Quantum FS MV ATF (CA) Bulk Not available. Liquid. 24 hr. CHEMTREC 1-800-424-9300 / International 1-703-527-3887 SAFETY DATA SHEET GHS product identifier Other means of identification Product type Emergency telephone number (with hours of operation) Section 1. Identification : : : : Supplier's details : Calumet Packaging 10411 Highway 1 Shreveport, LA 71115 USA 318-795-3800 Quantum FS MV ATF (CA) Bulk Relevant identified uses of the substance or mixture and uses advised against Identified uses Not available. Uses advised against Reason Industrial applications: Lubricating Oil Product code : 7921500 Section 2. Hazards identification AQUATIC HAZARD (ACUTE) - Category 2Classification of the substance or mixture : Signal word : No signal word. Hazard statements : Toxic to aquatic life. Precautionary statements Prevention : Avoid release to the environment. Response : Not applicable. Storage : Not applicable. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 1.1% OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Hazards not otherwise classified : None known. Date of issue/Date of revision : 06/03/2015 Version : 1 1/10 Quantum FS MV ATF (CA) Bulk Section 3. Composition/information on ingredients Distillates (petroleum), hydrotreated light paraffinic ?5 - <10 64742-55-8 Alkyl Phosphites ?1 - <2 Trade Secret Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification : Not available. CAS number : Not applicable. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Eye contact : No specific data. Potential acute health effects Date of issue/Date of revision : 06/03/2015 Version : 1 2/10 Quantum FS MV ATF (CA) Bulk Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides phosphorus oxides In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic to aquatic life. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. For non-emergency personnel For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision : 06/03/2015 Version : 1 3/10 Quantum FS MV ATF (CA) Bulk Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Distillates (petroleum), hydrotreated light paraffinic ACGIH TLV (United States, 4/2014). TWA: 5 mg/m? 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2013). TWA: 5 mg/m? 10 hours. Form: Mist STEL: 10 mg/m? 15 minutes. Form: Mist OSHA PEL (United States, 2/2013). TWA: 5 mg/m? 8 hours. Alkyl Phosphites ACGIH TLV (United States). TWA: 5 mg/m?, (Mist) STEL: 10 mg/m?, (Mist) Section 8. Exposure controls/personal protection Ingredient name Exposure limits Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Control parameters Occupational exposure limits Date of issue/Date of revision : 06/03/2015 Version : 1 4/10 Quantum FS MV ATF (CA) Bulk Section 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Vapor density Liquid. Not available. Not available. Not available. Not available.Odor pH Clear. Red.Color Evaporation rate Not available. Flash point Open cup: 224?C (435.2?F) [Cleveland.] Not available. Not available.Odor threshold : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Date of issue/Date of revision : 06/03/2015 Version : 1 5/10 Quantum FS MV ATF (CA) Bulk Section 9. Physical and chemical properties Relative density Solubility 0.8471 Insoluble in the following materials: cold water and hot water. Auto-ignition temperature Not available. Not available. Viscosity Kinematic (40?C (104?F)): 0.2935 cm2/s (29.35 cSt) Partition coefficient: n- octanol/water : : : : : Decomposition temperature : Not available. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Distillates (petroleum), hydrotreated light paraffinic LC50 Inhalation Dusts and mists Rat >5.53 mg/l 4 hours LD50 Dermal Rabbit >2000 mg/kg - LD50 Oral Rat >5000 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion Not available. Sensitization Not available. Specific target organ toxicity (single exposure) Information on toxicological effects Date of issue/Date of revision : 06/03/2015 Version : 1 6/10 Quantum FS MV ATF (CA) Bulk Section 11. Toxicological information Not available. Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact No known significant effects or critical hazards.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (repeated exposure) Not available. Not available. Numerical measures of toxicity Not available. Acute toxicity estimates Aspiration hazard Name Result Distillates (petroleum), hydrotreated light paraffinic ASPIRATION HAZARD - Category 1 : Not available. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Date of issue/Date of revision : 06/03/2015 Version : 1 7/10 Quantum FS MV ATF (CA) Bulk Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Distillates (petroleum), hydrotreated light paraffinic >6 - high Product/ingredient name Aquatic half-life Photolysis Biodegradability Distillates (petroleum), hydrotreated light paraffinic - - Inherent Alkyl Phosphites - - Not readily Toxicity Distillates (petroleum), hydrotreated light paraffinic Acute EC50 >100 mg/l Algae 72 hours Acute EC50 >100 mg/l Daphnia 48 hours Acute LC50 >100 mg/l Fish 96 hours Alkyl Phosphites Acute EC50 0.09 mg/l Daphnia 48 hours Acute LC50 1.5 mg/l Fresh water Fish 96 hours Acute NOEC 0.13 mg/l Algae 72 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods RCRA classification : Not Regulated Section 14. Transport information Not regulated.Not regulated. Not regulated. DOT Classification IMDG IATA UN number TDG Classification Not regulated. Date of issue/Date of revision : 06/03/2015 Version : 1 8/10 Quantum FS MV ATF (CA) Bulk Section 14. Transport information Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : Section 15. Regulatory information U.S. Federal regulations The following components are listed: MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED LIGHT PARAFFINIC This product is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. Clean Water Act (CWA) 307: ethylbenzene Clean Water Act (CWA) 311: xylene; ethylbenzene Massachusetts : : California Prop. 65 Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed New York : None of the components are listed. New Jersey : The following components are listed: MINERAL OIL (UNTREATED and MILDLY TREATED); MINERAL OIL (UNTREATED and MILDLY TREATED) Pennsylvania : None of the components are listed. State regulations TSCA 8(a) CDR Exempt/Partial exemption: Not determined All components are listed or exempted. SARA 302/304 SARA 304 RQ : 19841269.8 lbs / 9007936.5 kg [2809166.7 gal / 10633852.6 L] sulphur dioxide <0.1 Yes. 500 - 500 - Composition/information on ingredients Name % EHS (lbs) (lbs)(gallons) (gallons) SARA 302 TPQ SARA 304 RQ SARA 311/312 Classification : Not applicable. No products were found. Composition/information on ingredients International lists National inventory Date of issue/Date of revision : 06/03/2015 Version : 1 9/10 Quantum FS MV ATF (CA) Bulk Section 15. Regulatory information Australia : All components are listed or exempted. Canada : All components are listed or exempted. China : All components are listed or exempted. Europe : At least one component is not listed in EINECS but all such components are listed in ELINCS. Please contact your supplier for information on the inventory status of this material. Japan : Not determined. Republic of Korea : All components are listed or exempted. Malaysia : Not determined. New Zealand : All components are listed or exempted. Philippines : All components are listed or exempted. Taiwan : Not determined. Section 16. Other information History Date of issue/Date of revision Version To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Notice to reader : : Indicates information that has changed from previously issued version. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 06/03/2015 1 Procedure used to derive the classification Classification Justification Aquatic Acute 2, H401 Calculation method Date of issue/Date of revision : 06/03/2015 Version : 1 10/10