1. IDENTIFICATION Product identifier Product Name 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Other means of identification Product Code 81464 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Aerosol Lubricant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Aspiration toxicity Category 1 Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 10 Danger Flammable aerosols SAFETY DATA SHEET Causes skin irritation Causes serious eye irritation May cause drowsiness or dizziness May be fatal if swallowed and enters airways Category 1 Version 1 Extremely flammable aerosol Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 28-May-2015 _____________________________________________________________________________________________ Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Precautionary Statements - Storage Store locked up Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Toxic to aquatic life with long lasting effects. The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346. This note applies only to certain complex oil derived substances in Annex I. Unknown acute toxicity 17.5 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret ACETONE 67-64-1 10 - 30 * HEPTANE 142-82-5 10 - 30 * DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC 64742-52-5 10 - 30 * CALCIUM OXIDE 1305-78-8 7 - 13 * ALUMINIUM POWDER 7429-90-5 5 - 10 * _____________________________________________________________________________________________ Page 2 / 10 Revision Date 28-May-201581464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Odor SolventAppearance Gray Physical state Liquid Aerosol _____________________________________________________________________________________________ GRAPHITE 7782-42-5 3 - 7 * CARBON DIOXIDE 124-38-9 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Call a physician or poison control center immediately. Do NOT induce vomiting. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire. Specific hazards arising from the chemical Extremely flammable. Keep product and empty container away from heat and sources of ignition. Vapors may travel to source of ignition and flash back. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Contents under pressure. Do not puncture or incinerate cans. Environmental precautions _____________________________________________________________________________________________ Page 3 / 10 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Revision Date 28-May-2015 _____________________________________________________________________________________________ Environmental precautions See Section 12 for additional ecological information. Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Take precautionary measures against static discharges. Do not puncture or incinerate cans. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ACETONE 67-64-1 STEL: 750 ppm TWA: 500 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 HEPTANE 142-82-5 STEL: 500 ppm TWA: 400 ppm TWA: 500 ppm TWA: 2000 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 1600 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 2000 mg/m3 IDLH: 750 ppm Ceiling: 440 ppm 15 min Ceiling: 1800 mg/m3 15 min TWA: 85 ppm TWA: 350 mg/m3 CALCIUM OXIDE 1305-78-8 TWA: 2 mg/m3 TWA: 5 mg/m3 (vacated) TWA: 5 mg/m3 not in effect as a result of reconsideration IDLH: 25 mg/m3 TWA: 2 mg/m3 ALUMINIUM POWDER 7429-90-5 TWA: 1 mg/m3 respirable fraction TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 5 mg/m3 Al Aluminum TWA: 5 mg/m3 Al _____________________________________________________________________________________________ Page 4 / 10 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Revision Date 28-May-2015 _____________________________________________________________________________________________ GRAPHITE 7782-42-5 TWA: 2 mg/m3 respirable fraction all forms except graphite fibers TWA: 15 mg/m3 total dust synthetic TWA: 5 mg/m3 respirable fraction synthetic (vacated) TWA: 2.5 mg/m3 respirable dust natural (vacated) TWA: 10 mg/m3 total dust synthetic (vacated) TWA: 5 mg/m3 respirable fraction synthetic TWA: 15 mppcf natural IDLH: 1250 mg/m3 TWA: 2.5 mg/m3 natural respirable dust CARBON DIOXIDE 124-38-9 STEL: 30000 ppm TWA: 5000 ppm TWA: 5000 ppm TWA: 9000 mg/m3 (vacated) TWA: 10000 ppm (vacated) TWA: 18000 mg/m3 (vacated) STEL: 30000 ppm (vacated) STEL: 54000 mg/m3 IDLH: 40000 ppm TWA: 5000 ppm TWA: 9000 mg/m3 STEL: 30000 ppm STEL: 54000 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid; Aerosol Appearance Gray Odor Solvent Odor threshold No information available _____________________________________________________________________________________________ Page 5 / 10 Flammability (solid, gas) No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available Vapor pressure No information available Boiling point / boiling range No information available Vapor density >1 Remarks ? Method Air = 1 Relative density 0.885-0.905 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Flash point Water solubility Insoluble in water < -18 ?C / < 0 ?F Gives a flame projection at full valve opening or flashback at any degree of valve opening pH No information available Evaporation rate No information available Revision Date 28-May-2015 _____________________________________________________________________________________________ Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 24.5% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Copper compounds 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. May cause drowsiness or dizziness. