SDS Repository

sds

Collection
3M SDS
Description
 
Tags
Search Tag
Filename
08752_msds.pdf
Source
 
Full Text
MATERIAL SAFETY DATA SHEET 3M? Rearview Mirror Adhesive, PN08752 11/03/14 _________________________________________________________________________________________________________ Page 1 of 2 Material Safety Data Sheet Copyright, 2014, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. PRODUCT NAME: 3M? Rearview Mirror Adhesive, PN08752 MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 11/03/14 Supercedes Date: 03/15/13 Document Group: 07-7693-0 ID Number(s): 60-4550-5186-6, 60-4550-6899-3 This product is a kit or a multipart product which consists of multiple, independently packaged components. An SDS for each of these components is included. Please do not separate the component SDSs from this cover page. The document numbers of the SDSs for components of this product are: 07-7690-6, 07-7689-8 Revision Changes: Section 16: Disclaimer (first paragraph) information was modified. Section 16: Disclaimer (second paragraph) information was modified. Kit: Component heading paragraph information was modified. Kit: ID Number(s) information was modified. Section 16: Web address information was modified. Section 1: Address information was modified. Copyright information was modified. Telephone header information was modified. Company Telephone information was modified. DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of MATERIAL SAFETY DATA SHEET 3M? Rearview Mirror Adhesive, PN08752 11/03/14 _________________________________________________________________________________________________________ Page 2 of 2 use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com 3M? Rearview Mirror Adhesive / Adhesive, P/N 08752; 3M? High Bond Rearview Mirror Adhesive / Adhesive, PN08749 11/03/14 __________________________________________________________________________________________ Page 1 of 11 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 07-7689-8 Version Number: 8.00 Issue Date: 11/03/14 Supercedes Date: 10/11/11 SECTION 1: Identification 1.1. Product identifier 3M? Rearview Mirror Adhesive / Adhesive, P/N 08752; 3M? High Bond Rearview Mirror Adhesive / Adhesive, PN08749 Product Identification Numbers LB-K000-1110-0 1.2. Recommended use and restrictions on use Recommended use Adhesive, Rear View Mirror Adhesive 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Acute Toxicity (dermal): Category 4. Serious Eye Damage/Irritation: Category 1. Skin Corrosion/Irritation: Category 1B. Skin Sensitizer: Category 1. Specific Target Organ Toxicity (repeated exposure): Category 1. Specific Target Organ Toxicity (repeated exposure): Category 2. 2.2. Label elements Signal word Danger Symbols 3M? Rearview Mirror Adhesive / Adhesive, P/N 08752; 3M? High Bond Rearview Mirror Adhesive / Adhesive, PN08749 11/03/14 __________________________________________________________________________________________ Page 2 of 11 Corrosion | Exclamation mark | Health Hazard | Pictograms Hazard Statements Harmful in contact with skin. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Causes damage to organs through prolonged or repeated exposure: nervous system | respiratory system | May cause damage to organs through prolonged or repeated exposure: skin | Precautionary Statements General: Keep out of reach of children. Prevention: Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves, protective clothing, and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified May cause chemical gastrointestinal burns. 21% of the mixture consists of ingredients of unknown acute dermal toxicity. 58% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients 3M? Rearview Mirror Adhesive / Adhesive, P/N 08752; 3M? High Bond Rearview Mirror Adhesive / Adhesive, PN08749 11/03/14 __________________________________________________________________________________________ Page 3 of 11 Ingredient C.A.S. No. % by Wt Aliphatic Urethane Acrylate Resin Trade Secret* 30 - 60 Trade Secret * Bisphenol A Polyethylene Glycol Diether Dimethacrylate 41637-38-1 10 - 30 Trade Secret * Hydroxypropyl Methacrylate 27813-02-1 7 - 20 Trade Secret * 1,6-Hexanediol Diacrylate 13048-33-4 7 - 15 Trade Secret * Isobornyl Acrylate 5888-33-5 7 - 13 Trade Secret * Acrylic Acid 79-10-7 1 - 10 Trade Secret * Polyester Resin Trade Secret* 5 - 10 Trade Secret * 3-(Trimethoxysilyl)Propyl Glycidyl Ether 2530-83-8 0.1 - 1 Trade Secret * Cumene Hydroperoxide 80-15-9 0.1 - 1 Trade Secret * Saccharin 81-07-2 0.1 - 1 Trade Secret * 1-Acetyl-2-Phenylhydrazine 114-83-0 0.1 - 1 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediate medical attention. Wash clothing before reuse. