1. IDENTIFICATION Product identifier Product Name PROFESSIONAL WINDSHIELD REPAIR KIT Other means of identification Product Code 09103 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Windshield Repair Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Skin sensitization Category 1 Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 8 Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 28-Apr-2015 Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction SAFETY DATA SHEET Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Warning _____________________________________________________________________________________________ Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Harmful to aquatic life with long lasting effects. Unknown acute toxicity 47% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret 2-HYDROXYETHYL METHACRYLATE 868-77-9 30 - 60 * URETHANE METHACYRLATE _ 10 - 30 * 2,2 -(ETHYLENEDIOXY)DIETHYL DIACRYLATE 1680-21-3 1 - 5 * ACRYLIC ACID 79-10-7 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash with soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. _____________________________________________________________________________________________ Page 2 / 8 09103 - PROFESSIONAL WINDSHIELD REPAIR KIT Revision Date 28-Apr-2015 Odor MildAppearance Clear Physical state Liquid _____________________________________________________________________________________________ Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling _____________________________________________________________________________________________ Page 3 / 8 09103 - PROFESSIONAL WINDSHIELD REPAIR KIT Revision Date 28-Apr-2015 _____________________________________________________________________________________________ Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ACRYLIC ACID 79-10-7 TWA: 2 ppm S* (vacated) TWA: 10 ppm (vacated) TWA: 30 mg/m3 (vacated) S* TWA: 2 ppm TWA: 6 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Clear Odor Mild Odor threshold No information available _____________________________________________________________________________________________ Page 4 / 8 Flash point 97 ?C / 207 ?F 09103 - PROFESSIONAL WINDSHIELD REPAIR KIT pH 6 Evaporation rate No information available Revision Date 28-Apr-2015 Flammability (solid, gas) No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available Boiling point / boiling range 205 ?C / 401 ?F Remarks ? Method _____________________________________________________________________________________________ Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) <1% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. May cause sensitization by skin contact. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 2-HYDROXYETHYL METHACRYLATE 868-77-9 = 5050 mg/kg ( Rat ) > 3000 mg/kg ( Rabbit ) - 2,2 -(ETHYLENEDIOXY)DIETHYL DIACRYLATE 1680-21-3 = 500 mg/kg ( Rat ) = 1900 mg/kg ( Rabbit ) - ACRYLIC ACID 79-10-7 = 193 mg/kg ( Rat ) = 33500 ?g/kg ( Rat ) = 280 ?L/kg ( Rabbit ) = 295 mg/kg ( Rabbit ) = 11.1 mg/L ( Rat ) 1 h = 3.6 mg/L ( Rat ) 4 h _____________________________________________________________________________________________ Page 5 / 8 Vapor density No information available Partition coefficient No information available 09103 - PROFESSIONAL WINDSHIELD REPAIR KIT Autoignition temperature No information available Vapor pressure Decomposition temperature No information available No data available Relative density 1.03 Kinematic viscosity No information available 0.1 hPa @ 20?C (68?F) Dynamic viscosity 100 mPas @ 20?C (68?F) Revision Date 28-Apr-2015 Water solubility Immiscible in water Solubility in other solvents No information available _____________________________________________________________________________________________ Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA ACRYLIC ACID 79-10-7 - Group 3 - - IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen Target Organ Effects Eyes, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 2864 mg/kg ATEmix (dermal) 2772 mg/kg ATEmix (inhalation-dust/mist) 39.8 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 50% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea 2-HYDROXYETHYL METHACRYLATE 868-77-9 - 213 - 242: 96 h Pimephales promelas mg/L LC50 flow-through 227: 96 h Pimephales promelas mg/L LC50 - ACRYLIC ACID 79-10-7 0.17: 96 h Pseudokirchneriella subcapitata mg/L EC50 0.04: 72 h Desmodesmus subspicatus mg/L EC50 222: 96 h Brachydanio rerio mg/L LC50 semi-static 95: 48 h Daphnia magna mg/L EC50 270: 24 h Daphnia magna mg/L LC50 Static Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient 2-HYDROXYETHYL METHACRYLATE 868-77-9 0.47 ACRYLIC ACID 79-10-7 0.38 - 0.46 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. _____________________________________________________________________________________________ Page 6 / 8 Revision Date 28-Apr-201509103 - PROFESSIONAL WINDSHIELD REPAIR KIT _____________________________________________________________________________________________ US EPA Waste Number Not applicable Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes ACRYLIC ACID 79-10-7 - - - U008 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Not Listed. PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % ACRYLIC ACID - 79-10-7 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) _____________________________________________________________________________________________ Page 7 / 8 Revision Date 28-Apr-201509103 - PROFESSIONAL WINDSHIELD REPAIR KIT _____________________________________________________________________________________________ CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACRYLIC ACID 79-10-7 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania ACRYLIC ACID 79-10-7 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 28-Apr-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 8 / 8 Revision Date 28-Apr-2015 - HMIS NFPA Health hazards 2 Flammability 1 Physical hazards 0 Personal protection B Health hazards 2 09103 - PROFESSIONAL WINDSHIELD REPAIR KIT Flammability 1 Instability 0