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ACETONE 67-64-1 = 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h HEPTANE 142-82-5 - = 3000 mg/kg ( Rabbit ) = 103 g/m3 ( Rat ) 4 h CALCIUM OXIDE 1305-78-8 = 500 mg/kg ( Rat ) - - Information on toxicological effects Symptoms No information available. _____________________________________________________________________________________________ Page 6 / 10 Partition coefficient No information available Dynamic viscosity No information available 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ No data available Solubility in other solvents Autoignition temperature No information available No information available Revision Date 28-May-2015 Decomposition temperature No information available Kinematic viscosity No information available _____________________________________________________________________________________________ Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC 64742-52-5 A2 Group 1 - X ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target Organ Effects Central nervous system, Central Vascular System (CVS), Eyes, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 3394 mg/kg ATEmix (dermal) 12375 mg/kg ATEmix (inhalation-dust/mist) 186 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/aquatic plants Fish Crustacea ACETONE 67-64-1 - 4.74 - 6.33: 96 h Oncorhynchus mykiss mL/L LC50 6210 - 8120: 96 h Pimephales promelas mg/L LC50 static 8300: 96 h Lepomis macrochirus mg/L LC50 10294 - 17704: 48 h Daphnia magna mg/L EC50 Static 12600 - 12700: 48 h Daphnia magna mg/L EC50 HEPTANE 142-82-5 - 375.0: 96 h Cichlid fish mg/L LC50 10: 24 h Daphnia magna mg/L EC50 DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC 64742-52-5 - 5000: 96 h Oncorhynchus mykiss mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 CALCIUM OXIDE 1305-78-8 - 1070: 96 h Cyprinus carpio mg/L LC50 static - Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient ACETONE 67-64-1 -0.24 HEPTANE 142-82-5 4.66 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS _____________________________________________________________________________________________ Page 7 / 10 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Revision Date 28-May-2015 _____________________________________________________________________________________________ Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U SeriesWastes ACETONE 67-64-1 - Included in waste stream: F039 - U002 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ACETONE 67-64-1 Ignitable HEPTANE 142-82-5 Toxic Ignitable CALCIUM OXIDE 1305-78-8 Corrosive ALUMINIUM POWDER 7429-90-5 Ignitable powder 14. TRANSPORT INFORMATION DOT UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 Emergency Response Guide Number 126 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 EmS-No F-D, S-U 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Not Listed. Contains: Natural substance(s) IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory _____________________________________________________________________________________________ Page 8 / 10 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Revision Date 28-May-2015 _____________________________________________________________________________________________ DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % ALUMINIUM POWDER - 7429-90-5 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania ACETONE 67-64-1 X X X HEPTANE 142-82-5 X X X CALCIUM OXIDE 1305-78-8 X X X ALUMINIUM POWDER 7429-90-5 X X X GRAPHITE 7782-42-5 X X X CARBON DIOXIDE 124-38-9 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) _____________________________________________________________________________________________ Page 9 / 10 Flammability 4 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Physical hazards 0 Personal protection B Health hazards 2 Flammability 4 Revision Date 28-May-2015 Instability 0 - HMIS NFPA Health hazards 2 _____________________________________________________________________________________________ Revision Date 28-May-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 10 / 10 81464 - 133MA ANTI-SEIZE LUBRICANT 8.5 OZ Revision Date 28-May-2015