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Rinse mouth. Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. 3M? Rearview Mirror Adhesive / Adhesive, P/N 08752; 3M? High Bond Rearview Mirror Adhesive / Adhesive, PN08749 11/03/14 __________________________________________________________________________________________ Page 4 of 11 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store away from heat. Store away from acids. Store away from oxidizing agents. Store away from amines. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments 1,6-Hexanediol Diacrylate 13048-33-4 AIHA TWA:1 mg/m3(0.11 ppm) Dermal Sensitizer 3-(Trimethoxysilyl)Propyl Glycidyl Ether 2530-83-8 CMRG TWA:5 ppm Hydroxypropyl Methacrylate 27813-02-1 CMRG CEIL:3 ppm Acrylic Acid 79-10-7 Manufacturer determined STEL:5 ppm(15 mg/m3) Acrylic Acid 79-10-7 ACGIH TWA:2 ppm A4: Not class. as human carcin, Skin Notation Cumene Hydroperoxide 80-15-9 AIHA TWA:6 mg/m3(1 ppm) Skin Notation ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 3M? Rearview Mirror Adhesive / Adhesive, P/N 08752; 3M? High Bond Rearview Mirror Adhesive / Adhesive, PN08749 11/03/14 __________________________________________________________________________________________ Page 5 of 11 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron ? Butyl rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: Yellow Liquid, Sharp Odor Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point >=300 ?F [@ 760 mmHg] Flash Point >=200 ?F [Test Method: Tagliabue Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure >=5.0 mmHg [Details: CONDITIONS: @ 75 F.] Vapor Density Not Applicable Density 1.1 g/ml Specific Gravity 1.1 [Ref Std: WATER=1] Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available 3M? Rearview Mirror Adhesive / Adhesive, P/N 08752; 3M? High Bond Rearview Mirror Adhesive / Adhesive, PN08749 11/03/14 __________________________________________________________________________________________ Page 6 of 11 Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 1.08 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 21.1 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 232 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 21.1 % weight VOC Less H2O & Exempt Solvents 232 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Strong acids Strong oxidizing agents Amines 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. 3M? Rearview Mirror Adhesive / Adhesive, P/N 08752; 3M? High Bond Rearview Mirror Adhesive / Adhesive, PN08749 11/03/14 __________________________________________________________________________________________ Page 7 of 11 Skin Contact: Harmful in contact with skin. Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. May cause target organ effects after skin contact. Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Ingestion: Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen. Target Organ Effects: Prolonged or repeated exposure may cause: Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Dermal Effects: Signs/symptoms may include redness, itching, acne, or bumps on the skin. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE 1,000 - 2,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE > 50 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Bisphenol A Polyethylene Glycol Diether Dimethacrylate Ingestion Rat LD50 > 2,000 mg/kg 1,6-Hexanediol Diacrylate Dermal Rabbit LD50 3,636 mg/kg Hydroxypropyl Methacrylate Dermal Rabbit LD50 > 5,000 mg/kg 1,6-Hexanediol Diacrylate Ingestion Rat LD50 > 5,000 mg/kg Hydroxypropyl Methacrylate Ingestion Rat LD50 11,200 mg/kg Isobornyl Acrylate Dermal Rabbit LD50 > 5,000 mg/kg Isobornyl Acrylate Ingestion Rat LD50 4,350 mg/kg Acrylic Acid Dermal Rabbit LD50 295 mg/kg Acrylic Acid Inhalation- Dust/Mist (4 hours) Rat LC50 3.8 mg/l Acrylic Acid Ingestion Rat LD50 1,250 mg/kg 1-Acetyl-2-Phenylhydrazine Dermal LD50 estimated to be 200 - 1,000 mg/kg 1-Acetyl-2-Phenylhydrazine Ingestion Mouse LD50 270 mg/kg Saccharin Ingestion Mouse LD50 17,000 mg/kg 3-(Trimethoxysilyl)Propyl Glycidyl Ether Dermal Rabbit LD50 4,000 mg/kg 3-(Trimethoxysilyl)Propyl Glycidyl Ether Inhalation- Dust/Mist (4 hours) Rat LC50 > 5.3 mg/l 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion Rat LD50 7,010 mg/kg Cumene Hydroperoxide Dermal Rat LD50 500 mg/kg Cumene Hydroperoxide Inhalation- Rat LC50 1.4 mg/l 3M? Rearview Mirror Adhesive / Adhesive, P/N 08752; 3M? High Bond Rearview