Skin Sensitization Name Species Value Ethoxylated C9-11 Alcohols Guinea pig Not sensitizing Respiratory Sensitization Name Species Value Germ Cell Mutagenicity Name Route Value Ethoxylated C9-11 Alcohols In Vitro Not mutagenic Carcinogenicity Name Route Species Value Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Ethoxylated C9-11 Alcohols Dermal Not toxic to female reproduction Rat NOAEL 250 mg/kg/day 2 generation Ethoxylated C9-11 Alcohols Dermal Not toxic to development Rat NOAEL 250 mg/kg/day 2 generation Ethoxylated C9-11 Alcohols Dermal Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 100 mg/kg/day 2 generation Target Organ(s) 3M? Heavy Duty Wheel Cleaner, 38374, 38375 10/02/14 __________________________________________________________________________________________ Page 9 of 11 Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Ethoxylated C9-11 Alcohols Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Not available NOAEL Not available not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Ethoxylated C9-11 Alcohols Dermal kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 125 mg/kg/day 13 weeks Ethoxylated C9-11 Alcohols Dermal hematopoietic system All data are negative Rat NOAEL 125 mg/kg/day 13 weeks Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations 3M? Heavy Duty Wheel Cleaner, 38374, 38375 10/02/14 __________________________________________________________________________________________ Page 10 of 11 Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Ammonium Bifluoride (AMMONIA COMPOUNDS) 1341-49-7 7 - 13 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 3 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 29-7822-9 Version Number: 2.00 Issue Date: 10/02/14 Supercedes Date: 07/20/11 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com 3M? Heavy Duty Wheel Cleaner, 38374, 38375 10/02/14 __________________________________________________________________________________________ Page 11 of 11