Mirror Adhesive / Adhesive, PN08749 11/03/14 __________________________________________________________________________________________ Page 8 of 11 Vapor (4 hours) Cumene Hydroperoxide Ingestion Rat LD50 382 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value 1,6-Hexanediol Diacrylate Rabbit Irritant Isobornyl Acrylate Rabbit Minimal irritation Acrylic Acid Rabbit Corrosive 3-(Trimethoxysilyl)Propyl Glycidyl Ether Rabbit Mild irritant Cumene Hydroperoxide Rabbit Corrosive Serious Eye Damage/Irritation Name Species Value 1,6-Hexanediol Diacrylate Rabbit Moderate irritant Isobornyl Acrylate Rabbit Mild irritant Acrylic Acid Rabbit Corrosive 3-(Trimethoxysilyl)Propyl Glycidyl Ether Rabbit Corrosive Cumene Hydroperoxide Rabbit Corrosive Skin Sensitization Name Species Value Bisphenol A Polyethylene Glycol Diether Dimethacrylate Guinea pig Not sensitizing 1,6-Hexanediol Diacrylate Guinea pig Sensitizing Isobornyl Acrylate Mouse Sensitizing Acrylic Acid Guinea pig Some positive data exist, but the data are not sufficient for classification 3-(Trimethoxysilyl)Propyl Glycidyl Ether Guinea pig Some positive data exist, but the data are not sufficient for classification Respiratory Sensitization Name Species Value Germ Cell Mutagenicity Name Route Value Bisphenol A Polyethylene Glycol Diether Dimethacrylate In Vitro Not mutagenic 1,6-Hexanediol Diacrylate In Vitro Some positive data exist, but the data are not sufficient for classification Isobornyl Acrylate In Vitro Some positive data exist, but the data are not sufficient for classification Acrylic Acid In vivo Not mutagenic Acrylic Acid In Vitro Some positive data exist, but the data are not sufficient for classification 3-(Trimethoxysilyl)Propyl Glycidyl Ether In vivo Not mutagenic 3-(Trimethoxysilyl)Propyl Glycidyl Ether In Vitro Some positive data exist, but the data are not sufficient for classification Cumene Hydroperoxide In vivo Not mutagenic Cumene Hydroperoxide In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value 1,6-Hexanediol Diacrylate Dermal Mouse Not carcinogenic Acrylic Acid Ingestion Rat Not carcinogenic Acrylic Acid Dermal Mouse Some positive data exist, but the data are not sufficient for classification 3-(Trimethoxysilyl)Propyl Glycidyl Ether Dermal Mouse Not carcinogenic Reproductive Toxicity 3M? Rearview Mirror Adhesive / Adhesive, P/N 08752; 3M? High Bond Rearview Mirror Adhesive / Adhesive, PN08749 11/03/14 __________________________________________________________________________________________ Page 9 of 11 Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration 1,6-Hexanediol Diacrylate Not Specified Not toxic to development Rat NOAEL 750 mg/kg/day during organogenesi s Acrylic Acid Ingestion Not toxic to female reproduction Rat NOAEL 460 mg/kg/day 2 generation Acrylic Acid Ingestion Not toxic to male reproduction Rat NOAEL 460 mg/kg/day 2 generation Acrylic Acid Inhalation Not toxic to development Rat NOAEL 1.1 mg/l during organogenesi s Acrylic Acid Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 53 mg/kg/day 2 generation 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion Not toxic to female reproduction Rat NOAEL 1,000 mg/kg/day 1 generation 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion Not toxic to male reproduction Rat NOAEL 1,000 mg/kg/day 1 generation 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 3,000 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 1,6-Hexanediol Diacrylate Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Isobornyl Acrylate Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification official classifica tion NOAEL Not available Acrylic Acid Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Cumene Hydroperoxide Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available occupational exposure Cumene Hydroperoxide Inhalation respiratory irritation May cause respiratory irritation Human NOAEL Not available occupational exposure Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 1,6-Hexanediol Diacrylate Dermal skin May cause damage to organs though prolonged or repeated exposure Mouse LOAEL 70 mg/kg/day 80 weeks 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion heart | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | liver | immune system | nervous system | kidney and/or bladder | respiratory system All data are negative Rat NOAEL 1,000 mg/kg/day 28 days Cumene Hydroperoxide Inhalation nervous system | respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.2 mg/l 7 days Cumene Hydroperoxide Inhalation heart | liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for Rat NOAEL 0.03 mg/l 90 days 3M? Rearview Mirror Adhesive / Adhesive, P/N 08752; 3M? High Bond Rearview Mirror Adhesive / Adhesive, PN08749 11/03/14 __________________________________________________________________________________________ Page 10 of 11 classification Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Acrylic Acid 79-10-7 1 - 10 Cumene Hydroperoxide 80-15-9 0.1 - 1 Saccharin 81-07-2 0.1 - 1 3M? Rearview Mirror Adhesive / Adhesive, P/N 08752; 3M? High Bond Rearview Mirror Adhesive / Adhesive, PN08749 11/03/14 __________________________________________________________________________________________ Page 11 of 11 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 3 Flammability: 2 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 07-7689-8 Version Number: 8.00 Issue Date: 11/03/14 Supercedes Date: 10/11/11 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com MATERIAL SAFETY DATA SHEET 3M? Rearview Mirror Adhesive (Primer), PN08752; 3M? High Bond Rearview Mirror Adhesive (Primer), PN08749 06/11/12 _________________________________________________________________________________________________ Page 1 of 8 Material Safety Data Sheet Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M? Rearview Mirror Adhesive (Primer), PN08752; 3M? High Bond Rearview Mirror Adhesive (Primer), PN08749 MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 06/11/12 Supercedes Date: 04/14/10 Document Group: 07-7690-6 Product Use: Intended Use: Adhesive Specific Use: Rear View Mirror Adhesive - Primer SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt ISOPROPYL ALCOHOL 67-63-0 60 - 100 STODDARD SOLVENT 8052-41-3 1 - 5 ORGANO COPPER COMPOUND 22221-10-9 <= 1 Neodecanoic acid, copper(2+) salt 68084-48-0 <= 1 Carboxylic acids, C3-10, copper(1+) salts, oxidized 85737-14-0 <= 1 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: Clear Liquid, Mild Organic Odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause target organ effects. MATERIAL SAFETY DATA SHEET 3M? Rearview Mirror Adhesive (Primer), PN08752; 3M? High Bond Rearview Mirror Adhesive (Primer), PN08749 06/11/12 _________________________________________________________________________________________________ Page 2 of 8 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point 53.0 ?F [Test Method: Tagliabue Closed Cup] Flammable Limits(LEL) 2.0 % Flammable Limits(UEL) 12.0 % OSHA Flammability Classification: Class IB Flammable Liquid 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS MATERIAL SAFETY DATA SHEET 3M? Rearview Mirror Adhesive (Primer), PN08752; 3M? High Bond Rearview Mirror Adhesive (Primer), PN08749 06/11/12 _________________________________________________________________________________________________ Page 3 of 8 Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures WARNING ! A motor could be an ignition source and cause flammable gases or vapors or dust in the spill area to burn or explode. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with detergent and water. Seal the container. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. No smoking while handling this material. Avoid breathing of vapors, mists or spray. Avoid prolonged or repeated skin contact. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Avoid contact with oxidizing agents. 7.2 STORAGE Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION MATERIAL SAFETY DATA SHEET 3M? Rearview Mirror Adhesive (Primer), PN08752; 3M? High Bond Rearview Mirror Adhesive (Primer), PN08749 06/11/12 _________________________________________________________________________________________________ Page 4 of 8 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers. If exhaust ventilation is not available, use appropriate respiratory protection. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber Neoprene . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors . Select and use respiratory protection to prevent an inhalation exposure based on the results of an exposure assessment. Consult with your respirator manufacturer for selection of appropriate types of respirators. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information ISOPROPYL ALCOHOL ACGIH TWA 200 ppm ISOPROPYL ALCOHOL ACGIH STEL 400 ppm ISOPROPYL ALCOHOL OSHA TWA 980 mg/m3 STODDARD SOLVENT ACGIH TWA 100 ppm STODDARD SOLVENT OSHA TWA 2900 mg/m3 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES MATERIAL SAFETY DATA SHEET 3M? Rearview Mirror Adhesive (Primer), PN08752; 3M? High Bond Rearview Mirror Adhesive (Primer), PN08749 06/11/12 _________________________________________________________________________________________________ Page 5 of 8 Odor, Color, Grade: Clear Liquid, Mild Organic Odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point 53.0 ?F [Test Method: Tagliabue Closed Cup] Flammable Limits(LEL) 2.0 % Flammable Limits(UEL) 12.0 % Boiling Point 180 ?F Density 0.79 g/ml Vapor Pressure 32.0 mmHg [Details: CONDITIONS: @ 68 F.] Specific Gravity 0.79 [Ref Std: WATER=1] pH Not Applicable Melting point Not Applicable Solubility In Water 95 - 100 % Solubility in Water Moderate Evaporation rate 7.7 Hazardous Air Pollutants 0 % weight [Test Method: Calculated] Volatile Organic Compounds 6.59 lb/gal [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 783 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 99.1 % weight [Test Method: calculated per CARB title 2] Kow - Oct/Water partition coef No Data Available Percent volatile 98.51 % VOC Less H2O & Exempt Solvents 783 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity 3 centipoise SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid None known 10.2 Materials to avoid Strong acids Strong oxidizing agents Amines Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified SECTION 11: TOXICOLOGICAL INFORMATION MATERIAL SAFETY DATA SHEET 3M? Rearview Mirror Adhesive (Primer), PN08752; 3M? High Bond Rearview Mirror Adhesive (Primer), PN08749 06/11/12 _________________________________________________________________________________________________ Page 6 of 8 Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION LB-K000-1119-0 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed Hazard - Yes STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. MATERIAL SAFETY DATA SHEET 3M? Rearview Mirror Adhesive (Primer), PN08752; 3M? High Bond Rearview Mirror Adhesive (Primer), PN08749 06/11/12 _________________________________________________________________________________________________ Page 7 of 8 This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 3 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product use information was modified. Section 16: Disclaimer (second paragraph) was modified. Section 3: Potential effects from skin contact information was modified. Section 10: Hazardous decomposition or by-products table was modified. Section 8: Respiratory protection - recommended respirators information was modified. Section 14: Transportation legal text was modified. Section 15: Inventories information was modified. Section 9: Density information was modified. Section 9: Vapor pressure value was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable limits (LEL) information was modified. Section 5: Autoignition temperature information was modified. Section 5: Flash point information was modified. Section 9: Property description for optional properties was modified. Section 9: Specific gravity information was modified. Section 9: pH information was modified. Section 9: Melting point information was modified. Section 9: Solubility in water value was modified. Section 9: Solubility in water text was modified. Section 8: Respiratory protection - recommended respirators guide was modified. Section 9: Flash point information was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 9: Autoignition temperature information was modified. Section 2: Ingredient table was modified. Section 8: Exposure guidelines ingredient information was modified. Section 6: Personal precautions information was modified. Section 6: Environmental procedures information was modified. Section 6: Methods for cleaning up information was modified. Section 6: 6.2. Environmental precautions heading was added. Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was added. Section 16: Web address was added. Section 1: Address was added. Copyright was added. Company logo was added. Section 6: Clean-up methods heading was added. Telephone header was added. Company Telephone was added. Section 1: Emergency phone information was added. MATERIAL SAFETY DATA SHEET 3M? Rearview Mirror Adhesive (Primer), PN08752; 3M? High Bond Rearview Mirror Adhesive (Primer), PN08749 06/11/12 _________________________________________________________________________________________________ Page 8 of 8 Section 1: Emergency phone information was deleted. Company Logo was deleted. Copyright was deleted. Section 6: Release measures heading was deleted. Section 1: Address line 1 was deleted. Section 1: Address line 2 was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M 3M USA MSDSs are available at www.3M.com